CN113383101A - 用于高温应用的镍基合金和方法 - Google Patents

用于高温应用的镍基合金和方法 Download PDF

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Publication number
CN113383101A
CN113383101A CN202080011255.1A CN202080011255A CN113383101A CN 113383101 A CN113383101 A CN 113383101A CN 202080011255 A CN202080011255 A CN 202080011255A CN 113383101 A CN113383101 A CN 113383101A
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Prior art keywords
nickel
alloy
percent
component
powder
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Inventor
马丁·戈特巴姆
马格努斯·哈斯尔奎斯特
克里斯托夫·海因策
马丁·舍费尔
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Siemens Energy Global GmbH and Co KG
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Siemens Energy Global GmbH and Co KG
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Publication of CN113383101A publication Critical patent/CN113383101A/zh
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/03Alloys based on nickel or cobalt based on nickel
    • C22C19/05Alloys based on nickel or cobalt based on nickel with chromium
    • C22C19/051Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
    • C22C19/056Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being at least 10% but less than 20%
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F10/00Additive manufacturing of workpieces or articles from metallic powder
    • B22F10/20Direct sintering or melting
    • B22F10/25Direct deposition of metal particles, e.g. direct metal deposition [DMD] or laser engineered net shaping [LENS]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F10/00Additive manufacturing of workpieces or articles from metallic powder
    • B22F10/20Direct sintering or melting
    • B22F10/28Powder bed fusion, e.g. selective laser melting [SLM] or electron beam melting [EBM]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F5/00Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
    • B22F5/009Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product of turbine components other than turbine blades
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/04Making non-ferrous alloys by powder metallurgy
    • C22C1/0433Nickel- or cobalt-based alloys
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2301/00Metallic composition of the powder or its coating
    • B22F2301/15Nickel or cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00Supplementary information concerning processes or compositions relating to powder metallurgy
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2999/00Aspects linked to processes or compositions used in powder metallurgy
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y10/00Processes of additive manufacturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00Materials specially adapted for additive manufacturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y80/00Products made by additive manufacturing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Powder Metallurgy (AREA)
  • Turbine Rotor Nozzle Sealing (AREA)
  • Laser Beam Processing (AREA)

Abstract

通过选择性地选择合金元素提供一种合金,通过所述合金能够产生无裂纹的构件。

Description

用于高温应用的镍基合金和方法
技术领域
本发明涉及一种用于高温应用,尤其用于燃气轮机的镍基合金,以及一种方法。
背景技术
迄今为止,借助于增材制造(SLM、SLS;借助于激光束,但是也能够借助于电子束(EBM))无法产生绝对无裂纹的部件,使得合金开发仍在继续。
该问题被着手研究并且限定具有决定性元素的规格的合金,所述合金引起无裂纹的部件。
发明内容
因此,本发明的目的是解决上述问题。
所述目的通过根据权利要求1的合金和根据权利要求2的方法实现。
在从属权利要求中列举了其他的有利措施,所述措施能够任意地彼此组合,以便实现其他的优点。
合金元素已经有针对性地选择,以便能够制造无裂纹的部件。在此,元素硅(Si)、硼(B)、锆(Zr)和铪(Hf)尤为重要并且同样需考虑碳(C)。
工艺条件,尤其在EBM工艺中的工艺条件的特征在于在长的时间段内从1173K至1373K的高的构造温度。与构件相关,可能需要数天。这是在其他已知的方法如铸造、锻造、焊接等中不会碰到的独特条件。源自这些条件,减少元素锆(Zr)、铪(Hf)和硅(Si),以便减少甚至完全避免合金的凝固裂纹趋势。这基于在从1173K直至构造温度的温度范围内降低液相/共晶份额并且同时设定更小的凝固间隔。
化学成分的变化优选由如下工艺参数补充的方式来确定:行进速度、行进策略、轨道间距、功率、能量束、层厚度、构造温度……,所述工艺参数实现无裂纹制造。
优点是:
·可以无裂纹地生产构件,确保构件整体性,可以通过AM设计提高效率。
·可以使用新型合金生产高质量的燃气轮机构件,使得能够满足未来的构件要求,并且为提高燃气轮机的效率做出贡献。
相关的合金的化学成分为(以重量%为单位):
铬(Cr)14.0%-16.0%,
尤其15.0%,
钴(Co)5.0%-6.0%
钼(Mo)0.8%-1.0%
钨(W)3.5%-4.0%
铝(Al)4.5%-5.0%
碳(C)0.04%-0.1%
硼(B)0.002%-0.013%
钽(Ta)7.4%-7.8%
铪(Hf)0.05%-0.15%
锆(Zr)<0.01%
硅(Si)<0.02%
杂质0.002%-0.01%,
尤其最小
铁(Fe),
锰(Mn),
钒(V),
铂(Pt),
钯(Pd),
铌(Nb),
钛(Ti),
铼(Re)或钌(Ru)
以及
其余为镍(Ni)。

Claims (4)

1.一种镍基合金,
所述镍基合金至少具有,
尤其由如下构成(以重量%为单位):
铬(Cr)14.0%-16.0%,
尤其15.0%,
钴(Co)5.0%-6.0%
钼(Mo)0.8%-1.0%
钨(W)3.5%-4.0%
铝(Al)4.5%-5.0%
碳(C)0.04%-0.1%
硼(B)0.002%-0.013%
钽(Ta)7.4%-7.8%
铪(Hf)0.05%-0.15%
锆(Zr)<0.01%
硅(Si)<0.02%
杂质0.002%-0.01%,
尤其最小
铁(Fe),
锰(Mn),
钒(V),
铂(Pt),
钯(Pd),
铌(Nb),
钛(Ti),
铼(Re)或钌(Ru)
以及
其余为镍(Ni)。
2.一种用于制造构件的方法,
其中使用根据权利要求1所述的合金并且借助于增材制造法,
尤其借助于在粉末床中的选择性烧结,在粉末床中的选择性熔化,
尤其借助于激光束或电子束,
或者
借助于粉末堆焊,
尤其激光粉末堆焊来制造。
3.根据权利要求2的方法,
其中使用借助于电子束(EBM)的工艺。
4.根据权利要求2或3的方法,
其中优化工艺参数,如行进速度、行进策略、轨道间距、功率、能量束、层厚度和/或构造温度……,所述工艺参数实现无裂纹的制造。
CN202080011255.1A 2019-01-29 2020-01-10 用于高温应用的镍基合金和方法 Pending CN113383101A (zh)

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Application Number Priority Date Filing Date Title
DE102019201095.4 2019-01-29
DE102019201095.4A DE102019201095A1 (de) 2019-01-29 2019-01-29 Nickelbasislegierung für Hochtemperaturanwendungen und Verfahren
PCT/EP2020/050506 WO2020156779A1 (de) 2019-01-29 2020-01-10 Nickelbasislegierung für hochtemperaturanwendungen und verfahren

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EP (1) EP3918100A1 (zh)
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DE (1) DE102019201095A1 (zh)
WO (1) WO2020156779A1 (zh)

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Publication number Priority date Publication date Assignee Title
CN113385689A (zh) * 2021-06-03 2021-09-14 广东工业大学 一种高熵合金及其制备方法和应用
CN115449669B (zh) * 2022-09-13 2023-08-08 中国联合重型燃气轮机技术有限公司 一种抗蠕变、抗氧化镍基高温合金及其制备方法和应用

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CN107486555A (zh) * 2016-06-13 2017-12-19 通用电器技术有限公司 Ni基超合金组合物以及用于SLM加工这种Ni基超合金组合物的方法

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EP1054072B1 (de) * 1999-05-20 2003-04-02 ALSTOM (Switzerland) Ltd Nickel-Basis-Superlegierung
JP2006104577A (ja) * 2004-10-04 2006-04-20 United Technol Corp <Utc> セグメント化ガドリニアジルコニア被膜およびその形成方法、セグメント化セラミック被覆システムならびに被膜部品
EP1914327A1 (en) * 2006-10-17 2008-04-23 Siemens Aktiengesellschaft Nickel-base superalloy
EP2859979A1 (de) * 2013-10-08 2015-04-15 Siemens Aktiengesellschaft Reparatur von Flächen mittels eines Lot/Grundwerkstoffgemischs und Bauteil
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Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030042233A1 (en) * 2001-08-31 2003-03-06 Kelly Thomas Joseph Production and use of welding filler metal
CN105828983A (zh) * 2013-12-23 2016-08-03 通用电器技术有限公司 用于基于粉末的增材制造过程的γ’沉淀增强镍基超合金
CN107486555A (zh) * 2016-06-13 2017-12-19 通用电器技术有限公司 Ni基超合金组合物以及用于SLM加工这种Ni基超合金组合物的方法

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DE102019201095A1 (de) 2020-07-30
EP3918100A1 (de) 2021-12-08
US20220119922A1 (en) 2022-04-21

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