CN113121915B - 家电产品用无卤阻燃石墨烯改性的阻燃聚丙烯材料 - Google Patents
家电产品用无卤阻燃石墨烯改性的阻燃聚丙烯材料 Download PDFInfo
- Publication number
- CN113121915B CN113121915B CN202110427843.XA CN202110427843A CN113121915B CN 113121915 B CN113121915 B CN 113121915B CN 202110427843 A CN202110427843 A CN 202110427843A CN 113121915 B CN113121915 B CN 113121915B
- Authority
- CN
- China
- Prior art keywords
- retardant
- graphene oxide
- flame
- polypropylene
- halogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- -1 flame-retardant graphene modified flame-retardant Chemical class 0.000 title claims abstract description 180
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 152
- 239000000463 material Substances 0.000 title claims abstract description 98
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 97
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 97
- 239000003063 flame retardant Substances 0.000 title claims abstract description 72
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 117
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 39
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 39
- 238000002360 preparation method Methods 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 42
- 235000006708 antioxidants Nutrition 0.000 claims description 38
- 238000001035 drying Methods 0.000 claims description 28
- 238000010438 heat treatment Methods 0.000 claims description 28
- 238000005406 washing Methods 0.000 claims description 28
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 24
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 239000002244 precipitate Substances 0.000 claims description 19
- 238000003756 stirring Methods 0.000 claims description 19
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 18
- 229910010272 inorganic material Inorganic materials 0.000 claims description 17
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 16
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 15
- DZKXDEWNLDOXQH-UHFFFAOYSA-N 1,3,5,2,4,6-triazatriphosphinine Chemical compound N1=PN=PN=P1 DZKXDEWNLDOXQH-UHFFFAOYSA-N 0.000 claims description 13
- 150000002484 inorganic compounds Chemical class 0.000 claims description 13
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 12
- 125000000304 alkynyl group Chemical group 0.000 claims description 10
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 9
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 9
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 claims description 9
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 claims description 9
- 229920005629 polypropylene homopolymer Polymers 0.000 claims description 9
- USAVSXJFTZUOGV-UHFFFAOYSA-N 4-azidobutan-1-ol Chemical compound OCCCCN=[N+]=[N-] USAVSXJFTZUOGV-UHFFFAOYSA-N 0.000 claims description 8
- 239000002131 composite material Substances 0.000 claims description 8
- 238000001125 extrusion Methods 0.000 claims description 8
- 238000005469 granulation Methods 0.000 claims description 8
- 230000003179 granulation Effects 0.000 claims description 8
- 229960005070 ascorbic acid Drugs 0.000 claims description 7
- 235000010323 ascorbic acid Nutrition 0.000 claims description 7
- 239000011668 ascorbic acid Substances 0.000 claims description 7
- TVDSBUOJIPERQY-UHFFFAOYSA-N prop-2-yn-1-ol Chemical compound OCC#C TVDSBUOJIPERQY-UHFFFAOYSA-N 0.000 claims description 7
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 7
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 6
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 6
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 6
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 6
- 238000002390 rotary evaporation Methods 0.000 claims description 6
- 238000009210 therapy by ultrasound Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 20
- 238000012360 testing method Methods 0.000 description 20
- 230000000052 comparative effect Effects 0.000 description 19
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- VHXXDVGCVGDKLH-UHFFFAOYSA-N 2-phenoxy-1,3,5-triaza-2lambda5,4,6-triphosphacyclohexa-1,3,5-triene-2-carboxylic acid Chemical class C(=O)(O)P1(=NP=NP=N1)OC1=CC=CC=C1 VHXXDVGCVGDKLH-UHFFFAOYSA-N 0.000 description 11
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 11
- 229910052698 phosphorus Inorganic materials 0.000 description 11
- 239000011574 phosphorus Substances 0.000 description 11
- 239000000126 substance Substances 0.000 description 11
- 238000002485 combustion reaction Methods 0.000 description 10
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 10
- 239000000347 magnesium hydroxide Substances 0.000 description 10
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 10
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 10
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 229910052710 silicon Inorganic materials 0.000 description 9
- 239000010703 silicon Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 230000005611 electricity Effects 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 239000004033 plastic Substances 0.000 description 8
- 229920003023 plastic Polymers 0.000 description 8
- 230000003068 static effect Effects 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 7
- 230000002776 aggregation Effects 0.000 description 6
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 5
- 238000001746 injection moulding Methods 0.000 description 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 150000002367 halogens Chemical class 0.000 description 4
- 239000011147 inorganic material Substances 0.000 description 4
- 150000002736 metal compounds Chemical class 0.000 description 4
- 238000000197 pyrolysis Methods 0.000 description 4
- 125000001425 triazolyl group Chemical group 0.000 description 4
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 238000005054 agglomeration Methods 0.000 description 3
- 238000004220 aggregation Methods 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 3
- 238000005452 bending Methods 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 239000002086 nanomaterial Substances 0.000 description 3
- 238000011056 performance test Methods 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- RGHHSNMVTDWUBI-UHFFFAOYSA-N 4-hydroxybenzaldehyde Chemical compound OC1=CC=C(C=O)C=C1 RGHHSNMVTDWUBI-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 125000000852 azido group Chemical group *N=[N+]=[N-] 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000003763 carbonization Methods 0.000 description 2
- 238000006006 cyclotrimerization reaction Methods 0.000 description 2
- 239000012796 inorganic flame retardant Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 150000002680 magnesium Chemical class 0.000 description 2
- 150000002815 nickel Chemical class 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- KSCAZPYHLGGNPZ-UHFFFAOYSA-N 3-chloropropyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)CCCCl KSCAZPYHLGGNPZ-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000012661 block copolymerization Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000021615 conjugation Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000012377 drug delivery Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003000 extruded plastic Substances 0.000 description 1
- UBIJTWDKTYCPMQ-UHFFFAOYSA-N hexachlorophosphazene Chemical compound ClP1(Cl)=NP(Cl)(Cl)=NP(Cl)(Cl)=N1 UBIJTWDKTYCPMQ-UHFFFAOYSA-N 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002991 molded plastic Substances 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 102220040412 rs587778307 Human genes 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2293—Oxides; Hydroxides of metals of nickel
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
拉伸强度/MPa | |
实施例1 | 25.4 |
实施例2 | 35.8 |
实施例3 | 33.1 |
实施例4 | 34.3 |
对比例1 | 30.2 |
对比例2 | 27.9 |
悬臂梁缺口冲击强度/(kJ/m<sup>2</sup>) | |
实施例1 | 4.69 |
实施例2 | 6.94 |
实施例3 | 6.65 |
实施例4 | 6.76 |
对比例1 | 6.22 |
对比例2 | 5.95 |
氧指数/% | |
实施例1 | 24.3 |
实施例2 | 37.9 |
实施例3 | 35.2 |
实施例4 | 36.4 |
对比例1 | 32.7 |
对比例2 | 30.4 |
垂直燃烧/(UL 94 1.6mm) | |
实施例1 | V-2 |
实施例2 | V-0 |
实施例3 | V-0 |
实施例4 | V-0 |
对比例1 | V-1 |
对比例2 | V-2 |
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202110427843.XA CN113121915B (zh) | 2021-04-21 | 2021-04-21 | 家电产品用无卤阻燃石墨烯改性的阻燃聚丙烯材料 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202110427843.XA CN113121915B (zh) | 2021-04-21 | 2021-04-21 | 家电产品用无卤阻燃石墨烯改性的阻燃聚丙烯材料 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN113121915A CN113121915A (zh) | 2021-07-16 |
CN113121915B true CN113121915B (zh) | 2022-03-04 |
Family
ID=76778327
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202110427843.XA Active CN113121915B (zh) | 2021-04-21 | 2021-04-21 | 家电产品用无卤阻燃石墨烯改性的阻燃聚丙烯材料 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN113121915B (zh) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11591457B1 (en) * | 2022-03-30 | 2023-02-28 | Lyten, Inc. | Composite material including three-dimensional (3D) graphene and maleated copolymers |
US11813774B2 (en) | 2022-03-30 | 2023-11-14 | Lyten, Inc. | Method of producing a composite material including three-dimensional (3D) graphene |
US11674031B1 (en) | 2022-03-30 | 2023-06-13 | Lyten, Inc. | Container formed of a composite material including three-dimensional (3D) graphene |
US12006388B2 (en) | 2022-03-30 | 2024-06-11 | Lyten, Inc. | Composite material including three-dimensional (3D) graphene |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106430172A (zh) * | 2015-08-07 | 2017-02-22 | 北京化工大学 | 一种氢氧化镁/氧化石墨烯复合材料及其制备方法与应用 |
CN106883450A (zh) * | 2017-02-20 | 2017-06-23 | 无锡市惠山区川大石墨烯应用研究中心 | 一种富磷化石墨烯阻燃剂及其制备方法 |
CN108314787A (zh) * | 2018-03-15 | 2018-07-24 | 厦门大学 | 一种含磷氮硅聚合物改性氧化石墨烯阻燃剂及其制备方法 |
CN108707236A (zh) * | 2018-05-02 | 2018-10-26 | 济南大学 | 点击化学合成氧化石墨烯接枝含氟聚合物的制备方法 |
WO2018201715A1 (zh) * | 2017-05-03 | 2018-11-08 | 广州特种承压设备检测研究院 | 石墨烯与四氧化三铁@金复合材料及其制备方法和应用 |
US20190249084A1 (en) * | 2016-09-12 | 2019-08-15 | The University Of Adelaide | Graphene-based composite flame retardants |
CN110804245A (zh) * | 2019-11-18 | 2020-02-18 | 中国科学院青海盐湖研究所 | 一种阻燃复合材料及其制备方法 |
-
2021
- 2021-04-21 CN CN202110427843.XA patent/CN113121915B/zh active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106430172A (zh) * | 2015-08-07 | 2017-02-22 | 北京化工大学 | 一种氢氧化镁/氧化石墨烯复合材料及其制备方法与应用 |
US20190249084A1 (en) * | 2016-09-12 | 2019-08-15 | The University Of Adelaide | Graphene-based composite flame retardants |
CN106883450A (zh) * | 2017-02-20 | 2017-06-23 | 无锡市惠山区川大石墨烯应用研究中心 | 一种富磷化石墨烯阻燃剂及其制备方法 |
WO2018201715A1 (zh) * | 2017-05-03 | 2018-11-08 | 广州特种承压设备检测研究院 | 石墨烯与四氧化三铁@金复合材料及其制备方法和应用 |
CN108314787A (zh) * | 2018-03-15 | 2018-07-24 | 厦门大学 | 一种含磷氮硅聚合物改性氧化石墨烯阻燃剂及其制备方法 |
CN108707236A (zh) * | 2018-05-02 | 2018-10-26 | 济南大学 | 点击化学合成氧化石墨烯接枝含氟聚合物的制备方法 |
CN110804245A (zh) * | 2019-11-18 | 2020-02-18 | 中国科学院青海盐湖研究所 | 一种阻燃复合材料及其制备方法 |
Non-Patent Citations (4)
Title |
---|
棉织物的六氯环三磷腈改性氧化石墨烯阻燃整理;许佳等;《印染》;20160815(第16期);第6-11,18页 * |
点击化学法修饰氧化石墨烯及其在高分子中的应用研究;熊军等;《高分子通报》;20170615(第06期);第68-74页 * |
通过"点击化学"对石墨烯和氧化石墨烯进行功能化改性;来常伟等;《化学学报》;20130915(第09期);第1201-1224页 * |
通过点击化学对氧化石墨烯进行改性的研究进展;吕生华等;《陕西科技大学学报》;20200425(第02期);第147-159,171页 * |
Also Published As
Publication number | Publication date |
---|---|
CN113121915A (zh) | 2021-07-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN113121915B (zh) | 家电产品用无卤阻燃石墨烯改性的阻燃聚丙烯材料 | |
Zhang et al. | A novel organic-inorganic hybrid K-HBPE@ APP performing excellent flame retardancy and smoke suppression for polypropylene | |
CN113150446B (zh) | 一种聚丙烯材料 | |
CN107286563B (zh) | 一种用于abs电器开关外罩的膨胀型阻燃剂及其制备与应用 | |
CN101280097A (zh) | 纳米阻燃聚对苯二甲酸乙二醇酯工程塑料及其制备方法 | |
CN108264720B (zh) | 一种无析出无卤素阻燃剂组合物 | |
Sun et al. | Improving the flame retardancy of polyamide 6 by incorporating hexachlorocyclotriphosphazene modified MWNT | |
CN103923450A (zh) | 金属离子处理蒙脱土协效阻燃pc/abs合金材料及其制备方法 | |
CN108102359A (zh) | 一种绿色环保、高性能、高cti阻燃增强尼龙材料及其制备方法 | |
CN1709968A (zh) | 无卤膨胀型阻燃聚烯烃复合物 | |
CN112029189A (zh) | 一种无卤阻燃聚丙烯复合材料及其制备方法 | |
Huang et al. | Flame retardant polypropylene with a single molecule intumescent flame retardant based on chitosan | |
CN108034126B (zh) | 无卤阻燃聚烯烃复合材料及其制备方法 | |
Zheng et al. | Fabrication of starch-based multi-source integrated halogen-free flame retardant in improving the fire safety of polypropylene | |
CN111363318B (zh) | 一种阻燃抑烟ptt聚酯复合材料及其制备方法 | |
CN112063163A (zh) | 一种防静电导热阻燃复合材料及其制备方法 | |
CN108250573B (zh) | 一种耐热氧老化的无卤环保阻燃聚丙烯材料及其制备方法 | |
Serbezeanu et al. | Poly (vinyl alcohol)-oligophosphonate eco-friendly composites with improved reaction-to-fire properties | |
CN115197528A (zh) | 一种阻燃abs复合材料及其制备方法 | |
CN113061302B (zh) | 汽车燃油箱底护板用无卤阻燃长玻纤增强pp复合材料 | |
CN111234367A (zh) | 一种阻燃抗静电聚丙烯薄膜复合材料及其制备方法 | |
CN115368673A (zh) | 一种石墨烯改性阻燃聚丙烯材料及其制备方法 | |
Jiang et al. | Improving the flame retardant and anti-dripping performance of polyamide 66 inspired by vegetable tanning | |
CN111363322B (zh) | 一种阻燃聚乳酸树脂组合物及其制备方法 | |
CN117089095B (zh) | 一种阻燃聚酰胺6薄膜的制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
EE01 | Entry into force of recordation of patent licensing contract | ||
EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20210716 Assignee: Guangdong Rongtong Financial Leasing Co.,Ltd. Assignor: Guangdong Yuhao New Material Technology Co.,Ltd. Contract record no.: X2022980013986 Denomination of invention: Flame retardant polypropylene material modified with halogen-free flame retardant graphene for home appliances Granted publication date: 20220304 License type: Exclusive License Record date: 20220902 |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Flame retardant polypropylene material modified with halogen-free flame retardant graphene for home appliances Effective date of registration: 20220906 Granted publication date: 20220304 Pledgee: Guangdong Rongtong Financial Leasing Co.,Ltd. Pledgor: Guangdong Yuhao New Material Technology Co.,Ltd. Registration number: Y2022980014581 |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20231101 Granted publication date: 20220304 Pledgee: Guangdong Rongtong Financial Leasing Co.,Ltd. Pledgor: Guangdong Yuhao New Material Technology Co.,Ltd. Registration number: Y2022980014581 |
|
PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
EC01 | Cancellation of recordation of patent licensing contract |
Assignee: Guangdong Rongtong Financial Leasing Co.,Ltd. Assignor: Guangdong Yuhao New Material Technology Co.,Ltd. Contract record no.: X2022980013986 Date of cancellation: 20231127 |
|
EC01 | Cancellation of recordation of patent licensing contract |