CN113563942A - 一种无灰防锈油复合添加剂 - Google Patents
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- 239000000654 additive Substances 0.000 title claims abstract description 31
- 230000000996 additive effect Effects 0.000 title claims abstract description 28
- 239000002131 composite material Substances 0.000 title claims abstract description 13
- -1 amine sulfonate Chemical class 0.000 claims abstract description 20
- 239000013556 antirust agent Substances 0.000 claims abstract description 8
- 229910052751 metal Inorganic materials 0.000 claims abstract description 8
- 239000002184 metal Substances 0.000 claims abstract description 8
- 150000001733 carboxylic acid esters Chemical class 0.000 claims abstract description 7
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 6
- 150000002148 esters Chemical class 0.000 claims abstract description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 11
- 230000003449 preventive effect Effects 0.000 claims description 10
- QDCPNGVVOWVKJG-VAWYXSNFSA-N 2-[(e)-dodec-1-enyl]butanedioic acid Chemical compound CCCCCCCCCC\C=C\C(C(O)=O)CC(O)=O QDCPNGVVOWVKJG-VAWYXSNFSA-N 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 4
- CJAYHOLRQJHSIP-NXVVXOECSA-N 2-[(z)-heptadec-2-enyl]-4,5-dihydro-1h-imidazole Chemical compound CCCCCCCCCCCCCC\C=C/CC1=NCCN1 CJAYHOLRQJHSIP-NXVVXOECSA-N 0.000 claims description 2
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 2
- 229940092714 benzenesulfonic acid Drugs 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims 3
- 239000003973 paint Substances 0.000 claims 1
- 239000003921 oil Substances 0.000 abstract description 25
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 abstract description 4
- 239000010720 hydraulic oil Substances 0.000 abstract description 4
- 229910021645 metal ion Inorganic materials 0.000 abstract description 4
- 238000010791 quenching Methods 0.000 abstract description 4
- 230000000171 quenching effect Effects 0.000 abstract description 4
- 239000002199 base oil Substances 0.000 abstract description 2
- UXOLDCOJRAMLTQ-UHFFFAOYSA-N ethyl 2-chloro-2-hydroxyiminoacetate Chemical compound CCOC(=O)C(Cl)=NO UXOLDCOJRAMLTQ-UHFFFAOYSA-N 0.000 abstract description 2
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 2
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 4
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical group CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 4
- 229940095259 butylated hydroxytoluene Drugs 0.000 description 4
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- CJMZLCRLBNZJQR-UHFFFAOYSA-N ethyl 2-amino-4-(4-fluorophenyl)thiophene-3-carboxylate Chemical compound CCOC(=O)C1=C(N)SC=C1C1=CC=C(F)C=C1 CJMZLCRLBNZJQR-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M163/00—Lubricating compositions characterised by the additive being a mixture of a compound of unknown or incompletely defined constitution and a non-macromolecular compound, each of these compounds being essential
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
- C10M2215/224—Imidazoles
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
本发明公开了一种无灰防锈油复合添加剂，其包括主防锈剂、辅助防锈添加剂、成膜剂及抗氧添加剂；所述主防锈剂为油溶性磺酸胺，所述辅助防锈添加剂为羧酸或羧酸酯、十七烯基咪唑啉烯基丁二酸盐、金属钝化剂中的一种或多种，所述成膜剂为氧化蜡或其酯，所述抗氧添加剂为BHT。本发明所用添加剂不含金属离子，不含邻苯二甲酸二丁酯等ECHA所列高关注物，也不含重金属，与常用的基础油能很好的混溶，具有良好的防锈性能；特别是不含有金属离子，经高温灼烧后会生成各自的氧化物，呈气态散去，不会遗留在工件表面，污染工件，即本发明的防锈油复合添加剂为无灰型，特别适用于无灰抗磨液压油、淬火件淬火前的工件防锈油等有控灰要求的防锈油应用。
Description
技术领域
本发明涉及一种无灰防锈油复合添加剂，属于化工领域。
背景技术
油溶性磺酸盐是国内最常用的一类防锈油添加剂，它的成盐物一般是碱金属或碱土金属，如钡、钙、镁、钠、锌等，这种防锈剂具有显著的防锈效果，但含有金属盐，使用后生灰分，不能满足某些特定场合的需求，如用于无灰抗磨液压油、淬火件淬火前的工件防锈油等，存在不足。
国外公司生产了一类无灰的磺酸胺(氨)类防锈油添加剂，如美国King公司生产的
AS、
EDA、
DTA、
LP、
TLT等，这类防锈油添加剂的防锈性能与相应的金属盐相似，但由于其无灰(不含金属离子，高温灼烧后无灰烬遗留)，可以满足某些特定场合的需求，但目前该类产品在国内尚未见有生产的报道。
发明内容
针对上述不足，本发明提供一种无灰防锈油复合添加剂，本发明所采用的技术方案为：
一种无灰防锈油复合添加剂，其包括主防锈剂、辅助防锈添加剂、成膜剂及抗氧添加剂；所述主防锈剂为油溶性磺酸胺，所述辅助防锈添加剂为羧酸或羧酸酯、十七烯基咪唑啉烯基丁二酸盐、金属钝化剂中的一种或多种，所述成膜剂为氧化蜡或其酯，所述抗氧添加剂为BHT。
其各组份的重量份数为：油溶性磺酸胺4-6份、羧酸或羧酸酯2-4份、十七烯基咪唑啉烯基丁二酸盐2-4份、金属钝化剂0-0.5份、氧化蜡或其酯1-3份、BHT 0.1-1份。
其制备方法为将上述组份搅拌混合均匀并加热溶解制成。
进一步地，所述油溶性磺酸胺的胺类为具有至少三个碳原子且没有氧原子的胺。
进一步地，所述油溶性磺酸胺为烷基芳族磺酸胺，优选为二壬基萘磺酸胺或重烷基苯磺酸胺。
进一步地，所述羧酸为十二烯基丁二酸，所述羧酸酯为十二烯基丁二酸单酯。
与现有技术相比，本发明的有益效果在于：本发明所用添加剂都不含金属离子，高温灼烧后无灰烬遗留；所用添加剂都不含邻苯二甲酸二丁酯等ECHA所列高关注物，也不含重金属；与常用的基础油能很好的混溶，具有良好的防锈性能；特别是不含有金属离子，其组成成分只含有碳、氮、氢、硫等，经高温灼烧后会生成各自的氧化物，呈气态散去，不会遗留在工件表面，污染工件，即本发明的防锈油复合添加剂为无灰型，特别适用于无灰抗磨液压油、淬火件淬火前的工件防锈油等有控灰要求的防锈油应用。
具体实施方式
下面结合实施例对本发明的技术方案做进一步的说明。
实施例：
在500ml的三口烧瓶中，加入二壬基萘磺酸胺80g、十二烯基丁二酸30g、十七烯基米唑啉丁二酸盐30g、氧化蜡40g，升温至80-100℃,充分搅匀后，降温至70℃以下，再加入甲基苯并三氮唑10g、BHT10g，冷却至常温，得红棕色透明粘稠液体，即得本发明的无灰防锈油复合添加剂。
本实施例制备的无灰防锈油复合添加剂质量指标如下：
本发明的无灰防锈油复合添加剂的防锈性能与性状与国内现在通用的由二壬基萘磺酸金属盐调制的常用防锈油相仿，其最大特点和优势是无灰，能够满足对灰分有要求的产品的防锈处理，如无灰抗磨液压油、淬火工件防锈油等。
以上所述是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也视为本发明的保护范围。
Claims (5)
1.一种无灰防锈油复合添加剂，其特征在于：其包括主防锈剂、辅助防锈添加剂、成膜剂及抗氧添加剂；所述主防锈剂为油溶性磺酸胺，所述辅助防锈添加剂为羧酸或羧酸酯、十七烯基咪唑啉烯基丁二酸盐、金属钝化剂中的一种或多种，所述成膜剂为氧化蜡或其酯，所述抗氧添加剂为BHT；所述油溶性磺酸胺的胺类为具有至少三个碳原子且没有氧原子的胺。
2.根据权利要求1所述的无灰防锈油复合添加剂，其特征在于：所述油溶性磺酸胺为烷基芳族磺酸胺。
3.根据权利要求1所述的无灰防锈油复合添加剂，其特征在于：所述油溶性磺酸胺为二壬基萘磺酸胺或重烷基苯磺酸胺。
4.根据权利要求1所述的无灰防锈油复合添加剂，其特征在于：所述羧酸为十二烯基丁二酸，所述羧酸酯为十二烯基丁二酸单酯。
5.根据权利要求1所述的无灰防锈油复合添加剂，其特征在于：其包括以下重量组份：油溶性磺酸胺4-6份、羧酸或羧酸酯2-4份、十七烯基咪唑啉烯基丁二酸盐2-4份、金属钝化剂0-0.5份、氧化蜡或其酯1-3份、BHT 0.1-1份。
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0335429A2 (en) * | 1988-03-22 | 1989-10-04 | King Industries, Inc. | Amine dinonylnaphthalene sulfonates with corrosion inhibiting properties |
| JP2007270323A (ja) * | 2006-03-31 | 2007-10-18 | Nippon Oil Corp | さび止め油組成物 |
| CN108913312A (zh) * | 2018-08-15 | 2018-11-30 | 广州兴产新材料科技有限公司 | 一种多功能防锈油的制备方法及多功能防锈油 |
| CN111073737A (zh) * | 2019-12-01 | 2020-04-28 | 苏州福瑞斯德新材料科技有限公司 | 一种不含重金属的防锈油 |
-
2021
- 2021-07-28 CN CN202110854192.2A patent/CN113563942A/zh active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0335429A2 (en) * | 1988-03-22 | 1989-10-04 | King Industries, Inc. | Amine dinonylnaphthalene sulfonates with corrosion inhibiting properties |
| JP2007270323A (ja) * | 2006-03-31 | 2007-10-18 | Nippon Oil Corp | さび止め油組成物 |
| CN108913312A (zh) * | 2018-08-15 | 2018-11-30 | 广州兴产新材料科技有限公司 | 一种多功能防锈油的制备方法及多功能防锈油 |
| CN111073737A (zh) * | 2019-12-01 | 2020-04-28 | 苏州福瑞斯德新材料科技有限公司 | 一种不含重金属的防锈油 |
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