CN113456562A - Preparation method of anhydrous shampoo - Google Patents

Preparation method of anhydrous shampoo Download PDF

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Publication number
CN113456562A
CN113456562A CN202110811565.8A CN202110811565A CN113456562A CN 113456562 A CN113456562 A CN 113456562A CN 202110811565 A CN202110811565 A CN 202110811565A CN 113456562 A CN113456562 A CN 113456562A
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percent
phase
extract
mixture
percentage
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Inventor
王长晶
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Dandong Xin Shi Dai Biotech Pharmaceuticals Co ltd
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Dandong Xin Shi Dai Biotech Pharmaceuticals Co ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783Angiosperms [Magnoliophyta]
    • A61K8/9794Liliopsida [monocotyledons]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783Angiosperms [Magnoliophyta]
    • A61K8/9789Magnoliopsida [dicotyledons]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P17/00Drugs for dermatological disorders
    • A61P17/04Antipruritics
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P17/00Drugs for dermatological disorders
    • A61P17/08Antiseborrheics
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P17/00Drugs for dermatological disorders
    • A61P17/14Drugs for dermatological disorders for baldness or alopecia
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/02Preparations for cleaning the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q7/00Preparations for affecting hair growth
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30Characterized by the absence of a particular group of ingredients
    • A61K2800/31Anhydrous

Abstract

The invention discloses a preparation method of anhydrous shampoo, which comprises the following components in percentage by mass: 1.9-5.1% of conditioner, 0.1-1.0% of pH regulator, 0.4-2.5% of thickening agent, 0.05-0.1% of chelating agent, 34-60% of surfactant and 30.8-64.05% of plant extract. The anhydrous shampoo provided by the invention has the advantages that the plant extract is used for replacing water in the formula, so that the nutrition of the hair can be increased, the hair has good flexibility and a function of uneasy crisping, the smooth and soft feeling is brought in the rinsing stage, the hair is fresh and soft after being dried, the hair is kept smooth and glossy, the itch is removed, and the alopecia is prevented. The added plant extract has the effects of resisting bacteria and diminishing inflammation, and can relieve inflammation of the head caused by excessive lipid secretion. Has the effects of removing dandruff, relieving itching, killing bacteria, preventing alopecia, promoting hair growth, consolidating hair, and nourishing scalp.

Description

Preparation method of anhydrous shampoo
Technical Field
The invention relates to the technical field of chemistry, in particular to shampoo.
Background
Shampoo is a common chemical product, the components of the shampoo which is produced and sold on the market at present are blended by water, surfactant represented by sodium laureth sulfate, preservative, essence and the like, and the formula product has the defects of large stimulation to scalp, large harm to scalp, single product performance and the like; the existing shampoo often contains raw materials of 'water', so that not only bacteria are bred, but also the quality guarantee period is short; in addition, the existing shampoo contains preservatives, essence and the like, which are easily absorbed by the skin to cause certain damage to the body.
Disclosure of Invention
In order to solve the technical problems, the invention aims to provide a preparation method of anhydrous shampoo, which comprises the following components in percentage by mass (namely the mass ratio of the anhydrous shampoo to the shampoo, the following is the same):
1.9-5.1% of conditioner, 0.1-1.0% of pH regulator, 0.4-2.5% of thickening agent, 0.05-0.1% of chelating agent, 34-60% of surfactant and 30.8-64.05% of plant extract.
The conditioner comprises the following specific components in percentage by mass:
polyquaternium-10: 0.1 to 0.3 percent of,
polyquaternium-7: 1.2 to 3 percent of the total weight of the mixture,
myristamidopropyl PG-dimethyl ammonium chloride phosphate: 0.5 to 1.5 percent of,
guar hydroxypropyltrimethylammonium chloride: 0.1 to 0.3 percent;
the pH regulator comprises the following specific components in percentage by mass:
citric acid: 0.09-0.98 percent of the total weight of the mixture,
potassium hydroxide: 0.01 to 0.02 percent.
The thickening agent comprises the following specific components in percentage by mass: 0.4-2.5%;
the chelating agent comprises the following specific components in percentage by mass: 0.05 to 0.1 percent of ethylenediamine tetraacetic acid.
The surfactant comprises the following specific components in percentage by mass:
sodium lauroamphoacetate: 2 to 6 percent of the total weight of the mixture,
cocamide DEA: 1.5 to 2 percent of the total weight of the mixture,
sodium methyl cocoyl taurate: 2 to 4 percent of the total weight of the mixture,
cocamidopropyl hydroxysultaine: 8.5 to 15 percent of the total weight of the mixture,
8 to 15 percent of sodium lauroyl sarcosinate,
cocamidopropyl betaine: 8 to 12 percent of the total weight of the mixture,
lauramidopropylamine oxide: 4-6 percent.
The plant extracting solution comprises the following specific components in percentage by mass:
2 to 4 percent of ginger extract,
0.2 to 0.5 percent of the extract of the root of the kuh-seng,
aloe extract 23.2-47.7%,
5 to 10 percent of rosemary extract,
0.4-0.85% of kiwi fruit extract;
the preparation method comprises the following steps:
accurately weighing the conditioner, the pH regulator, the thickening agent, the chelating agent, the surfactant and the plant extract according to the proportion, adding the mixture into a stirring kettle at 30rpm, stirring and heating, keeping the temperature for half an hour after heating to 90 ℃, cooling to 30 ℃ and discharging.
The herbaceous stock solution comprises the following components in percentage by mass:
phase A: 47.3 percent of aloe extract,
Kiwi fruit extract 0.8%, and radix Sophorae Flavescentis extract 0.4%;
phase B: 3% of ginger extract and 0.25% of guar gum hydroxypropyl trimethyl ammonium chloride;
and C phase: 0.4% of citric acid;
phase D: myristyl glycol 1.5%, polyquaternium-100.15%, and ethylenediamine tetraacetic acid 0.1%;
phase E: sodium lauroyl sarcosinate 10%, cocamide DEA 1.5%, imidazoline AMC 2%, lauramidopropylamine oxide 4%, cocamidopropyl betaine 10%, cocamidopropyl hydroxysultaine 9%, sodium methyl cocoyl taurate 2%;
and (3) phase F: 1% of myristamidopropyl PG-dimethyl ammonium chloride phosphate and-71.5% of polyquaternium;
phase G: 5% of rosemary extract and 0.1% of potassium hydroxide;
the preparation method of the herbal stock solution comprises the following steps:
(1) accurately weighing the phase A, adding the phase A into a stirring tank, starting stirring at 30rpm,
(2) dispersing guar hydroxypropyl trimethyl ammonium chloride in the ginger extract, and then pouring the phase B into a stirring tank;
(3) adding phase C, and starting to heat the stirring tank;
(4) adding the phase D into a stirring tank;
(5) adding phase E into a stirring tank;
(6) after the temperature is heated to 90 ℃, preserving the heat for half an hour and beginning to cool;
(7) when the temperature is reduced to 60 ℃, adding the F phase;
(8) dispersing potassium hydroxide in the herbal stock solution, and adding the G phase when the temperature of the stirring tank is reduced to 50 ℃; the temperature is reduced to 30 ℃, and the material is discharged.
Compared with the prior art, the advantages or positive effects are as follows:
1. the formula does not contain water raw materials, and the plant extract replaces water, so that the hair nutrition can be increased, the hair has good flexibility and a function of uneasy crisping, silky and smooth feeling is brought in a rinsing stage, the hair is fresh and soft after being dried, the hair is kept smooth and glossy, the itch is removed, and the alopecia is prevented.
2. Preservative and essence are not added in the formula;
3. the plant extracts in the formula have the effects of resisting bacteria and diminishing inflammation, and can enable the anhydrous shampoo to have the effects of keeping hair smooth and glossy, removing dandruff, relieving itching, preventing alopecia and the like
Detailed Description
Example 1
The technical scheme mainly comprises the following components in percentage by mass: 1.9% of conditioner, 1.0% of pH regulator, 1.8% of thickening agent, 0.05% of chelating agent, 34% of surfactant and 64.05% of plant extract.
Wherein:
1.9% of the conditioner specifically comprises:
0.1% of polyquaternium-10 (JR-400 conditioner), the common name in parentheses, the same as below;
1.2 percent of polyquaternium-7 (M550 conditioner),
myristamidopropyl PG-dimethyl ammonium chloride phosphate (MP conditioner) 0.5%, guar hydroxypropyl trimethyl ammonium chloride (C-14/S cation conditioner) 0.1%;
1.0 percent of pH regulator is specifically;
0.99 percent of citric acid (pH regulator),
0.91% of potassium hydroxide (pH regulator);
1.8% of thickening agent is:
ceteth-60 myristyl glycol (282S thickener) 1.7%;
the chelating agent 0.05% is specifically:
ethylenediaminetetraacetic acid (EDTA chelator) 0.05%;
34% of surfactant specifically;
2 percent of lauroamphoacetate (imidazoline AMC, surfactant),
1.5 percent of cocamide DEA (6501 surfactant),
2 percent of methyl cocoyl sodium taurate (SCMT-35 surfactant),
cocamidopropyl hydroxysultaine (CHSB surfactant) 8.5%
8 percent of sodium lauroyl sarcosinate (S-12 surfactant),
8 percent of cocamidopropyl betaine (C-60 surfactant),
lauramidopropyl amine oxide (LAO-30 surfactant) 4%;
64.05% of plant extract:
4 percent of ginger extract,
0.5 percent of the extract of the kuh-seng root,
47.7 percent of aloe extract,
10 percent of rosemary extract,
1.85% of kiwi fruit extract;
the herbal stock solution components and the process production process are shown in the following table:
the process comprises the following steps:
Figure BDA0003168469420000041
the preparation method comprises the following steps:
accurately weighing the conditioner, the pH regulator, the thickening agent, the chelating agent, the surfactant and the plant extract according to the proportion, adding the mixture into a stirring kettle at 30rpm, stirring and heating, keeping the temperature for half an hour after heating to 90 ℃, cooling to 30 ℃ and discharging.
Example 2
5.1% of conditioner, 0.1% of pH regulator, 0.4% of thickening agent, 0.1% of chelating agent, 60% of surfactant and 30.8% of plant extract;
the conditioner comprises the following specific components in percentage by mass:
polyquaternium-10: 0.3 percent of the total weight of the mixture,
polyquaternium-7: 3 percent of the total weight of the mixture,
myristamidopropyl PG-dimethyl ammonium chloride phosphate: 1.5 percent of the total weight of the mixture,
guar hydroxypropyltrimethylammonium chloride: 0.3 percent;
the pH regulator comprises the following specific components in percentage by mass:
citric acid: 0.09 percent of the total weight of the mixture,
potassium hydroxide: 0.01 percent;
the thickening agent comprises the following specific components in percentage by mass: 0.4 percent;
the chelating agent comprises the following specific components in percentage by mass: 0.1 percent of ethylenediamine tetraacetic acid.
The surfactant comprises the following specific components in percentage by mass:
sodium lauroamphoacetate: 6 percent of the total weight of the mixture,
cocamide DEA: 2 percent of the total weight of the mixture,
sodium methyl cocoyl taurate: 4 percent of the total weight of the mixture,
cocamidopropyl hydroxysultaine: 15 percent of the total weight of the mixture is less than or equal to 15 percent,
15 percent of sodium lauroyl sarcosinate,
cocamidopropyl betaine: 12 percent of the total weight of the mixture,
lauramidopropylamine oxide: 6 percent.
The plant extracting solution comprises the following specific components in percentage by mass:
2 percent of ginger extract,
0.2 percent of the extract of the kuh-seng root,
23.2 percent of aloe extract,
5 percent of rosemary extract,
0.4% of kiwi fruit extracting solution;
the preparation method of the herbal stock solution is the same as that of example 1;
the preparation method comprises the following steps:
accurately weighing the conditioner, the pH regulator, the thickening agent, the chelating agent, the surfactant and the plant extract according to the proportion, adding the mixture into a stirring kettle at 30rpm, stirring and heating, keeping the temperature for half an hour after heating to 90 ℃, cooling to 30 ℃ and discharging.
Example 3
A preparation method of anhydrous shampoo comprises the following components in percentage by mass (namely the mass ratio of the anhydrous shampoo to the shampoo, the same below):
3% of conditioner, 0.8% of pH regulator, 1.6% of thickening agent, 0.08% of chelating agent, 45% of surfactant and 42% of plant extract.
The conditioner comprises the following specific components in percentage by mass:
polyquaternium-10: 0.2 percent of the total weight of the mixture,
polyquaternium-7: 1.8 percent of the total weight of the steel,
myristamidopropyl PG-dimethyl ammonium chloride phosphate: 0.7 percent of the total weight of the mixture,
guar hydroxypropyltrimethylammonium chloride: 0.3 percent;
the pH regulator comprises the following specific components in percentage by mass:
citric acid: 0.785 percent of the total weight of the mixture,
potassium hydroxide: 0.015 percent.
The thickening agent comprises the following specific components in percentage by mass: 1.6 percent;
the chelating agent comprises the following specific components in percentage by mass: 0.08 percent of ethylenediamine tetraacetic acid.
The surfactant comprises the following specific components in percentage by mass:
sodium lauroamphoacetate: 5 percent of the total weight of the mixture,
cocamide DEA: 1.8 percent of the total weight of the steel,
sodium methyl cocoyl taurate: 3 percent of the total weight of the mixture,
cocamidopropyl hydroxysultaine: 12 percent of the total weight of the mixture,
10 percent of sodium lauroyl sarcosinate,
cocamidopropyl betaine: 8.2 percent of the total weight of the mixture,
lauramidopropylamine oxide: 5 percent.
The plant extracting solution comprises the following specific components in percentage by mass:
3 percent of ginger extract,
0.4 percent of the extract of the kuh-seng root,
30 percent of aloe extract,
8 percent of rosemary extract,
0.6% of kiwi fruit extracting solution;
the preparation method of the herbal stock solution is the same as that of example 1;
the preparation method comprises the following steps:
accurately weighing the conditioner, the pH regulator, the thickening agent, the chelating agent, the surfactant and the plant extract according to the proportion, adding the mixture into a stirring kettle at 30rpm, stirring and heating, keeping the temperature for half an hour after heating to 90 ℃, cooling to 30 ℃ and discharging.
The various components of the present invention may be commercially available products.
The anhydrous shampoo provided by the invention has the advantages that the plant extract is used for replacing water in the formula, so that the nutrition of the hair can be increased, the hair has good flexibility and a function of uneasy crisping, the smooth and soft feeling is brought in the rinsing stage, the hair is fresh and soft after being dried, the hair is kept smooth and glossy, the itch is removed, and the alopecia is prevented. The added plant extract has the effects of resisting bacteria and diminishing inflammation, and can relieve inflammation of the head caused by excessive lipid secretion. Has the effects of removing dandruff, relieving itching, killing bacteria, preventing alopecia, promoting hair growth, consolidating hair, and nourishing scalp.
Efficacy experiment, 100 persons are selected to respectively adopt the product of the example 1 and a certain common shampoo sold in the market to evaluate the smoothness, the dandruff removal, the itching relieving, the alopecia and the like. Specific results are shown in the following table;
table 1 comparative test table
Figure BDA0003168469420000071
The experimental result proves that the anhydrous shampoo disclosed by the invention is mild in the whole formula system, free of stimulation and harmless to human scalp because of no water, no preservative and essence and the selection of a mild surfactant; according to different effects of the plant extract, different extracts are selected, so that the anhydrous shampoo has the effects of softening, smoothing, removing dandruff, relieving itching, sterilizing and preventing alopecia, growing and fixing hair, nourishing scalp and the like.

Claims (7)

1. A preparation method of anhydrous shampoo is characterized in that: the composition comprises the following components in percentage by mass:
1.9-5.1% of conditioner, 0.1-1.0% of pH regulator, 0.4-2.5% of thickening agent, 0.05-0.1% of chelating agent, 34-60% of surfactant and 30.8-64.05% of plant extract;
the preparation method comprises the following steps:
accurately weighing the conditioner, the pH regulator, the thickening agent, the chelating agent, the surfactant and the plant extract according to the proportion, adding the mixture into a stirring kettle at 30rpm, stirring and heating, keeping the temperature for half an hour after heating to 90 ℃, cooling to 30 ℃ and discharging.
2. The method for preparing anhydrous shampoo according to claim 1, characterized in that: the conditioner comprises the following specific components in percentage by mass:
polyquaternium-10: 0.1 to 0.3 percent of,
polyquaternium-7: 1.2 to 3 percent of the total weight of the mixture,
myristamidopropyl PG-dimethyl ammonium chloride phosphate: 0.5 to 1.5 percent of,
guar hydroxypropyltrimethylammonium chloride: 0.1 to 0.3 percent.
3. The method for preparing anhydrous shampoo according to claim 1, characterized in that: the pH regulator comprises the following specific components in percentage by mass:
citric acid: 0.09-0.98 percent of the total weight of the mixture,
potassium hydroxide: 0.01 to 0.02 percent.
4. The method for preparing anhydrous shampoo according to claim 1, characterized in that: the thickening agent comprises the following specific components in percentage by mass: 0.4-2.5%;
the chelating agent comprises the following specific components in percentage by mass: 0.05 to 0.1 percent of ethylenediamine tetraacetic acid.
5. The method for preparing anhydrous shampoo according to claim 1, characterized in that: the surfactant comprises the following specific components in percentage by mass:
sodium lauroamphoacetate: 2 to 6 percent of the total weight of the mixture,
cocamide DEA: 1.5 to 2 percent of the total weight of the mixture,
sodium methyl cocoyl taurate: 2 to 4 percent of the total weight of the mixture,
cocamidopropyl hydroxysultaine: 8.5 to 15 percent of the total weight of the mixture,
8 to 15 percent of sodium lauroyl sarcosinate,
cocamidopropyl betaine: 8 to 12 percent of the total weight of the mixture,
lauramidopropylamine oxide: 4-6 percent.
6. The method for preparing anhydrous shampoo according to claim 1, characterized in that: the plant extracting solution comprises the following specific components in percentage by mass:
2 to 4 percent of ginger extract,
0.2 to 0.5 percent of the extract of the root of the kuh-seng,
aloe extract 23.2-47.7%,
5 to 10 percent of herbal stock solution,
0.4-0.85% of kiwi fruit extract;
the preparation method comprises the following steps:
accurately weighing the conditioner, the pH regulator, the thickening agent, the chelating agent, the surfactant and the plant extract according to the proportion, adding the mixture into a stirring kettle at 30rpm, stirring and heating, keeping the temperature for half an hour after heating to 90 ℃, cooling to 30 ℃ and discharging.
7. The method for preparing an anhydrous shampoo according to claim 6, wherein the method comprises the following steps: the herbaceous stock solution comprises the following components in percentage by mass:
phase A: 47.3 percent of aloe extract,
Kiwi fruit extract 0.8%, and radix Sophorae Flavescentis extract 0.4%;
phase B: 3% of ginger extract and 0.25% of guar gum hydroxypropyl trimethyl ammonium chloride;
and C phase: 0.4% of citric acid;
phase D: myristyl glycol 1.5%, polyquaternium-100.15%, and ethylenediamine tetraacetic acid 0.1%;
phase E: sodium lauroyl sarcosinate 10%, cocamide DEA 1.5%, imidazoline AMC 2%, lauramidopropylamine oxide 4%, cocamidopropyl betaine 10%, cocamidopropyl hydroxysultaine 9%, sodium methyl cocoyl taurate 2%;
and (3) phase F: 1% of myristamidopropyl PG-dimethyl ammonium chloride phosphate and-71.5% of polyquaternium;
phase G: 5% of rosemary extract and 0.1% of potassium hydroxide;
the preparation method of the herbal stock solution comprises the following steps:
(1) after the phase A is accurately weighed, adding the phase A into a stirring tank, and starting stirring at 30 rpm;
(2) dispersing guar hydroxypropyl trimethyl ammonium chloride in the ginger extract, and then pouring the phase B into a stirring tank;
(3) adding phase C, and starting to heat the stirring tank;
(4) adding the phase D into a stirring tank;
(5) adding phase E into a stirring tank;
(6) after the temperature is heated to 90 ℃, preserving the heat for half an hour and beginning to cool;
(7) when the temperature is reduced to 60 ℃, adding the F phase;
(8) dispersing potassium hydroxide in the herbal stock solution, and adding the G phase when the temperature of the stirring tank is reduced to 50 ℃; the temperature is reduced to 30 ℃, and the material is discharged.
CN202110811565.8A 2021-07-19 2021-07-19 Preparation method of anhydrous shampoo Pending CN113456562A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115721573A (en) * 2022-11-24 2023-03-03 广州花语精细化工有限公司 Amino acid shampoo and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN109288779A (en) * 2018-12-10 2019-02-01 湖南添寿堂药业有限公司 Anticreep Haircare composition and shampoo
CN111700843A (en) * 2020-07-14 2020-09-25 孙开军 Hair loss preventing and hair nourishing shampoo and preparation method thereof
CN112999138A (en) * 2021-03-19 2021-06-22 河南董欣生物科技有限公司 Plant dandruff-removing and itching-relieving composition, plant dandruff-removing and itching-relieving shampoo and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109288779A (en) * 2018-12-10 2019-02-01 湖南添寿堂药业有限公司 Anticreep Haircare composition and shampoo
CN111700843A (en) * 2020-07-14 2020-09-25 孙开军 Hair loss preventing and hair nourishing shampoo and preparation method thereof
CN112999138A (en) * 2021-03-19 2021-06-22 河南董欣生物科技有限公司 Plant dandruff-removing and itching-relieving composition, plant dandruff-removing and itching-relieving shampoo and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115721573A (en) * 2022-11-24 2023-03-03 广州花语精细化工有限公司 Amino acid shampoo and preparation method thereof

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