CN112778836A - Low-temperature spraying ink for glass and production process thereof - Google Patents
Low-temperature spraying ink for glass and production process thereof Download PDFInfo
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- CN112778836A CN112778836A CN202110138178.2A CN202110138178A CN112778836A CN 112778836 A CN112778836 A CN 112778836A CN 202110138178 A CN202110138178 A CN 202110138178A CN 112778836 A CN112778836 A CN 112778836A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a glass low-temperature spraying ink and a production process thereof, and is characterized by comprising the following raw materials in parts by weight, 60-90 parts of polyurethane; 80-120 parts of epoxy resin; 40-60 parts of glycerol rosin ester; 20-30 parts of water; 10-20 parts of a solid dispersing agent; 10-20 parts of a coloring agent; 10-20 parts of a curing agent; 10-15 parts of polyethylene glycol; 5-10 parts of ethyl cellulose; 1-5 parts of a surfactant; 1-5 parts of a nano pigment; 1-3 parts of turpentine; 1-3 parts of rosin; 1-3 parts of frankincense. The invention relates to a low-temperature glass spraying ink and a production process thereof, belonging to the field of glass ink.
Description
Technical Field
The invention relates to the field of glass ink, in particular to glass low-temperature spraying ink and a production process thereof.
Background
The glass ink can be printed on glass and can be firmly adhered to the glass according to the following processing temperature: the high-temperature glass printing ink is widely used for building curtain walls, automobile glass, household appliance glass and the like; the toughened glass ink enables the glass pigment and the glass body to be fused into a whole, the adhesion and durability of the color are realized, the glass which is colored and strengthened has rich color and luster, the structure of the glass has high strength and safety, and has certain resistance to the corrosion of the atmosphere, good corrosion resistance and covering power; the glass decoration firing ink is widely applied to industries such as glass, ceramics, sports equipment and the like, and the low-temperature glass ink has good adhesive force and strong solvent resistance; the common glass ink is suitable for printing various glass and polyester non-setting adhesive paper, wherein the pattern printed by the low-temperature glass ink has bright color and no silk screen, the service life of a silk screen printing plate is long, and the plate making and printing equipment is simple. However, the existing low-temperature glass ink has certain disadvantages that the low-temperature glass ink cannot meet the requirements on viscosity, the adhesion effect with glass raw materials is not enough when the low-temperature glass ink is used, and the effect of mutual fusion of components during manufacturing is poor, so that the expected effect cannot be achieved.
Disclosure of Invention
The invention mainly aims to provide a low-temperature spraying ink for glass and a production process thereof, which can effectively solve the problem of fixed heating effect of a heating bag in the background technology.
In order to achieve the purpose, the invention adopts the technical scheme that:
the low temperature sprayed ink for glass consists of polyurethane 60-90 weight portions; 80-120 parts of epoxy resin; 40-60 parts of glycerol rosin ester; 20-30 parts of water; 10-20 parts of a solid dispersing agent; 10-20 parts of a coloring agent; 10-20 parts of a curing agent; 10-15 parts of polyethylene glycol; 5-10 parts of ethyl cellulose; 1-5 parts of a surfactant; 1-5 parts of a nano pigment; 1-3 parts of turpentine; 1-3 parts of rosin; 1-3 parts of frankincense.
Preferably, the total weight of the turpentine, the rosin, the frankincense and the ethyl cellulose is not lower than 20% of the total weight of the raw materials of the product.
Preferably, the nano pigment is selected from any one or combination of nano titanium oxide, zirconium oxide and zinc sulfide.
Preferably, the solid dispersant is one or a mixture of sodium dodecyl sulfate, polyacrylamide and fatty acid polyethylene glycol ester.
Preferably, the surfactant is one or a mixture of two of a silicon surfactant and an acrylic surfactant.
A production process of low-temperature ink spraying on glass comprises the following steps,
s1, preparing materials, namely preparing needed raw materials of polyurethane, epoxy resin, rosin ester, water, a solid dispersing agent, a coloring agent, a curing agent, polyethylene glycol, ethyl cellulose, a surfactant, a nano pigment, turpentine, rosin and frankincense, and then weighing the raw materials by a weighing device to prepare the raw materials according to the required parts by weight;
s2, dividing the raw materials into a component A and a component B, wherein the component A comprises polyurethane, epoxy resin, rosin ester, water, a solid dispersing agent, a coloring agent, a curing agent, polyethylene glycol, a surfactant and a nano pigment, and the component B comprises ethyl cellulose, turpentine, rosin and frankincense.
S3, performing high-temperature treatment on the component A, putting the component A into a heating device for fully mixing and heating the component A into a liquid state;
s4, heating the component B until the component B is completely dissolved, heating the component B, and cooling and filtering the heated component B;
s5, mixing the component A and the component B at high temperature;
s6, cooling the raw materials to form viscous colloidal fluid;
and S7, spraying ink on the finished product for packaging and storage.
Preferably, the heating container of the component A in the S3 is a high-temperature clamp boiler, the heating temperature is 800-.
Preferably, the component B in the S4 is heated to 150 ℃ and 200 ℃ by a split-type boiler after being completely dissolved, and the heating time is 10-15 min.
Preferably, the finished product in S6 is packaged in certain amount and stored in dry and cool place.
Compared with the prior art, the invention has the following beneficial effects: this glass low temperature spouts fat liquoring, through add solid dispersant and surfactant active in the raw materials, can improve and glass raw materials between the adhesive effect, when preparing in addition, through carrying out high temperature treatment to A and B component, and highly be higher than the heating temperature of ordinary preparation method for mix between the raw materials love rapidly more, and strengthen that the fusion effect between the raw materials is better, relatively more practical.
Detailed Description
In order to make the technical means, the creation characteristics, the achievement purposes and the effects of the invention easy to understand, the invention is further described with the specific embodiments.
The low temperature sprayed ink for glass consists of polyurethane 60-90 weight portions; 80-120 parts of epoxy resin; 40-60 parts of glycerol rosin ester; 20-30 parts of water; 10-20 parts of a solid dispersing agent; 10-20 parts of a coloring agent; 10-20 parts of a curing agent; 10-15 parts of polyethylene glycol; 5-10 parts of ethyl cellulose; 1-5 parts of a surfactant; 1-5 parts of a nano pigment; 1-3 parts of turpentine; 1-3 parts of rosin; 1-3 parts of frankincense.
The total weight of the turpentine, the rosin, the frankincense and the ethyl cellulose is not lower than 20 percent of the total weight of the raw materials of the product; the nano pigment is selected from any one or combination of nano titanium oxide, zirconium oxide and zinc sulfide; the solid dispersant is one or a mixture of sodium dodecyl sulfate, polyacrylamide and fatty acid polyethylene glycol ester; the surfactant is one or a mixture of two of a silicon surfactant and an acrylic surfactant.
Example one
The low-temperature glass spraying ink consists of polyurethane 60 weight portions; 80 parts of epoxy resin; 40 parts of glycerol rosin ester; 20 parts of water; 10 parts of a solid dispersing agent; 10 parts of a coloring agent; 10 parts of a curing agent; 10 parts of polyethylene glycol; 15 parts of ethyl cellulose; 1 part of a surfactant; 1 part of a nano pigment; 1 part of turpentine; 1 part of rosin; 1 part of frankincense.
Example two
The low-temperature glass spraying ink consists of polyurethane in 75 weight portions; 100 parts of epoxy resin; 50 parts of glycerol rosin ester; 25 parts of water; 15 parts of a solid dispersing agent; 15 parts of a coloring agent; 10 parts of a curing agent; 12 parts of polyethylene glycol; 8 parts of ethyl cellulose; 3 parts of a surfactant; 3 parts of a nano pigment; 2 parts of turpentine; 2 parts of rosin; 2 parts of frankincense.
EXAMPLE III
The low-temperature glass spraying ink consists of polyurethane in 90 weight portions; 120 parts of epoxy resin; 60 parts of glycerol rosin ester; 30 parts of water; 20 parts of a solid dispersant; 20 parts of a coloring agent; 20 parts of a curing agent; 15 parts of polyethylene glycol; 5 parts of ethyl cellulose; 5 parts of a surfactant; 5 parts of a nano pigment; 3 parts of turpentine; 3 parts of rosin; and 3 parts of frankincense.
A production process of low-temperature ink spraying on glass comprises the following steps,
s1, preparing materials, namely preparing needed raw materials of polyurethane, epoxy resin, rosin ester, water, a solid dispersing agent, a coloring agent, a curing agent, polyethylene glycol, ethyl cellulose, a surfactant, a nano pigment, turpentine, rosin and frankincense, and then weighing the raw materials by a weighing device to prepare the raw materials according to the required parts by weight;
s2, dividing the raw materials into a component A and a component B, wherein the component A comprises polyurethane, epoxy resin, rosin ester, water, a solid dispersing agent, a coloring agent, a curing agent, polyethylene glycol, a surfactant and a nano pigment, and the component B comprises ethyl cellulose, turpentine, rosin and frankincense.
S3, performing high-temperature treatment on the component A, putting the component A into a heating device for fully mixing and heating the component A into a liquid state;
s4, heating the component B until the component B is completely dissolved, heating the component B, and cooling and filtering the heated component B;
s5, mixing the component A and the component B at high temperature;
s6, cooling the raw materials to form viscous colloidal fluid;
and S7, spraying ink on the finished product for packaging and storage.
The heating container of the component A in the S3 is a high-temperature split-core type boiler, the heating temperature is 800-; after the component B in the S4 is completely dissolved, heating to 150 ℃ and 200 ℃ by a split-type boiler for 10-15 min; and (6) packaging the finished product in the S6 according to a certain weight by spraying ink, and storing the packaged finished product in a dry and cool place.
The invention relates to a production process of glass low-temperature spraying ink, which comprises the steps of preparing required raw materials of polyurethane, epoxy resin, rosin ester, water, solid dispersing agent, coloring agent, curing agent, polyethylene glycol, ethyl cellulose, surfactant, nano pigment, turpentine, rosin and frankincense, weighing the raw materials by a weighing device to prepare the raw materials according to required parts, classifying the raw materials according to the A component of the polyurethane, the epoxy resin, the rosin ester, the water, the solid dispersing agent, the coloring agent, the curing agent, the polyethylene glycol, the surfactant and the nano pigment, the B component of the ethyl cellulose, the turpentine, the rosin and the frankincense, putting the A component into a heating device for fully mixing and heating into a liquid state, heating a container of a high-temperature clamped boiler, heating temperature of 800-, heating for 0.5-1.5h, heating the component B, cooling and filtering the heated component B, heating the component B to 150-.
The foregoing shows and describes the general principles and broad features of the present invention and advantages thereof. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are described in the specification and illustrated only to illustrate the principle of the present invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the present invention, which fall within the scope of the invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (9)
1. The low-temperature glass spraying ink is characterized by comprising 60-90 parts by weight of polyurethane; 80-120 parts of epoxy resin; 40-60 parts of glycerol rosin ester; 20-30 parts of water; 10-20 parts of a solid dispersing agent; 10-20 parts of a coloring agent; 10-20 parts of a curing agent; 10-15 parts of polyethylene glycol; 5-10 parts of ethyl cellulose; 1-5 parts of a surfactant; 1-5 parts of a nano pigment; 1-3 parts of turpentine; 1-3 parts of rosin; 1-3 parts of frankincense.
2. The low-temperature glass spraying ink as claimed in claim 1, wherein the total weight of the turpentine, the rosin, the frankincense and the ethyl cellulose is not less than 20% of the total weight of the raw materials of the product.
3. The glass low-temperature spraying ink as claimed in claim 1, wherein the nano pigment is selected from any one or combination of nano titanium oxide, zirconium oxide and zinc sulfide.
4. The low-temperature glass spraying ink as claimed in claim 1, wherein the solid dispersant is one or a mixture of sodium dodecyl sulfate, polyacrylamide and fatty acid polyglycol ester.
5. The low-temperature glass inkjet ink according to claim 1, wherein the surfactant is one or a mixture of two of a silicon surfactant and an acrylic surfactant.
6. A production process for spraying ink on glass at low temperature is characterized by comprising the following steps,
s1, preparing materials, namely preparing needed raw materials of polyurethane, epoxy resin, rosin ester, water, a solid dispersing agent, a coloring agent, a curing agent, polyethylene glycol, ethyl cellulose, a surfactant, a nano pigment, turpentine, rosin and frankincense, and then weighing the raw materials by a weighing device to prepare the raw materials according to the required parts by weight;
s2, dividing the raw materials into a component A and a component B, wherein the component A comprises polyurethane, epoxy resin, rosin ester, water, a solid dispersing agent, a coloring agent, a curing agent, polyethylene glycol, a surfactant and a nano pigment, and the component B comprises ethyl cellulose, turpentine, rosin and frankincense.
S3, performing high-temperature treatment on the component A, putting the component A into a heating device for fully mixing and heating the component A into a liquid state;
s4, heating the component B until the component B is completely dissolved, heating the component B, and cooling and filtering the heated component B;
s5, mixing the component A and the component B at high temperature;
s6, cooling the raw materials to form viscous colloidal fluid;
and S7, spraying ink on the finished product for packaging and storage.
7. The production process of glass low-temperature ink spraying according to claim 6, wherein the component A heating container in the S3 is a high-temperature split-core boiler, the heating temperature is 800-1000 ℃, and the heating time is 0.5-1.5 h.
8. The production process of glass low-temperature spraying ink as claimed in claim 6, wherein the B component in the S4 is completely dissolved and then heated to 150 ℃ and 200 ℃ by a conventional tong-type boiler for 10-15 min.
9. The process of claim 6, wherein the finished product ink jet of S6 is packaged in portions and stored in dry and cool places.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110138178.2A CN112778836A (en) | 2021-02-01 | 2021-02-01 | Low-temperature spraying ink for glass and production process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110138178.2A CN112778836A (en) | 2021-02-01 | 2021-02-01 | Low-temperature spraying ink for glass and production process thereof |
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| Publication Number | Publication Date |
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| CN112778836A true CN112778836A (en) | 2021-05-11 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN202110138178.2A Pending CN112778836A (en) | 2021-02-01 | 2021-02-01 | Low-temperature spraying ink for glass and production process thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103275557A (en) * | 2013-05-31 | 2013-09-04 | 苏州凹凸彩印厂 | Environment-friendly glass printing ink |
| CN105255253A (en) * | 2015-11-13 | 2016-01-20 | 苏州市灵通玻璃制品有限公司 | Environment-friendly glass printing ink |
| CN110669377A (en) * | 2019-09-09 | 2020-01-10 | 广州视源电子科技股份有限公司 | Glass printing ink, preparation method and application |
-
2021
- 2021-02-01 CN CN202110138178.2A patent/CN112778836A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103275557A (en) * | 2013-05-31 | 2013-09-04 | 苏州凹凸彩印厂 | Environment-friendly glass printing ink |
| CN105255253A (en) * | 2015-11-13 | 2016-01-20 | 苏州市灵通玻璃制品有限公司 | Environment-friendly glass printing ink |
| CN110669377A (en) * | 2019-09-09 | 2020-01-10 | 广州视源电子科技股份有限公司 | Glass printing ink, preparation method and application |
Non-Patent Citations (5)
| Title |
|---|
| 司航: "《有机化工原料》", 31 January 1995, 化学工业出版社 * |
| 宋小平: "《纺织染整助剂生产工艺与技术》", 30 April 2017, 科学技术文献出版社 * |
| 张宪荣: "《现代设计辞典》", 31 December 1998, 北京理工大学出版社 * |
| 潘功配: "《烟火药材料手册》", 31 May 1983, 华东工程学院 * |
| 金银河: "《包装印刷技术》", 31 December 2005, 中国纺织出版社 * |
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Application publication date: 20210511 |