CN112647311A - 一种高弹耐磨阳离子纤维面料及其制备方法 - Google Patents

一种高弹耐磨阳离子纤维面料及其制备方法 Download PDF

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CN112647311A
CN112647311A CN202010899967.3A CN202010899967A CN112647311A CN 112647311 A CN112647311 A CN 112647311A CN 202010899967 A CN202010899967 A CN 202010899967A CN 112647311 A CN112647311 A CN 112647311A
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蒋建云
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Nantong Yongyishi Dyeing And Finishing Technology Co ltd
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Abstract

本发明公开了一种高弹耐磨阳离子纤维面料及其制备方法，包括棉纤维、真丝和腈纶纤维，还包括：25‑35份的阳离子涤纶丝、45‑55份的聚酯纤维纤维、93‑95份的聚氨酯甲酸酯纤维、1‑3份的固化剂、0.5‑1份的渗透剂、25‑35份的纳米染料。本发明中，通过棉纤维、真丝和腈纶纤维混纺后得到混纺纱线，然后与25‑35份的阳离子涤纶丝以及45‑55份的聚酯纤维相互交错编织成高弹阳离子纤维面料，其中，PBT/PET纤维在干湿态条件下均具有特殊的伸缩性，而且弹性不受周围环境温度变化的影响，改善提高面料的弹性。

Description

一种高弹耐磨阳离子纤维面料及其制备方法
技术领域
本发明涉及面料技术领域，尤其涉及一种高弹耐磨阳离子纤维面料及其制备方法。
背景技术
面料就是用来制作服装的材料，作为服装三要素之一，面料不仅可以诠释服装的风格和特性，而且直接左右着服装的色彩、造型的表现效果。
然而，传统服装面料功能单一，不能满足人们对服装面料多功能性的要求，因此，本发明提供一种高弹耐磨阳离子纤维面料，来改善面料的弹性和耐磨性，以满足人们对服装面料的性能要求。
发明内容
本发明的目的是为了解决上述问题，而提出的一种高弹耐磨阳离子纤维面料及其制备方法。
为了实现上述目的，本发明采用了如下技术方案：
一种高弹耐磨阳离子纤维面料，包括棉纤维、真丝和腈纶纤维，还包括：25-35份的阳离子涤纶丝、45-55份的聚酯纤维纤维、93-95份的聚氨酯甲酸酯纤维、1-3份的固化剂、0.5-1份的渗透剂、25-35份的纳米染料。
作为上述技术方案的进一步描述：
所述聚酯纤维采用PBT或者PET复合纤维。
作为上述技术方案的进一步描述：
所述聚氨酯甲酸酯纤维是液态。
作为上述技术方案的进一步描述：
所述纳米染料由纳米二氧化硅微球和颜料混合制成。
作为上述技术方案的进一步描述：
所述纳米二氧化硅微球和颜料的重量比为3：2。
作为上述技术方案的进一步描述：
一种高弹耐磨阳离子纤维面料的制备方法，包括以下步骤：
S1、将棉纤维、真丝和腈纶纤维，得到混纺纱线；
S2、将25-35份的阳离子涤纶丝、45-55份的聚酯纤维纤维和S1中得到的混纺纱线相互交错编织成高弹阳离子纤维面料；
S3、将容器内的据聚氨基甲酸酯纤维进行搅拌，搅拌速度不高于50rpm；
S4、往容器内分批量添加1-3份的固化剂、0.5-1份的渗透剂，继续搅拌至均匀得到浆料A备用。
S5、将S1中得到的低弹性阳离子纤维面料浸泡在浆料A中，匀速搅拌30min，形成1mm-2mm的聚氨基甲酸酯涂层，置于80℃烘箱中干燥1h，得到高弹阳离子纤维面料；
S6、将重量比为3：2的纳米二氧化硅微球和颜料加入到球磨机中，以1500r/min的转速进行球磨粉碎，粉碎、过筛后制得粒径为9-60μm的纳米染料；
S7、将纳米染料加入100mL去离子水中，搅拌30min后将高弹性阳离子纤维面料浸泡在纳米染料中，匀速搅拌，形成1mm-2mm的纳米颜料涂层，置于80℃烘箱内干燥2h，制得高弹耐磨阳离子纤维面料。
综上所述，由于采用了上述技术方案，本发明的有益效果是：
1、本发明中，通过棉纤维、真丝和腈纶纤维混纺后得到混纺纱线，然后与25-35份的阳离子涤纶丝以及45-55份的聚酯纤维相互交错编织成高弹阳离子纤维面料，其中，PBT/PET纤维在干湿态条件下均具有特殊的伸缩性，而且弹性不受周围环境温度变化的影响，改善提高面料的弹性。
2、本发明中，通过在液态的聚氨基甲酸酯纤维中添加渗透剂，使聚氨基甲酸酯纤维更好地渗入面料内部，通过在液态的聚氨基甲酸酯纤维里面添加固化剂，使液态的聚氨基甲酸酯纤维附着在面料上可以固化成型，形成均匀涂层，从而进一步提高面料的弹性及回复力。
3、本发明中，通过重量比3：2的纳米二氧化硅微球和颜料制备的纳米涂料，并将纳米涂料涂覆在高弹阳离子纤维面料表面，提高面料的耐磨性。
具体实施方式
下面对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其它实施例，都属于本发明保护的范围。
选用三份高弹耐磨阳离子纤维面料试样，试样尺寸统一采用30cm*5cm*2cm(长*宽*高)，重量15g的条状面料：
在织物拉伸仪上进行面料弹性试验，其原理是：织物经过定负荷拉伸长度发生形变，释负后根据其变形大小计算弹性伸长率L和弹性回复率K。可通过定伸长法和定负荷法，根据拉伸方向可以分为单向拉伸和双向拉伸，以及单次和多次拉伸等，并根据试样面料的弹性伸长率L和弹性回复率K来检测面料的弹性性能，其中，弹性伸长率L越大，面料越容易变形，弹性回复率K越大，该面料在外力作用下越容易恢复，面料的拉伸弹性越好。
其中，弹性伸长率的计算公式为
Figure BDA0002659469230000041
弹性回复率的计算公式为
Figure BDA0002659469230000042
式中，L0——为试样预加张力后的长度(cm)；
L1——为试样加上一定负荷后，经一定时间试样的伸长长度(cm)；
L'1——为除去负荷后，经一定3时间试样的长度(cm)。
其中，本测试中采用定负荷、单向拉伸方法进行测试，在定负荷(5N)拉伸，停顿一定的时间(如1min)后，使试样松弛，在停顿一定时间，(一般比前一段停顿时间要长，如3min)，记录试样拉伸长度变化。
在织物的动态耐磨仪上进行面料的耐磨性试验，根据试样面料的重量减少率G和厚度减少率T来检测面料的耐磨性能，其中，重量减少率G越小，该面料在摩擦状态下越不容易磨损，厚度减少率T越小，面料耐磨性越好；
其中，重量减少率的计算公式为
Figure BDA0002659469230000051
式中，G0——磨损前的试样重量；G1——磨损后的试样重量。
其中，厚度减少率的计算公式为
Figure BDA0002659469230000052
式中，T0——磨损前的试样厚度；T1——磨损后的试样厚度。
实施例一：
一种高弹耐磨阳离子纤维面料，包括棉纤维、真丝和腈纶纤维，还包括：25份的阳离子涤纶丝，通过阳离子改性多功能仿毛，可使面料具有手感柔软、抗静电、抗起毛起球、常温常压与毛共染，45份的聚酯纤维，聚酯纤维采用PBT或者PET复合纤维，PBT/PET复合纤维在干湿态条件下均具有特殊的伸缩性，而且弹性不受周围环境温度变化的影响，93份的聚氨酯甲酸酯纤维，聚氨酯甲酸酯纤维是液态，1份的固化剂，0.5份的渗透剂、25份的纳米染料，纳米染料由纳米二氧化硅微球和颜料混合制成，纳米二氧化硅微球和颜料的重量比为3：2。
一种高弹耐磨阳离子纤维面料的制备方法，包括以下步骤：
S1、将棉纤维、真丝和腈纶纤维，得到混纺纱线；
S2、将25份的阳离子涤纶丝、45份的聚酯纤维和S1中得到的混纺纱线相互交错编织成高弹阳离子纤维面料；
S3、将容器内的据聚氨基甲酸酯纤维进行搅拌，搅拌速度不高于50rpm；
S4、往容器内分批量添加1份的固化剂、0.5份的渗透剂，继续搅拌至均匀得到浆料A备用。
S5、将S1中得到的低弹性阳离子纤维面料浸泡在浆料A中，匀速搅拌30min，形成1mm-2mm的聚氨基甲酸酯涂层，置于80℃烘箱中干燥1h，得到高弹阳离子纤维面料；
S6、将重量比为3：2的纳米二氧化硅微球和颜料加入到球磨机中，以1500r/min的转速进行球磨粉碎，粉碎、过筛后制得粒径为9-60μm的纳米染料；
S7、将纳米染料加入100mL去离子水中，搅拌30min后将高弹性阳离子纤维面料浸泡在纳米染料中，匀速搅拌，形成1mm-2mm的纳米颜料涂层，置于80℃烘箱内干燥2h，制得高弹耐磨阳离子纤维面料。
对试样高弹耐磨阳离子纤维面料进行弹性和耐磨性测试试验，试验结果如下：
表1高弹耐磨阳离子纤维面料的弹性和耐磨性测试试验结果
Figure BDA0002659469230000071
综合评价：弹性伸长率L较大和弹性回复率K较大，面料的弹性性能好，重量减少率G和厚度减少率T较小，面料的耐磨性能好。
实施例二：
与实施例一不同的是
一种高弹耐磨阳离子纤维面料，包括棉纤维、真丝和腈纶纤维，还包括：30份的阳离子涤纶丝，通过阳离子改性多功能仿毛，可使面料具有手感柔软、抗静电、抗起毛起球、常温常压与毛共染，50份的聚酯纤维，聚酯纤维采用PBT或者PET复合纤维，PBT/PET复合纤维在干湿态条件下均具有特殊的伸缩性，而且弹性不受周围环境温度变化的影响，94份的聚氨酯甲酸酯纤维，聚氨酯甲酸酯纤维是液态，2份的固化剂，1份的渗透剂、30份的纳米染料，纳米染料由纳米二氧化硅微球和颜料混合制成，纳米二氧化硅微球和颜料的重量比为3：2。
一种高弹耐磨阳离子纤维面料的制备方法，包括以下步骤：
S1、将棉纤维、真丝和腈纶纤维，得到混纺纱线；
S2、将30份的阳离子涤纶丝、50份的聚酯纤维和S1中得到的混纺纱线相互交错编织成高弹阳离子纤维面料；
S3、将容器内的据聚氨基甲酸酯纤维进行搅拌，搅拌速度不高于50rpm；
S4、往容器内分批量添加2份固化剂、1份渗透剂，继续搅拌至均匀得到浆料A备用。
S5、将S1中得到的低弹性阳离子纤维面料浸泡在浆料A中，匀速搅拌30min，形成1mm-2mm的聚氨基甲酸酯涂层，置于80℃烘箱中干燥1h，得到高弹阳离子纤维面料；
S6、将重量比为3：2的纳米二氧化硅微球和颜料加入到球磨机中，以1500r/min的转速进行球磨粉碎，粉碎、过筛后制得粒径为9-60μm的纳米染料；
S7、将纳米染料加入100mL去离子水中，搅拌30min后将高弹性阳离子纤维面料浸泡在纳米染料中，匀速搅拌，形成1mm-2mm的纳米颜料涂层，置于80℃烘箱内干燥2h，制得高弹耐磨阳离子纤维面料。
对试样高弹耐磨阳离子纤维面料进行弹性和耐磨性测试试验，试验结果如下：
表2高弹耐磨阳离子纤维面料的弹性和耐磨性测试试验结果
Figure BDA0002659469230000091
综合评价：弹性伸长率L较大和弹性回复率K较大，面料的弹性性能好，重量减少率G和厚度减少率T较小，面料的耐磨性能好。
实施例三：
与实施例一不同的是
一种高弹耐磨阳离子纤维面料，包括棉纤维、真丝和腈纶纤维，还包括：35份的阳离子涤纶丝，通过阳离子改性多功能仿毛，可使面料具有手感柔软、抗静电、抗起毛起球、常温常压与毛共染，55份的聚酯纤维，聚酯纤维采用PBT或者PET复合纤维，PBT/PET复合纤维在干湿态条件下均具有特殊的伸缩性，而且弹性不受周围环境温度变化的影响，95份的聚氨酯甲酸酯纤维，聚氨酯甲酸酯纤维是液态，3份的固化剂，1.5份的渗透剂、35份的纳米染料，纳米染料由纳米二氧化硅微球和颜料混合制成，纳米二氧化硅微球和颜料的重量比为3：2。
一种高弹耐磨阳离子纤维面料的制备方法，包括以下步骤：
S1、将棉纤维、真丝和腈纶纤维，得到混纺纱线；
S2、将35份的阳离子涤纶丝、55份的聚酯纤维和S1中得到的混纺纱线相互交错编织成高弹阳离子纤维面料；
S3、将容器内的据聚氨基甲酸酯纤维进行搅拌，搅拌速度不高于50rpm；
S4、往容器内分批量添加固化剂、渗透剂，继续搅拌至均匀得到浆料A备用。
S5、将S1中得到的低弹性阳离子纤维面料浸泡在浆料A中，匀速搅拌30min，形成1mm-2mm的聚氨基甲酸酯涂层，置于80℃烘箱中干燥1h，得到高弹阳离子纤维面料；
S6、将重量比为3：2的纳米二氧化硅微球和颜料加入到球磨机中，以1500r/min的转速进行球磨粉碎，粉碎、过筛后制得粒径为9-60μm的纳米染料；
S7、将纳米染料加入100mL去离子水中，搅拌30min后将高弹性阳离子纤维面料浸泡在纳米染料中，匀速搅拌，形成1mm-2mm的纳米颜料涂层，置于80℃烘箱内干燥2h，制得高弹耐磨阳离子纤维面料。
对试样高弹耐磨阳离子纤维面料进行弹性和耐磨性测试试验，试验结果如下：
表3高弹耐磨阳离子纤维面料的弹性和耐磨性测试试验结果
Figure BDA0002659469230000111
综合评价：弹性伸长率L较大和弹性回复率K较大，面料的弹性性能好，重量减少率G和厚度减少率T较小，面料的耐磨性能好。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。

Claims (6)

1.一种高弹耐磨阳离子纤维面料，包括棉纤维、真丝和腈纶纤维，其特征在于，还包括：25-35份的阳离子涤纶丝、45-55份的聚酯纤维纤维、93-95份的聚氨酯甲酸酯纤维、1-3份的固化剂、0.5-1份的渗透剂、25-35份的纳米染料。
2.根据权利要求1所述的一种高弹耐磨阳离子纤维面料，其特征在于，所述聚酯纤维采用PBT或者PET复合纤维。
3.根据权利要求1所述的一种高弹耐磨阳离子纤维面料，其特征在于，所述聚氨酯甲酸酯纤维是液态。
4.根据权利要求1所述的一种高弹耐磨阳离子纤维面料，其特征在于，所述纳米染料由纳米二氧化硅微球和颜料混合制成。
5.根据权利要求4所述的一种高弹耐磨阳离子纤维面料，其特征在于，所述纳米二氧化硅微球和颜料的重量比为3：2。
6.根据权利要求1所述的一种高弹耐磨阳离子纤维面料的制备方法，其特征在于，包括以下步骤：
S1、将棉纤维、真丝和腈纶纤维，得到混纺纱线；
S2、将25-35份的阳离子涤纶丝、45-55份的聚酯纤维纤维和S1中得到的混纺纱线相互交错编织成高弹阳离子纤维面料；
S3、将容器内的据聚氨基甲酸酯纤维进行搅拌，搅拌速度不高于50rpm；
S4、往容器内分批量添加1-3份的固化剂、0.5-1份的渗透剂，继续搅拌至均匀得到浆料A备用。
S5、将S1中得到的低弹性阳离子纤维面料浸泡在浆料A中，匀速搅拌30min，形成1mm-2mm的聚氨基甲酸酯涂层，置于80℃烘箱中干燥1h，得到高弹阳离子纤维面料；
S6、将重量比为3：2的纳米二氧化硅微球和颜料加入到球磨机中，以1500r/min的转速进行球磨粉碎，粉碎、过筛后制得粒径为9-60μm的纳米染料；
S7、将纳米染料加入100mL去离子水中，搅拌30min后将高弹性阳离子纤维面料浸泡在纳米染料中，匀速搅拌，形成1mm-2mm的纳米颜料涂层，置于80℃烘箱内干燥2h，制得高弹耐磨阳离子纤维面料。
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CN109722884A (zh) * 2018-12-24 2019-05-07 安徽劲派纺织服饰有限公司 一种耐磨高弹性棉麻面料的制备方法
CN110158221A (zh) * 2018-01-08 2019-08-23 孙艳 一种高弹性耐磨牛仔面料的制备方法
CN110644252A (zh) * 2019-10-28 2020-01-03 广东省建言智能系统有限公司 一种弹性面料及其制备方法

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CN104611955A (zh) * 2015-01-23 2015-05-13 江苏金太阳纺织科技有限公司 一种高经密三色提花面料的染整加工方法
CN110158221A (zh) * 2018-01-08 2019-08-23 孙艳 一种高弹性耐磨牛仔面料的制备方法
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