CN113365947A - 锂化学品和金属锂的制备 - Google Patents

锂化学品和金属锂的制备 Download PDF

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Publication number
CN113365947A
CN113365947A CN201980090674.6A CN201980090674A CN113365947A CN 113365947 A CN113365947 A CN 113365947A CN 201980090674 A CN201980090674 A CN 201980090674A CN 113365947 A CN113365947 A CN 113365947A
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Prior art keywords
lithium
nitrate
lithium nitrate
oxide
product
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CN201980090674.6A
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English (en)
Chinese (zh)
Inventor
R·亨威克
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Yishipu Private Ltd
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Yishipu Private Ltd
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Priority claimed from AU2018904540A external-priority patent/AU2018904540A0/en
Application filed by Yishipu Private Ltd filed Critical Yishipu Private Ltd
Priority to CN202410589557.7A priority Critical patent/CN118811837A/zh
Priority to CN202410589556.2A priority patent/CN118811836A/zh
Publication of CN113365947A publication Critical patent/CN113365947A/zh
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01DCOMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00Lithium compounds
    • C01D15/02Oxides; Hydroxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053Details of the reactor
    • B01J19/0066Stirrers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18Stationary reactors having moving elements inside
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J3/00Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
    • B01J3/04Pressure vessels, e.g. autoclaves
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    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00Nitrogen; Compounds thereof
    • C01B21/20Nitrogen oxides; Oxyacids of nitrogen; Salts thereof
    • C01B21/24Nitric oxide (NO)
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    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00Nitrogen; Compounds thereof
    • C01B21/20Nitrogen oxides; Oxyacids of nitrogen; Salts thereof
    • C01B21/38Nitric acid
    • C01B21/40Preparation by absorption of oxides of nitrogen
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    • C01DCOMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00Lithium compounds
    • C01D15/10Nitrates
    • CCHEMISTRY; METALLURGY
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    • C01DCOMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D3/00Halides of sodium, potassium or alkali metals in general
    • C01D3/04Chlorides
    • C01D3/06Preparation by working up brines; seawater or spent lyes
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    • C01DCOMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D9/00Nitrates of sodium, potassium or alkali metals in general
    • C01D9/04Preparation with liquid nitric acid
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    • C01FCOMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F11/00Compounds of calcium, strontium, or barium
    • C01F11/18Carbonates
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    • C01F11/00Compounds of calcium, strontium, or barium
    • C01F11/20Halides
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    • C01F11/28Chlorides by chlorination of alkaline-earth metal compounds
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    • C01F11/00Compounds of calcium, strontium, or barium
    • C01F11/46Sulfates
    • C01F11/464Sulfates of Ca from gases containing sulfur oxides
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    • C01F5/00Compounds of magnesium
    • C01F5/14Magnesium hydroxide
    • C01F5/22Magnesium hydroxide from magnesium compounds with alkali hydroxides or alkaline- earth oxides or hydroxides
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01FCOMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00Compounds of aluminium
    • C01F7/02Aluminium oxide; Aluminium hydroxide; Aluminates
    • C01F7/20Preparation of aluminium oxide or hydroxide from aluminous ores using acids or salts
    • C01F7/24Preparation of aluminium oxide or hydroxide from aluminous ores using acids or salts with nitric acid or nitrogen oxides
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B26/00Obtaining alkali, alkaline earth metals or magnesium
    • C22B26/10Obtaining alkali metals
    • C22B26/12Obtaining lithium
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/22Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
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    • C22B5/00General methods of reducing to metals
    • C22B5/02Dry methods smelting of sulfides or formation of mattes
    • C22B5/12Dry methods smelting of sulfides or formation of mattes by gases
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    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B5/00General methods of reducing to metals
    • C22B5/02Dry methods smelting of sulfides or formation of mattes
    • C22B5/16Dry methods smelting of sulfides or formation of mattes with volatilisation or condensation of the metal being produced
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/36Accumulators not provided for in groups H01M10/05-H01M10/34
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/04Processes of manufacture in general
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/04Processes of manufacture in general
    • H01M4/0471Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/04Processes of manufacture in general
    • H01M4/0473Filling tube-or pockets type electrodes; Applying active mass in cup-shaped terminals
    • H01M4/0476Filling tube-or pockets type electrodes; Applying active mass in cup-shaped terminals with molten material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2219/00002Chemical plants
    • B01J2219/00027Process aspects
    • B01J2219/0004Processes in series
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00074Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00076Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
    • B01J2219/00083Coils
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J6/00Heat treatments such as Calcining; Fusing ; Pyrolysis
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    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/04Extraction of metal compounds from ores or concentrates by wet processes by leaching
    • C22B3/06Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
    • C22B3/065Nitric acids or salts thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • General Chemical & Material Sciences (AREA)
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  • Environmental & Geological Engineering (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Agronomy & Crop Science (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Manufacture And Refinement Of Metals (AREA)
CN201980090674.6A 2018-11-29 2019-11-29 锂化学品和金属锂的制备 Withdrawn CN113365947A (zh)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN202410589557.7A CN118811837A (zh) 2018-11-29 2019-11-29 锂化学品和金属锂的制备
CN202410589556.2A CN118811836A (zh) 2018-11-29 2019-11-29 锂化学品和金属锂的制备

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
AU2018904540 2018-11-29
AU2018904540A AU2018904540A0 (en) 2018-11-29 Production of lithium chemicals and metallic lithium
PCT/AU2019/051308 WO2020107074A1 (en) 2018-11-29 2019-11-29 Production of lithium chemicals and metallic lithium

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CN202410589556.2A Division CN118811836A (zh) 2018-11-29 2019-11-29 锂化学品和金属锂的制备
CN202410589557.7A Division CN118811837A (zh) 2018-11-29 2019-11-29 锂化学品和金属锂的制备

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CN113365947A true CN113365947A (zh) 2021-09-07

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CN201980090674.6A Withdrawn CN113365947A (zh) 2018-11-29 2019-11-29 锂化学品和金属锂的制备
CN202410589557.7A Pending CN118811837A (zh) 2018-11-29 2019-11-29 锂化学品和金属锂的制备
CN202410589556.2A Pending CN118811836A (zh) 2018-11-29 2019-11-29 锂化学品和金属锂的制备

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CN202410589556.2A Pending CN118811836A (zh) 2018-11-29 2019-11-29 锂化学品和金属锂的制备

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US (6) US12415733B2 (https=)
EP (1) EP3887315A4 (https=)
JP (2) JP7621949B2 (https=)
KR (1) KR20260007633A (https=)
CN (3) CN113365947A (https=)
AU (3) AU2019390253B2 (https=)
CA (2) CA3201685C (https=)
CL (2) CL2021001400A1 (https=)
WO (1) WO2020107074A1 (https=)
ZA (1) ZA202104358B (https=)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115784274A (zh) * 2022-11-02 2023-03-14 四川顺应锂材料科技有限公司 一种硝酸铝溶液中微量锂的分离回收方法
CN117821748A (zh) * 2022-03-02 2024-04-05 胡波 电热还原法一步提锂工艺

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CN111097920B (zh) * 2020-01-03 2021-02-02 四川万邦胜辉新能源科技有限公司 一种气态共冷凝法生产镁锂合金的方法
CN112522525B (zh) * 2020-12-01 2022-10-18 四川轻化工大学 金属锂渣料连续水解装置及水解方法
CN113387374B (zh) * 2021-06-28 2023-06-16 四川能投鼎盛锂业有限公司 一种矿石提锂生产系统除钾工艺
CN119528181A (zh) 2022-01-17 2025-02-28 Icsip私人有限公司 用于锂生产的方法和系统
CN115305351B (zh) * 2022-07-18 2023-07-21 中南大学 一种强化提钒尾渣还原挥发脱除碱金属的方法
US20240068070A1 (en) * 2022-08-23 2024-02-29 Clean Energy Systems, Inc. Lithium extraction with an oxy-fuel combustor
US12091727B2 (en) 2022-09-30 2024-09-17 James G. Blencoe Process for extracting lithium, aluminum, and silicon materials from a hard rock source
US20240228310A1 (en) * 2023-01-06 2024-07-11 Lithium Nevada Corporation Magnesium removal process
WO2024178460A1 (en) * 2023-02-27 2024-09-06 ICSIP Pty Ltd Lithium recovery from sedimentary silicates
WO2026039136A1 (en) * 2024-08-13 2026-02-19 Massachusetts Institute Of Technology Oxygen-containing lithium compounds and methods of production and uses thereof

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