CN113234261B - 含有4-乙氧基苯酚的矿用工程轮胎胎面胶及其制备方法 - Google Patents
含有4-乙氧基苯酚的矿用工程轮胎胎面胶及其制备方法 Download PDFInfo
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- CN113234261B CN113234261B CN202110608881.5A CN202110608881A CN113234261B CN 113234261 B CN113234261 B CN 113234261B CN 202110608881 A CN202110608881 A CN 202110608881A CN 113234261 B CN113234261 B CN 113234261B
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 74
- 239000005060 rubber Substances 0.000 title claims abstract description 74
- LKVFCSWBKOVHAH-UHFFFAOYSA-N 4-Ethoxyphenol Chemical compound CCOC1=CC=C(O)C=C1 LKVFCSWBKOVHAH-UHFFFAOYSA-N 0.000 title claims abstract description 62
- 238000005065 mining Methods 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000006229 carbon black Substances 0.000 claims abstract description 42
- 229920005989 resin Polymers 0.000 claims abstract description 28
- 239000011347 resin Substances 0.000 claims abstract description 28
- 244000043261 Hevea brasiliensis Species 0.000 claims abstract description 21
- 229920003052 natural elastomer Polymers 0.000 claims abstract description 21
- 229920001194 natural rubber Polymers 0.000 claims abstract description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 14
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 14
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 11
- 235000019808 microcrystalline wax Nutrition 0.000 claims abstract description 11
- 239000004200 microcrystalline wax Substances 0.000 claims abstract description 11
- 229920003048 styrene butadiene rubber Polymers 0.000 claims abstract description 8
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 7
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 7
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000008117 stearic acid Substances 0.000 claims abstract description 7
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 7
- 239000011593 sulfur Substances 0.000 claims abstract description 7
- 239000011787 zinc oxide Substances 0.000 claims abstract description 7
- 239000000839 emulsion Substances 0.000 claims abstract description 5
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 claims abstract description 3
- ODUCDPQEXGNKDN-UHFFFAOYSA-N nitroxyl Chemical compound O=N ODUCDPQEXGNKDN-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 27
- 238000002156 mixing Methods 0.000 claims description 27
- 238000003825 pressing Methods 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 15
- 238000007599 discharging Methods 0.000 claims description 13
- 238000001816 cooling Methods 0.000 claims description 9
- 238000007670 refining Methods 0.000 claims description 8
- 235000014692 zinc oxide Nutrition 0.000 claims description 4
- 239000004014 plasticizer Substances 0.000 claims description 3
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 claims description 2
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 230000002902 bimodal effect Effects 0.000 claims description 2
- PBRIXADXGMHVMW-UHFFFAOYSA-N formaldehyde;4-(2,4,4-trimethylpentan-2-yl)phenol Chemical compound O=C.CC(C)(C)CC(C)(C)C1=CC=C(O)C=C1 PBRIXADXGMHVMW-UHFFFAOYSA-N 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- DEQZTKGFXNUBJL-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)cyclohexanamine Chemical compound C1CCCCC1NSC1=NC2=CC=CC=C2S1 DEQZTKGFXNUBJL-UHFFFAOYSA-N 0.000 claims description 2
- 229920001568 phenolic resin Polymers 0.000 claims description 2
- 239000005011 phenolic resin Substances 0.000 claims description 2
- -1 polycyclic hydrocarbon Chemical class 0.000 claims description 2
- 229940124530 sulfonamide Drugs 0.000 claims 1
- 125000000565 sulfonamide group Chemical group 0.000 claims 1
- 230000020169 heat generation Effects 0.000 abstract description 8
- 238000005520 cutting process Methods 0.000 abstract description 7
- 239000006057 Non-nutritive feed additive Substances 0.000 abstract description 6
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 13
- 238000000034 method Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000003292 glue Substances 0.000 description 4
- 238000010058 rubber compounding Methods 0.000 description 4
- 230000035882 stress Effects 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 241000208125 Nicotiana Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 229910001294 Reinforcing steel Inorganic materials 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000003172 aldehyde group Chemical group 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000010117 shenhua Substances 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical group [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/80—Technologies aiming to reduce greenhouse gasses emissions common to all road transportation technologies
- Y02T10/86—Optimisation of rolling resistance, e.g. weight reduction
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
物性测试项目 | 实施例1 | 实施例2 | 实施例3 | 实施例4 | 对比例1 |
门尼粘度/ML | 64 | 65 | 63 | 64 | 64 |
拉伸强度/MPa | 24.5 | 25.2 | 25.7 | 25.3 | 24.3 |
100%定伸应力/MPa | 2.7 | 2.6 | 2.8 | 2.7 | 2.6 |
300%定伸应力/MPa | 13.2 | 13.5 | 13.8 | 13.6 | 12.4 |
扯断伸长率/% | 612 | 603 | 587 | 596 | 580 |
邵氏硬度A/度 | 67 | 68 | 68 | 68 | 67 |
撕裂强度KN/m | 90 | 92 | 92 | 96 | 86 |
磨耗/cm<sup>3</sup>/1.61km | 0.110 | 0.112 | 0.107 | 0.105 | 0.116 |
切割减量/g | 0.22 | 0.18 | 0.16 | 0.13 | 0.25 |
最终疲劳温升/℃ | 33 | 32 | 30 | 27 | 36 |
永久变形/% | 12 | 14 | 15 | 17 | 12 |
60℃Tanδ | 0.1348 | 0.1225 | 0.1187 | 0.1040 | 0.1437 |
老化保持率/% | 60 | 62 | 64 | 65 | 58 |
Claims (8)
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CN202110608881.5A CN113234261B (zh) | 2021-06-01 | 2021-06-01 | 含有4-乙氧基苯酚的矿用工程轮胎胎面胶及其制备方法 |
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CN202110608881.5A CN113234261B (zh) | 2021-06-01 | 2021-06-01 | 含有4-乙氧基苯酚的矿用工程轮胎胎面胶及其制备方法 |
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CN113234261A CN113234261A (zh) | 2021-08-10 |
CN113234261B true CN113234261B (zh) | 2022-07-12 |
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CN114316401B (zh) * | 2022-01-14 | 2023-09-22 | 泰凯英(青岛)专用轮胎技术研究开发有限公司 | 抗切割低生热的矿用工程轮胎胎面胶及其制备方法 |
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Publication number | Priority date | Publication date | Assignee | Title |
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NL94196C (zh) * | 1954-06-04 | |||
JPS6022026B2 (ja) * | 1981-04-10 | 1985-05-30 | 株式会社ブリヂストン | 接着剤処理ポリエステル繊維材料の製造方法 |
BRPI0604797A (pt) * | 2005-11-30 | 2007-10-09 | Goodyear Tire & Rubber | polìmeros de borracha funcionalizados |
KR102055471B1 (ko) * | 2012-07-30 | 2019-12-12 | 우베 고산 가부시키가이샤 | 변성 시스-1,4-폴리뷰타다이엔 및 그 제조 방법 |
CN109439178A (zh) * | 2018-11-15 | 2019-03-08 | 段瑶瑶 | 一种减摩水性聚氨酯涂料的制备方法 |
CN111721192B (zh) * | 2020-06-30 | 2020-12-29 | 暨南大学 | 一种基于图形化诱导裂纹的应变传感器及其制备方法 |
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Address after: 266061, 9th and 10th floors, Building 2, No. 6 Keyuan Jingsan Road, Laoshan District, Qingdao City, Shandong Province Patentee after: Taikaiying (Qingdao) special tire technology research and Development Co.,Ltd. Country or region after: China Address before: 266000 room 1901, building 2, Tianbao international business center, 61 Haier Road, Laoshan District, Qingdao City, Shandong Province Patentee before: Taikaiying (Qingdao) special tire technology research and Development Co.,Ltd. Country or region before: China |