CN106479322A - A kind of aqueous glass paint of wearable environment protection and preparation method thereof - Google Patents
A kind of aqueous glass paint of wearable environment protection and preparation method thereof Download PDFInfo
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- CN106479322A CN106479322A CN201610896267.2A CN201610896267A CN106479322A CN 106479322 A CN106479322 A CN 106479322A CN 201610896267 A CN201610896267 A CN 201610896267A CN 106479322 A CN106479322 A CN 106479322A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention belongs to technical field of construction and decoration materials, and in particular to a kind of aqueous glass paint of wearable environment protection and preparation method thereof, is made up of the material of following parts by weight proportioning：9 21 parts of epoxy resin, 12 25 parts of polyaminoester emulsion, 18 24 parts of acrylic modified epoxy resin, 11 27 parts of glycol ether, 8 19 parts of aluminium oxide, 10 17 parts of quartz sand, 27 33 parts of methyl methacrylate, formaldehyde specially good effect 10 17 parts of enzyme crystal of dissolving, 20 27 parts of methyl anyl alcohol, 17 30 parts of sericite, 9 19 parts of plasticizer, 13 parts of sodium alkyl benzene sulfonate, 35 parts of Tissuemat E, 35 parts of microwax, 14 parts of calcium stearate, 24 parts of higher alcohol, 15 parts of nano-silicon and 68 parts of water lustering oil etc.；The aqueous glass paint of wearable environment protection provided by the present invention, has excellent anti-wear performance and adhesion strength, and releasable negative oxygen ion, the indoor pollutant such as purifying formaldehyde.
Description
Technical field
The invention belongs to technical field of construction and decoration materials and in particular to a kind of aqueous glass paint of wearable environment protection and its
Preparation method.
Background technology
Glass has very high hardness, cleaning avirulence, good corrosion resistance and resistance to ag(e)ing, is a kind of extensively application
Decorated package (being applied to the fields such as building decoration, automobile, lamp decoration, bottle, bottle for cosmetics, water tumbler).China is the world
The maximum country of glass throughput, in order to improve the attractive in appearance of glass, improves the decorative effect of glass drying oven, present glass further
Glass industry more using the different glass coating of color or ink in glass surface application, in the hope of reaching higher decoration effect
Really.General glass coating requires there is the bases such as good glass attachment power, hardness, gloss, application property, resistance to water, polishing processing
This performance, special glass coating proposes some characteristic requirements according to the difference of application：Such as lighting glass requires higher
Resisting high-temperature yellowing, and bottle container glass coating requires water boiling resistance and alcohol resistance.
It is diluent that existing market main flow glass coating typically all adopts organic solvent, however as social progress, people
Pay attention to day by day to environmental conservation and health, aqueous glass paint is because easy construction, curing apparatus are simple, in glass
Field of coating causes most commonly used concern.Existing aqueous glass paint anti-wear performance difference and adhesion strength are poor, and cannot
The indoor pollutants such as purifying formaldehyde.
Content of the invention
The technical problem to be solved in the present invention is to provide a kind of intensity high, corrosion-resistant, the aqueouss of the wearable environment protection of anti-fine fisssure
Glass coating.
For solving the above problems, the present invention adopts the following technical scheme that：
A kind of aqueous glass paint of wearable environment protection, is made up of the material of following parts by weight proportioning, epoxy resin 9-21
Part, polyaminoester emulsion 12-25 part, acrylic modified epoxy resin 18-24 part, glycol ether 11-27 part, aluminium oxide 8-19 part,
Quartz sand 10-17 part, methyl methacrylate 27-33 part, formaldehyde specially good effect dissolving enzyme crystal 10-17 part, methyl anyl alcohol 20-27
Part, sericite 17-30 part, plasticizer 9-19 part, sodium alkyl benzene sulfonate 1-3 part, Tissuemat E 3-5 part, microwax 3-5 part, hard
Fat acid calcium 1-4 part, higher alcohol 2-4 part, nano-silicon 1-5 part, water lustering oil 6-8 part, tourmaline powder 11-13 part, coconut activated
Charcoal 17-33 part, wetting dispersing agent 7-11 part, titanium dioxide 21-27 part, styrene 3-9 part, alcohol ether cosolvent 5-9 part, initiator 7-
11 parts, Polyethylene Glycol 10-20 part and 99 parts of deionized water.
Further, the aqueous glass paint of described wearable environment protection is made up of the material of following parts by weight proportioning, epoxy
15 parts of resin, 18 parts of polyaminoester emulsion, 21 parts of acrylic modified epoxy resin, 19 parts of glycol ether, 13 parts of aluminium oxide, quartz sand
13 parts, 30 parts of methyl methacrylate, formaldehyde specially good effect 13 parts of enzyme crystal of dissolving, 23 parts of methyl anyl alcohol, 23 parts of sericite, plasticizer
14 parts, 2 parts of sodium alkyl benzene sulfonate, 4 parts of Tissuemat E, 4 parts of microwax, 3 parts of calcium stearate, 3 parts of higher alcohol, 3 parts of nano-silicon, water
7 parts of oil polish of property, 12 parts of tourmaline powder, 25 parts of cocoanut active charcoal, 9 parts of wetting dispersing agent, 24 parts of titanium dioxide, 6 parts of styrene, alcohol
7 parts of ether cosolvent, 9 parts of initiator, 15 parts of Polyethylene Glycol and 99 parts of deionized water.
Further, the aqueous glass paint of described wearable environment protection is made up of the material of following parts by weight proportioning, epoxy
9 parts of resin, 12 parts of polyaminoester emulsion, 18 parts of acrylic modified epoxy resin, 11 parts of glycol ether, 8 parts of aluminium oxide, quartz sand 10
Part, 27 parts of methyl methacrylate, formaldehyde specially good effect 10 parts of enzyme crystal of dissolving, 20 parts of methyl anyl alcohol, 17 parts of sericite, plasticizer 9
Part, 1 part of sodium alkyl benzene sulfonate, 3 parts of Tissuemat E, 3 parts of microwax, 1 part of calcium stearate, 2 parts of higher alcohol, 1 part of nano-silicon, aqueouss
6 parts of oil polish, 11 parts of tourmaline powder, 17 parts of cocoanut active charcoal, 7 parts of wetting dispersing agent, 21 parts of titanium dioxide, 3 parts of styrene, alcohol ether
5 parts of cosolvent, 7 parts of initiator, 10 parts of Polyethylene Glycol and 99 parts of deionized water.
Further, the aqueous glass paint of described wearable environment protection is made up of the material of following parts by weight proportioning, epoxy
21 parts of resin, 25 parts of polyaminoester emulsion, 24 parts of acrylic modified epoxy resin, 27 parts of glycol ether, 19 parts of aluminium oxide, quartz sand
17 parts, 33 parts of methyl methacrylate, formaldehyde specially good effect 17 parts of enzyme crystal of dissolving, 27 parts of methyl anyl alcohol, 30 parts of sericite, plasticizer
19 parts, 3 parts of sodium alkyl benzene sulfonate, 5 parts of Tissuemat E, 5 parts of microwax, 4 parts of calcium stearate, 4 parts of higher alcohol, 5 parts of nano-silicon, water
8 parts of oil polish of property, 13 parts of tourmaline powder, 33 parts of cocoanut active charcoal, 11 parts of wetting dispersing agent, 27 parts of titanium dioxide, 9 parts of styrene,
9 parts of alcohol ether cosolvent, 11 parts of initiator, 20 parts of Polyethylene Glycol and 99 parts of deionized water.
Above-mentioned cocoanut active charcoal be using high-quality import coconut husk be material, using the inlet gas way of distillation or kiln process,
It is fired into cocoanut active charcoal with coconut husk, rear knock is about the cocoanut active charcoal of 1cm3, fritter coconut husk charcoal is loaded totally thin nylon
In mesh bag, prick toward bag mouth, be then placed in filling in the household pressure-cooker of 5% sodium carbonate liquor or medical pressure cooker, pressure cook
Boiling about 30 minutes, to wash out micro- hole in oil and dredging Linesless charcoal；For preventing coconut husk charcoal from floating on sodium carbonate liquor, can be in nylon
Bag is outer to be that one block of clean stone falls；Secondary with clear water rinsing Linesless charcoal after boiling, to remove oil, place into 5% sodium carbonate
Solution mesohigh boils about 30 minutes, is rinsed three times with 80 DEG C about of clear water after taking-up, to clean oily and a small amount of sodium carbonate,
Last being boiled about 30 minutes with clear-water high-pressure again dredges minute aperture in coconut husk charcoal further；Taking-up is dried and is obtained final product activated carbon, uses
Front rebake is once to reach optimum efficiency；The absorbability that this legal system obtains activated carbon exceeds well over Linesless charcoal；Used activated carbon also may be used
Regenerated with this method.The granular active carbon being obtained using the inlet gas way of distillation or kiln process, product absorption affinity is good, intensity
Height, epigranular；Surface micropore adsorption rate is 5 times of sintering activity charcoal, and outward appearance is black, has space prosperity, and adsorption rate is high,
Intensity is good, easily regenerates, the features such as durable；Abnormal flavour in eliminating water and heterochromatic can effectively be removed, can effectively help people to go
Except carcinogen so that water quality is limpid, the soft silk floss of mouthfeel.Activated coco nut charcoal is for drinking water purification, dechlorinating, remove at present
The best a kind of activated carbon of algae, oxygen uptake, catalytic carrier aspect effect, can be used for water purifier, considers the purifiers such as core implant；Can
For carbon slurry processes, dump leaching method and gold extract and metallurgical industry in the separation of noble metal and extraction it can also be used to purification of water quality.
And by adding cocoanut active charcoal, the activity of existing tourmaline powder is improve about 30%, anion yield is by original
700-1000/cm3 brings up to 1000 to 1300/cm3, even up to 1600/more than cm3.
Tourmaline powder is through going after the removal of impurity tourmaline powder raw ore, the powder body obtaining through mechanical activation comminution.Through adding
The tourmaline powder of work purification has higher anion yield and far infrared transmissivity.Tourmaline powder is different according to purposes,
Mainly there are tourmaline powder, ultra-fine tourmaline powder, nano-tourmaline powder by granularity difference.Applicable industry is related to：Environmental protection, Medicated cigarette, painting
Material, weaving, cosmetics, purify water, purify air, anti-electromagnetic radiation, health product etc..Tourmaline powder can absorb paint, colloid
The abnormal flavour being sent Deng product.Paint interior wall, the abnormal flavour that adsorbable paint, colloid, coating are sent for building decoration.Applying
Add in material a small amount of ultra-fine tourmaline powder, brush on interior wall and ceiling, not only can rapidly peculiar smell suction, can also inhale for a long time
Removing taste.The anion burst size of tourmaline powder：The anion burst size of 100 mesh is the anion release of 200IONS 325 mesh
Amount is about that the anion burst size of 400IONS 1250 mesh can reach 800IONS.
Sericite is a kind of natural particulate white mica, is the silicate of layer structure, can strengthen the comprehensive mechanical of coating
Can, water proof anti-seepage, freedom from cracking.Acidproof, alkaline-resisting, high temperature resistant, improve the heat-resisting and antiseptic property of coating.
Quartz sand is the broken quartz particles processing of quartz warp, and quartz is a kind of nonmetallic mineral, is one
Plant hard, wear-resisting, stable chemical performance silicate mineral.
Aluminium oxide is by bauxite and diaspore preparation, can provide for powdery paints and flow freely and caking performance
Can, these performances will promote smoothly electrostatic spraying and fluidized bed painting.In addition it is provided that rheology control performance in powdery paints,
Control edges cover, sagging and drippage.It is added in coating and can play anti-settling, anti-sag, levelling control, anti-settling, metal
Scale aligns, anticorrosion, moisture resistance effect.
The invention solves the problems that another technical problem be provide a kind of preparation method of the aqueous glass paint of wearable environment protection,
Comprise the following steps：
1) first by cocoanut active charcoal, sericite, aluminium oxide, nano-silicon, quartz sand and formaldehyde specially good effect dissolving enzyme crystal respectively
With machine fine ground 300-800 mesh, the powder of prepared polish, standby；
2) by step 1) powder and tourmaline powder, wetting dispersing agent and the titanium dioxide mixing addition that are obtained put into sand milling, divide
Dissipate, stirring multiple purpose aeroplane in interior mixed, after disperseing 15min at a high speed under the conditions of rotating speed is for 30000rmp, add deionized water
And open steam intensification, the moderate-speed mixer 15min when 50 DEG C；
3) by step 2) be obtained mixed liquor in add epoxy resin, polyaminoester emulsion, acrylic modified epoxy resin, two
First alcohol ether, methyl methacrylate and ionized water, are passed through noble gases, after air in exclusion reactor, warming while stirring is extremely
75-85 DEG C, mixing speed is adjusted to 1200r/min, continues 40min, standby；
4) take initiator 7-11 part, be slowly dropped in step 3 with dropper) it is obtained in reacted mixed solution, make initiation
Agent is reacted with mixed solution, and is incubated 2 hours so that initiator sustained response in mixed solution, standby；
5) add surplus stock, stir 5-10 minute, then heat to 70-80 DEG C, insulation was placed in without sunlight after 40 minutes
The local placement irradiated cools down；
6) by step 5) solution testing conversion ratio after cooling, if do not have qualified; add suitable prepare material, carry out
Adjustment specification, if qualified, carries out filtering, discharging, obtains final product.
The invention has the beneficial effects as follows：By add water lustering oil and Tissuemat E can improve overall glossiness,
Resistance to water, and keep stable chemical performance；Overall wear resistance energy can be improved by interpolation sericite, aluminium oxide, quartz sand, and
And be combined with nano-silicon there is excellent water proof anti-seepage effect；By add cocoanut active charcoal, formaldehyde specially good effect dissolve enzyme crystal and
Tourmaline powder can adsorb abnormal flavour, remove formaldehyde, releasing negative oxygen ion, purify air.
Specific embodiment
Embodiment 1：
By weight proportioning weigh 15 parts of epoxy resin, 18 parts of polyaminoester emulsion, 21 parts of acrylic modified epoxy resin,
19 parts of glycol ether, 13 parts of aluminium oxide, 13 parts of quartz sand, 30 parts of methyl methacrylate, formaldehyde specially good effect 13 parts of enzyme crystal of dissolving,
23 parts of methyl anyl alcohol, 23 parts of sericite, 14 parts of plasticizer, 2 parts of sodium alkyl benzene sulfonate, 4 parts of Tissuemat E, 4 parts of microwax, Hard Fat
3 parts of sour calcium, 3 parts of higher alcohol, 3 parts of nano-silicon, 7 parts of water lustering oil, 12 parts of tourmaline powder, 25 parts of cocoanut active charcoal, moistening divide
9 parts of powder, 24 parts of titanium dioxide, 6 parts of styrene, 7 parts of alcohol ether cosolvent, 9 parts of initiator, 15 parts of Polyethylene Glycol and deionized water 99
Part.
A kind of preparation method of the aqueous glass paint of wearable environment protection, comprises the following steps：
1) first by cocoanut active charcoal, sericite, aluminium oxide, nano-silicon, quartz sand and formaldehyde specially good effect dissolving enzyme crystal respectively
With machine fine ground 300-800 mesh, the powder of prepared polish, standby；
2) by step 1) powder and tourmaline powder, wetting dispersing agent and the titanium dioxide mixing addition that are obtained put into sand milling, divide
Dissipate, stirring multiple purpose aeroplane in interior mixed, after disperseing 15min at a high speed under the conditions of rotating speed is for 30000rmp, add deionized water
And open steam intensification, the moderate-speed mixer 15min when 50 DEG C；
3) by step 2) be obtained mixed liquor in add epoxy resin, polyaminoester emulsion, acrylic modified epoxy resin, two
First alcohol ether, methyl methacrylate and ionized water, are passed through noble gases, after air in exclusion reactor, warming while stirring is extremely
75-85 DEG C, mixing speed is adjusted to 1200r/min, continues 40min, standby；
4) take initiator 7-11 part, be slowly dropped in step 3 with dropper) it is obtained in reacted mixed solution, make initiation
Agent is reacted with mixed solution, and is incubated 2 hours so that initiator sustained response in mixed solution, standby；
5) add surplus stock, stir 5-10 minute, then heat to 70-80 DEG C, insulation was placed in without sunlight after 40 minutes
The local placement irradiated cools down；
6) by step 5) solution testing conversion ratio after cooling, if do not have qualified; add suitable prepare material, carry out
Adjustment specification, if qualified, carries out filtering, discharging, obtains final product.
Embodiment 2：
By weight proportioning weigh 9 parts of epoxy resin, 12 parts of polyaminoester emulsion, 18 parts of acrylic modified epoxy resin,
11 parts of glycol ether, 8 parts of aluminium oxide, 10 parts of quartz sand, 27 parts of methyl methacrylate, formaldehyde specially good effect 10 parts of enzyme crystal of dissolving,
20 parts of methyl anyl alcohol, 17 parts of sericite, 9 parts of plasticizer, 1 part of sodium alkyl benzene sulfonate, 3 parts of Tissuemat E, 3 parts of microwax, Hard Fat
1 part of sour calcium, 2 parts of higher alcohol, 1 part of nano-silicon, 6 parts of water lustering oil, 11 parts of tourmaline powder, 17 parts of cocoanut active charcoal, moistening divide
7 parts of powder, 21 parts of titanium dioxide, 3 parts of styrene, 5 parts of alcohol ether cosolvent, 7 parts of initiator, 10 parts of Polyethylene Glycol and deionized water 99
Part.
A kind of preparation method of the aqueous glass paint of wearable environment protection, comprises the following steps：
1) first by cocoanut active charcoal, sericite, aluminium oxide, nano-silicon, quartz sand and formaldehyde specially good effect dissolving enzyme crystal respectively
With machine fine ground 300-800 mesh, the powder of prepared polish, standby；
2) by step 1) powder and tourmaline powder, wetting dispersing agent and the titanium dioxide mixing addition that are obtained put into sand milling, divide
Dissipate, stirring multiple purpose aeroplane in interior mixed, after disperseing 15min at a high speed under the conditions of rotating speed is for 30000rmp, add deionized water
And open steam intensification, the moderate-speed mixer 15min when 50 DEG C；
3) by step 2) be obtained mixed liquor in add epoxy resin, polyaminoester emulsion, acrylic modified epoxy resin, two
First alcohol ether, methyl methacrylate and ionized water, are passed through noble gases, after air in exclusion reactor, warming while stirring is extremely
75-85 DEG C, mixing speed is adjusted to 1200r/min, continues 40min, standby；
4) take initiator 7-11 part, be slowly dropped in step 3 with dropper) it is obtained in reacted mixed solution, make initiation
Agent is reacted with mixed solution, and is incubated 2 hours so that initiator sustained response in mixed solution, standby；
5) add surplus stock, stir 5-10 minute, then heat to 70-80 DEG C, insulation was placed in without sunlight after 40 minutes
The local placement irradiated cools down；
6) by step 5) solution testing conversion ratio after cooling, if do not have qualified; add suitable prepare material, carry out
Adjustment specification, if qualified, carries out filtering, discharging, obtains final product.
Embodiment 3：
By weight proportioning weigh 21 parts of epoxy resin, 25 parts of polyaminoester emulsion, 24 parts of acrylic modified epoxy resin,
27 parts of glycol ether, 19 parts of aluminium oxide, 17 parts of quartz sand, 33 parts of methyl methacrylate, formaldehyde specially good effect 17 parts of enzyme crystal of dissolving,
27 parts of methyl anyl alcohol, 30 parts of sericite, 19 parts of plasticizer, 3 parts of sodium alkyl benzene sulfonate, 5 parts of Tissuemat E, 5 parts of microwax, Hard Fat
4 parts of sour calcium, 4 parts of higher alcohol, 5 parts of nano-silicon, 8 parts of water lustering oil, 13 parts of tourmaline powder, 33 parts of cocoanut active charcoal, moistening divide
11 parts of powder, 27 parts of titanium dioxide, 9 parts of styrene, 9 parts of alcohol ether cosolvent, 11 parts of initiator, 20 parts of Polyethylene Glycol and deionized water
99 parts.
A kind of preparation method of the aqueous glass paint of wearable environment protection, comprises the following steps：
1) first by cocoanut active charcoal, sericite, aluminium oxide, nano-silicon, quartz sand and formaldehyde specially good effect dissolving enzyme crystal respectively
With machine fine ground 300-800 mesh, the powder of prepared polish, standby；
2) by step 1) powder and tourmaline powder, wetting dispersing agent and the titanium dioxide mixing addition that are obtained put into sand milling, divide
Dissipate, stirring multiple purpose aeroplane in interior mixed, after disperseing 15min at a high speed under the conditions of rotating speed is for 30000rmp, add deionized water
And open steam intensification, the moderate-speed mixer 15min when 50 DEG C；
3) by step 2) be obtained mixed liquor in add epoxy resin, polyaminoester emulsion, acrylic modified epoxy resin, two
First alcohol ether, methyl methacrylate and ionized water, are passed through noble gases, after air in exclusion reactor, warming while stirring is extremely
75-85 DEG C, mixing speed is adjusted to 1200r/min, continues 40min, standby；
4) take initiator 7-11 part, be slowly dropped in step 3 with dropper) it is obtained in reacted mixed solution, make initiation
Agent is reacted with mixed solution, and is incubated 2 hours so that initiator sustained response in mixed solution, standby；
5) add surplus stock, stir 5-10 minute, then heat to 70-80 DEG C, insulation was placed in without sunlight after 40 minutes
The local placement irradiated cools down；
6) by step 5) solution testing conversion ratio after cooling, if do not have qualified; add suitable prepare material, carry out
Adjustment specification, if qualified, carries out filtering, discharging, obtains final product.Experimental example：
Experimental subject：90 blocks of glass, randomized is divided into 3 groups：Matched group one, matched group two and experimental group, every group 40 pieces.
Test method：Matched group one coats the aqueous glass paint of market upper inlet, and matched group two is coated general on the market
Aqueous glass paint, experimental group coats the aqueous glass paint of the wearable environment protection of the present invention, is placed in painting after coating corresponding coating
Carry out abrasion test in layer abrasion resistance tester.
Criterion：
Remarkable result：Significantly lifted using anti-wear performance, antifraying property, anti-scratch performance after corresponding coating.
Effectively：It is obviously improved using anti-wear performance, antifraying property after corresponding PU coating.
Invalid：Little using anti-wear performance lifting after corresponding PU coating.
The abrasion test result of three groups of glass see table：
| Group | Remarkable result | Effectively | Invalid |
| Matched group one | 16 | 9 | 15 |
| Matched group two | 8 | 7 | 25 |
| Experimental group | 32 | 1 | 7 |
Three groups of glass are carried out with ion concentration detection compare, result such as following table：
In the air negative ion concentration and healthy relation reference table：
From above experimental result, the effect of the aqueous glass paint of the wearable environment protection of the present invention is best.
The invention has the beneficial effects as follows：By add water lustering oil and Tissuemat E can improve overall glossiness,
Resistance to water, and keep stable chemical performance；Overall wear resistance energy can be improved by interpolation sericite, aluminium oxide, quartz sand, and
And be combined with nano-silicon there is excellent water proof anti-seepage effect；By add cocoanut active charcoal, formaldehyde specially good effect dissolve enzyme crystal and
Tourmaline powder can adsorb abnormal flavour, remove formaldehyde, releasing negative oxygen ion, purify air.
The above, the only specific embodiment of the present invention, but protection scope of the present invention is not limited thereto, and any
The change or replacement expected without creative work, all should cover within the scope of the present invention.
Claims (5)
1. a kind of aqueous glass paint of wearable environment protection it is characterised in that：It is made up of the material of following parts by weight proportioning, epoxy
Resin 9-21 part, polyaminoester emulsion 12-25 part, acrylic modified epoxy resin 18-24 part, glycol ether 11-27 part, aluminium oxide
8-19 part, quartz sand 10-17 part, methyl methacrylate 27-33 part, formaldehyde specially good effect dissolving enzyme crystal 10-17 part, methyl anyl alcohol
20-27 part, sericite 17-30 part, plasticizer 9-19 part, sodium alkyl benzene sulfonate 1-3 part, Tissuemat E 3-5 part, microwax 3-5
Part, calcium stearate 1-4 part, higher alcohol 2-4 part, nano-silicon 1-5 part, water lustering oil 6-8 part, tourmaline powder 11-13 part, coconut husk
Activated carbon 17-33 part, wetting dispersing agent 7-11 part, titanium dioxide 21-27 part, styrene 3-9 part, alcohol ether cosolvent 5-9 part, initiation
Agent 7-11 part, Polyethylene Glycol 10-20 part and 99 parts of deionized water.
2. wearable environment protection as claimed in claim 1 aqueous glass paint it is characterised in that：By following parts by weight proportioning
Material is made, 15 parts of epoxy resin, 18 parts of polyaminoester emulsion, 21 parts of acrylic modified epoxy resin, 19 parts of glycol ether, oxidation
13 parts of aluminum, 13 parts of quartz sand, 30 parts of methyl methacrylate, formaldehyde specially good effect 13 parts of enzyme crystal of dissolving, 23 parts of methyl anyl alcohol, thin,tough silk cloud
23 parts of mother, 14 parts of plasticizer, 2 parts of sodium alkyl benzene sulfonate, 4 parts of Tissuemat E, 4 parts of microwax, 3 parts of calcium stearate, higher alcohol 3
Part, 3 parts of nano-silicon, 7 parts of water lustering oil, 12 parts of tourmaline powder, 25 parts of cocoanut active charcoal, 9 parts of wetting dispersing agent, titanium dioxide 24
Part, 6 parts of styrene, 7 parts of alcohol ether cosolvent, 9 parts of initiator, 15 parts of Polyethylene Glycol and 99 parts of deionized water.
3. wearable environment protection as claimed in claim 1 aqueous glass paint it is characterised in that：By following parts by weight proportioning
Material is made, 9 parts of epoxy resin, 12 parts of polyaminoester emulsion, 18 parts of acrylic modified epoxy resin, 11 parts of glycol ether, oxidation
8 parts of aluminum, 10 parts of quartz sand, 27 parts of methyl methacrylate, formaldehyde specially good effect 10 parts of enzyme crystal of dissolving, 20 parts of methyl anyl alcohol, thin,tough silk cloud
Female 17 parts, 9 parts of plasticizer, 1 part of sodium alkyl benzene sulfonate, 3 parts of Tissuemat E, 3 parts of microwax, 1 part of calcium stearate, 2 parts of higher alcohol,
1 part of nano-silicon, 6 parts of water lustering oil, 11 parts of tourmaline powder, 17 parts of cocoanut active charcoal, 7 parts of wetting dispersing agent, 21 parts of titanium dioxide,
3 parts of styrene, 5 parts of alcohol ether cosolvent, 7 parts of initiator, 10 parts of Polyethylene Glycol and 99 parts of deionized water.
4. wearable environment protection as claimed in claim 1 aqueous glass paint it is characterised in that：By following parts by weight proportioning
Material is made, 21 parts of epoxy resin, 25 parts of polyaminoester emulsion, 24 parts of acrylic modified epoxy resin, 27 parts of glycol ether, oxidation
19 parts of aluminum, 17 parts of quartz sand, 33 parts of methyl methacrylate, formaldehyde specially good effect 17 parts of enzyme crystal of dissolving, 27 parts of methyl anyl alcohol, thin,tough silk cloud
30 parts of mother, 19 parts of plasticizer, 3 parts of sodium alkyl benzene sulfonate, 5 parts of Tissuemat E, 5 parts of microwax, 4 parts of calcium stearate, higher alcohol 4
Part, 5 parts of nano-silicon, 8 parts of water lustering oil, 13 parts of tourmaline powder, 33 parts of cocoanut active charcoal, 11 parts of wetting dispersing agent, titanium dioxide
27 parts, 9 parts of styrene, 9 parts of alcohol ether cosolvent, 11 parts of initiator, 20 parts of Polyethylene Glycol and 99 parts of deionized water.
5. the aqueous glass paint of wearable environment protection as claimed in claim 1 preparation method it is characterised in that：Walk including following
Suddenly：
1) first cocoanut active charcoal, sericite, aluminium oxide, nano-silicon, quartz sand and formaldehyde specially good effect dissolving enzyme crystal is used machine respectively
Device fine ground 300-800 mesh, the powder of prepared polish, standby；
2) by step 1) be obtained powder put into sand milling, disperse, stir with tourmaline powder, wetting dispersing agent and titanium dioxide mixing addition
Mix interior in multiple purpose aeroplane mixed, after disperseing 15min at a high speed under the conditions of rotating speed is for 30000rmp, add deionized water simultaneously to open steaming
Vapour heats up, the moderate-speed mixer 15min when 50 DEG C；
3) by step 2) be obtained mixed liquor in add epoxy resin, polyaminoester emulsion, acrylic modified epoxy resin, dihydroxylic alcohols
Ether, methyl methacrylate and ionized water, are passed through noble gases, after air in exclusion reactor, warming while stirring to 75-85
DEG C, mixing speed is adjusted to 1200r/min, continues 40min, standby；
4) take initiator 7-11 part, be slowly dropped in step 3 with dropper) be obtained reacted mixed solution in, make initiator with
Mixed solution reacts, and is incubated 2 hours so that initiator sustained response in mixed solution, standby；
5) add surplus stock, stir 5-10 minute, then heat to 70-80 DEG C, insulation was placed in depletion of YANG light irradiation after 40 minutes
Local place cooling；
6) by step 5) solution testing conversion ratio after cooling, if do not have qualified; add suitable prepare material, be adjusted
Specification, if qualified, carries out filtering, discharging, obtains final product.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610896267.2A CN106479322A (en) | 2016-10-13 | 2016-10-13 | A kind of aqueous glass paint of wearable environment protection and preparation method thereof |
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| CN201610896267.2A CN106479322A (en) | 2016-10-13 | 2016-10-13 | A kind of aqueous glass paint of wearable environment protection and preparation method thereof |
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| CN106479322A true CN106479322A (en) | 2017-03-08 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106752624A (en) * | 2016-11-28 | 2017-05-31 | 江苏环宇纺织科技有限公司 | A kind of aqueous glass paint of flame-proof environmental protection and preparation method thereof |
| CN107141904A (en) * | 2017-07-10 | 2017-09-08 | 张庆珠 | A kind of environmentally friendly diatom ceramic tile joint trimming agent and preparation method thereof |
| CN109055959A (en) * | 2018-08-27 | 2018-12-21 | 安徽江杰实业有限公司 | A kind of aluminum alloy surface rust remover and preparation method thereof |
| CN114456697A (en) * | 2022-01-26 | 2022-05-10 | 中山市大一涂料有限公司 | Polyurethane coating and preparation method and application thereof |
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2016
- 2016-10-13 CN CN201610896267.2A patent/CN106479322A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106752624A (en) * | 2016-11-28 | 2017-05-31 | 江苏环宇纺织科技有限公司 | A kind of aqueous glass paint of flame-proof environmental protection and preparation method thereof |
| CN107141904A (en) * | 2017-07-10 | 2017-09-08 | 张庆珠 | A kind of environmentally friendly diatom ceramic tile joint trimming agent and preparation method thereof |
| CN109055959A (en) * | 2018-08-27 | 2018-12-21 | 安徽江杰实业有限公司 | A kind of aluminum alloy surface rust remover and preparation method thereof |
| CN114456697A (en) * | 2022-01-26 | 2022-05-10 | 中山市大一涂料有限公司 | Polyurethane coating and preparation method and application thereof |
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