CN105255253A - Environmental-protection glass printing ink - Google Patents

Environmental-protection glass printing ink Download PDF

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Publication number
CN105255253A
CN105255253A CN201510773027.9A CN201510773027A CN105255253A CN 105255253 A CN105255253 A CN 105255253A CN 201510773027 A CN201510773027 A CN 201510773027A CN 105255253 A CN105255253 A CN 105255253A
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CN
China
Prior art keywords
parts
environment
friendly type
nano silicon
type glass
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Pending
Application number
CN201510773027.9A
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Chinese (zh)
Inventor
陆志文
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Suzhou Lingtong Glass Products Co Ltd
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Suzhou Lingtong Glass Products Co Ltd
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Priority to CN201510773027.9A priority Critical patent/CN105255253A/en
Publication of CN105255253A publication Critical patent/CN105255253A/en
Pending legal-status Critical Current

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Abstract

The invention discloses environmental-protection glass printing ink. The glass printing ink is prepared from, by weight, 90-110 parts of epoxy resin, 40-50 parts of soybean oil, 20-35 parts of esterase, 15-24 parts of nano silicon dioxide ethyl alcohol dispersion liquid, 2-5 parts of talcum powder, 10-16 parts of butyl stearate, 10-14 parts of polyethylene glycol, 1-3 parts of xanthan gum, 20-30 parts of water, 0.5-0.8 part of sodium dodecylbenzene sulfonate and 3-8 parts of dispersants. According to the environmental-protection glass printing ink, the raw materials all adopt the raw materials without toxicity and odorlessness, toxic substances are not produced in the machining process, influence to the body of a user is small, all the raw materials are acted synergistically, the cost is low, the environmental-protection glass printing ink is suitable for glass, the adhesive force is strong, and the covering property is high.

Description

A kind of environment-friendly type glass ink
Technical field
The present invention relates to a kind of environment-friendly type glass ink, belong to glass working arts field.
Background technology
Traditional glass ink is generally made up of resin, pigment, solvent, auxiliary agent and filler etc.In solvent and resin, often containing volatile organic compounds, their major parts are poisonous, produce infringement, and the solvent in solvent-borne type glass ink generally exceed 30% of total ink, also will add partial solvent and carry out adjustment viscosity during use to human body.During printing construction, the organic solvent overwhelming majority does not participate in reaction and is discharged in air, pollutes.Desolventize outside volatilization, in printing construction process, layer of ink also needs high bake ability dry, lot of energy; Simultaneously owing to may contain aminoresin in starting material, so along with the prolongation of baking time and the raising of temperature thereof, reacting from contracting of aminoresin also can discharge the objectionable impuritiess such as formaldehyde, affects the healthy of user.
Therefore, necessary during the glass ink of environment-friendly type.
Summary of the invention
In order to overcome the deficiencies in the prior art, the invention provides a kind of environment-friendly type glass ink.
The present invention is achieved through the following technical solutions:
A kind of environment-friendly type glass ink, comprises the raw material of following parts by weight: epoxy resin 90-110 part, soybean oil 40-50 part, esterase 20-35 part, nano silicon alcohol dispersion liquid 15-24 part, talcum powder 2-5 part, butyl stearate 10-16 part, polyoxyethylene glycol 10-14 part, xanthan gum 1-3 part, water 20-30 part, Sodium dodecylbenzene sulfonate 0.5-0.8 part and dispersion agent 3-8 part.
Described a kind of environment-friendly type glass ink, described nano silicon alcohol dispersion liquid is obtained by following steps: in ethanolic soln, add nano silicon and water glass, mix under the condition of earthquake, add silane coupling agent and Magnesium Stearate, ultrasonic reaction 40-60min under temperature is 40-50 DEG C of condition.
Described a kind of environment-friendly type glass ink, be 100 parts in the parts by weight of ethanolic soln, the parts by weight of described nano silicon, water glass, silane coupling agent and Magnesium Stearate are respectively: 30-40 part, 1-3 part, 0.2-0.6 part and 2-5 part.
Described a kind of environment-friendly type glass ink, the described concussion time is 30-40min.
Described a kind of environment-friendly type glass ink, described dispersion agent is the mixture of Tristearoylglycerol, polyethylene wax, urethane and hydroxycarboxylic acid.
Described a kind of environment-friendly type glass ink, each raw material weight number of described dispersion agent is respectively Tristearoylglycerol 15-20 part, polyethylene wax 3-7 part, urethane 10-16 part and hydroxycarboxylic acid 20-25 part.
The beneficial effect that the present invention reaches:
The raw material of glass ink of the present invention all adopts nontoxic scentless raw material, also can not produce toxic substance in the course of processing, little to user's physical effects, simultaneously each raw material synergy, and cost is not high, and is suitable for glass, strong adhesion, opacifying property height.
The nano silicon alcohol dispersion liquid good stability that the present invention prepares, acts synergistically with esterase, talcum powder, butyl stearate and xanthan gum, improves the opacifying property of ink and wear resistance, does not affect again the mobility of ink simultaneously.
The present invention adopts the mixture of Tristearoylglycerol, polyethylene wax, urethane and hydroxycarboxylic acid as dispersion agent, and dispersion effect is good, acts synergistically with other raw materials, ink overall flow and sticking power good, easily printing is on the glass surface.
Embodiment
Embodiment 1
A kind of environment-friendly type glass ink, comprises the raw material of following parts by weight: epoxy resin 90 parts, soybean oil 50 parts, esterase 20 parts, nano silicon alcohol dispersion liquid 24 parts, talcum powder 2 parts, butyl stearate 10 parts, polyoxyethylene glycol 14 parts, xanthan gum 1 part, 30 parts, water, Sodium dodecylbenzene sulfonate 0.5 part and dispersion agent 8 parts.
Wherein, described nano silicon alcohol dispersion liquid is obtained by following steps: in ethanolic soln, add nano silicon and water glass, mixing 30-40min is carried out under the condition of earthquake, add silane coupling agent and Magnesium Stearate, ultrasonic reaction 40-60min under temperature is 40-50 DEG C of condition.Be 100 parts in the parts by weight of ethanolic soln, the parts by weight of described nano silicon, water glass, silane coupling agent and Magnesium Stearate are respectively: 30 parts, 1 part, 0.6 part and 2 parts.
The each raw material weight number of the described dispersion agent of institute is respectively Tristearoylglycerol 15 parts, polyethylene wax 3 parts, urethane 16 parts and hydroxycarboxylic acid 25 parts.
Embodiment 2
A kind of environment-friendly type glass ink, comprises the raw material of following parts by weight: epoxy resin 110 parts, soybean oil 40 parts, esterase 35 parts, nano silicon alcohol dispersion liquid 15 parts, talcum powder 5 parts, butyl stearate 16 parts, polyoxyethylene glycol 10 parts, xanthan gum 3 parts, 20 parts, water, Sodium dodecylbenzene sulfonate 0.8 part and dispersion agent 3 parts.
Wherein, described nano silicon alcohol dispersion liquid is obtained by following steps: in ethanolic soln, add nano silicon and water glass, mixing 30-40min is carried out under the condition of earthquake, add silane coupling agent and Magnesium Stearate, ultrasonic reaction 40-60min under temperature is 40-50 DEG C of condition.Be 100 parts in the parts by weight of ethanolic soln, the parts by weight of described nano silicon, water glass, silane coupling agent and Magnesium Stearate are respectively: 40 parts, 3 parts, 0.2 part and 5 parts.
The each raw material weight number of the described dispersion agent of institute is respectively Tristearoylglycerol 20 parts, polyethylene wax 7 parts, urethane 10 parts and hydroxycarboxylic acid 20 parts.
Embodiment 3
A kind of environment-friendly type glass ink, comprises the raw material of following parts by weight: epoxy resin 100 parts, soybean oil 48 parts, esterase 30 parts, nano silicon alcohol dispersion liquid 22 parts, talcum powder 3 parts, butyl stearate 14 parts, polyoxyethylene glycol 12 parts, xanthan gum 2 parts, 26 parts, water, Sodium dodecylbenzene sulfonate 0.6 part and dispersion agent 5 parts.
Wherein, described nano silicon alcohol dispersion liquid is obtained by following steps: in ethanolic soln, add nano silicon and water glass, mixing 30-40min is carried out under the condition of earthquake, add silane coupling agent and Magnesium Stearate, ultrasonic reaction 40-60min under temperature is 40-50 DEG C of condition.Be 100 parts in the parts by weight of ethanolic soln, the parts by weight of described nano silicon, water glass, silane coupling agent and Magnesium Stearate are respectively: 36 parts, 2 parts, 0.4 part and 3 parts.
The each raw material weight number of the described dispersion agent of institute is respectively Tristearoylglycerol 17 parts, polyethylene wax 5 parts, urethane 12 parts and hydroxycarboxylic acid 22 parts.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the prerequisite not departing from the technology of the present invention principle; can also make some improvement and distortion, these improve and distortion also should be considered as protection scope of the present invention.

Claims (6)

1. an environment-friendly type glass ink, it is characterized in that, comprise the raw material of following parts by weight: epoxy resin 90-110 part, soybean oil 40-50 part, esterase 20-35 part, nano silicon alcohol dispersion liquid 15-24 part, talcum powder 2-5 part, butyl stearate 10-16 part, polyoxyethylene glycol 10-14 part, xanthan gum 1-3 part, water 20-30 part, Sodium dodecylbenzene sulfonate 0.5-0.8 part and dispersion agent 3-8 part.
2. a kind of environment-friendly type glass ink according to claim 1, it is characterized in that, described nano silicon alcohol dispersion liquid is obtained by following steps: in ethanolic soln, add nano silicon and water glass, mix under the condition of earthquake, add silane coupling agent and Magnesium Stearate, ultrasonic reaction 40-60min under temperature is 40-50 DEG C of condition.
3. a kind of environment-friendly type glass ink according to claim 2, it is characterized in that, be 100 parts in the parts by weight of ethanolic soln, the parts by weight of described nano silicon, water glass, silane coupling agent and Magnesium Stearate are respectively: 30-40 part, 1-3 part, 0.2-0.6 part and 2-5 part.
4. a kind of environment-friendly type glass ink according to claim 2, is characterized in that, the described concussion time is 30-40min.
5. a kind of environment-friendly type glass ink according to claim 1, is characterized in that, described dispersion agent is the mixture of Tristearoylglycerol, polyethylene wax, urethane and hydroxycarboxylic acid.
6. a kind of environment-friendly type glass ink according to claim 5, is characterized in that, each raw material weight number of described dispersion agent is respectively Tristearoylglycerol 15-20 part, polyethylene wax 3-7 part, urethane 10-16 part and hydroxycarboxylic acid 20-25 part.
CN201510773027.9A 2015-11-13 2015-11-13 Environmental-protection glass printing ink Pending CN105255253A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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Publications (1)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106084996A (en) * 2016-06-21 2016-11-09 覃树强 A kind of formula of high-intensity foam glass ink
CN106243830A (en) * 2016-07-31 2016-12-21 梁枭 The gel ink pen ink that writing can be eliminated
CN112778836A (en) * 2021-02-01 2021-05-11 广东翔鹰化工有限公司 Low-temperature spraying ink for glass and production process thereof
CN116656172A (en) * 2023-06-21 2023-08-29 雅昌文化(集团)有限公司 High-adhesiveness fragrant ink and preparation and printing methods thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101914190A (en) * 2010-08-17 2010-12-15 浙江理工大学 Preparation method of modified nano-silica monomer dispersion liquid
CN102816275A (en) * 2012-08-24 2012-12-12 浙江理工大学 Textile deepening agent and preparation method thereof
CN103013182A (en) * 2012-12-06 2013-04-03 常州大学 Surface modification method of nanosilicon dioxide
CN104610806A (en) * 2015-01-15 2015-05-13 长兴艾飞特塑料科技有限公司 Nano-silica-modified composite water-based ink and preparation method thereof
CN104804516A (en) * 2014-01-26 2015-07-29 北京中科纳通电子技术有限公司 Graphene cover plate glass printing ink

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101914190A (en) * 2010-08-17 2010-12-15 浙江理工大学 Preparation method of modified nano-silica monomer dispersion liquid
CN102816275A (en) * 2012-08-24 2012-12-12 浙江理工大学 Textile deepening agent and preparation method thereof
CN103013182A (en) * 2012-12-06 2013-04-03 常州大学 Surface modification method of nanosilicon dioxide
CN104804516A (en) * 2014-01-26 2015-07-29 北京中科纳通电子技术有限公司 Graphene cover plate glass printing ink
CN104610806A (en) * 2015-01-15 2015-05-13 长兴艾飞特塑料科技有限公司 Nano-silica-modified composite water-based ink and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106084996A (en) * 2016-06-21 2016-11-09 覃树强 A kind of formula of high-intensity foam glass ink
CN106243830A (en) * 2016-07-31 2016-12-21 梁枭 The gel ink pen ink that writing can be eliminated
CN112778836A (en) * 2021-02-01 2021-05-11 广东翔鹰化工有限公司 Low-temperature spraying ink for glass and production process thereof
CN116656172A (en) * 2023-06-21 2023-08-29 雅昌文化(集团)有限公司 High-adhesiveness fragrant ink and preparation and printing methods thereof

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Application publication date: 20160120