CN107141904A - A kind of environmentally friendly diatom ceramic tile joint trimming agent and preparation method thereof - Google Patents
A kind of environmentally friendly diatom ceramic tile joint trimming agent and preparation method thereof Download PDFInfo
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- CN107141904A CN107141904A CN201710555709.1A CN201710555709A CN107141904A CN 107141904 A CN107141904 A CN 107141904A CN 201710555709 A CN201710555709 A CN 201710555709A CN 107141904 A CN107141904 A CN 107141904A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0806—Silver
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Engineering & Computer Science (AREA)
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- Curing Cements, Concrete, And Artificial Stone (AREA)
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Abstract
The invention discloses a kind of environmentally friendly diatom ceramic tile joint trimming agent and preparation method thereof, mixed by weight percentage by following components：5 15 parts of Portland cement, 7 18 parts of diatom ooze, 7 12 parts of Epoxy Modified Styrene Acrylate Emulsion, 15 25 parts of epoxy resin, 17 23 parts of cation-modified styrene-acrylic emulsion, 7 11 parts of silane-modified fluorine-containing emulsion, 38 56 parts of filler, 60 76 parts of deionized water, 5 15 parts of auxiliary agent, 13 parts of Nano silver grain, 10 20 parts of zinc stearate, 10 20 parts of polyethylene glycol (PEG) oleate, 20 24 parts of neopelex, 10 20 parts of cocoanut active charcoal.The present invention is not only environment friendly and pollution-free, can also effectively absorb, remove the harmful substances such as free formaldehyde in air, benzene, ammonia, play a part of purifying the air of a room.
Description
Technical field
The present invention relates to technical field of paint preparation, and in particular to a kind of environmentally friendly diatom ceramic tile joint trimming agent and its making side
Method.
Background technology
During modern house ornamentation, the wall floor ceramic tile such as parlor, kitchen, toilet, mosaic gap, mainly using jointing
The materials such as agent, gap filler or white cement are filled.These materials are functionally poor, general only to have filling function.
The invention of joint trimming agent, solves the function of these packing materials in other respects, and ceramic tile joint trimming agent is the high-grade production of gap decoration
Product, it is adaptable to ceramic tile, mosaic, the beautification of the gap such as stone material.
Existing ceramic tile joint trimming agent is used in building tile decoration, has without free formaldehyde, benzene, ammonia etc. in air is removed
Evil material and the effect that purifies the air of a room, and sterilization, mould proof, anti-fouling effect are general.
The content of the invention
In view of this, may be used also it is an object of the invention to provide one kind for not only environment friendly and pollution-free in building tile decoration
Effectively to remove the harmful substances such as free formaldehyde in air, benzene, ammonia, play a part of the environmentally friendly diatom ceramic tile purified the air of a room
Joint trimming agent.
In order to solve the above-mentioned technical problem, the present invention is adopted the following technical scheme that：
A kind of environmentally friendly diatom ceramic tile joint trimming agent, is mixed by weight percentage by following components：Portland cement
5-15 parts, 7-18 parts of diatom ooze, 7-12 parts of Epoxy Modified Styrene Acrylate Emulsion, 15-25 parts of epoxy resin, cation-modified styrene-acrylic emulsion
17-23 parts, 7-11 parts of silane-modified fluorine-containing emulsion, 38-56 parts of filler, 60-76 parts of deionized water, 5-15 parts of auxiliary agent,
1-3 parts of Nano silver grain, 10-20 parts of zinc stearate, 10-20 parts of polyethylene glycol (PEG) oleate, neopelex 20-24
Part, 10-20 parts of cocoanut active charcoal.
The present invention provides a kind of preparation method of environmentally friendly diatom ceramic tile joint trimming agent for another technical problem to be solved, including
Following steps：
1) by 5-15 parts of Portland cement, 7-18 parts of diatom ooze, 38-56 parts of filler, neopelex 20-
24 parts, 15-25 parts of epoxy resin, 10-20 parts of cocoanut active charcoal and the mixing of 1-3 parts of Nano silver grain, pour into grinder, it is fine ground extremely
The powder of finishing is made in 600-1000 mesh, screening, standby；
2) step 1) obtained by mixture be added in 60-76 parts of deionized water, at a temperature of 91 DEG C, stir 25 minutes,
Stirring is constantly passed through fresh air simultaneously, then through filtering, filter cake dries, is ground to 800 mesh powder, standby；
3) by step 2) made from powder and 7-12 parts of Epoxy Modified Styrene Acrylate Emulsion, cation-modified styrene-acrylic emulsion 17-23
Part, 7-11 parts of silane-modified fluorine-containing emulsion, 5-15 parts of auxiliary agent and the mixing of 10-20 parts of zinc stearate add with enamel or
In the reactor of stainless steel, with 10 DEG C per hour of speed, 50 DEG C are warming up to, constant temperature is maintained；
4) to step 3) mixed solution in add 10-20 part of polyethylene glycol (PEG) oleate, stirring 5-10 minutes, then heat up
To 80-90 DEG C, cooling is placed in insulation is placed in without sunlight irradiation place after 30 minutes；
5) by step 4) made from stirring and dissolving, filtering, discharging in mixed powder, get product.
Further, described filler by the silica of 400-500 mesh and the calcium carbonate of the mesh of 450 mesh -500 according to weight
Than for 11:7 mixing compositions.
Further, the auxiliary agent includes thixotropic agent, levelling agent, defoamer, and the auxiliary component and ratio be, thixotropic agent
: levelling agent: defoamer=6: 2: 2.
Further, the cocoanut active charcoal is using granular activated carbon made from the inlet gas way of distillation or kiln process.
(above-mentioned cocoanut active charcoal is to use high-quality import coconut husk for material, using the inlet gas way of distillation or kiln process,
Cocoanut active charcoal is fired into coconut husk, fritter coconut husk charcoal is loaded clean thin nylon by the cocoanut active charcoal that rear knock is about 1cm3
In mesh bag, prick toward sack, be then placed in the household pressure-cooker for the sodium carbonate liquor for filling 5% or medical pressure cooker, pressure cook
Boiling about 30 minutes, to wash out micro- hole in oil and dredging charcoal；, can be in nylon to prevent coconut husk charcoal from floating on sodium carbonate liquor
It is that one block of clean stone falls that bag is outer；It is secondary with clear water rinsing charcoal after boiling, to remove oil, place into 5% sodium carbonate
Solution mesohigh boils about 30 minutes, is rinsed three times with 80 DEG C or so of clear water after taking-up, to clean oily and a small amount of sodium carbonate,
Finally boiled about 30 minutes with clear-water high-pressure again and further dredge micropore in coconut husk charcoal；Taking-up, which is dried, produces activated carbon, uses
It is preceding to toast again with up to optimum efficiency；The adsorption capacity that this legal system obtains activated carbon exceeds well over charcoal；Used activated carbon also may be used
Regenerated with this method.Using granular activated carbon made from the inlet gas way of distillation or kiln process, product absorption affinity is good, intensity
Height, epigranular；Surface micropore adsorption rate is 5 times of sintering activity charcoal, and outward appearance is black, flourishing with space, and adsorption rate is high,
Intensity is good, easily regeneration, the features such as durable；The peculiar smell and heterochromatic that can effectively go in water removal, effectively can help people to go
Except carcinogen so that water quality is limpid, the soft silk floss of mouthfeel.Current activated coco nut charcoal be for drinking water purification, dechlorinate, remove
The best a kind of activated carbon of effect in terms of algae, oxygen uptake, catalytic carrier, available for water purifier, considers the purifiers such as core filler；Can
For carbon slurry processes, the separation and extraction of noble metal in dump leaching method and gold extraction and metallurgical industry, it can also be used to purification of water quality.
And by adding cocoanut active charcoal, the activity of existing diatom ooze is improved about 30%, anion yield is by original 700-
1000/cm3Bring up to 1000 to 1300/cm3, even up to 1600/more than cm3).
Beneficial effects of the present invention are：
1st, epoxy resin, diatom ooze and cocoanut active charcoal with the addition of by rational technique, epoxy resin can absorb first
Aldehyde；Diatom ooze and cocoanut active charcoal can also effectively absorb the harmful substance such as free formaldehyde, benzene, ammonia in removal air, play net
Change the effect of room air.Diatom ooze have eliminate formaldehyde, purification air, regulation humidity, releasing negative oxygen ion, fire protection flame retarding,
The functions such as metope is self-cleaning, deodorization and sterilization.Unique " molecular sieve " structure of diatom ooze, its micropore is 5000-6000 times of activated carbon, tool
For extremely strong absorption property.And collocation cocoanut active charcoal is used, activity is stronger.Can effectively remove free formaldehyde in air, benzene,
The harmful substances such as ammonia, solve household pollution problem.
2nd, one layer of hydrophobic and oil repellent film can be formed after blind of the present invention on surface (due to neopelex and silicon
Ion exchange occurs for the metal cation in hydrochlorate, so as to enter the molecule interlayer of silicate in the way of molecule intercalation, assigns
Give silicate branched structure.When silicone acrylic emulsion solidifies, in the side chain insertion polymer in modified Portland, so as to be formed
Network structure, reduces the shrinkage factor of joint trimming agent), prevent the intrusion of bacterium；Meanwhile, the present invention adds Nano silver grain as killing
Microbial inoculum, can exist steadily in the long term, and bactericidal effect is good, it is ensured that joint trimming agent can be used for a long time do not turn yellow, it is not blackening, mildewproof.
3rd, by adding polyethylene glycol (PEG) oleate oleate, the not hydrophilic not oleophylic of polyethylene glycol (PEG) oleate oleate so that
Greasy dirt and the globule are difficult be attached to joint trimming agent surface, assign joint trimming agent excellent antifouling property.Fill, disappear in other component
The scrub resistance of joint trimming agent, anti-stain characteristic has been effectively ensured in infusion, thickener, the auxiliary agent such as dispersant.
Embodiment
Embodiment 1
A kind of environmentally friendly diatom ceramic tile joint trimming agent, is mixed by weight percentage by following components：Portland cement 5
It is part, 7 parts of diatom ooze, 7 parts of Epoxy Modified Styrene Acrylate Emulsion, 17 parts of cation-modified styrene-acrylic emulsion, 15 parts of epoxy resin, silane-modified
It is 7 parts of fluorine-containing emulsion, 38 parts of filler, 60 parts of deionized water, 5 parts of auxiliary agent, 1 part of Nano silver grain, 10 parts of zinc stearate, poly-
10 parts of ethylene glycol oleate, 20 parts of neopelex, 10 parts of cocoanut active charcoal.
The present invention provides a kind of preparation method of environmentally friendly diatom ceramic tile joint trimming agent for another technical problem to be solved, including
Following steps：
1) by 5 parts of Portland cement, 7 parts of diatom ooze, 38 parts of filler, 20 parts of neopelex, asphalt mixtures modified by epoxy resin
15 parts of fat, the 1 part of mixing of 10 parts of cocoanut active charcoal and Nano silver grain, pour into grinder, fine ground to 600 mesh, finishing is made in screening
The powder of work, it is standby；
2) step 1) obtained by mixture be added in 60 parts of deionized water, at a temperature of 91 DEG C, stir 25 minutes, stirring
Fresh air is constantly passed through simultaneously, then through filtering, filter cake dries, is ground to 800 mesh powder, standby；
3) by step 2) made from powder and 7 parts of Epoxy Modified Styrene Acrylate Emulsion, 17 parts of cation-modified styrene-acrylic emulsion, silane
7 parts of modified fluoride-containing acrylic emulsion, the 10 parts of mixing of 5 parts of auxiliary agent and zinc stearate add the reactor with enamel or stainless steel
It is interior, with 10 DEG C per hour of speed, 50 DEG C are warming up to, constant temperature is maintained；
4) to step 3) mixed solution in add 10 parts of polyethylene glycol (PEG) oleate, stir 5 minutes, then heat to 80
DEG C, cooling is placed in insulation is placed in without sunlight irradiation place after 30 minutes；
5) by step 4) made from stirring and dissolving, filtering, discharging in mixed powder, get product.
Described filler is 11 according to weight ratio by the silica of 400 mesh and the calcium carbonate of 450 mesh:7 mixing compositions.
The auxiliary agent includes thixotropic agent, levelling agent, defoamer, and the auxiliary component and ratio be, thixotropic agent: levelling agent:
Defoamer=6: 2: 2.
The cocoanut active charcoal is using granular activated carbon made from the inlet gas way of distillation or kiln process.
Embodiment 2
A kind of environmentally friendly diatom ceramic tile joint trimming agent, is mixed by weight percentage by following components：Portland cement
15 parts, 18 parts of diatom ooze, 12 parts of Epoxy Modified Styrene Acrylate Emulsion, 23 parts of cation-modified styrene-acrylic emulsion, 25 parts of epoxy resin, silane
11 parts of modified fluoride-containing acrylic emulsion, 56 parts of filler, 76 parts of deionized water, 15 parts of auxiliary agent, 3 parts of Nano silver grain, zinc stearate
20 parts, 20 parts of polyethylene glycol (PEG) oleate, 24 parts of neopelex, 20 parts of cocoanut active charcoal.
The present invention provides a kind of preparation method of environmentally friendly diatom ceramic tile joint trimming agent for another technical problem to be solved, including
Following steps：
1) by 15 parts of Portland cement, 18 parts of diatom ooze, 56 parts of filler, 24 parts of neopelex, epoxy
25 parts of resin, the 3 parts of mixing of 20 parts of cocoanut active charcoal and Nano silver grain, pour into grinder, fine ground to 1000 mesh, screen, are made
The powder of finishing, it is standby；
2) step 1) obtained by mixture be added in 76 parts of deionized water, at a temperature of 91 DEG C, stir 25 minutes, stirring
Fresh air is constantly passed through simultaneously, then through filtering, filter cake dries, is ground to 800 mesh powder, standby；
3) by step 2) made from powder and 12 parts of Epoxy Modified Styrene Acrylate Emulsion, 23 parts of cation-modified styrene-acrylic emulsion, silicon
11 parts of alkane modified fluoride-containing acrylic emulsion, the 20 parts of mixing of 15 parts of auxiliary agent and zinc stearate add the reaction with enamel or stainless steel
In kettle, with 10 DEG C per hour of speed, 50 DEG C are warming up to, constant temperature is maintained；
4) to step 3) mixed solution in add 20 parts of polyethylene glycol (PEG) oleate, stir 10 minutes, then heat to 90
DEG C, cooling is placed in insulation is placed in without sunlight irradiation place after 30 minutes；
5) by step 4) made from stirring and dissolving, filtering, discharging in mixed powder, get product.
Described filler is 11 according to weight ratio by the silica of 500 mesh and the calcium carbonate of 500 mesh:7 mixing compositions.
The auxiliary agent includes thixotropic agent, levelling agent, defoamer, and the auxiliary component and ratio be, thixotropic agent: levelling agent:
Defoamer=6: 2: 2.
The cocoanut active charcoal is using granular activated carbon made from the inlet gas way of distillation or kiln process.
Embodiment 3
A kind of environmentally friendly diatom ceramic tile joint trimming agent, is mixed by weight percentage by following components：Portland cement
10 parts, 12 parts of diatom ooze, 9 parts of Epoxy Modified Styrene Acrylate Emulsion, 20 parts of cation-modified styrene-acrylic emulsion, 20 parts of epoxy resin, silane
9 parts of modified fluoride-containing acrylic emulsion, 45 parts of filler, 68 parts of deionized water, 10 parts of auxiliary agent, 2 parts of Nano silver grain, zinc stearate 15
Part, 15 parts of polyethylene glycol (PEG) oleate, 22 parts of neopelex, 15 parts of cocoanut active charcoal.
The present invention provides a kind of preparation method of environmentally friendly diatom ceramic tile joint trimming agent for another technical problem to be solved, including
Following steps：
1) by 10 parts of Portland cement, 12 parts of diatom ooze, 45 parts of filler, 22 parts of neopelex, epoxy
20 parts of resin, the 2 parts of mixing of 15 parts of cocoanut active charcoal and Nano silver grain, pour into grinder, fine ground to 800 mesh, essence is made in screening
The powder of processing, it is standby；
2) step 1) obtained by mixture be added in 68 parts of deionized water, at a temperature of 91 DEG C, stir 25 minutes, stirring
Fresh air is constantly passed through simultaneously, then through filtering, filter cake dries, is ground to 800 mesh powder, standby；
3) by step 2) made from powder and 9 parts of Epoxy Modified Styrene Acrylate Emulsion, 20 parts of cation-modified styrene-acrylic emulsion, silane
9 parts of modified fluoride-containing acrylic emulsion, the 15 parts of mixing of 10 parts of auxiliary agent and zinc stearate add the reactor with enamel or stainless steel
It is interior, with 10 DEG C per hour of speed, 50 DEG C are warming up to, constant temperature is maintained；
4) to step 3) mixed solution in add 15 parts of polyethylene glycol (PEG) oleate, stir 7 minutes, then heat to 85
DEG C, cooling is placed in insulation is placed in without sunlight irradiation place after 30 minutes；
5) by step 4) made from stirring and dissolving, filtering, discharging in mixed powder, get product.
Described filler is 11 according to weight ratio by the silica of 450 mesh and the calcium carbonate of 475 mesh:7 mixing compositions.
The auxiliary agent includes thixotropic agent, levelling agent, defoamer, and the auxiliary component and ratio be, thixotropic agent: levelling agent:
Defoamer=6: 2: 2.
The cocoanut active charcoal is using granular activated carbon made from the inlet gas way of distillation or kiln process.
Experimental example
Experimental subjects：150 blocks of identical ceramic tiles, are divided into 3 groups, every group of 50 blocks of ceramic tiles according to experimental method.
Experimental method and time：Control group 1 sprays common ceramic tile joint trimming agent, and control group 2 sprays import ceramic tile joint trimming agent,
Experimental group is using the environmentally friendly diatom ceramic tile joint trimming agent of the present invention, and experimental period is 3 months, and record number of times is 3 times, records ceramic tile feelings
Condition.
Three groups of ceramic tiles carry out first month effect and compared, and as a result see chart 1.
Tested by first month, three groups of situations have notable difference.
Three groups of ceramic tiles carry out second month effect and compared, and as a result see chart 2.
Tested by second month, three groups of situations have highly significant sex differernce.
Three groups of ceramic tiles carry out three month effect and compared, and as a result see chart 3.
Tested by three months, three groups of situations have highly significant sex differernce.
From above experimental result, the effect of distortion-free environment protection tile of the invention is best.
Certainly, it is the representative instance of the present invention above, in addition, the present invention can also have other a variety of specific implementations
The technical scheme of mode, all use equivalent substitutions or equivalent transformation formation, all falls within the scope of protection of present invention.
Claims (5)
1. a kind of environmentally friendly diatom ceramic tile joint trimming agent, it is characterised in that mixed by weight percentage by following components：Ordinary silicon
It is 5-15 parts of acid salt cement, 7-18 parts of diatom ooze, 7-12 parts of Epoxy Modified Styrene Acrylate Emulsion, 15-25 parts of epoxy resin, cation-modified
17-23 parts of styrene-acrylic emulsion, 7-11 parts of silane-modified fluorine-containing emulsion, 38-56 parts of filler, 60-76 parts of deionized water, auxiliary agent
5-15 parts, 1-3 parts of Nano silver grain, 10-20 parts of zinc stearate, 10-20 parts of polyethylene glycol (PEG) oleate, neopelex
20-24 parts, 10-20 parts of cocoanut active charcoal.
2. a kind of preparation method of environmentally friendly diatom ceramic tile joint trimming agent, comprises the following steps：
1) by 5-15 parts of Portland cement, 7-18 parts of diatom ooze, 38-56 parts of filler, neopelex 20-24
Part, 15-25 parts of epoxy resin, 10-20 parts of cocoanut active charcoal and the mixing of 1-3 parts of Nano silver grain, pour into grinder, it is fine ground extremely
The powder of finishing is made in 600-1000 mesh, screening, standby；
2) step 1) obtained by mixture be added in 60-76 parts of deionized water, at a temperature of 91 DEG C, stir 25 minutes, stirring
Fresh air is constantly passed through simultaneously, then through filtering, filter cake dries, is ground to 800 mesh powder, standby；
3) by step 2) made from powder and 7-12 parts of Epoxy Modified Styrene Acrylate Emulsion, cation-modified styrene-acrylic emulsion 17-23 parts, silicon
7-11 parts of alkane modified fluoride-containing acrylic emulsion, the 10-20 parts of mixing of 5-15 parts of auxiliary agent and zinc stearate add and carry enamel or stainless
In the reactor of steel, with 10 DEG C per hour of speed, 50 DEG C are warming up to, constant temperature is maintained；
4) to step 3) mixed solution in add 10-20 part of polyethylene glycol (PEG) oleate, stirring 5-10 minutes, then heat to
80-90 DEG C, cooling is placed in insulation is placed in without sunlight irradiation place after 30 minutes；
5) by step 4) made from stirring and dissolving, filtering, discharging in mixed powder, get product.
3. environmentally friendly diatom ceramic tile joint trimming agent according to claim 1, it is characterised in that described filler is by 400-500 mesh
Silica and the mesh of 450 mesh -500 calcium carbonate according to weight ratio be 11:7 mixing compositions.
4. environmentally friendly diatom ceramic tile joint trimming agent according to claim 1, it is characterised in that the auxiliary agent includes thixotropic agent, stream
Flat agent, defoamer, the auxiliary component and ratio be, thixotropic agent: levelling agent: defoamer=6: 2: 2.
5. environmentally friendly diatom ceramic tile joint trimming agent according to claim 1, it is characterised in that the cocoanut active charcoal is to use
Granular activated carbon made from the gas way of distillation or kiln process.
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| CN201710555709.1A CN107141904A (en) | 2017-07-10 | 2017-07-10 | A kind of environmentally friendly diatom ceramic tile joint trimming agent and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107652835A (en) * | 2017-09-21 | 2018-02-02 | 福州三坊建材有限公司 | A kind of two-component antibacterial anti-fouling epoxy joint trimming agent and preparation method thereof |
| CN107721296A (en) * | 2017-09-22 | 2018-02-23 | 江苏昶浩建材有限公司 | A kind of environmentally friendly jointing agent of ceramic tile |
| CN107814529A (en) * | 2017-09-22 | 2018-03-20 | 江苏昶浩建材有限公司 | A kind of preparation technology of the environmentally friendly jointing agent of ceramic tile |
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| CN107652835A (en) * | 2017-09-21 | 2018-02-02 | 福州三坊建材有限公司 | A kind of two-component antibacterial anti-fouling epoxy joint trimming agent and preparation method thereof |
| CN107652835B (en) * | 2017-09-21 | 2019-10-25 | 福州三坊建材有限公司 | A kind of two-component antibacterial anti-fouling epoxy joint trimming agent and preparation method thereof |
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| CN108610718A (en) * | 2018-05-24 | 2018-10-02 | 合肥语林装饰工程有限公司 | A kind of novel joint trimming agent and preparation method thereof |
| CN112341901A (en) * | 2020-11-03 | 2021-02-09 | 濮阳职业技术学院 | Architectural decoration material for floor |
| CN114907734A (en) * | 2022-06-17 | 2022-08-16 | 山东尚雅建材有限公司 | Formula of seam beautifying agent capable of adsorbing formaldehyde and preparation process thereof |
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Application publication date: 20170908 |