CN113652133A - 一种两亲性印刷用涂层及其制备方法和应用 - Google Patents

一种两亲性印刷用涂层及其制备方法和应用 Download PDF

Info

Publication number
CN113652133A
CN113652133A CN202110796802.8A CN202110796802A CN113652133A CN 113652133 A CN113652133 A CN 113652133A CN 202110796802 A CN202110796802 A CN 202110796802A CN 113652133 A CN113652133 A CN 113652133A
Authority
CN
China
Prior art keywords
amphiphilic
printing coating
aqueous
printing
emulsion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202110796802.8A
Other languages
English (en)
Inventor
陈诚
王君
王卫华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hubei Agile Zhicheng Logo Technology Co ltd
Original Assignee
Hubei Agile Zhicheng Logo Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hubei Agile Zhicheng Logo Technology Co ltd filed Critical Hubei Agile Zhicheng Logo Technology Co ltd
Priority to CN202110796802.8A priority Critical patent/CN113652133A/zh
Publication of CN113652133A publication Critical patent/CN113652133A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/10—Homopolymers or copolymers of methacrylic acid esters
    • C09D133/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/0427—Coating with only one layer of a composition containing a polymer binder
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/002—Priming paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2333/10—Homopolymers or copolymers of methacrylic acid esters
    • C08J2333/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2433/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2433/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2433/10—Homopolymers or copolymers of methacrylic acid esters
    • C08J2433/12—Homopolymers or copolymers of methyl methacrylate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Paints Or Removers (AREA)

Abstract

本发明提出了一种两亲性印刷用涂层及其制备方法和应用，所述涂层按照重量份数计算，包括水性树脂乳液15‑20份、聚丙烯酸水溶液15‑20份、水性蜡乳液3‑5份、水性流平剂1‑3份、水性润湿剂1‑3份和水性消泡剂0.5‑1.5份，通过混合搅拌调节固含量至30％可以得到本发明的两亲性印刷用涂层，本发明的两亲性印刷用涂层可以应用于PMMA面板的表面印刷中，改善了PMMA面板的水性印刷效果差的问题，具有良好的应用前景。

Description

一种两亲性印刷用涂层及其制备方法和应用
技术领域
本发明涉及印刷技术领域，尤其涉及一种两亲性印刷用涂层及其制备方法和应用。
背景技术
随着对环境保护的要求日益严格，原为包装印刷邻域服务的凹版印刷，使用含有大量有机溶剂的油性油墨，在印刷生产过程中排放污染大气的有机溶剂，为了适应环保的要求，水性印刷技术应运而生，水性印刷采用含有少量有机溶剂甚至不含有机溶剂的水性油墨，对环境的污染较少，但是水性油墨对于高分子有机材料制成的承印材料而言，亲和性较低，因此印刷的效果差，印刷涂层在承印材料上的结合力较低，不耐摩擦。
为了改善水性印刷材料在高分子有机面板上的结合力，需要对高分子有机面板的表面进行底涂处理，利用具有两亲性的底涂层改善水性油墨的亲和力和结合力。
发明内容
有鉴于此，本发明提出了一种两亲性的印刷用涂层及其制备方法和应用。
本发明的技术方案是这样实现的：本发明提供了一种两亲性印刷用涂层，按质量分数计算，包括：
Figure BDA0003163079280000011
Figure BDA0003163079280000021
在以上技术方案的基础上，优选的，所述水性树脂乳液为聚甲基丙烯酸甲酯乳液。
在以上技术方案的基础上，优选的，所述聚甲基丙烯酸甲酯乳液的固含量为25-35％。
在以上技术方案的基础上，优选的，所述聚甲基丙烯酸甲酯乳液中聚甲基丙烯酸甲酯的数均分子量为2000-3000。
更进一步优选的，所述聚甲基丙烯酸甲酯乳液中聚甲基丙烯酸甲酯的数均分子量为2000-3000。
在以上技术方案的基础上，优选的，所述水性蜡乳液为氧化聚乙烯蜡乳液，所述氧化聚乙烯蜡乳液的固含量为25-35％。
在以上技术方案的基础上，优选的，所述水性润湿剂为聚丙二醇二乙酸盐和聚丙二醇二硫酸盐中的一种或两种的混合物。
在以上技术方案的基础上，优选的，所述水性流平剂为聚醚改性聚二甲基硅氧烷，所述水性消泡剂为有机硅消泡剂。
本发明还提供一种两亲性印刷用涂层的制备方法，其特征在于，包括如下步骤：
按照重量份数分别称取水性树脂乳液、聚丙烯酸水溶液、水性蜡乳液、水性流平剂、水性润湿剂和水性消泡剂，混合均匀后加入去离子水，调节至固含量为30％，得到两亲性印刷用涂层。
本发明的两亲性印刷用涂层可以应用在PMMA面板的表面印刷中。
本发明的两亲性印刷用涂层及其制备方法和应用相对于现有技术具有以下有益效果：
(1)本发明提供了一种两亲性的印刷用涂层材料的技术方案，采用本发明的技术方案可以克服常规印刷用涂层材料无法同时满足与有机聚合物底层面板材料以及水性印刷涂料之间均具有较好亲和力要求的问题，同时本发明的涂层材料在PMMA材质的底层面板上具有良好的亲和力和附着力，同时本发明的涂层材料具有良好的基础力学性能，采用水性的树脂、丙烯酸和蜡乳液，使本发明的材料自身具有良好的双亲性和机械性能，同时采用Bola型润湿剂，改善了其与水性打印涂料之间的结合力，同时不影响本发明的印刷涂层与高分子聚合物底板之间的结合力；
(2)本发明还公开了对应的印刷用涂层的制备方法，整体方法简单，采用本发明的制备方法制备得到的印刷用涂层可以直接应用于PMMA底板的表面印刷底涂处理，克服了PMMA底板表面水性印刷效果差的问题。
具体实施方式
下面将结合本发明实施方式，对本发明实施方式中的技术方案进行清楚、完整地描述，显然，所描述的实施方式仅仅是本发明一部分实施方式，而不是全部的实施方式。基于本发明中的实施方式，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施方式，都属于本发明保护的范围。
实施例1
按照重量份数，分别称取固含量为25％的聚甲基丙烯酸甲酯乳液15kg，其中聚甲基丙烯酸甲酯的数均分子量为2000、固含量为45％的丙烯酸水溶液15kg、固含量为25％的氧化聚乙烯蜡乳液3kg、1kg购买自青田新材料的聚醚改性聚二甲基硅氧烷DH-4033、1kg聚丙二醇二乙酸钠和0.5kg陶氏AFE 1410有机硅消泡剂，混合后加入2kg去离子水，混合搅拌均匀后，得到固含量为30％的两亲性印刷用涂层。
实施例2
按照重量份数，分别称取固含量为30％的聚甲基丙烯酸甲酯乳液18kg，其中聚甲基丙烯酸甲酯的数均分子量为2500、固含量为50％的丙烯酸水溶液18kg、固含量为30％的氧化聚乙烯蜡乳液4kg、2kg购买自青田新材料的聚醚改性聚二甲基硅氧烷DH-4033、2kg聚丙二醇二硫酸钠和1kg陶氏AFE 1410有机硅消泡剂，混合后加入7kg去离子水，混合搅拌均匀后，得到固含量为30％的两亲性印刷用涂层。
实施例3
按照重量份数，分别称取固含量为35％的聚甲基丙烯酸甲酯乳液20kg，其中聚甲基丙烯酸甲酯的数均分子量为3000、固含量为55％的丙烯酸水溶液20kg、固含量为35％的氧化聚乙烯蜡乳液5kg、3kg购买自青田新材料的聚醚改性聚二甲基硅氧烷DH-4033、3kg聚丙二醇二硫酸钠和1.5kg陶氏AFE 1410有机硅消泡剂，混合后加入13.3kg去离子水，混合搅拌均匀后，得到固含量为30％的两亲性印刷用涂层。
对比例1
本对比例所用原料和制备方法与实施例2相同，区别在于，采用十二烷基硫酸钠代替聚丙二醇二硫酸钠。(改善附着力)
对比例2
本对比例所用原料和制备方法与实施例2相同，区别在于，采用聚乙烯蜡乳液代替氧化聚乙烯蜡乳液。(改善附着力、光泽度、摩擦力、硬度)
对比例3
本对比例所用原料和制备方法与实施例2相同，区别在于，采用聚醚型水性聚氨酯树脂代替数均分子量为2500的聚甲基丙烯酸甲酯。(改善附着力)
将上述实施例1-3以及对比例1-3制备得到的两亲性印刷用涂层涂敷在PMMA材质的面板上，待涂层固化后，进行一系列的性能测试，测试项目包括常温下的涂层表面的粘度、涂层与面板之间的附着力，涂层表面的光泽度，涂层的硬度，涂层在沸水中的稳定效果，测试结果如下：
Figure BDA0003163079280000051
以上数据可以看出，采用本发明的两亲性印刷用涂层可以在PMMA材料的面板的表面形成良好的涂层结构，涂层的附着力较强，同时涂层的机械性能较强，外观平滑有光泽。
分别在上述实施例和对比例的涂层表面进行水性喷涂印刷，印刷完毕后，在500g压力下擦拭喷涂印刷的位置100次，观察喷涂印刷的位置是否有明显的掉色，结果如下：
分组 实施例1 实施例2 实施例3 对比例1 对比例2 对比例3
是否掉色 无 无 无 有掉色 无 无
以上结果可以看出，本发明采用了特定的润湿剂，从而使两亲性的印刷用涂层不仅能够附着在PMMA材质的基板上，同时还能够承印水性印刷涂料，具有良好的两亲性和印刷稳定性。
以上所述仅为本发明的较佳实施方式而已，并不用以限制本发明，凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。

Claims (9)

1.一种两亲性印刷用涂层，其特征在于，按质量份数计算，包括：
Figure FDA0003163079270000011
2.如权利要求1所述的两亲性印刷用涂层，其特征在于，所述水性树脂乳液为聚甲基丙烯酸甲酯乳液。
3.如权利要求2所述的两亲性印刷用涂层，其特征在于，所述聚甲基丙烯酸甲酯乳液的固含量为25-35％。
4.如权利要求2所述的两亲性印刷用涂层，其特征在于，所述聚甲基丙烯酸甲酯乳液中聚甲基丙烯酸甲酯的数均分子量为2000-3000。
5.如权利要求1所述的两亲性印刷用涂层，其特征在于，所述聚丙烯酸水溶液的固含量为45-55％。
6.如权利要求1所述的两亲性印刷用涂层，其特征在于，所述水性蜡乳液为氧化聚乙烯蜡乳液，所述氧化聚乙烯蜡乳液的固含量为25-35％。
7.如权利要求1所述的两亲性印刷用涂层，其特征在于，所述水性润湿剂为聚丙二醇二乙酸盐和聚丙二醇二硫酸盐中的一种或两种的混合物。
8.如权利要求1-7中任一所述的两亲性印刷用涂层的制备方法，其特征在于，包括如下步骤：
按照重量份数分别称取水性树脂乳液、聚丙烯酸水溶液、水性蜡乳液、水性流平剂、水性润湿剂和水性消泡剂，混合均匀后加入去离子水，调节至固含量为30％，得到两亲性印刷用涂层。
9.如权利要求1-7中任一所述的两亲性印刷用涂层在PMMA面板表面印刷中的应用。
CN202110796802.8A 2021-07-14 2021-07-14 一种两亲性印刷用涂层及其制备方法和应用 Pending CN113652133A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110796802.8A CN113652133A (zh) 2021-07-14 2021-07-14 一种两亲性印刷用涂层及其制备方法和应用

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110796802.8A CN113652133A (zh) 2021-07-14 2021-07-14 一种两亲性印刷用涂层及其制备方法和应用

Publications (1)

Publication Number Publication Date
CN113652133A true CN113652133A (zh) 2021-11-16

Family

ID=78489475

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202110796802.8A Pending CN113652133A (zh) 2021-07-14 2021-07-14 一种两亲性印刷用涂层及其制备方法和应用

Country Status (1)

Country Link
CN (1) CN113652133A (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115044258A (zh) * 2022-05-13 2022-09-13 海盐华港印刷股份有限公司 一种不易掉色的服装吊牌及表面涂层

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003055582A (ja) * 2001-08-10 2003-02-26 Toyo Ink Mfg Co Ltd 硬化性被覆組成物、硬化性印刷インキ、硬化性ニスおよびそれらの印刷物
CN102146243A (zh) * 2011-01-25 2011-08-10 深圳市嘉卓成科技发展有限公司 水性单组份热塑性塑胶涂料及其生产、施工方法
CN105385285A (zh) * 2015-12-30 2016-03-09 上海奇想青晨新材料科技股份有限公司 一种高耐磨水性光油及其制备方法
CN107739561A (zh) * 2017-10-19 2018-02-27 武汉华工图像技术开发有限公司 哑光涂料、其制备方法及表观细腻的哑光涂层
CN109679429A (zh) * 2018-12-28 2019-04-26 中国印刷科学技术研究院有限公司 喷墨印刷用水性光油和其制造方法
CN109810559A (zh) * 2019-02-28 2019-05-28 江苏艾森半导体材料股份有限公司 高分散性的哑光阻焊油墨
CN110204978A (zh) * 2019-05-24 2019-09-06 深圳市嘉卓成科技发展有限公司 一种水性塑胶涂料及其制备方法和使用方法
CN111777905A (zh) * 2020-07-08 2020-10-16 上海德粼水性油墨有限公司 环保水性涂层及其制备方法

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003055582A (ja) * 2001-08-10 2003-02-26 Toyo Ink Mfg Co Ltd 硬化性被覆組成物、硬化性印刷インキ、硬化性ニスおよびそれらの印刷物
CN102146243A (zh) * 2011-01-25 2011-08-10 深圳市嘉卓成科技发展有限公司 水性单组份热塑性塑胶涂料及其生产、施工方法
CN105385285A (zh) * 2015-12-30 2016-03-09 上海奇想青晨新材料科技股份有限公司 一种高耐磨水性光油及其制备方法
CN107739561A (zh) * 2017-10-19 2018-02-27 武汉华工图像技术开发有限公司 哑光涂料、其制备方法及表观细腻的哑光涂层
CN109679429A (zh) * 2018-12-28 2019-04-26 中国印刷科学技术研究院有限公司 喷墨印刷用水性光油和其制造方法
CN109810559A (zh) * 2019-02-28 2019-05-28 江苏艾森半导体材料股份有限公司 高分散性的哑光阻焊油墨
CN110204978A (zh) * 2019-05-24 2019-09-06 深圳市嘉卓成科技发展有限公司 一种水性塑胶涂料及其制备方法和使用方法
CN111777905A (zh) * 2020-07-08 2020-10-16 上海德粼水性油墨有限公司 环保水性涂层及其制备方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115044258A (zh) * 2022-05-13 2022-09-13 海盐华港印刷股份有限公司 一种不易掉色的服装吊牌及表面涂层
CN115044258B (zh) * 2022-05-13 2023-10-31 海盐华港印刷股份有限公司 一种不易掉色的服装吊牌

Similar Documents

Publication Publication Date Title
CN105086805B (zh) 一种高硬高耐磨水性双组份木器清漆及其制备方法
CN103740173B (zh) 油墨
CN107201122B (zh) 一种水性罩光亮光烤漆及其制备方法
CN107266963B (zh) 一种pvc装饰膜凹版表印水性油墨及其颜色冲淡金油
CN104530930B (zh) 一种橘纹涂料
CN111500174A (zh) 一种用于汽车内饰的水性哑光涂料及其制备方法、应用
CN106947351A (zh) 一种抗涂鸦防盗门水漆及其制备方法
CN111471387A (zh) 水性木器涂料及其使用方法
CN110028858A (zh) 一种可湿喷湿施工的配套漆及其制备方法和施工工艺
CN105385336A (zh) 一种具有绒感的、抗刮的水性聚氨酯涂料
CN107629656A (zh) 一种快干且活化期长的水性弹性漆及其制备方法
CN109021804A (zh) 水性手感涂料及其制备方法和应用
CN103360570A (zh) 水性聚氨酯及其制备方法与水性转移涂料
CN110903723A (zh) 一种高硬度的水性漆及其制备方法、应用、木器
CN103483995A (zh) 一种pe亮光清漆及其制备方法
CN113652133A (zh) 一种两亲性印刷用涂层及其制备方法和应用
CN112694805A (zh) 一种低温烘烤水性电镀银涂料及其制备方法
CN107686691B (zh) 一种水性丙烯酸离型硅油及其制备方法和应用
CN103666179A (zh) 一种无voc环氧改性水基聚氨酯面漆及其制备方法
CN114539895A (zh) 一种水性pu涂料及涂装工艺
CN111793990B (zh) 一种水性自粘贴装饰布涂料及其制备方法
CN111154415B (zh) 一种热升华打印不干胶标签
CN107286770A (zh) 一种耐擦洗黑板用漆及其制备方法
CN114752252B (zh) 一种pet表印水性哑光油及其制备方法
CN109517566A (zh) 一种水性热转印pp胶黏剂及其制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CB03 Change of inventor or designer information

Inventor after: Chen Cheng

Inventor after: Wang Jun

Inventor after: Wang Weihua

Inventor before: Chen Cheng

Inventor before: Wang Jun

Inventor before: Wang Weihua

CB03 Change of inventor or designer information
RJ01 Rejection of invention patent application after publication

Application publication date: 20211116

RJ01 Rejection of invention patent application after publication