CN113149124B - Water mineralized rock composition and application thereof - Google Patents
Water mineralized rock composition and application thereof Download PDFInfo
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- CN113149124B CN113149124B CN202110371840.9A CN202110371840A CN113149124B CN 113149124 B CN113149124 B CN 113149124B CN 202110371840 A CN202110371840 A CN 202110371840A CN 113149124 B CN113149124 B CN 113149124B
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/23—Sulfur; Selenium; Tellurium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/27—Zinc; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/965—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of inanimate origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
Abstract
The invention provides a water mineralized rock combination and application thereof, wherein the water mineralized rock combination comprises at least two rocks; in the water mineralization rock combination, any dissolved harmful element is adsorbed by at least one other rock except any rock in the water mineralization rock combination; through the collocation of different proportions of different kinds of natural rocks, the effect of heavy metal adsorption is formed, the heavy metal elements in the dissolved elements can be ensured to reach the standard, the dissolution of beneficial elements is promoted, and the method can be widely applied to the fields of cosmetology, skin care, bath and the like.
Description
Technical Field
The invention relates to the technical field of water mineralization, in particular to a water mineralization rock composition and application thereof.
Background
The existing domestic water heater in the industry has no obvious health efficacy except cleaning. In addition, due to the existing tap water treatment process, substances such as residual chlorine, impurities and the like which are unfavorable for human health are still contained in the tap water, and can be absorbed by skin during bath, so that the human health is influenced. Various skin care products exist in the market at present, but the skin dermal cells have low absorption efficiency on chemical elements, have strict requirements on absorption substances, damage skin health if improper selection is performed, reduce the activity of the dermal cells, even kill the cells directly, the skin care and improvement effects cannot be achieved if the content is small, and the chemical elements are deposited on the surface layer of the skin if the content is too high, so that the skin is chronically poisoned.
Currently, in the bath appliance industry, various extracted salts or organic compositions are used to increase the beneficial elements and minerals in water. However, when the product is used, the requirements on the water environment are severe, such as vitamin C showers, the vitamin C showers can fail in a high-temperature environment, and in addition, the use amount needs to be paid attention, such as various bath salts on the market, when the product is used excessively, the content of chemical element salts in water exceeds the acceptable degree of human body, and the chemical element salts can be deposited on the skin surface to cause chronic poisoning.
The natural rock can release chemical elements and minerals to mineralize water and improve the mineralization degree of raw water. The chemical elements which can be dissolved out of different natural rocks are different, and each natural rock contains beneficial chemistry required by human bodies and a plurality of heavy metal elements such as lead, cadmium, mercury and the like in the corresponding chemical element spectrum. The unreasonable collocation can cause the excessive heavy metal element in the water.
For example, hot spring bathing, which is currently popular, relies mainly on natural environment mineralized spring water, which has a high content of beneficial elements and minerals. The skin can be cleaned, meanwhile, skin cells of a human body can be activated and stimulated, one part of beneficial elements and minerals contained in the water can permeate into skin cuticle cells and then reach dermis through other layers of the epidermis to be absorbed, and the other part of the beneficial elements and minerals can be absorbed by hair follicles, sebaceous glands and sweat gland ducts to play a role in regulating physiological health in the human body. The hot spring resources are rare, the consumption is expensive, and the hot spring cannot be widely popularized and used. At present, people mostly clean the clothes at home by means of showering and bathing. When the water quality of the water outlet of the water heater is similar to that of the hot spring water, people can obtain the bath effect of the hot spring water at home, and the water heater is convenient and quick.
However, the commonly accepted mineralization treatment technology of natural rock is limited by the difference of dissolved elements of the natural rock and has the defects of a plurality of heavy metal elements such as lead, cadmium, mercury and the like.
Therefore, the development of the water mineralized rock which has low leaching amount of heavy metals and is harmless to human bodies is very critical to the application of the water mineralized rock in the fields of bath, skin care and the like.
Disclosure of Invention
In view of the problems existing in the prior art, the invention provides a water mineralized rock combination and application thereof, wherein the water mineralized rock combination utilizes the different absorption and adhesion efficiencies of natural rocks to various heavy metal elements and the dissolution influence among chemical elements to mutually match various natural rocks so as to form a heavy metal adsorption chain, and the natural rocks are cooperatively allocated to ensure that the natural rocks dissolve enough beneficial elements and adsorb harmful heavy metal elements, so that the water mineralized rock combination can be widely applied to the fields of cosmetology, skin care, bath and the like.
To achieve the purpose, the invention adopts the following technical scheme:
in a first aspect, the present invention provides a water mineralization rock combination comprising at least two rocks; in the water mineralization rock combination, any dissolved harmful element is adsorbed by at least one other rock except any rock in the water mineralization rock combination.
The rock in the water mineralized rock combination provided by the invention contains beneficial mineral elements, and dissolved harmful elements in any rock can be adsorbed by at least one other rock, so that the dissolved heavy metal elements in the water mineralized rock combination can reach the standard, different kinds of rocks are utilized to adsorb and attach different efficiencies on the heavy metal elements, and the dissolution of various beneficial trace elements and mineral substances is realized through specific proportion collocation, and the dissolution of the harmful elements is inhibited, so that the water mineralized rock combination has a wide application prospect. The water mineralized rock composition is not added with an adsorbent, and the adsorbent is not required to be added when the water mineralized rock composition is applied. The rock adopted by the invention has smaller adsorptivity of autogenous water body impurities, and more prominently, the rock self-component dissolves out and diffuses. If the water-based composite material is mixed with an adsorbent for use, a certain dirt layer can be generated around the rock due to long-term impurity adsorption, and the problem of bacterial growth can occur.
Preferably, the deleterious elements include any one or a combination of at least two of cadmium, chromium, lead, mercury, arsenic, manganese, copper, silver, nickel or selenium, wherein typical non-limiting combinations are combinations of cadmium and chromium, combinations of cadmium and mercury, combinations of cadmium and arsenic, combinations of chromium and mercury, combinations of chromium and arsenic, combinations of mercury and arsenic, combinations of arsenic and copper, combinations of copper and silver, and combinations of silver and nickel.
Preferably, the rock contains beneficial elements.
Preferably, the beneficial elements include any one or a combination of at least two of potassium, calcium, sodium, magnesium, zinc, strontium, or metasilicic acid, wherein typical non-limiting combinations are combinations of potassium and calcium, combinations of potassium and strontium, combinations of calcium and metasilicic acid, combinations of sodium and magnesium, combinations of zinc and strontium, combinations of metasilicic acid and potassium, and combinations of metasilicic acid and strontium.
Preferably, the water mineralized rock composition comprises, by mass, 6-10 parts of dolomite, 6-8 parts of celestite, 3-4 parts of magnesite, 2-3 parts of medical stone, 1-2 parts of zeolite, 3-4 parts of stone needle and 1-2 parts of calcite.
The combination of the mineralized rock of the water body can ensure that the leaching amount of heavy metals reaches the standard, and can comprehensively leach elements such as sodium, calcium, magnesium, zinc, strontium, metasilicic acid and the like, and has various effects. In the combination, zeolite can enhance the absorption of toxic metal elements and the accumulation of water impurities, improve the silicon content in water, enable dolomite to provide main elements including calcium, magnesium and strontium, enable celestite to provide strontium elements with more components, enable magnesite to provide zinc elements with more components, enable medical stone to provide main elements including silicon, potassium and magnesium, enable stone needle to activate water, provide elements including calcium, sodium and the like, enable calcite to provide main elements including calcium, magnesium and strontium, enable all the components to cooperate with each other, promote the dissolution of beneficial elements and effectively inhibit the dissolution of heavy metals.
First combination of water mineralized rock combinations in the present invention:
the dolomite may be 6 to 10 parts, for example, 6 parts, 6.5 parts, 6.9 parts, 7.4 parts, 7.8 parts, 8.3 parts, 8.7 parts, 9.2 parts, 9.6 parts or 10 parts, etc., but the present invention is not limited to the above-mentioned values, and other values not mentioned in the above range are equally applicable.
The celestite may be 6 to 8 parts, for example, 6 parts, 6.3 parts, 6.5 parts, 6.7 parts, 6.9 parts, 7.2 parts, 7.4 parts, 7.6 parts, 7.8 parts or 8 parts, etc., but the present invention is not limited to the values recited, and other values not recited in the range are equally applicable.
The zinc oxide ore 3 to 4 parts may be, for example, 3 parts, 3.2 parts, 3.3 parts, 3.4 parts, 3.5 parts, 3.6 parts, 3.7 parts, 3.8 parts, 3.9 parts, or 4 parts, but is not limited to the listed values, and other non-listed values within this range are equally applicable.
The medical stone 2 to 3 parts may be, for example, 2 parts, 2.2 parts, 2.3 parts, 2.4 parts, 2.5 parts, 2.6 parts, 2.7 parts, 2.8 parts, 2.9 parts or 3 parts, etc., but are not limited to the listed values, and other non-listed values within the range are equally applicable.
The zeolite 1 to 2 parts may be, for example, 1 part, 1.2 parts, 1.3 parts, 1.4 parts, 1.5 parts, 1.6 parts, 1.7 parts, 1.8 parts, 1.9 parts, or 2 parts, etc., but are not limited to the recited values, and other non-recited values within the range are equally applicable.
The stone needle 3 to 4 parts may be, for example, 3 parts, 3.2 parts, 3.3 parts, 3.4 parts, 3.5 parts, 3.6 parts, 3.7 parts, 3.8 parts, 3.9 parts or 4 parts, etc., but are not limited to the recited values, and other non-recited values within this range are equally applicable.
The calcite may be 1 to 2 parts, for example, 1 part, 1.2 parts, 1.3 parts, 1.4 parts, 1.5 parts, 1.6 parts, 1.7 parts, 1.8 parts, 1.9 parts, or 2 parts, but the present invention is not limited to the values recited therein, and other values not recited therein are equally applicable.
Preferably, the water mineralized rock composition comprises 8-10 parts by weight of dolomite, 6-8 parts by weight of celestite, 2-3 parts by weight of medical stone, 1-2 parts by weight of zeolite and 1-2 parts by weight of stone needle.
The combination of the mineralized rock of the water body is optionally the second combination, and the combination can ensure that the leaching amount of heavy metals reaches the standard, can leach more strontium elements, and can be effectively applied to the fields of antioxidation, aging resistance or beauty maintenance, etc. In the combination, the zeolite can enhance the absorption of toxic metal elements and the accumulation of impurities in water, improve the silicon content in water, enable dolomite to provide main elements including calcium, magnesium and strontium, enable celestite to provide strontium elements with more components, enable medical stone to provide main elements including silicon, potassium and magnesium, enable stone needle to activate the water, provide elements including calcium, sodium and the like, enable the components to cooperate with each other, promote the dissolution of beneficial elements and effectively inhibit the dissolution of heavy metals.
The second combination of the water mineralized rock combination of the present invention:
the dolomite may be 8 to 10 parts, for example, 8 parts, 8.3 parts, 8.5 parts, 8.7 parts, 8.9 parts, 9.2 parts, 9.4 parts, 9.6 parts, 9.8 parts or 10 parts, etc., but the present invention is not limited to the above-mentioned values, and other values not mentioned in the above range are equally applicable.
The celestite may be 6 to 8 parts, for example, 6 parts, 6.3 parts, 6.5 parts, 6.7 parts, 6.9 parts, 7.2 parts, 7.4 parts, 7.6 parts, 7.8 parts or 8 parts, etc., but the present invention is not limited to the values recited, and other values not recited in the range are equally applicable.
The medical stone 2 to 3 parts may be, for example, 2 parts, 2.2 parts, 2.3 parts, 2.4 parts, 2.5 parts, 2.6 parts, 2.7 parts, 2.8 parts, 2.9 parts or 3 parts, etc., but are not limited to the listed values, and other non-listed values within the range are equally applicable.
The zeolite 1 to 2 parts may be, for example, 1 part, 1.2 parts, 1.3 parts, 1.4 parts, 1.5 parts, 1.6 parts, 1.7 parts, 1.8 parts, 1.9 parts, or 2 parts, etc., but are not limited to the recited values, and other non-recited values within the range are equally applicable.
The stone needle may be 1 to 2 parts, for example, 1 part, 1.2 parts, 1.3 parts, 1.4 parts, 1.5 parts, 1.6 parts, 1.7 parts, 1.8 parts, 1.9 parts or 2 parts, etc., but is not limited to the recited values, and other non-recited values within this range are equally applicable.
Preferably, the water mineralized rock composition has a dissolved strontium content of greater than or equal to 300. Mu.g/L, such as 300. Mu.g/L, 320. Mu.g/L, 345. Mu.g/L, 360. Mu.g/L, 380. Mu.g/L, 410. Mu.g/L, 430. Mu.g/L, 450. Mu.g/L, 470. Mu.g/L, 500. Mu.g/L, etc., but is not limited to the recited values, as other non-recited values within this range are equally applicable.
Preferably, the water mineralized rock composition comprises, by mass, 4-6 parts of dolomite, 8-10 parts of rhombohedral zinc ores, 6-8 parts of calamine, 2-3 parts of medical stones and 2-3 parts of zeolite.
The combination of the mineralized rock of the water body is optionally the fourth combination, and the combination can ensure that the leaching amount of the heavy metal reaches the standard, can dissolve more zinc, and can be effectively applied to the fields of antioxidation, aging resistance, beauty maintenance and the like. In the combination, the water chestnut zinc ore can provide more zinc elements, the calamine can provide more zinc elements, the zeolite can enhance the absorption of toxic metal elements and the accumulation of water impurities, and improve the silicon content in water, the dolomite can provide main elements including calcium, magnesium and strontium, the medical stone can provide main elements including silicon, potassium and magnesium, and the components are mutually cooperated, so that the dissolution of beneficial elements is promoted, and the dissolution of heavy metals can be effectively inhibited.
Third combination of water mineralized rock combinations in the present invention:
the dolomite may be 4 to 6 parts, for example, 4 parts, 4.3 parts, 4.5 parts, 4.7 parts, 4.9 parts, 5.2 parts, 5.4 parts, 5.6 parts, 5.8 parts or 6 parts, etc., but the present invention is not limited to the above-mentioned values, and other values not mentioned in the above range are equally applicable.
8 to 10 parts of the zinc oxide ore may be, for example, 8 parts, 8.3 parts, 8.5 parts, 8.7 parts, 8.9 parts, 9.2 parts, 9.4 parts, 9.6 parts, 9.8 parts or 10 parts, etc., but the present invention is not limited to the listed values, and other values not listed in the range are equally applicable.
The calamine may be 6 to 8 parts, for example, 6 parts, 6.3 parts, 6.5 parts, 6.7 parts, 6.9 parts, 7.2 parts, 7.4 parts, 7.6 parts, 7.8 parts, or 8 parts, etc., but the present invention is not limited to the recited values, and other values not recited in the range are equally applicable.
The medical stone 2 to 3 parts may be, for example, 2 parts, 2.2 parts, 2.3 parts, 2.4 parts, 2.5 parts, 2.6 parts, 2.7 parts, 2.8 parts, 2.9 parts or 3 parts, etc., but are not limited to the listed values, and other non-listed values within the range are equally applicable.
The zeolite 2 to 3 parts may be, for example, 2 parts, 2.2 parts, 2.3 parts, 2.4 parts, 2.5 parts, 2.6 parts, 2.7 parts, 2.8 parts, 2.9 parts or 3 parts, etc., but are not limited to the recited values, and other non-recited values within the range are equally applicable.
Preferably, the water mineralized rock composition has a dissolved zinc content of greater than or equal to 300. Mu.g/L, such as 300. Mu.g/L, 320. Mu.g/L, 345. Mu.g/L, 360. Mu.g/L, 380. Mu.g/L, 410. Mu.g/L, 430. Mu.g/L, 450. Mu.g/L, 470. Mu.g/L, 500. Mu.g/L, etc., but is not limited to the recited values, as other non-recited values within this range are equally applicable.
Preferably, the water mineralized rock composition comprises, by mass, 4-6 parts of dolomite, 3-5 parts of rhombohedral mineral, 8-10 parts of granite, 6-8 parts of medical stone, 2-3 parts of zeolite and 1-2 parts of calcite.
The combination of the mineralized rock of the water body is optionally the fourth combination, and the combination can ensure that the leaching amount of heavy metals reaches the standard, and more metasilicic acid can be leached, so that the combination can be effectively applied to the fields of activating cell activity, increasing skin elasticity and the like. In the combination, the magnesite can provide more zinc elements, the granite can provide main elements including calcium, magnesium and strontium, the zeolite can enhance the absorption of toxic metal elements and the accumulation of water impurities, the silicon content in water is improved, the dolomite can provide main elements including calcium, magnesium and strontium, the medical stone can provide main elements including silicon, potassium and magnesium, the calcite can provide main elements including calcium, magnesium and strontium, the components cooperate with each other, the dissolution of beneficial elements is promoted, and the dissolution of heavy metals can be effectively inhibited.
Fourth combination of water mineralized rock combinations in the present invention:
the dolomite may be 4 to 6 parts, for example, 4 parts, 4.3 parts, 4.5 parts, 4.7 parts, 4.9 parts, 5.2 parts, 5.4 parts, 5.6 parts, 5.8 parts or 6 parts, etc., but the present invention is not limited to the above-mentioned values, and other values not mentioned in the above range are equally applicable.
The zinc oxide ore may be 3 to 5 parts, for example, 3 parts, 3.3 parts, 3.5 parts, 3.7 parts, 3.9 parts, 4.2 parts, 4.4 parts, 4.6 parts, 4.8 parts, or 5 parts, but is not limited to the listed values, and other non-listed values within this range are equally applicable.
The granite 8 to 10 parts may be, for example, 8 parts, 8.3 parts, 8.5 parts, 8.7 parts, 8.9 parts, 9.2 parts, 9.4 parts, 9.6 parts, 9.8 parts or 10 parts, etc., but are not limited to the recited values, and other non-recited values within the range are equally applicable.
The medical stone 6 to 8 parts may be, for example, 6 parts, 6.3 parts, 6.5 parts, 6.7 parts, 6.9 parts, 7.2 parts, 7.4 parts, 7.6 parts, 7.8 parts or 8 parts, etc., but are not limited to the recited values, and other non-recited values within the range are equally applicable.
The zeolite 2 to 3 parts may be, for example, 2 parts, 2.2 parts, 2.3 parts, 2.4 parts, 2.5 parts, 2.6 parts, 2.7 parts, 2.8 parts, 2.9 parts or 3 parts, etc., but are not limited to the recited values, and other non-recited values within the range are equally applicable.
The calcite may be 1 to 2 parts, for example, 1 part, 1.2 parts, 1.3 parts, 1.4 parts, 1.5 parts, 1.6 parts, 1.7 parts, 1.8 parts, 1.9 parts, or 2 parts, but the present invention is not limited to the values recited therein, and other values not recited therein are equally applicable.
Preferably, the water mineralized rock composition has a dissolved metasilicic acid content of ∈250. Mu.g/L, such as, but not limited to, 250. Mu.g/L, 300. Mu.g/L, 350. Mu.g/L, 400. Mu.g/L, 450. Mu.g/L, 500. Mu.g/L, 520. Mu.g/L, 545. Mu.g/L, 560. Mu.g/L, 580. Mu.g/L, 610. Mu.g/L, 630. Mu.g/L, 650. Mu.g/L, 670. Mu.g/L, or 700. Mu.g/L, etc., as well as other non-enumerated values within this range.
In a second aspect, the present invention provides the use of a water mineralized rock composition according to the first aspect in water treatment, bathing, skin care and cosmetology.
The mineralized rock composition for water body provided by the invention has low heavy metal content during dissolution, accords with national standards, can dissolve more mineral substances and beneficial microelements, can be widely applied to water treatment, bath, skin care and cosmetology, and has the advantages of high temperature resistance, slow release, high microelement content, multiple applicable scenes and the like.
Compared with the prior art, the invention has at least the following beneficial effects:
(1) The water mineralized rock composition provided by the invention utilizes the fact that the absorption and attachment efficiencies of natural rocks to each heavy metal element are different, and the various rocks are mutually allocated, so that not only can the natural rocks dissolve enough beneficial elements be ensured, but also the heavy metal elements can be ensured to reach the standard;
(2) The water mineralized rock composition provided by the invention has different effects when different proportions are adopted, and can be suitable for different application occasions;
(3) The water mineralized rock composition provided by the invention can be widely applied to the fields of water treatment, bath, skin care, cosmetology and the like, and solves the problem of heavy metal leaching of the existing natural rock.
Detailed Description
To facilitate understanding of the present invention, examples are set forth below. It will be apparent to those skilled in the art that the examples are merely to aid in understanding the invention and are not to be construed as a specific limitation thereof.
1. Examples
Example 1-1
The embodiment provides a water mineralization rock combination, which is as follows: 100g of dolomite, 800g of celestite, 40g of siderite, 30g of medical stone, 20g of zeolite, 40g of stone needle and 20g of calcite.
Examples 1 to 2
The embodiment provides a water mineralization rock combination, which is as follows: 60g of dolomite, 70g of celestite, 35g of magnesite, 20g of medical stone, 10g of zeolite, 35g of stone needle and 15g of calcite.
Examples 1 to 3
The embodiment provides a water mineralization rock combination, which is as follows: 80g of dolomite, 60g of celestite, 30g of siderite, 25g of medical stone, 15g of zeolite, 30g of stone needle and 10g of calcite.
Example 2-1
The embodiment provides a water mineralization rock combination, which is as follows: 100g of dolomite, 80g of celestite, 30g of medical stone, 20g of zeolite and 20g of stone needle.
Example 2-2
The embodiment provides a water mineralization rock combination, which is as follows: 80g of dolomite, 60g of celestite, 20g of medical stone, 10g of zeolite and 10g of stone needle.
Examples 2 to 3
The embodiment provides a water mineralization rock combination, which is as follows: 90g of dolomite, 70g of celestite, 25g of medical stone, 18g of zeolite and 12g of stone needle.
Example 3-1
The embodiment provides a water mineralization rock combination, which is as follows: 60g of dolomite, 100g of magnesite, 80g of calamine, 30g of medical stone and 30g of zeolite.
Example 3-2
The embodiment provides a water mineralization rock combination, which is as follows: 40g of dolomite, 90g of calamine, 70g of calamine, 25g of medical stone and 22g of zeolite.
Examples 3 to 3
The embodiment provides a water mineralization rock combination, which is as follows: 52g of dolomite, 80g of magnesite, 60g of calamine, 20g of medical stone and 20g of zeolite.
Example 4-1
The embodiment provides a water mineralization rock combination, which is as follows: 60g of dolomite, 50g of rhombohedral zinc ore, 100g of granite, 80g of medical stone, 30g of zeolite and 20g of calcite.
Example 4-2
The embodiment provides a water mineralization rock combination, which is as follows: 40g of dolomite, 42g of magnesite, 80g of granite, 68g of medical stone, 20g of zeolite and 13g of calcite.
Examples 4 to 3
The embodiment provides a water mineralization rock combination, which is as follows: 50g of dolomite, 30g of rhombohedral zinc ore, 86g of granite, 60g of medical stone, 24g of zeolite and 10g of calcite.
2. Comparative example
Comparative examples 1 to 1
This comparative example provides a water mineralized rock composition, which is the same as example 1-1 except for 5g of the rhombohedral zinc ore.
Comparative examples 1 to 2
This comparative example provides a water mineralized rock composition, which is identical to example 1-1, except for 60g of the rhombohedral zinc ore.
Comparative examples 1 to 3
This comparative example provides a water mineralized rock composition, which is the same as example 1-1 except that the stone needle is 2g.
Comparative examples 1 to 4
This comparative example provides a water mineralized rock composition, which is identical to example 1-1 except that the stone needle is 60 g.
Comparative example 2-1
This comparative example provides a water mineralized rock composition, which is identical to example 2-1, except that it does not contain zeolite.
Comparative examples 2 to 2
This comparative example provides a water mineralized rock composition, which is the same as example 2-1 except that the medical stone is 5g.
Comparative examples 2 to 3
This comparative example provides a water mineralized rock composition, which is the same as example 2-1 except that the medical stone is 50 g.
Comparative examples 2 to 4
This comparative example provides a water mineralized rock composition, which is the same as example 2-1 except that the stone needle is 40 g.
Comparative example 3-1
This comparative example provides a water mineralized rock composition, which is the same as example 3-1 except for 40g of calamine.
Comparative example 3-2
This comparative example provides a water mineralized rock composition, which is identical to example 3-1, except that the calamine is 120 g.
Comparative examples 3 to 3
This comparative example provides a water mineralized rock composition, which is identical to example 3-1 except for 40g of the rhombohedral zinc ore.
Comparative example 4-1
This comparative example provides a water mineralized rock composition, which is the same as example 4-1 except that the medical stone is 40 g.
Comparative example 4-2
This comparative example provides a water mineralized rock composition, which is identical to example 4-1 except that the medical stone is 120 g.
Comparative examples 4 to 3
This comparative example provides a water mineralized rock composition, which is identical to example 4-1, except that it does not contain granite.
Comparative examples 4 to 4
This comparative example provides a water mineralized rock composition, which is identical to example 4-1, except that the granite is 130 g.
The main composition or sources of each rock in the above examples and comparative examples are as follows:
dolomite rock: guangxi Bama; celestite: shandong Jiaxiang; rhombohedral zinc ore: liking in Shanxi province; medical stone: xinjiang Tianshan; zeolite: zhejiang four Mingshan; stone needle): sibing in Shandong; calcite: guangxi Bama; calamine: calamine; granite: laoshan mountain
3. Testing and results
100g of mineralized materials mixed uniformly are taken from the mineralized rock combinations of the water bodies with different proportions in the examples and the comparative examples, added into 3L of purified water, heated to 75 ℃ by a water bath pot, stirred for 1min by a glass rod, and kept stand for soaking for 3h, and the leaching amount of elements in the leaching water is tested, wherein the leaching amount of heavy metal elements is shown in a table 1 (unit: mug/L).
TABLE 1
From table 1, the following points can be seen:
(1) According to comprehensive embodiments, the leaching of harmful elements can be inhibited by compounding different combinations, the leaching amount of each harmful element is balanced to be at a reasonable level, under the test conditions of 100g/3L purified water and 75 ℃ soaking for 3 hours, the leaching amount of cadmium is less than or equal to 0.36 mu g/L, the leaching amount of chromium is less than or equal to 0.21 mu g/L, the leaching amount of lead is less than or equal to 1.90 mu g/L, the leaching amount of mercury is less than or equal to 0.05 mu g/L, the leaching amount of arsenic is less than or equal to 0.12 mu g/L, the leaching amount of manganese is less than or equal to 0.96 mu g/L, the leaching amount of copper is less than or equal to 0.21 mu g/L, the leaching amount of silver is less than or equal to 0.08 mu g/L, the leaching amount of nickel is less than or equal to 0.22 mu g/L, the leaching amount of selenium is less than or equal to 0.12 mu g/L, and the requirements of water quality, skin care, bathing and other fields can be well met;
(2) It can be seen from the combination of examples 1-1 to 1-3 and comparative examples 1-1 to 3 that the ratio of each component in examples 1-1 to 1-3 is within a reasonable range, the leaching of harmful elements can be inhibited, the leaching amount of each element is at a reasonable level, the leaching amount of chromium in comparative examples 1-1 and 1-3 reaches 0.38 mug/L and 0.35 mug/L, respectively, and the leaching amount of nickel in comparative examples 1-2 reaches 0.33 mug/L, thus showing that the leaching of harmful elements can be inhibited by reasonable formulation of each component.
Other examples and comparative examples can also show that the invention can form the effect of heavy metal adsorption by matching different proportions of different types of natural rocks, can ensure that the heavy metal elements in the dissolved elements reach the standard and promote the dissolution of beneficial elements.
The leaching amount of the beneficial elements is shown in Table 2 (unit: μg/L).
TABLE 2
| Element(s) | Potassium | Calcium | Sodium salt | Magnesium (Mg) | Zinc alloy | Strontium (strontium) | Metasilicic acid |
| Example 1-1 | 125 | 617 | 1271 | 129 | 193 | 172 | 357 |
| Examples 1 to 2 | 113 | 609 | 1096 | 97 | 162 | 160 | 332 |
| Examples 1 to 3 | 115 | 613 | 1220 | 99 | 189 | 159 | 331 |
| Example 2-1 | 183 | 695 | 994 | 133 | 117 | 499 | 263 |
| Example 2-2 | 175 | 669 | 921 | 126 | 109 | 415 | 250 |
| Examples 2 to 3 | 167 | 693 | 987 | 127 | 108 | 429 | 266 |
| Example 3-1 | 219 | 676 | 1200 | 154 | 411 | 158 | 293 |
| Example 3-2 | 184 | 653 | 1090 | 131 | 341 | 133 | 250 |
| Examples 3 to 3 | 197 | 641 | 1230 | 149 | 359 | 141 | 281 |
| Example 4-1 | 259 | 812 | 1301 | 251 | 210 | 290 | 690 |
| Example 4-2 | 213 | 790 | 1190 | 225 | 193 | 210 | 621 |
| Examples 4 to 3 | 220 | 789 | 1270 | 219 | 199 | 279 | 590 |
From table 2, it can be seen that the water mineralized rock composition provided by this embodiment has a higher leaching amount for beneficial elements, and can play a role in beautifying and skin care when applied to the fields of beautifying and bathing.
In conclusion, the water mineralized rock composition provided by the invention has the effect of heavy metal adsorption through the collocation of different proportions of different types of natural rocks, can ensure that the heavy metal elements in the dissolved elements reach the standard and promote the dissolution of beneficial elements, and can be widely applied to the fields of cosmetology, skin care, bath and the like.
The applicant states that the detailed process equipment and process flows of the present invention are described by the above examples, but the present invention is not limited to, i.e., does not mean that the present invention must be practiced in dependence upon, the above detailed process equipment and process flows. It should be apparent to those skilled in the art that any modification of the present invention, equivalent substitution of raw materials for the product of the present invention, addition of auxiliary components, selection of specific modes, etc., falls within the scope of the present invention and the scope of disclosure.
Claims (9)
1. A water mineralized rock assembly, characterized in that the water mineralized rock assembly comprises at least two rocks;
in the water mineralization rock combination, any dissolved harmful element is adsorbed by at least one other rock except any rock in the water mineralization rock combination; the harmful elements comprise any one or a combination of at least two of cadmium, chromium, lead, mercury, arsenic, manganese, copper, silver, nickel or selenium; the rock contains beneficial elements; the beneficial elements include any one or a combination of at least two of potassium, calcium, sodium, magnesium, zinc, strontium or metasilicic acid.
2. The water mineralized rock composition according to claim 1, wherein the water mineralized rock composition comprises, by mass, 6-10 parts of dolomite, 6-8 parts of celestite, 3-4 parts of siderite, 2-3 parts of medical stone, 1-2 parts of zeolite, 3-4 parts of stone needle and 1-2 parts of calcite.
3. The water mineralized rock composition according to claim 1, wherein the water mineralized rock composition comprises 8-10 parts by weight of dolomite, 6-8 parts by weight of celestite, 2-3 parts by weight of medical stone, 1-2 parts by weight of zeolite and 1-2 parts by weight of stone needle.
4. A water mineralized rock composition according to claim 3, wherein the dissolved strontium content of the water mineralized rock composition is greater than or equal to 300 μg/L.
5. The water mineralized rock composition according to claim 1, wherein the water mineralized rock composition comprises, by mass, 4-6 parts of dolomite, 8-10 parts of calamine, 6-8 parts of calamine, 2-3 parts of medical stone and 2-3 parts of zeolite.
6. The water mineralized rock composition according to claim 5, wherein the water mineralized rock composition has a dissolved zinc content of greater than or equal to 300 μg/L.
7. The water mineralized rock composition according to claim 1, wherein the water mineralized rock composition comprises, by mass, 4-6 parts of dolomite, 3-5 parts of magnesite, 8-10 parts of granite, 6-8 parts of medical stone, 2-3 parts of zeolite and 1-2 parts of calcite.
8. The water mineralized rock composition according to claim 7, wherein the water mineralized rock composition has a dissolved metasilicic acid content of greater than or equal to 250 μg/L.
9. Use of a water mineralized rock combination according to any one of claims 1 to 8 in water treatment, bathing, skin care and cosmetology.
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