CN112841196A - Weeding composition containing pyrimidine benzyl carboxylate compounds and application thereof - Google Patents

Weeding composition containing pyrimidine benzyl carboxylate compounds and application thereof Download PDF

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Publication number
CN112841196A
CN112841196A CN201911317851.8A CN201911317851A CN112841196A CN 112841196 A CN112841196 A CN 112841196A CN 201911317851 A CN201911317851 A CN 201911317851A CN 112841196 A CN112841196 A CN 112841196A
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Prior art keywords
herbicidal composition
active ingredient
benzyl
weeds
pyrimidinecarboxylate
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CN201911317851.8A
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CN112841196B (en
Inventor
彭学岗
金涛
赵德
张景远
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Jiangsu Qingyuan Nongguan Weed Control Co ltd
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Jiangsu Qingyuan Nongguan Weed Control Co ltd
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
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    • A01N41/10—Sulfones; Sulfoxides
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Abstract

The invention belongs to the field of pesticides, and particularly relates to a weeding composition containing pyrimidine benzyl carboxylate compounds and application thereof. The weeding composition comprises an active ingredient A and an active ingredient B with herbicidally effective amounts, wherein the active ingredient A is

Description

Weeding composition containing pyrimidine benzyl carboxylate compounds and application thereof
The application is a divisional application of a Chinese invention patent application with the application date of 2019, 11 and 12 months and the application number of 201911099429.X, and the invention name of the invention is 'weeding composition containing pyrimidine benzyl carboxylate compounds and application thereof'.
Technical Field
The invention belongs to the field of pesticides, and particularly relates to a weeding composition containing pyrimidine benzyl carboxylate compounds and application thereof.
Background
Chemical weeding is the most economic and effective means in preventing and removing weeds in farmlands, but the problems of drug resistance and resistance evolution of weeds and the like are easily caused by using a single variety or a single action mode of chemical herbicide continuously at a high dose for a long time. The reasonable compounding or mixing of the herbicide compound has the advantages of expanding the weed spectrum, improving the control effect, delaying the occurrence and development of drug resistance and drug resistance of weeds and the like, and is one of the most effective methods for solving the problems. For example, patent CN108774179A discloses a substituted pyrimidine-4-carboxylic acid derivative and its use as herbicide, and there is still a need to develop a herbicidal composition with high safety, broad herbicidal spectrum, synergistic effect and solving the problem of resistant weeds.
Disclosure of Invention
In order to solve the problems in the prior art, the invention provides a weeding composition containing pyrimidine benzyl carboxylate compounds and application thereof. The composition can effectively prevent and kill Cyperus rotundus L and other Cyperus weeds, crabgrass, cockspur grass, eleusine indica, green dog tail and other gramineous weeds in crop fields, and Amaranthus retroflexus L, piemarker, monochoria vaginalis L, Chinese violet, purslane, millet grass and other broadleaf weeds, and has the characteristics of expanding a weed control spectrum, reducing the application amount, generating a synergistic effect, solving resistant weeds and the like.
A weeding composition containing pyrimidine benzyl carboxylate compounds comprises an active ingredient A and an active ingredient B which are in herbicidally effective amounts,
the active ingredient A is
Figure BDA0002326326880000011
The active ingredient B is selected from one or more of the following compounds and salts/esters thereof:
EPSPS inhibitors: glyphosate (CAS: 1071-83-6);
a GS inhibitor: glufosinate-ammonium (CAS:77182-82-2), refined glufosinate-ammonium (CAS: 35597-44-5);
PSI inhibitors: paraquat (CAS:1910-42-5), diquat (CAS: 6385-62-2);
cellulose synthesis inhibitors: triazinyl flumioxazin (CAS:131475-57-5), indexazin (CAS: 950782-86-2);
other herbicides: cinmethylin (CAS:87818-31-3), oxaziclomefone (CAS: 153197-14-9).
In the context of the present specification, if the abbreviated forms of the common name of the active compounds are used, all customary derivatives, such as esters and salts, and also isomers, in particular optical isomers, in particular one or more commercially available forms, are included in each case. If the generic name denotes esters or salts, all other customary derivatives, such as other esters and salts, free acids and neutral compounds, and also isomers, in particular optical isomers, in particular one or more commercially available forms, are also included in each case. The chemical name given for a compound means at least one compound covered by the generic name, with compounds generally being preferred. In the case of sulfonamides, such as sulfonylureas, salts also include those formed by exchange of cations with hydrogen atoms in the sulfonamide group. For example, 2-methyl-4-chloro derivatives include, but are not limited to: 2 methyl 4 chloro sodium salt, potassium salt, dimethyl ammonium salt, isopropyl amine salt, etc., and 2 methyl 4 chloromethyl ester, ethyl ester, isooctyl ester, ethyl thioester, etc.; 2,4-D derivatives include, but are not limited to: 2,4-D salts such as sodium salt, potassium salt, dimethylammonium salt, triethanolamine salt, isopropylamine salt, choline and the like, and 2,4-D esters such as methyl ester, ethyl ester, butyl ester, isooctyl ester and the like.
Wherein A, B is in a weight ratio of 1: 500-200: 1 and 1: 400-150: 1 in the weeding composition; preferably 1: 300-100: 1 and 1: 200-80: 1; more preferably 1:150 to 50:1 and 1:120 to 30: 1; further preferably 1: 100-20: 1 and 1: 80-15: 1; further preferred are 1:50 to 10:1, 1:30 to 5:1, 1:10 to 4:1 and 1:5 to 1: 1.
The weight percentage of A and B in the weeding composition accounts for 1-95% of the total weight, and preferably 10-80%.
The weeding composition also comprises conventional auxiliaries which comprise a carrier and a surfactant.
The term "carrier" herein denotes an organic or inorganic, natural or synthetic substance. They facilitate the application of the active ingredient, the carrier being generally inert and must be agriculturally acceptable, in particular for the treated plant. The carrier may be a solid, such as a clay, natural or synthetic silicate, silica, resin, wax, solid fertilizer, or the like; or liquids such as water, alcohols, ketones, petroleum distillates, aromatic or waxy hydrocarbons, chlorinated hydrocarbons, liquefied gases, etc.
Surfactants may include emulsifying, dispersing or wetting agents, which may be ionic or non-ionic. Examples which may be mentioned are salts of polyacrylic acids, lignosulphonates, salts of phenolsulphonic or naphthalenesulphonic acids, polymers of ethylene oxide with aliphatic alcohols or with aliphatic acids or with aliphatic amines and substituted phenols, in particular alkylphenols or arylphenols, sulphosuccinates, taurine derivatives, in particular taurine alkyl esters, and phosphoric esters of alcohols or polyhydroxyethylated phenols, alkylsulfonates, alkylarylsulphonates, alkylsulfates, lauryl ether sulphates, fatty alcohol sulphates, and sulphated hexadec, heptadeca-and octadecanols and sulphated fatty alcohol glycol ethers, and furthermore condensates of naphthalene or naphthalenesulphonic acids with phenol and formaldehyde, polyoxyethylene octylphenyl ether, ethoxylated isooctylphenol, octylphenol or nonylphenol, alkylphenyl polyglycol ethers, tributylphenyl polyglycol ether, tristearylphenyl polyglycol ether, polystearylphenyl polyglycol ether, Alkylaryl polyether alcohols, alcohol and fatty alcohol/ethylene oxide condensates, ethoxylated castor oil, polyoxyethylene alkyl ethers, ethoxylated polyoxypropylene, lauryl alcohol polyglycol ether acetal, sorbitol esters, lignosulfite waste liquors, and also proteins, denatured proteins, polysaccharides (e.g. methylcellulose), hydrophobically modified starches, polyvinyl alcohols, polycarboxylates, polyalkoxylates, polyvinylamines, polyvinylpyrrolidone and copolymers thereof. At least one surfactant is required to be present to facilitate dispersion of the active ingredients in water and to facilitate their proper application to the plant.
The compositions may also contain various other components such as protective colloids, binders, thickeners, thixotropic agents, penetrants, stabilizers, chelating agents, dyes, colorants, and polymers.
The herbicidal composition further comprises at least one safener, preferably one or more of isoxadifen (CAS: 163520-33-0), cyprosulfamide (CAS: 221667-31-8), mefenpyr (CAS: 135590-91-9), cloquintocet (CAS: 99607-70-2), gibberellic acid (CAS: 7-06-5), furilazole (CAS: 121776-33-8), metacamifen (CAS: 129531-12-0).
The compositions of the present invention may be diluted or used directly by the user prior to use. The formulation can be prepared by conventional processing methods, i.e., mixing the active substance with a liquid solvent or solid carrier, and adding one or more surfactants such as dispersants, stabilizers, wetting agents, binders, defoamers, etc.
The specific preparation of the weeding composition is dispersible oil suspending agent, water suspending agent, suspending emulsion, wettable powder, missible oil, water dispersible granule (dry suspending agent), emulsion in water and microemulsion.
In short, the compositions of the present invention may be mixed with solid and liquid additives conventionally used in prior art formulations. The amount of the effective ingredient to be used varies depending on external conditions such as temperature, humidity, the nature of the herbicide to be used, and the like. It may vary widely, for example between 0.001 and 1.0kg/ha, or more of active substance, but preferably between 0.005 and 750g/ha, in particular between 0.005 and 500 g/ha.
The invention also provides an application of the weeding composition in weed control; and to provide a method of controlling unwanted plant growth comprising applying the herbicidal composition to a plant, part of a plant, plant seed, or area where a plant is growing.
In addition, the compositions according to the invention can be applied by spraying to the foliage of the plants to be treated, i.e. to the weeds, in particular to surfaces infested or susceptible to infestation by weeds.
When the herbicidal composition of the present invention is applied, an unexpected synergistic effect is obtained, and the herbicidal activity is more remarkable than the expected sum of the activities using individual herbicides, and the activities of the individual herbicides. The synergistic effect is manifested by reduced application rates, a broader spectrum of weed control, and a faster and longer lasting herbicidal action, which are desirable in the practice of weed control. These new compositions are clearly superior to existing herbicides in terms of the properties described, achieving reduced use and being more environmentally friendly.
The synergistic herbicidal composition of the invention also has the following advantages:
(1) the composition of the invention is environment-friendly and is easy to degrade in the environment.
(2) The weeding composition has low cost and convenient use, and has great economic and social benefits when being popularized and applied.
All patents, patent applications, and publications mentioned or cited herein are incorporated by reference in their entirety to the same extent as if individually incorporated.
Detailed Description
The following examples are not intended to limit the invention, but merely to illustrate how the invention may be carried out. These examples show particularly significant effectiveness against certain weeds. Examples are as follows:
A) examples of the embodiments
1.20.2% microemulsion of glyphosate A (0.2+20)
0.2% of A, 20% of glyphosate, 7.5% of monoisopropylamine, 5% of cyclohexanone, 6% of fatty alcohol polyoxyethylene ether phosphate, 20% of glucoside emulsifier and deionized water
2.20.2% A-glufosinate (0.2+20) microemulsion
0.2 percent of A, 20 percent of glufosinate-ammonium, 5 percent of cyclohexanone, 6 percent of fatty alcohol polyoxyethylene ether phosphate, 10 percent of glucoside emulsifier, 10 percent of cocoamine polyoxyethylene ether and deionized water
3.20.2% microemulsion of paraquat A (0.2+20)
0.2% of A, 20% of paraquat, 5% of cyclohexanone, 6% of nonylphenol polyoxyethylene ether phosphate, 12% of glucoside emulsifier, 8% of cocoamine polyoxyethylene ether and deionized water
4.18.1% microemulsion of A-diquat (0.1+18)
0.1 percent of A, 18 percent of diquat, 5 percent of cyclohexanone, 6 percent of fatty alcohol polyoxyethylene ether phosphate, 15 percent of glucoside emulsifier, 12 percent of cocoamine polyoxyethylene ether and deionized water
5.1.4% A.triazine flumioxazin (0.4+1) dispersible oil suspending agent
0.4 percent of A, 1 percent of triazine flumioxazin, 5 percent of calcium dodecyl benzene sulfonate, 12 percent of cardanol polyoxyethylene ether, 4 percent of castor oil oxyethylene ether, 3.0 percent of organobentonite, 2.5 percent of fumed silica, 8 percent of 100# solvent oil and methyl oleate
6.2.4% of A-cycloheptane ether (0.4+2) missible oil
0.4 percent of A, 2 percent of cycloheptane ether, 10 percent of N-methyl pyrrolidone, 5 percent of calcium dodecyl benzene sulfonate, 10 percent of cardanol polyoxyethylene ether and 100# solvent oil for foot supplement
The missible oil processing equipment comprises: mixing kettles, storage tanks and the like.
The processing process of the missible oil comprises the following steps: and putting all the materials into a mixing kettle, stirring and mixing until all the materials are completely dissolved, transferring to a storage tank for filling after the materials are qualified in the test.
The microemulsion processing equipment comprises the following steps: mixing kettles, storage tanks and the like.
The processing process of the microemulsion comprises the following steps: putting the original medicine, the solvent and the emulsifier into a mixing kettle, stirring and mixing until all materials are completely dissolved, then slowly pumping deionized water, stirring while pumping until the final homogeneous liquid is qualified, transferring to a storage tank and filling after the assay is qualified.
The processing equipment of the dispersible oil suspending agent comprises the following steps: mixing kettles, colloid mills, sand mills, shearing machines and the like.
The processing process of the dispersible oil suspending agent comprises the following steps: putting all materials into a mixing kettle, stirring and mixing, passing through a colloid mill, then entering a sand mill for three-stage sand milling, finally uniformly shearing in a shearing machine, and transferring to a storage tank for filling after the test is qualified.
B) Test of drug efficacy
Spraying treatment of stems and leaves after seedling:
1) test conditions
1.1) test target
The large crabgrass herb, the goosegrass herb and the green dog tail are collected from Shaanxi salted yang. The weeds are cultured by a pot culture method, plastic nutrition bowls with the size of 180 х 140mm are placed in an enamel tray, surface soil (4/5) which is collected from a farmland and is dried and sieved is filled in the enamel tray, the soil humidity is controlled to be 20% at the initial stage, weed seeds with full and uniform seeds are selected, the weed seeds are soaked in warm water with the temperature of 25 ℃ for 6 hours, germination is accelerated in a biochemical incubator (dark) with the temperature of 28 ℃, the weed seeds which are just exposed to the white are uniformly placed on the surface of the soil, and then the enamel tray is covered with 0.5-1cm of soil according to the particle size of the seeds.
1.2) culture conditions
The method is carried out in a controllable sunlight greenhouse, the temperature is 20-30 ℃, the natural illumination is carried out, and the relative humidity is 57-72%. The soil type is loam, the organic matter content is 1.63%, the pH value is 7.1, the alkaline hydrolysis nitrogen is 84.3mg/kg, the quick-acting phosphorus is 38.5mg/kg, and the quick-acting potassium is 82.1 mg/kg.
1.3), instrumentation
3WP-2000 model walking spray tower, Minn Jing agricultural machinery research institute of agricultural department. Ten thousandth electronic balance type GA0 (germany); ZDR2000 intelligent data recorder (hangzhou ze large instruments ltd); SPX type intelligent biochemical incubator (Ningbo Jiangnan Instrument factory).
2) Design of experiments
2.1), reagents
The desired active ingredient a comes from patent CN 108774179A; the desired active ingredient B was purchased from the reagent company. The raw medicines are all diluted by using an emulsifier Tween-80 aqueous solution with the content of 0.1 percent and taking acetone as a solvent.
2.2) test treatment
2.2.1), dose setting
When determining the ratio or content of the component A and the component B, the main use purpose of the formula is also considered according to the action characteristics of the two medicaments and the measurement of toxicity and the like. On the basis of preliminary experiments, A, B active ingredients are respectively used singly and mixed in different amounts. Water without drug, containing the same solvent and emulsifier was used as a blank.
2.2.2), test repetition
Each treatment was repeated 4 times, 3 pots each time, and 20 weed seeds were sown per pot for 60 plants each time.
2.3) treatment method
2.3.1), treatment time and number of times
The test was performed 1 time in total. And (3) thinning after 1.5-2 leaf period of weeds, keeping 10 weeds in each pot, keeping 30 weeds in each treatment, and then continuously culturing until 3-4 leaves are treated.
2.3.2), instruments and methods of use
Uniformly placing the cultured test material on a 0.5m area2Spraying stem and leaf by using a 3WP-2000 model walking spray tower on the platform, wherein the liquid spraying amount is 450 kg/hectare, and the spraying pressure is 0.3 MPa. And after all the liquid medicine is sprayed, closing the air valve, opening the spraying tower door after 30 seconds, and taking out the nutrition pot. Then the air valve is opened, 50mL of clean water is sprayed, and the liquid spraying pipe is cleaned.
3) Test method
The potting method is adopted. The weed cultivation is shown in 1.1), and the method is carried out according to 'herbicide in pesticide indoor bioassay test guidelines'. The application method is shown in 2.3.2), and stem and leaf treatment method is adopted. After treatment, the cells were transferred to a greenhouse for conventional culture.
4) Data investigation and statistical analysis
4.1) investigation method
The complete survival weed seedlings are cut off along the soil surface by a blade by adopting an absolute number survey method, and the fresh weight of the weeds is weighed by an analytical balance. For the weeds that have died, the fresh weight is zero.
4.2), investigation time and number of surveys
The investigation was carried out 21 days after the treatment, and the total number of the investigations was 1.
4.3), statistical analysis of data
The theoretical fresh weight inhibition rate (E0 ═ X + Y-X Y/100) of each treatment mixed combination is calculated by a Gowing method, and then compared with the actually measured inhibition rate (E), the combined action type of the two mixed combinations on the weeds is evaluated, and when the E-E0 value is more than 10 percent, the effect is synergistic, when the E-E0 value is less than-10 percent, the effect is antagonistic, and when the E-E0 value is between-10 percent and 10 percent, the effect is additive. And the optimal proportion is determined according to factors such as actual control effect, characteristics of the herbicide, balance of the formula and the like. Wherein X is the fresh weight inhibition rate when the dosage of the active component A is P; y is the fresh weight inhibition rate of the active component B when the dosage is Q.
Soil sealing treatment:
1) test conditions
1.1) test target
The monochoria chinensis and the monochoria vaginalis are collected from Heilongjiang sentinel farms.
1.2) culture conditions
The method is carried out in a controllable sunlight greenhouse, the temperature is 20-30 ℃, the natural illumination is carried out, and the relative humidity is 57-72%.
The soil type is loam, the organic matter content is 1.63%, the pH value is 7.1, the alkaline hydrolysis nitrogen is 84.3mg/kg, the quick-acting phosphorus is 38.5mg/kg, and the quick-acting potassium is 82.1 mg/kg. The test soil was quantitatively loaded at 3/4 points of the pot and then poured from the bottom of the pot to completely wet the soil to saturation. And (3) accelerating germination of the weed seeds to be tested until the weed seeds are exposed to the white, then uniformly and quantitatively sowing the seeds on the surface, covering the seeds with 0.5-1cm of soil according to the size of the seeds, and reserving the seeds for 72 hours after sowing.
1.3), instrumentation
Ten thousandth electronic balance type GA10 (germany); ZDR2000 intelligent data recorder (hangzhou ze large instruments ltd); SPX type intelligent biochemical incubator (Ningbo Jiangnan Instrument plant), pipettor and the like.
2) Design of experiments
2.1), reagents
2.1.1) test Agents
The raw medicines are all diluted by using an emulsifier T-80 aqueous solution with the content of 0.1 percent by using acetone as a solvent.
2.2) test treatment
2.2.1), dose setting
When determining the ratio or content of the components A and the active component B, the main purpose of the formula should be considered in consideration of the action characteristics of the two medicaments and the toxicity thereof. On the basis of preliminary experiments, A, B active ingredients are respectively used singly and mixed in different amounts. Water without drug, containing the same solvent and emulsifier was used as a blank.
2.2.2), test repetition
Each treatment was repeated 4 times, 3 pots each time, and 30 weed seeds were sown in each pot.
2) Test method
Before treatment, the mixture was irrigated and a 1-2cm aqueous layer was maintained. Taking quantitative liquid medicine by a pipettor, and respectively carrying out irrigation treatment from low dosage to high dosage according to experimental design, wherein the treatment is repeated for 4 times each time; after treatment, the cells were transferred to a greenhouse for conventional culture, and a 1-2cm water layer was maintained throughout the experiment.
3) Data investigation and statistical analysis
The spray treatment is the same as the spray treatment of the stem leaves after seedling, so the detailed description is omitted.
The statistical results are shown in tables 1-6 below, except for the explicit label "soil treatment", the other results are "post-emergence stem and leaf spray treatment".
TABLE 1 evaluation of actual control and Combined action of Glyphosate blends on crab and Tang
Figure BDA0002326326880000061
Table 2A evaluation of actual control and combination of Achillea alpina with mixed glufosinate
Figure BDA0002326326880000062
Table 3A evaluation of the actual control and combination of paraquat mixed on green dog tail
Figure BDA0002326326880000063
TABLE 4 evaluation of the actual control and combination of diquat compounded on green dog tail
Figure BDA0002326326880000071
TABLE 5 evaluation of the actual control and Combined action of the Mixed triazinone flumioxazin on the Pond-Dioscorea
Figure BDA0002326326880000072
TABLE 6 evaluation of actual control and Combined action of the Bidens pilosa blended with cinmethylin on monochoria vaginalis (soil treatment)
Figure BDA0002326326880000073
C) Demonstration of field
The herbicidal compositions prepared in examples 1 to 6 were used for field weed effect tests. An exemplary promotional test was conducted in 2017 at the Shandong yellow island test point. The weeds in the field are mainly: barnyard grass, crab grass, green grass, goosegrass, redroot amaranth, purslane, millet grass, juncellaran, and the like.
The test method comprises the following steps:
stem and leaf treatment (F): when the weeds are in the 2-3 leaf stage, a manual sprayer is used for adding 30 kg of water per 667m2The stem and leaf are sprayed evenly.
Soil treatment (S): before weed germination, a manual sprayer is used for adding water with the amount of 45 kg/667 m2The soil surface is uniformly sprayed.
The specific test agents and doses are detailed in table 7, with a cell area of 20 square meters, repeated 3 times per treatment. The control effect 20 days after application is shown in Table 7.
Figure BDA0002326326880000074
Table 7 demonstrates the field effects of the compounded compositions
Figure BDA0002326326880000075
Figure BDA0002326326880000081
Through a large number of tests and explorations, the invention unexpectedly discovers that the composition is used for preventing and removing main gramineous weeds, broadleaf weeds, cyperaceae weeds and the like, has a surprising and unexpected synergistic effect, is more obvious under a low dosage, can reduce the dosage, reduce the pollution to the environment, reasonably compounds and reduce the agricultural cost, is efficient on ALS and ACCase inhibitor resistant weeds, and has a good application prospect. Meanwhile, the herbicide composition shows good selectivity and excellent synergistic effect in wheat fields, corn fields, paddy fields, peanuts, sugarcane, sorghum, millet, potatoes, rape, soybeans, cotton, vegetables, bluegrass, tall fescue, zoysia japonica and other plants through tests, and can be developed into herbicide mixtures with wide market value.

Claims (10)

1. A weeding composition containing a pyrimidine benzyl carboxylate compound is characterized by comprising an active ingredient A and an active ingredient B which are in herbicidally effective amounts,
the active ingredient A is
Figure FDA0002326326870000011
The active ingredient B is selected from one or more of the following compounds and salts/esters thereof:
glyphosate, glufosinate-ammonium, paraquat, diquat, triaziflam, indexazine-flumioxazin, cycloheptane-ethyl, oxaziclomefone.
2. A herbicidal composition containing pyrimidine benzyl carboxylate compounds as claimed in claim 1, wherein the weight ratio of A, B in the herbicidal composition is 1: 500-200: 1 and 1: 400-150: 1; preferably 1: 300-100: 1 and 1: 200-80: 1; more preferably 1:150 to 50:1 and 1:120 to 30: 1; further preferably 1: 100-20: 1 and 1: 80-15: 1; further preferred are 1:50 to 10:1, 1:30 to 5:1, 1:10 to 4:1 and 1:5 to 1: 1.
3. A herbicidal composition according to claim 1 or 2, comprising benzyl pyrimidinecarboxylate compounds, wherein the mass percentage of a and B in the herbicidal composition is 1-95%, preferably 10-80% of the total.
4. A herbicidal composition comprising benzyl pyrimidinecarboxylate compounds according to any of claims 1 to 3, wherein conventional adjuvants are also included in the herbicidal composition.
5. A herbicidal composition comprising benzyl pyrimidinecarboxylate compounds according to claim 4, wherein the conventional adjuvant comprises a carrier or a surfactant.
6. A herbicidal composition comprising benzyl pyrimidinecarboxylate compounds according to any of claims 1 to 5, characterized in that the herbicidal composition further comprises at least one safener.
7. A herbicidal composition according to claim 6, wherein the safener is selected from one or more of isoxadifen, cyprosulfamide, mefenpyr, cloquintocet-mexyl, gibberellic acid, furilazole and mecamifen.
8. A weeding composition containing benzyl pyrimidinecarboxylate compounds according to any one of claims 1 to 7, wherein the weeding composition is formulated as dispersible oil suspension, aqueous suspension, suspoemulsion, wettable powder, emulsifiable concentrate, water dispersible granule, aqueous emulsion or microemulsion.
9. Use of the herbicidal composition comprising a benzyl pyrimidinecarboxylate compound according to any one of claims 1 to 8 for controlling weeds.
10. A method for controlling undesired plant growth, which comprises applying the herbicidal composition comprising a benzyl pyrimidinecarboxylate compound according to any one of claims 1 to 8 to a plant, a plant part, a plant seed or an area where a plant is grown.
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CN112841197B (en) 2022-02-01
CN112841198B (en) 2022-02-01
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CN112841195B (en) 2021-11-05
CN112841200A (en) 2021-05-28
CN112841199A (en) 2021-05-28
CN112841196B (en) 2022-02-01
CN112841202A (en) 2021-05-28
CN112841202B (en) 2022-02-01
CN112841198A (en) 2021-05-28
CN112841200B (en) 2022-02-01

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