CN110124392A - A kind of zinc for teenagers growth, calcium mineralising composite filter element and preparation method thereof - Google Patents

A kind of zinc for teenagers growth, calcium mineralising composite filter element and preparation method thereof Download PDF

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Publication number
CN110124392A
CN110124392A CN201910258399.6A CN201910258399A CN110124392A CN 110124392 A CN110124392 A CN 110124392A CN 201910258399 A CN201910258399 A CN 201910258399A CN 110124392 A CN110124392 A CN 110124392A
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modified
parts
filter element
composite filter
smithsonite
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范奇
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Wuhan In Water Environmental Protection Science And Technology Ltd Co
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Wuhan In Water Environmental Protection Science And Technology Ltd Co
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/14Other self-supporting filtering material ; Other filtering material
    • B01D39/20Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/68Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Engineering & Computer Science (AREA)
  • Hydrology & Water Resources (AREA)
  • Geology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Water Treatment By Sorption (AREA)
  • Filtering Materials (AREA)

Abstract

The present invention provides the preparation method of a kind of zinc for teenagers growth, calcium mineralising composite filter element, the following steps are included: modified: being modified processing respectively to natural quartz porphyry, natural clinoptilolite, natural calcite and natural smithsonite, obtain modified quartz porphyry, modified zeolite, modified calcite and modified smithsonite;Mixing: modified quartz porphyry, modified zeolite, modified calcite, modified smithsonite, active carbon and binder are weighed and is uniformly mixed, solid mixture is obtained;It is sintered, demoulding dedusting: solid mixture being put into mold and is sintered, dedusting is demoulded after the completion of sintering, be cooled to room temperature to get mineralising composite filter element is arrived.The present invention also provides a kind of zinc for teenagers growth, calcium mineralising composite filter element.Zinc provided by the invention, calcium mineralising composite filter element is safe, without secondary pollution, heavy metal free is exceeded;Calcium containing mineral matter element and trace element zinc, can increase the calcium content and Zn content of water outlet under the conditions of water flowing, suitable teenager drinks.

Description

A kind of zinc for teenagers growth, calcium mineralising composite filter element and preparation method thereof
Technical field
The present invention relates to pure water remineralization field of material preparation more particularly to a kind of zinc for teenagers growth, calcium mine Change composite filter element and preparation method thereof.
Background technique
Big health industry is a Main way of today's society economic development, and water is object indispensable in people's life Matter, therefore health of drinking water is particularly important.Household water filter has stepped into huge numbers of families at present, provides safety for resident Drinking water, and provide the safely and effectively mineralising filter core of the water purifier product of healthy water due to lacking core, lead to not mention For healthy water truly.
Pursuit with consumer to quality of the life, drinking-water health, industry consumption upgrading increase, and current mineralization ball occupies The market share it is smaller and smaller, and the natural rock mineralising filter core based on modified proportion technique is just gradually occupying the market mainstream, together When, the understanding that deepens continuously with consumer to healthy water, healthy water use, for the demand of healthy drinking water also gradually walk to Diversification, the requirement such as different crowd, different constitutions to quality of drinking water is different, water quality of the different usage scenarios to drinking water It is required that also different.
Currently, having there are some products for the drinking water of different crowd and constitution in the market, as NongFuShanQuan is released Infant's drinking water, the high strontium mineral water for the elderly that ether brand is released, there are also the mineral waters of some Changshou villages, still This group of teenager is but paid close attention to less, is also easy to be ignored by everybody, and teenager is the Huang of people's growth and development in the stage Golden age bracket, therefore a drinking water mineralising filter core for population of adolescent of exploitation is particularly important.
Summary of the invention
In view of this, the present invention provides a kind of zinc for teenagers growth, calcium mineralising composite filter element, by natural rich Zinc calcic rock modification is made, and can increase zinc, calcium content in water outlet, and the water handled through the filter core is suitble to teenager's drink With, may advantageously facilitate adolescent growth development, improve intelligence, whet the appetite, strengthen immunity, promote skeleton development;The present invention Additionally provide a kind of preparation method for the zinc of teenagers growth, calcium mineralising composite filter element of simple process.
The present invention provides the preparation method of a kind of zinc for teenagers growth, calcium mineralising composite filter element, including following step It is rapid:
S1, it is modified: natural quartz porphyry, natural clinoptilolite, natural calcite and natural smithsonite are changed respectively Property processing, obtain modified quartz porphyry, modified zeolite, modified calcite and modified smithsonite;
Mixing: S2 weighs modified quartz porphyry, modified zeolite, modified calcite, modified smithsonite, active carbon and bonding Agent is uniformly mixed, and obtains solid mixture;
S3, sintering, demoulding dedusting: the solid mixture of step S2 being put into mold and is sintered, de- after the completion of sintering Mould dedusting is cooled to room temperature to get mineralising composite filter element is arrived.
Further, the modified quartz porphyry is prepared by the following method: natural quartz porphyry is crushed, it is ground Sieve, be then placed in acetic acid solution and impregnate, then use deionized water supersound washing, then dry, be cooled to room temperature, sieving, i.e., Obtain modified quartz porphyry.
Further, the modified zeolite is prepared by the following method: then natural clinoptilolite is broken, sieving is soaked Then stain is immersed in the alkaline solution modulated by magnesite rock in phosphoric acid solution, then with deionized water supersound washing, then It with deionized water supersound washing, then roasts, is ground up, sieved after cooling to get modified zeolite is arrived.
Further, the modified calcite is prepared by the following method: natural calcite being crushed, is ground up, sieved, so It is immersed in the mixed solution of calcium chloride and sodium bicarbonate afterwards, then with deionized water supersound washing, it is dry, it is cooled to room temperature, mistake It sieves to get modified calcite is arrived.
Further, the modified smithsonite is prepared by the following method: natural smithsonite being crushed, is ground up, sieved, is roasted It burns, is then immersed in by quick lime and the alkaline solution of ferric sulfate modulation, then use deionized water supersound washing, it is dry, it cools down To room temperature, it is sieved to get modified smithsonite is arrived.
Further, in step S3, the temperature of sintering is 250 DEG C, pressure 15MPa.
Further, it is the pickling cocoanut active charcoal of 35~325 mesh that the active carbon, which selects partial size,;The binder is selected Ultra high molecular polyethylene.
The present invention also provides it is a kind of using made from the above method be used for teenagers growth zinc, calcium mineralising composite filter element, Raw material including following mass parts: major ingredient: modified 5~8 parts of quartz porphyry, 10~15 parts of modified zeolite, modified calcite 3~5 Part, modified 1~3 part of smithsonite;Auxiliary material: 60~120 parts of active carbon, 20~40 parts of binder.
Further, the raw material including following mass parts: major ingredient: modified 6 parts of quartz porphyry, it is 12 parts of modified zeolite, modified 4 parts of calcite, modified 2 parts of smithsonite;Auxiliary material: 65 parts of active carbon, 25 parts of binder.
Further, the raw material including following mass parts: major ingredient: modified 7 parts of quartz porphyry, it is 14 parts of modified zeolite, modified 5 parts of calcite, modified 2 parts of smithsonite;Auxiliary material: 80 parts of active carbon, 36 parts of binder.
Technical solution provided by the invention has the benefit that zinc provided by the invention, calcium mineralising composite filter element peace Entirely, without secondary pollution, heavy metal free is exceeded;Calcium containing mineral matter element and trace element zinc can increase water outlet under the conditions of water flowing Calcium content and Zn content, suitable teenager drinks;Preparation method simple process provided by the invention is suitable for large-scale production.
Detailed description of the invention
Fig. 1 is a kind of process signal of zinc, the preparation method of calcium mineralising composite filter element for teenagers growth of the present invention Figure.
Specific embodiment
To make the object, technical solutions and advantages of the present invention clearer, below in conjunction with attached drawing to embodiment party of the present invention Formula is further described.
The embodiment provides a kind of zinc for teenagers growth, calcium mineralising composite filter element, including following matter Measure the raw material of part: major ingredient: modified 5~8 parts of quartz porphyry, 10~15 parts of modified zeolite, modified 3~5 parts of calcite, modified water chestnut zinc 1~3 part of mine;Auxiliary material: 60~120 parts of active carbon, 20~40 parts of binder;Wherein, it is 35~325 purposes that active carbon, which selects partial size, Pickling cocoanut active charcoal;It is the ultra high molecular polyethylene of 35~325 mesh that binder, which selects partial size,.
In above-mentioned raw materials, the preparation process of modified quartz porphyry are as follows: natural quartz porphyry is crushed, is ground, cross 35 mesh and Then powdered quartz porphyry is impregnated 3h by 200 mesh screens in 0.5mol/L acetic acid solution, then with deionized water in ultrasound 2h is washed in wave cleaning device, it is then sufficiently dry in 200 DEG C of circulating baking ovens, after being cooled to room temperature, cross 35 mesh and 200 mesh Sieve is to get to modified quartz porphyry.
The preparation process of modified zeolite are as follows: natural clinoptilolite is crushed, 6 mesh and 18 mesh screens is crossed, then will tiltedly send out boiling Stone particle is immersed in 3h in the phosphoric acid solution of 0.2mol/L, then 2h is washed in ultrasonic washing instrument with deionized water, then will The modified zeolite of acid is immersed in 2.5h in the alkaline solution modulated by magnesite rock that pH is 11, then with deionized water super Wash 2 hours in sound wave cleaning device, then roast 2h under 400 DEG C of -500 DEG C of high temperature, after cooling, grinding, cross 100 mesh and 325 meshes to get arrive modified zeolite;The wherein preparation process of the alkaline solution of magnesite rock modulation are as follows: by magnesite rock It is soluble in water, it has bicarbonate ion dissolution and is taken out magnesite rock, the solution left is i.e. when detecting that pH value is 11 For the alkaline solution of magnesite rock modulation.
The preparation process of modified calcite are as follows: natural calcite is crushed, is ground, crosses 100 mesh and 200 mesh screens, then Powdered calcite is immersed in the mixed solution of calcium chloride and sodium bicarbonate for 24 hours, then clear in ultrasonic wave with deionized water It washes and washs 2h in instrument, it is then sufficiently dry in 200 DEG C of circulating baking ovens, after being cooled to room temperature, 100 mesh and 200 mesh screens are crossed, Obtain modified calcite.
The preparation process of modified smithsonite are as follows: natural smithsonite is crushed, is ground, 200 mesh and 325 mesh screens are crossed, 500 2h is roasted under DEG C -625 DEG C of high temperature, it is 9.5 to be modulated by quick lime and ferric sulfate that powdered smithsonite, which is then immersed in pH, Alkaline solution in 3h, then 2 hours are washed in ultrasonic washing instrument with deionized water, are filled in 200 DEG C of circulating baking ovens Divide drying, after being cooled to room temperature, crosses 200 mesh and 325 meshes to get modified smithsonite is arrived;Wherein, quick lime and ferric sulfate modulation Alkaline solution preparation process are as follows: quick lime and ferric sulfate are added to the water be configured to pH value be 9.5 solution.
Referring to FIG. 1, the embodiments of the present invention also provide the above-mentioned zinc for teenagers growth, calcium mineralising composite filter element Preparation method, comprising the following steps:
Step S1, it is modified: according to above-mentioned technique to natural quartz porphyry, natural clinoptilolite, natural calcite and natural Smithsonite is modified processing respectively, obtains modified quartz porphyry, modified zeolite, modified calcite and modified smithsonite;
Step S2, mixing: in parts by mass, weighing 5~8 parts of modified quartz porphyry, and 10~15 parts of modified zeolite, modification side 3~5 parts of stone of solution, modified 1~3 part of smithsonite, 60~120 parts of pickling cocoanut active charcoal, 20~40 parts of ultra high molecular polyethylene mixed It closes uniformly, obtains solid mixture;
Sintering, demoulding dedusting: solid mixture is pumped into sintering continuous tunnel furnace by certain speed using material system is taken out by step S3 Mold in, mold given to the pressure of 15MPa, tunnel furnace temperature is adjusted to 250 DEG C, adjusts continuous tunnel furnace flowing water linear velocity, is protected The card firing time reaches 40min, and after the completion of sintering, demoulding using automatic dust dedusting, is cooled to room temperature, i.e. production obtains Mineralising composite filter element.
Below with reference to embodiment to zinc, calcium mineralising composite filter element and its preparation provided by the present invention for teenagers growth Method is described in detail.
In following embodiment, quartz porphyry picks up from Shangri-La, Yunnan Province, and zeolite picks up from Shandong Laixi clinoptilolite, calcite Laibin, Guangxi Province is picked up from, smithsonite picks up from Guangxi Rongxian county.
Processing is modified to quartz porphyry, zeolite, calcite, smithsonite respectively according to above-mentioned modified technique, is changed Property quartz porphyry, modified zeolite, modified calcite and modified smithsonite, in embodiment 1- embodiment 4.
Embodiment 1:
Weigh modified quartz porphyry 5g, modified zeolite 10g, modified calcite 3g, modified smithsonite 1g, partial size is 80~ The pickling cocoanut active charcoal 60g of 325 mesh, partial size are that the ultra high molecular polyethylene 20g of 80~325 mesh is uniformly mixed, and are pumped into sintering In the mold of continuous tunnel furnace, mold is given to the pressure of 15MPa, tunnel furnace temperature is adjusted to 250 DEG C, adjusts continuous tunnel furnace flowing water linear speed Degree, guarantees that the firing time reaches 40min, is finally cooled to room temperature sintering carbon-point demoulding, i.e., and with automatic dust dedusting Obtain 7 cun, the zinc under the conditions of flow velocity 1.0L/min, calcium mineralising composite filter element.
In embodiment 1, every 1g is portion.
Embodiment 2:
Weigh above-mentioned modified quartz porphyry 8g, modified zeolite 15g, modified calcite 5g, modified smithsonite 3g, pickling coconut husk Active carbon 120g, ultra high molecular polyethylene 40g are uniformly mixed, and are pumped into the mold of sintering continuous tunnel furnace, are given 15MPa's for mold Pressure, tunnel furnace temperature adjust to 250 DEG C, adjust continuous tunnel furnace flowing water linear velocity, guarantee that the firing time reaches 40min, finally will Be sintered carbon-point demoulding, and with automatic dust dedusting, be cooled to room temperature to get under the conditions of 8 cun, flow velocity 1.5L/min zinc, Calcium mineralising composite filter element.
In embodiment 2, every 1g is portion.
Embodiment 3:
Weigh above-mentioned modified quartz porphyry 6g, modified zeolite 12g, modified calcite 4g, modified smithsonite 2g, pickling coconut husk Active carbon 65g, ultra high molecular polyethylene 25g are uniformly mixed, and are pumped into the mold of sintering continuous tunnel furnace, are given 15MPa's for mold Pressure, tunnel furnace temperature adjust to 250 DEG C, adjust continuous tunnel furnace flowing water linear velocity, guarantee that the firing time reaches 40min, finally will Be sintered carbon-point demoulding, and with automatic dust dedusting, be cooled to room temperature to get under the conditions of 7 cun, flow velocity 1.5L/min zinc, Calcium mineralising composite filter element.
In embodiment 3, every 1g is portion.
Embodiment 4:
Weigh above-mentioned modified quartz porphyry 7g, modified zeolite 14g, modified calcite 5g, modified smithsonite 2g, pickling coconut husk Active carbon 80g, ultra high molecular polyethylene 36g are uniformly mixed, and are pumped into the mold of sintering continuous tunnel furnace, are given 15MPa's for mold Pressure, tunnel furnace temperature adjust to 250 DEG C, adjust continuous tunnel furnace flowing water linear velocity, guarantee that the firing time reaches 40min, finally will Be sintered carbon-point demoulding, and with automatic dust dedusting, be cooled to room temperature to get under the conditions of 8 cun, flow velocity 1.5L/min zinc, Calcium mineralising composite filter element.
In embodiment 4, every 1g is portion.
Water test is carried out to zinc made from embodiment 1- embodiment 4, calcium mineralising composite filter element, is found under the conditions of water flowing TDS (Total dissolved solids, total dissolved solidss), which stablizes, in the water filtered through zinc, calcium mineralising composite filter element increases 3- 10mg/L, calcium constituent incrementss are in 0.5~2mg/L, and Zn-ef ficiency incrementss are in 0.01~0.1mg/L, and filter core complies fully with " Drinking Water transmission & distribution wetting system and protective materials health safety evaluation norms " health, which is impregnated, to be required.
In the absence of conflict, the feature in embodiment and embodiment herein-above set forth can be combined with each other.
The foregoing is merely presently preferred embodiments of the present invention, is not intended to limit the invention, it is all in spirit of the invention and Within principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.

Claims (10)

1. the preparation method of a kind of zinc for teenagers growth, calcium mineralising composite filter element, which is characterized in that including following step It is rapid:
S1, it is modified: place is modified respectively to natural quartz porphyry, natural clinoptilolite, natural calcite and natural smithsonite Reason obtains modified quartz porphyry, modified zeolite, modified calcite and modified smithsonite;
Mixing: S2 it is mixed to weigh modified quartz porphyry, modified zeolite, modified calcite, modified smithsonite, active carbon and binder It closes uniformly, obtains solid mixture;
Sintering, demoulding dedusting: S3 the solid mixture of step S2 is put into mold and is sintered, demoulding removes after the completion of sintering Dirt is cooled to room temperature to get mineralising composite filter element is arrived.
2. the preparation method of the zinc according to claim 1 for teenagers growth, calcium mineralising composite filter element, feature exist In the modified quartz porphyry is prepared by the following method: natural quartz porphyry being crushed, is ground up, sieved, second is then placed within It is impregnated in acid solution, then with deionized water supersound washing, then dries, be cooled to room temperature, sieving is to get to modified quartzy spot Rock.
3. the preparation method of the zinc according to claim 1 for teenagers growth, calcium mineralising composite filter element, feature exist In the modified zeolite is prepared by the following method: then natural clinoptilolite is broken, sieving is immersed in phosphoric acid solution, Deionized water supersound washing is used again, is then immersed in the alkaline solution modulated by magnesite rock, then ultrasonic with deionized water Washing, then roasts, and is ground up, sieved after cooling to get modified zeolite is arrived.
4. the preparation method of the zinc according to claim 1 for teenagers growth, calcium mineralising composite filter element, feature exist In the modified calcite is prepared by the following method: natural calcite being crushed, is ground up, sieved, calcium chloride is then immersed in It is dry in the mixed solution of sodium bicarbonate, then with deionized water supersound washing, it is cooled to room temperature, sieving is to get arriving modification side Xie Shi.
5. the preparation method of the zinc according to claim 1 for teenagers growth, calcium mineralising composite filter element, feature exist In the modified smithsonite is prepared by the following method: natural smithsonite being crushed, is ground up, sieved, roasts, is then immersed in In the alkaline solution modulated by quick lime and ferric sulfate, then deionized water supersound washing is used, it is dry, it is cooled to room temperature, sieving, i.e., Obtain modified smithsonite.
6. the preparation method of the zinc according to claim 1 for teenagers growth, calcium mineralising composite filter element, feature exist In in step S3, the temperature of sintering is 250 DEG C, pressure 15MPa.
7. the preparation method of the zinc according to claim 1 for teenagers growth, calcium mineralising composite filter element, feature exist In it is the pickling cocoanut active charcoal of 35~325 mesh that the active carbon, which selects partial size,;The binder selects the poly- second of supra polymer Alkene.
8. a kind of utilize the zinc, the calcium mineralising that are used for teenagers growth made from the described in any item preparation methods of claim 1-7 Composite filter element, which is characterized in that the raw material including following mass parts: major ingredient: modified 5~8 parts of quartz porphyry, modified zeolite 10~ 15 parts, modified 3~5 parts of calcite, modified 1~3 part of smithsonite;Auxiliary material: 60~120 parts of active carbon, 20~40 parts of binder.
9. the zinc according to claim 8 for teenagers growth, calcium mineralising composite filter element, which is characterized in that including with The raw material of lower mass parts: major ingredient: modified 6 parts of quartz porphyry, 12 parts of modified zeolite, modified 4 parts of calcite, modified 2 parts of smithsonite; Auxiliary material: 65 parts of active carbon, 25 parts of binder.
10. the zinc according to claim 8 for teenagers growth, calcium mineralising composite filter element, which is characterized in that including with The raw material of lower mass parts: major ingredient: modified 7 parts of quartz porphyry, 14 parts of modified zeolite, modified 5 parts of calcite, modified 2 parts of smithsonite; Auxiliary material: 80 parts of active carbon, 36 parts of binder.
CN201910258399.6A 2019-04-01 2019-04-01 A kind of zinc for teenagers growth, calcium mineralising composite filter element and preparation method thereof Pending CN110124392A (en)

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Cited By (4)

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CN113149124A (en) * 2021-04-07 2021-07-23 青岛经济技术开发区海尔热水器有限公司 Water body mineralized rock combination and application thereof
CN113304547A (en) * 2021-06-11 2021-08-27 武汉中地水石环保科技有限公司 Zinc-mineralized composite filter material, preparation method thereof and zinc-mineralized composite filter element
CN114229981A (en) * 2021-12-17 2022-03-25 青岛海尔施特劳斯水设备有限公司 Mineralized filter element and preparation method thereof
CN117164351A (en) * 2023-08-10 2023-12-05 山东鑫永恒新材料有限公司 Calcium-rich slow-release mineralized material and preparation method thereof

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CN108675429A (en) * 2018-05-21 2018-10-19 中国地质大学(武汉) A kind of alkalescent zinc, the complex sintered active carbon filter core of strontium mineralising and preparation method thereof
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CN108722018A (en) * 2018-05-03 2018-11-02 武汉中地水石环保科技有限公司 A kind of strontium mineralising filter core and preparation method thereof based on natural rock material
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Publication number Priority date Publication date Assignee Title
CN113149124A (en) * 2021-04-07 2021-07-23 青岛经济技术开发区海尔热水器有限公司 Water body mineralized rock combination and application thereof
CN113149124B (en) * 2021-04-07 2023-07-14 青岛经济技术开发区海尔热水器有限公司 Water mineralized rock composition and application thereof
CN113304547A (en) * 2021-06-11 2021-08-27 武汉中地水石环保科技有限公司 Zinc-mineralized composite filter material, preparation method thereof and zinc-mineralized composite filter element
CN113304547B (en) * 2021-06-11 2024-03-29 武汉中地水石环保科技有限公司 Zinc mineralization composite filter material, preparation method thereof and zinc mineralization composite filter element
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CN117164351A (en) * 2023-08-10 2023-12-05 山东鑫永恒新材料有限公司 Calcium-rich slow-release mineralized material and preparation method thereof
CN117164351B (en) * 2023-08-10 2024-03-19 山东鑫永恒新材料有限公司 Calcium-rich slow-release mineralized material and preparation method thereof

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Application publication date: 20190816