CN112933014A

CN112933014A - Natural shampoo product with rose flower and fruit stock solution formula and preparation method thereof

Info

Publication number: CN112933014A
Application number: CN202110252651.XA
Authority: CN
Inventors: 余和光
Original assignee: Chongqing Tuodao Agricultural Development Co ltd
Current assignee: Chongqing Tuodao Agricultural Development Co ltd
Priority date: 2021-03-09
Filing date: 2021-03-09
Publication date: 2021-06-11

Abstract

The invention discloses a natural shampoo product with a rose flower and fruit stock solution formula and a preparation method thereof, wherein the shampoo comprises the following components in percentage by weight: 60-70% of rose flower and fruit stock solution; 5-10% of corn steep liquor; 8-12% of a surfactant; 3-6% of an emulsifier; 1-3% of edible salt; 2-4% of dietary alkali and the balance of sweet wormwood herb and folium artemisiae argyi soaking liquid. The shampoo disclosed by the invention is environment-friendly, non-toxic, free of side effects, non-adhesive, low in preparation cost, free of any preservative or essence, and has a rose fragrance, can resist bacteria and remove dandruff, can be automatically degraded, does not influence the environment and water quality, and is environment-friendly and safe in plant formula.

Description

Natural shampoo product with rose flower and fruit stock solution formula and preparation method thereof

Technical Field

The invention relates to a natural shampoo product, in particular to a natural shampoo product with a rose flower and fruit stock solution formula and a preparation method thereof.

Background

At present, hundreds of hair washing products in domestic market are available, most of the hair washing products adopt chemically synthesized raw materials, and certain selected raw materials possibly have potential safety hazards to human health due to impurity-containing components, so that the safety risk is higher after long-term use. For example, formaldehyde-releasing agents, paraben preservatives have been reported to present a carcinogenic risk to humans; the kasong, the synthetic essence, the pigment and the like are easy to cause the skin allergy of the human body; the raw material containing an ethylene oxide structure can bring in trace amount of dioxane which is easy to cause carcinogenesis; some raw materials may inevitably carry impurity components harmful to human health in the chemical synthesis process, such as acrylamide monomer, chloroacetic acid, formaldehyde, methanol, nitrosamine, phenol and the like. In addition, after the shampoo products are used for a plurality of times for a long time, some conditioning agents such as polymers, silicone oil and the like in the components of the shampoo products are easy to accumulate on the hair, so that the hair is damaged, dry and itchy.

The existing shampoo not only hurts human skin, has side effects and cannot be degraded, but also cannot be degraded after being discharged into rivers to cause environmental pollution, and due to the characteristics of the shampoo, the shampoo usually needs to be soaked for a certain time before washing, is repeatedly scrubbed, wastes a large amount of fresh water, causes unnecessary loss to countries and individuals, causes endless deterioration to ecology, and has an unsatisfactory washing effect.

Although some researchers have proposed some shampoo products with plant formula, such as saponin tea, tea saponin, olive oil, ginger root, etc., the natural plant extract has low solubility at the lowest effective concentration, so that other chemical substances are often needed to be matched, which is why the application of the natural plant extract in the natural shampoo is not wide.

Therefore, the technology of the existing natural shampoo gradually focuses on the research and improvement of the natural surfactant, but the natural surfactant has a weak solubilizing effect, so that some water-insoluble oil or natural plant extract cannot be completely solubilized, and the main effect of the product developed on the market at present is focused on cleaning and softening hair, so that the natural shampoo has a weak effect on functionality such as nourishing scalp and maintaining scalp health.

In the conventional shampoo, chemically synthesized surfactants are widely used, and typical examples thereof include AES (laureth sulfate), K12 (lauryl sulfate ammonium salt), CAB (lauramidopropyl betaine), and the like. These synthetic surfactants require high temperature, strong acid and strong alkali environment during chemical synthesis, and thus inevitably produce various by-products such as dioxane in the production of AES. Harmful by-products in the synthesized surfactant seriously affect the safety of products and the health of human bodies.

Besides the cleaning function, the shampoo also needs to meet the requirements of consumers on functional effects, such as scalp nourishing, damaged hair restoration, dandruff removal and the like. However, the realization of these functions in the market at present is often completed by functional additives, including organosilicon, zinc compounds synthesized by chemical industry, and the like. Although the chemically synthesized additives have certain effects in the initial stage, the long-term use of the chemically synthesized additives can cause scalp itching, destroy human embryos and harm human health. Meanwhile, the synthetic additives are often insoluble in water and surfactants, are easily adsorbed on human scalp and hair, are permanently harmful to human bodies, and are also easily polluted to the environment.

Disclosure of Invention

In view of the above, the present invention aims to provide a natural shampoo product with a rose flower and fruit stock solution formula and a preparation method thereof, such as a shampoo, which has characteristics of environmental protection, no toxicity, no side effect, no adhesion, good solubility of active ingredients, no addition of any preservative or essence, rose fragrance, antibacterial and dandruff removing, automatic degradation, no influence on environment and water quality, and high-end shampoo.

The adopted technical scheme is as follows:

a natural shampoo product with a rose flower and fruit stock solution formula comprises the following components in percentage by weight:

preferably, the natural shampoo product of the rose flower and fruit stock solution formula is characterized by comprising the following components in percentage by weight:

preferably, the rose flower and fruit stock solution is prepared by the following method:

selecting materials, namely selecting fresh petals for roses; selecting the rose fruit with medium, thin, thick and yellow olive blanks;

rinsing, namely rinsing the rose with clear water and airing; soaking fructus Rosae Davuricae in clear water for about 12 hr to remove salt;

step three, sterilizing, namely lightly tapping the rosehips until the rosehips are slightly cracked, and respectively placing the rosehips and the rosehips in a sterilization environment;

frying, namely frying the sterilized rose fruits for 30-60 minutes at 300-400 ℃, then sending the fried materials into an oil press for squeezing and filtering, and adding water for degumming and precipitation after alkali refining and hydration to obtain rose fruit oil;

and step five, extracting, namely adding 2 times of deionized water into the rose and the rose hip oil according to the weight ratio of 1:5, distilling or decocting, and filtering or extracting the rose hip stock solution.

Preferably, the sweet wormwood herb and Chinese mugwort leaf soaking solution is prepared by the following method:

cleaning wild plants of herba Artemisiae Annuae and folium Artemisiae Argyi, sterilizing, adding 1 weight times of deionized water, decocting for 180min-240min, soaking for 24 hr, standing, and filtering to obtain herba Artemisiae Annuae and folium Artemisiae Argyi soak solution.

Preferably, the surfactant is one or more of AES, 6501, CAB and K12. Wherein the AES surfactant is fatty alcohol polyoxyethylene ether sodium sulfate; 6501 coconut oil fatty acid diethanolamide CAB is cocamidopropyl betaine; k12 is sodium lauryl sulfate.

Further preferred, the surfactants are AES, 6501, CAB and K12.

Preferably, the emulsifier is one or more of the OP series. The OP series includes OP-4,7,9,10,13,15,20,30,40, 50.

Further preferably, the emulsifier is OP-10.

The invention also provides a preparation method of the natural shampoo product with the rose flower and fruit stock solution formula, which comprises the following steps:

s1, blending rose flower and fruit stock solution and sweet wormwood and folium artemisiae argyi soaking solution;

s2, heating the mixed solution to 75-80 ℃, and stirring until the mixed solution is completely dissolved;

s3, cooling to below 30 ℃, and adding corn steep liquor;

s4, adding edible alkali, fully dissolving and stirring, and adjusting the pH value to 5.5-6.5;

s5, adding a surfactant and an emulsifier, and fully and uniformly stirring;

s6, adding edible salt to adjust viscosity uniformly, and performing ultrasonic dispersion to form semitransparent pale yellow liquid.

And further, S7, automatic high-pressure sterile filling and packaging are carried out.

In the technical scheme, 60-70% of rose flower and fruit stock solution is used as a main raw material, and the original fresh flower aromatic agent is used, so that the whole product forms a natural rose flower fragrant shampoo product; the characteristics of the corn steep liquor grain are mixed with the original source of the rose flowers and fruits, and the edible salt and the edible alkali are added to form the clean and environment-friendly rose flower fragrance shampoo. The corn steep liquor grain is mixed with rose stock solution, sweet wormwood herb and folium artemisiae argyi soaking solution, edible salt and edible alkali to form the effect of promoting the growth of scalp and hair quality.

The large amount of bacteria on the surface of scalp and the unbalanced number of flora are one of the important reasons for generating dandruff, and the shampoo disclosed by the invention contains antibacterial components (artemisia apiacea and artemisia argyi have the effects of resisting bacteria and relieving itching), can inhibit the growth and the propagation of the bacteria on the surface of scalp and has an obvious dandruff removing effect.

The edible salt is sodium chloride, and edible alkali is used for adjusting the pH value; the dietary alkali is soda ash, can remove redundant grease of oil hair, and can release nicotinic acid in corn steep liquor, thereby achieving the effect of removing dandruff. Surfactants such as CAB cocamidopropyl betaine and AES sodium alcohol ether sulphate, emulsifiers such as OP-10, AES and K12 foam rapidly but foam is not stable enough, so CAB and 6501 can be compounded for thickening, and the CAB and 6501 can make foam fine and stable, and can also be used for increasing the softness of hair. The emulsifier OP-10 plays a role in emulsification.

In conclusion, the beneficial effects of the invention are as follows:

the natural shampoo product prepared by taking the rose stock solution as a plant, the sweet wormwood herb and folium artemisiae argyi soak solution as a plant liquid medicine and the corn steep liquor decocted by the corn as the raw grain stock solution and mixing the plant fresh flower stock solution and the grain has the advantages of environmental protection, no toxicity, no side effect, no adhesion, low manufacturing cost, no addition of any preservative or essence, rose fragrance, antibiosis, scrap removal, automatic degradation and no influence on environment and water quality.

The natural shampoo product of the invention is composed of high-quality all-natural plant extract, does not contain hormone, does not add pigment and other chemical synthetics, and has no stimulation and side effect on human bodies after long-term continuous use. The natural plant stock solution contains various effective nutrient components such as saponin, alkaloid, amino acid, vitamin and the like which are easy to be absorbed by human bodies, so that the hair follicles can be deeply nourished after being frequently used, and the hair is smooth, elastic and natural and glossy.

The natural shampoo (such as shampoo, liquid shampoo and shampoo) can be used in a broad spectrum, including the old, children, pregnant women, allergic people and used as an over-the-counter adjuvant therapy for scalp pruritus, and can increase the absorption of effective nutrient components on the head, promote blood circulation, reduce or remove scalp pruritus and prevent premature hair loss.

Detailed Description

The present invention is described in detail below with reference to specific examples, but the use and purpose of these exemplary embodiments are merely to exemplify the present invention, and do not set forth any limitation on the actual scope of the present invention in any form, and the scope of the present invention is not limited thereto.

Example 1

The natural shampoo product of the rose flower and fruit stock solution formula in the embodiment comprises the following components in percentage by weight:

The wild rose contains 17 kinds of amino acids required by human body, and the total amount of the amino acids is up to 10.9 percent, which is a preferred material for preparing natural shampoo products. In the invention, the rose and rose fruit are preferably wild varieties.

The rose is rich in protein, fat, starch, various amino acids and vitamins, and also rich in macroelements, microelements and other various essential nutrients for human body. The protein content in the rose reaches 16.33 percent. The rose contains 17 kinds of amino acids necessary for human body, and the total amount of amino acids is up to 10.9%, and 7 kinds of the amino acids are necessary for human body, and account for 34.42% of the amino acid content. The rose contains a large amount of vitamin A, B, C, wherein the content of vitamin C is the most abundant.

The rose contains 4 main unsaturated fatty acids, Linoleic acid (Linolenic acid) contains 80.10%, Linolenic acid (Linolenic acid) contains 6.84%, oleic acid (oleic acid) contains 3.47%, and hexadecenoic acid (Cetenic acid) contains 0.23%.

The rose hip seeds have a high oil content, wherein the percentage of unsaturated fatty acids is high. The total content of essential fatty acid, namely linoleic acid (50.10%) and linolenic acid (29.77%) in the rose seed oil is close to 80%. Therefore, the rich vegetable oil contained in the rose hip seeds can well dissolve the effective components of the shampoo products. The fructus Rosae Davuricae also contains higher unsaturated fatty acids such as eicosadienoic acid and eicosatrienoic acid. The rose hip contains multiple nutrients and thus has unique function. The rose pectin extracted from rose hip has the functions of strengthening tissue, activating collateral tissue, easily permeating corium layer, regenerating, repairing and healing hair scales, and reconstructing and recovering damaged hair follicle. Especially compared with the hair designed by permanent dyeing, the hair dye has excellent color fixing and repairing effects.

The edible salt is sodium chloride, and edible alkali is used for adjusting the pH value; the dietary alkali is soda ash, can remove redundant grease of oil hair, and can release nicotinic acid in corn steep liquor, thereby achieving the effect of removing dandruff.

Surfactants such as CAB cocamidopropyl betaine and AES sodium alcohol ether sulphate, emulsifiers such as OP-10, AES and K12 foam rapidly but foam is not stable enough, so CAB and 6501 can be compounded for thickening, and the CAB and 6501 can make foam fine and stable, and can also be used for increasing the softness of hair. The emulsifier OP-10 plays a role in emulsification.

The shampoo prepared by the invention does not contain silicone oil components, and has the effects of controlling oil, relieving itching, nourishing scalp and improving the problems of dry hair and frizzy hair. The long-term use of the hair-restoring shampoo has good healing effect on the injury caused by perm, restores the natural beauty of hair and strengthens hair follicles and hair roots.

The rose flower and fruit stock solution is prepared by the following method:

frying, namely frying the sterilized rose fruits for 30-60 minutes at the temperature of 150-;

The sweet wormwood herb and folium artemisiae argyi soaking solution is prepared by the following method: cleaning wild plants of herba Artemisiae Annuae and folium Artemisiae Argyi, sterilizing, adding 1 weight times of deionized water, decocting for 180min-240min, soaking for 24 hr, standing, and filtering to obtain herba Artemisiae Annuae and folium Artemisiae Argyi soak solution.

Wherein the surfactant is a mixture of AES, 6501, CAB and K12, and the preferred weight ratio is 1:1:1: 1.

Wherein the emulsifier is OP-10.

s3, cooling to below 30 ℃, and adding corn steep liquor;

s5, adding a surfactant and an emulsifier, and fully and uniformly stirring;

s6, adding edible salt to uniformly adjust the viscosity, and performing ultrasonic dispersion to form semitransparent pale yellow liquid;

and S7, automatic high-pressure sterile filling, packaging and packaging.

Example 2

Referring to example 1, unlike example 1, the natural shampoo product of the fig raw liquid formula of this example is composed of the following components by weight percentage:

example 3

comparative example 1

Referring to example 1, unlike example 1, the natural shampoo of this comparative example, a rose-hip stock formulation, consists of the following components in weight percent:

comparative example 2

test one:

user satisfaction test

180 volunteers of 20-50 years old were selected as trial subjects, of which 90 used the shampoo of example 1 and the other 90 used the shampoo of comparative example 1. Washing hair once every 2-3 days, continuously using for one month, filling a feedback table after trial use, and scoring. The scoring indexes in the feedback table are as follows: cleaning effect, softening effect, non-adhesive effect, non-irritant effect, and dandruff removing effect. The highest score of each index is 10 points, the lowest score is 0 point, and the higher the score is, the better the evaluation is. And finally, averaging all the items. The scoring results are shown in table 1.

TABLE 1

	Cleaning effect	Softening effect	Non-adhesive effect	Without irritating effects	Anti-dandruff effect
						Example 1	9.8	9.7	9.5	9.6	9.7
Comparative example 1	8.4	8.6	9.4	9.5	8.5

Test II:

the bacteriostatic activity of the antibacterial composition of example 1 and comparative example 2 on escherichia coli e.coliatcc25922 and staphylococcus aureus s.aureus ATCC25923 was tested by the bacteriostatic circle method. The results are shown in Table 3.

TABLE 3

Note: the data in the table show the diameter of the zone of inhibition (diameter of the filter paper sheet 12.80mm)

And test III:

biodegradability test

The shampoo in the example 1 is subjected to a biodegradation test, and the test method refers to a GB/T15818-2006 surfactant biodegradation test method.

Test results show that the biodegradation rate of the shampoo product in 5 days (120 hours) can reach 92%.

The above-listed detailed description is only a specific description of a possible embodiment of the present invention, and they are not intended to limit the scope of the present invention, and equivalent embodiments or modifications made without departing from the technical spirit of the present invention should be included in the scope of the present invention.

Claims

1. The natural shampoo product with the rose flower and fruit stock solution formula is characterized by comprising the following components in percentage by weight:

2. the natural shampoo product of rose flower and fruit stock solution formula of claim 1, which is characterized by comprising the following components by weight percentage:

3. the natural shampoo product of the rose-flower-fruit stock solution formula of claim 1, wherein the rose-flower-fruit stock solution is prepared by the following method:

4. The natural shampoo product of rose flower and fruit stock solution formula of claim 1, wherein the sweet wormwood and argy wormwood leaf soak solution is prepared by the following method:

5. The natural shampoo product of claim 1 wherein the surfactant is one or more of AES, 6501, CAB, K12.

6. The natural shampoo product of claim 5 wherein the surfactant is a mixture of AES, 6501, CAB and K12.

7. The natural shampoo product of claim 1 wherein the emulsifier is one or more of the OP family.

8. The natural shampoo product of claim 7 wherein the emulsifier is OP-10.

9. A method of preparing a natural shampoo product of the rose flower and fruit stock solution formula of any one of claims 1 to 8, comprising the steps of:

s3, cooling to below 30 ℃, and adding corn steep liquor;

s5, adding a surfactant and an emulsifier, and fully and uniformly stirring;

10. The method for preparing the shampoo for mixing the plant flower stock solution with the food according to claim 9, further comprising the steps of:

and S7, automatic high-pressure sterile filling, packaging and packaging.