CN112569127A - Liquid oily composition and preparation method and application thereof - Google Patents
Liquid oily composition and preparation method and application thereof Download PDFInfo
- Publication number
- CN112569127A CN112569127A CN202011613355.XA CN202011613355A CN112569127A CN 112569127 A CN112569127 A CN 112569127A CN 202011613355 A CN202011613355 A CN 202011613355A CN 112569127 A CN112569127 A CN 112569127A
- Authority
- CN
- China
- Prior art keywords
- oil
- oily composition
- liquid
- liquid oily
- fumed silica
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/63—Steroids; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/67—Vitamins
- A61K8/671—Vitamin A; Derivatives thereof, e.g. ester of vitamin A acid, ester of retinol, retinol, retinal
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/67—Vitamins
- A61K8/678—Tocopherol, i.e. vitamin E
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/12—Face or body powders for grooming, adorning or absorbing
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/02—Preparations for care of the skin for chemically bleaching or whitening the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/08—Anti-ageing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Emergency Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Gerontology & Geriatric Medicine (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The invention belongs to the field of cosmetics, and particularly relates to a liquid oily composition, and a preparation method and application thereof. The liquid oily composition at least comprises polar grease or oil soluble substances and filler; the polar oil or oil soluble substance is selected from one or more of liquid vegetable oil, liquid animal oil, and oil soluble ultraviolet absorbent. According to the invention, through matching the hydrophilic fumed silica with the oils with different polarities and different structures, the oil-water emulsion has the advantages of high suspension capacity, low viscosity, transparency, freshness, good spreadability, low cost, skin moistening, anti-aging oil and difficult oxidative deterioration.
Description
Technical Field
The invention belongs to the field of cosmetics, and particularly relates to a liquid oily composition, and a preparation method and application thereof.
Background
In order to increase the water resistance to sweat or moisture, an oily product is generally prepared if the cosmetic is a cosmetic requiring sustainability, and the oily product has a very excellent sustainability but has a disadvantage of a thick and sticky feeling in use. Meanwhile, in general, liquid oil molecules are not too large, and strong action is lacked, so that the suspension force is weak, and the addition of an oily thickener can reduce the transparency of an oily composition, reduce the use feeling and does not influence the stability of the liquid oily composition.
Accordingly, it is highly desirable to provide a low viscosity, high buoyancy, clear, fresh liquid oily composition.
Disclosure of Invention
In order to solve the problems, the invention utilizes hydrophilic fumed silica and combines polar grease or oil soluble matters with different polarities to achieve the effects of good suspension, low viscosity, transparency and good use feeling.
In a first aspect, the present invention provides a liquid oily composition comprising at least a polar oil or oil-soluble substance, a filler; the polar oil or oil soluble substance is selected from one or more of liquid vegetable oil, liquid animal oil, and oil soluble ultraviolet absorbent.
In a preferred embodiment, the liquid vegetable oil and fat is selected from one or more of ethylhexyl palmitate, caprylic/capric glyceride, olive oil, grape seed oil, and macadamia nut oil.
As a preferable technical proposal, the saponification value of the caprylic/capric glyceride is 325-345 mg/g.
As a preferred embodiment, the liquid oily composition further comprises an anti-ageing active and an antioxidant.
As a preferred technical solution, the anti-aging active is selected from one or more of bisabolol, vitamin a, vitamin E, cholesterol, lanosterol, and vitamin E acetate.
As a preferred embodiment, the filler comprises hydrophilic fumed silica.
As a preferable technical proposal, the specific surface area of the hydrophilic fumed silica is 170-230m2(ii)/g; the pH value of the hydrophilic fumed silica is 3.8-4.3.
As a preferable technical scheme, the filler further comprises one or more of mica, pearl powder, zinc oxide, titanium dioxide, silicon oxide, nylon powder, talcum powder, silver white powder, walnut shell grinding sand, wax-coated VC, silicone oil-coated iron yellow pigment and silicone oil-coated iron red pigment.
The second aspect of the present invention provides a method for producing the above liquid oily composition, comprising the steps of:
(1) heating polar oil or oil solution, antiaging active substance and antioxidant to 60-80 deg.C, and stirring for 15-30 min;
(2) stirring and cooling to 20-30 ℃, and measuring the refractive index;
(3) adding hydrophilic fumed silica, and rapidly stirring for 60-120 min;
(4) the refractive index was measured.
(5) Adding the rest filler, and stirring for 20-40min to obtain the liquid oily composition.
In a third aspect, the invention provides an application of the liquid oily composition in body milk, sun-block milk, whitening milk, foundation liquid and makeup removing milk.
Has the advantages that: according to the invention, through matching the hydrophilic fumed silica with the oils with different polarities and different structures, the oil-water emulsion has the advantages of high suspension capacity, low viscosity, transparency, freshness, good spreadability, low cost, skin moistening, anti-aging oil and difficult oxidative deterioration.
Detailed Description
The technical features of the technical solutions provided by the present invention are further clearly and completely described below with reference to the specific embodiments, and the scope of protection is not limited thereto.
When an amount, concentration, or other value or parameter is expressed as a range, preferred range, or as a range of upper preferable values and lower preferable values, this is to be understood as specifically disclosing all ranges formed from any pair of any upper range limit or preferred value and any lower range limit or preferred value, regardless of whether ranges are separately disclosed. For example, when the range "1 to 5" is disclosed, the described range should be construed as including the ranges "1 to 4", "1 to 3", "1 to 2", "2 to 3" and "3 to 4", "4 to 5" and "3 to 5", etc. When a range of values is described herein, unless otherwise stated, the range is intended to include the endpoints thereof and all integers and fractions within the range.
The singular forms "a", "an" and "the" include plural referents unless the context clearly dictates otherwise. "optional" or "any" means that the subsequently described event or events may or may not occur, and that the description includes instances where the event occurs and instances where it does not.
In addition, the indefinite articles "a" and "an" preceding an element or component of the invention are not intended to limit the number requirement (i.e., the number of occurrences) of the element or component. Thus, "a" or "an" should be read to include one or at least one, and the singular form of an element or component also includes the plural unless the stated number clearly indicates that the singular form is intended.
In order to solve the above technical problems, a first aspect of the present invention provides a liquid oily composition comprising at least a polar oil or oil-soluble substance, a filler; the polar oil or oil soluble substance is selected from one or more of liquid vegetable oil, liquid animal oil, and oil soluble ultraviolet absorbent.
In one embodiment, the polar oil or oil-soluble substance is present in an amount of 20 to 99.74 wt%.
In one embodiment, the filler is present in an amount of 0.11 to 10 wt%.
In the present invention, the contents of the polar oil or oil-soluble substance, the filler, the anti-aging active substance and the antioxidant, and the corresponding specific sub-concepts thereof are all percentage contents relative to the mass of the liquid oily composition.
Polar fats or oil-soluble substances
In one embodiment, the polar oil or fat-soluble substance is selected from at least two of liquid vegetable oil and fat, liquid animal oil and fat, and oil-soluble ultraviolet absorber.
In a preferred embodiment, the polar oil or oil-soluble substance includes at least liquid vegetable oil or liquid animal oil.
(liquid vegetable oil)
In one embodiment, the liquid vegetable fat is selected from one or more of ethylhexyl palmitate, caprylic/capric glycerides, olive oil, grape seed oil, macadamia nut oil.
In a preferred embodiment, the liquid vegetable fat comprises at least ethylhexyl palmitate, caprylic/capric glycerides.
According to the invention, the ethyl hexyl palmitate is the main oil, and the content of the ethyl hexyl palmitate is the balance, namely, the total content is up to 100 wt%.
Ethyl hexyl palmitate
The ethylhexyl palmitate (2-EHP), namely isooctyl hexadecanoate, octyl palmitate, 2-ethylhexyl palmitate and 2-ethylhexyl palmitate, is clear and transparent liquid, is tasteless, insoluble in water and soluble in most solvents, is a high-purity high-grade fatty acid ester product, is mainly used as a cosmetic raw material, and is an excellent skin softening agent. Has stable property, and is not easy to oxidize or generate peculiar smell. The molecular formula is as follows: c24H48O2CAS number: 29806-73-3, refreshing, easy to push away, noneGenerally, vegetable oils have a sticky feeling, and are easy to permeate into pores to clean greasy dirt due to their small molecular size, so that they are very good for makeup removal, but they also permeate into keratinocytes, and when used excessively, the skin becomes keratinized and coarse with waxy yellow. The common ethylhexyl palmitate content is 1-5 wt%, and can be added into oil phase to make oily raw material for various cosmetics.
Caprylic/capric glycerides
In one embodiment, the glyceryl caprylate/caprate is present in an amount of 15 to 20 wt%; preferably, the caprylic/capric glyceride content is 17 wt%.
In the invention, the caprylic/capric glyceride is light yellow, is high-cleanness odorless grease, and belongs to derivatives of palm oil or coconut oil. Can be widely used in food, medicine, and cosmetic industries, and can be used as base material of moisturizing factor, cosmetic stabilizer, antifreezing agent, and homogenizing agent.
In one embodiment, the glyceryl caprylate/caprate has a saponification value of 325-.
In the present invention, the saponification number is defined as the number of milligrams of potassium hydroxide consumed by the alkaline hydrolysis of 1g of fats and oils.
In the invention, the ethylhexyl palmitate and the caprylic/capric glyceride act together to build a main oily combined structure, the price is low, the polarity is proper, good steric hindrance is formed inside the oily combined structure, the oily combined structure can slide, and the viscosity is not too high. And the polarity of the caprylic/capric glyceride, the olive oil and the grape seed oil are mutually influenced, so that the liquid oily composition has the characteristics of high suspension capacity and low viscosity, and the phenomena of skin keratinization becoming coarse wax yellow and the like can not occur under the action of hydrophilic fumed silica under higher content.
When the liquid oily composition is used in body milk, the liquid vegetable oil comprises ethylhexyl palmitate, caprylic/capric glyceride, olive oil, grapeseed oil.
Olive oil
In one embodiment, the olive oil is present in an amount of 4-6 wt%; preferably, the content of the olive oil is 5 wt%.
In the invention, the olive oil belongs to woody plant oil, is directly cold-pressed from fresh olive fruits, does not undergo heating and chemical treatment, retains natural nutrient components, and is considered as the most suitable oil for human nutrition in the oil discovered so far. The six most important fatty acids in olive oil are oleic, linoleic, linolenic, palmitoleic, palmitic and stearic acids, respectively. The oleic acid content (the most predominant fraction of monounsaturated fatty acids) is highest. Because olive oil contains polyphenol and lipopolysaccharide components, olive oil also has the radiation protection function. Among the components of olive oil, carotene and chlorophyll give olive oil a yellow-green color, while chlorophyll plays a role in metabolism, promotes cell growth, and accelerates wound healing. It also helps to beautify the appearance of people and reduce the generation of wrinkles. The olive oil contains antioxidant capable of eliminating free radicals in vivo.
In one embodiment, the olive oil is purchased from debo, france.
Grape seed oil
In one embodiment, the grape seed oil is present in an amount of 2 to 4 wt%; preferably, the content of the grape seed oil is 3 wt%.
The oil content of the grape seeds is 10-20 wt%, and the linoleic acid proportion in the grape seed oil of most varieties is more than 70 wt% of the total fatty acid, and some varieties are even as high as 81 wt%, and the varieties with the linoleic acid proportion lower than 60 wt% are very rare. Therefore, the grape seed oil belongs to high linoleic acid type grease. The grape seed oil contains rich unsaturated fatty acid, mainly oleic acid and linoleic acid, wherein the content of the linoleic acid is up to 72-76 wt%. Linoleic acid is essential fatty acid for human body, and is easy to be absorbed by human body, and grape seed oil is rich in vitamin E, has strong oxidation resistance, and is not easy to cause oxidation rancidity phenomenon caused by illumination, heat radiation and contact with air. Oxidation resistance and color spot lightening; regulating xerosis cutis caused by endocrine disturbance, reducing melanin, whitening skin, and removing chloasma; stimulating cell division and tissue regeneration, activating surface cells, reducing wrinkles and delaying senescence; inhibit and eliminate free radicals in vivo. Grape seed oil has a dual effect on the skin, on the one hand it promotes the formation of moderate cross-links of collagen, and on the other hand it acts as an effective free radical scavenger, preventing the skin from "over-cross-linking", thus also preventing the appearance of skin wrinkles and vesicles, maintaining the skin smooth and soft.
In one embodiment, the grape seed oil is purchased from northern star, uk.
When the liquid oily composition is used for whitening milk, the liquid vegetable oil comprises ethylhexyl palmitate, caprylic/capric glyceride, olive oil.
When the liquid oily composition is used in a liquid foundation, the liquid vegetable oil or fat includes ethylhexyl palmitate, caprylic/capric glyceride, olive oil, macadamia nut oil.
Macadamia nut oil
In one embodiment, the macadamia nut oil is present in an amount of 2 to 4 wt%; preferably, the content of the macadamia nut oil is 3 wt%.
In the invention, the macadamia nut oil is edible oil obtained by processing macadamia nuts by different methods (such as cold pressing method, supercritical extraction and subcritical extraction method).
In one embodiment, the macadamia nut oil is purchased from lebekang, usa.
The macadamia nut oil contains nutrients which are necessary for forming an oil protective layer on the skin, most importantly, the macadamia nut oil is mild in oiliness, does not stimulate the skin, can make the skin soft and active, protects cell membranes, moistens and moisturizes, increases the smoothness and the nourishment degree, is good in ductility, has a greasy feeling and is good in permeability. The pigment has excellent discoloration and flaw covering effects under the combined action of the silicon oil-coated iron yellow pigment, the silicon oil-coated iron red pigment and the silicon oil-coated titanium dioxide, and simultaneously the viscosity of the pigment is 1600cps and the appearance of the pigment is transparent.
(liquid animal fat)
In one embodiment, the liquid animal fat is hydrogenated polyisobutene.
In one embodiment, the hydrogenated polyisobutene is from 7.5 to 15 wt%; preferably, the hydrogenated polyisobutene content is from 9.5 to 10% by weight.
In the present invention, the hydrogenated polyisobutene is otherwise known as: squalane and isotridecane (duSqualane) were synthesized. Is hydrocarbon oil obtained by hydrogenating squalene extracted from deep sea shark liver, and is named as deep sea shark liver oil. CAS is 61693-08-1.
Hydrogenated polyisobutenes are rare animal fats and oils which have high chemical stability and an excellent sensation in use, have a better affinity for the skin, have a lower polarity and moderate spreadability. Hydrogenated polyisobutene added into cosmetics does not cause damage to skin, and on the contrary, the hydrogenated polyisobutene also has a good skin care effect: the epidermis is repaired in an enhanced way, a natural protective film is effectively formed, and the balance between the skin and the sebum is assisted; the skin-protecting agent has strong affinity, can be integrated with the skin lipid membrane of human body, and forms a natural barrier on the skin surface; inhibiting the peroxidation of skin lipid, effectively permeating into the skin, promoting the proliferation of skin basal cells, and having obvious physiological effects of delaying skin aging, improving and eliminating chloasma; the skin pore is opened, the blood microcirculation is promoted, the metabolism of cells is enhanced, and the damaged cells are repaired.
When the liquid oily composition is used for sunscreen emulsion, the polar oil or oil-soluble substance comprises liquid vegetable oil, liquid animal oil, and oil-soluble ultraviolet absorbent.
(oil-soluble ultraviolet absorber)
In one embodiment, the oil-soluble ultraviolet absorber is selected from one or more of ethylhexyl methoxylaurate, octocrylene, and UVinal a plus; preferably, the oil-soluble ultraviolet absorber includes ethylhexyl methoxylaurate, octocrylene, and UVinal a plus.
Methoxylauric acid ethylhexyl ester
In one embodiment, the ethylhexyl methoxylaurate is present in an amount of 6 to 10 wt%; preferably, the content of the ethylhexyl methoxylaurate is 8 wt%.
In the invention, the methoxy ethyl hexyl laurate is a medical intermediate and is colorless to faint yellowThe viscous liquid is insoluble in water, can be dissolved in organic solvents such as ethanol, has good oil solubility, and is suitable for being stored in a shade place in a sealed manner. The ethylhexyl methoxycinnamate is a good absorbent in an ultraviolet UVB region, can effectively prevent ultraviolet rays with the wavelength of 280-310nm, and has high absorptivity. Has no irritation to skin and good safety, and is almost an ideal sun-screening agent. Chemical formula C18H26O3Structural formula is
Ockelelin
In one embodiment, the amount of the ocreliline is 3 to 5 wt%; preferably, the content of the octocrylene is 4 wt%.
In the present invention, the octocrylene, the oil-soluble ultraviolet absorber, is insoluble in water. To aid in the dissolution of other oil-soluble solid sunscreen agents. Has the advantages of high absorption rate, no toxicity, no teratogenesis, good stability to light and heat and the like, can absorb UV-B and a small amount of UV-A, and has CAS number: 6197-30-4, molecular formula: c24H27NO2Viscous, pale yellow, clear oily liquid.
UVinal A plus
In one embodiment, the amount of UVinal A plus is 1 to 3 wt%; preferably, the content of the UVinal Aplus is 2 wt%.
In the present invention, the UVinal A plus active sunscreen ingredient is purchased from Pasteur, Germany.
According to the invention, different types of polar grease or oil soluble matters are adopted, and particularly, the combined action of the ethyl hexyl palmitate, the caprylic/capric glyceride, hydrogenated polyisobutene and other liquid vegetable grease and liquid animal grease with different polarities is adopted, so that the intermolecular acting force of the polar grease or oil soluble matters is obviously improved under the action of the hydrophilic fumed silica, and the suspension force of the liquid oily composition is improved.
Filler material
In one embodiment, the filler comprises hydrophilic fumed silica.
In the invention, the hydrophilic fumed silica is prepared by hydrolyzing volatile chlorosilane in oxyhydrogen flame. From a chemical point of view, hydrophilic fumed silica consists of highly pure amorphous silica. Hydrophilic silicas are wettable by water and dispersible in water.
In one embodiment, the hydrophilic fumed silica is present in an amount of 0.1 to 5 wt%.
When the liquid oily composition is used for body milk, the content of the hydrophilic fumed silica is 0.1-3 wt%.
Further, when the liquid oily composition is used for the body fluid, the content of the hydrophilic fumed silica is 0.1 wt%; when the liquid oily composition is used for moistening the magic body lotion, the content of the hydrophilic fumed silica is 0.5 wt%; when the liquid oily composition is used for rubbing massage body milk, the content of the hydrophilic fumed silica is 3 wt%.
When the liquid oily composition is used in a sun protection cream, the content of the hydrophilic fumed silica is 0.3 wt%.
When the liquid oily composition is used for whitening milk, the content of the hydrophilic fumed silica is 0.7 wt%.
When the liquid oily composition is used for a liquid foundation, the content of the hydrophilic fumed silica is 5% by weight.
In one embodiment, the hydrophilic fumed silica is selected from one or more of Y150, Y200, Y300, Y380, A150, A200, A300, A380, V15, V15P, N20, N20P, T30, T40, LM-150, M-5, EH-5, QS-102, QS-20LS, QS-30, QS-40, K150, K200.
In one embodiment, the hydrophilic fumed silica has a specific surface area of 170-230m2(ii)/g; the pH value of the hydrophilic fumed silica is 3.8-4.3.
In the present invention, the pH of the hydrophilic fumed silica of 3.8 to 4.3 means the pH of a dispersion having a concentration of 4 wt%.
In a preferred embodiment, the hydrophilic fumed silica is N20, purchased from Wake International group, Inc., Germany.
The hydrophilic fumed silica N20 with high specific surface area is adopted, so that the viscosity index of liquid can be effectively changed, the suspension property and the dispersibility of the hydrophilic fumed silica and other fillers in a liquid system are improved, the water resistance is improved, the hydrophilic fumed silica has super strong water phase thickening capability, particularly the pH value of the hydrophilic fumed silica is 3.8-4.3, the charge quantity and the charge stability of the composition are effectively improved, and the hydrophilic fumed silica can be combined with different polar oils to achieve good suspension, low viscosity, transparency and good use feeling.
In one embodiment, the filler further comprises one or more of mica, pearl powder, zinc oxide, titanium dioxide, silicon oxide, nylon powder, talc, silvery white powder, walnut shell grit, wax-coated VC, silicone oil-coated iron yellow pigment, and silicone oil-coated iron red pigment.
In a preferred embodiment, the filler further comprises at least one of a pearl powder, titanium dioxide, silver white powder, walnut shell grit, wax-coated VC, silicone oil-coated iron yellow pigment, and silicone oil-coated iron red pigment.
Further, when the liquid oily composition is used for smoothing body cream and moistening magic body cream, the filler comprises hydrophilic fumed silica and pearl powder.
(Pearl essence)
In one embodiment, the particle size of the pearlescent flakes is 0.05 to 0.2 microns.
In one embodiment, the pearlescent flakes are present in an amount of 0.1 to 0.3 wt%.
Further, when the liquid oily composition is used for the body fluid, the pearl powder is fluorescent white pearl powder; the grain size of the pearl fluorescent powder is 0.05 micron; the content of the fluorescent pearl powder is 0.1 wt%; the glittering white bead powder was purchased from merck, netherlands.
Further, when the liquid oily composition is used for moistening the magic body lotion, the pearl powder is the colorful pearl powder; the grain size of the colorful pearl powder is 0.2 micron; the content of the colorful pearl powder is 0.3 wt%; the colorful pearlescent powder is purchased from merck, the netherlands.
Further, when the liquid oily composition is used for rubbing massage body milk, the filler comprises hydrophilic fumed silica, walnut shell abrasive grains.
(walnut shell grit)
In one embodiment, the walnut shell abrasive grain has a particle size of 0.5 microns; the content of the walnut shell abrasive grains is 5 wt%; the walnut shell grit particles were purchased from shanghai puren company.
Further, when the liquid oily composition is used for sun protection cream, the filler comprises hydrophilic fumed silica and silver white powder.
(silver white light powder)
In one embodiment, the silver white powder has a particle size of 0.7 microns; the content of the silver white light powder is 0.2 wt%; the silver white powder was purchased from merck, the netherlands.
Further, when the liquid oily composition is used for whitening milk, the filler comprises hydrophilic fumed silica, wax-coated VC.
(VC in wax wrap)
In one embodiment, the wax-encapsulated VC has a particle size of 0.7 microns; the content of VC wrapped by the wax is 0.2 wt%; the wax-wrapped VC was purchased from Shanghai Puen.
In the invention, the wax-coated VC is VC coated with beeswax.
Further, when the liquid oily composition is used for a liquid foundation, the filler comprises hydrophilic fumed silica, silicone oil-coated iron yellow pigment, silicone oil-coated iron red pigment and titanium dioxide.
(silicon oil coated iron yellow pigment)
In one embodiment, the silicone oil encapsulates iron yellow pigment with a particle size of 1.5 microns; the content of the silicone oil-coated iron yellow pigment is 1 wt%; the silicone oil-coated iron yellow pigment was purchased from Senxin, France.
In the invention, the silicone oil coated iron yellow pigment refers to iron oxide yellow pigment coated with dimethyl silicone oil on the surface.
(silicon oil coated iron red pigment)
In one embodiment, the silicone oil encapsulates the iron red pigment to have a particle size of 1.5 microns; the content of the silicone oil-coated iron red pigment is 1 wt%; the silicone oil-coated ferrirubin was purchased from shin corporation, france.
In the invention, the silicone oil-coated iron red pigment refers to iron oxide yellow pigment with the surface coated with dimethyl silicone oil.
(titanium dioxide)
In one embodiment, the titanium dioxide is a silicone oil coated titanium dioxide.
In one embodiment, the silicone oil coated titanium dioxide has a particle size of 1.5 microns; the content of titanium dioxide wrapped by the silicone oil is 2 wt%; the silicone oil-coated titanium dioxide was purchased from the company forest, france.
In one embodiment, the liquid oily composition further comprises an anti-aging active and an antioxidant.
Anti-aging actives
In one embodiment, the anti-aging active is selected from one or more of bisabolol, vitamin a, vitamin E, cholesterol, lanosterol, vitamin E acetate; preferably, the anti-aging active is selected from at least one of bisabolol, lanosterol, vitamin E acetate.
In a preferred embodiment, the anti-aging active comprises at least bisabolol.
(bisabolol)
In one embodiment, the bisabolol is present in an amount of 0.1 to 0.3 wt%; preferably, the content of the bisabolol is 0.2 wt%.
In the invention, the bisabolol is a component existing in the chamomile, and the anti-inflammatory effect of the chamomile is mainly derived from the bisabolol. The molecular formula is as follows: c15H26O, CAS number: 515-69-5. Colorless to a glutinous liquid of rice straw yellow, soluble in lower alcohols (ethanol, isopropanol), fatty alcohols, glycerides and vinegar, hardly soluble in water and glycerin.
The addition of bisabolol can improve the stability of the liquid oily composition and the compatibility with skin, and the liquid oily composition does not discolor after long-term storage, does not seep out of a plastic container, has no problems in use, not only has anti-inflammatory performance, but also is proved to have bacteriostatic activity.
When the liquid oily composition is used for moisturizing magic body lotion, the anti-aging actives include bisabolol, lanosterol.
(lanosterol)
In one embodiment, the lanosterol content is 1 wt.%.
Lanosterol is present in non-saponificates within lanolin and is an intermediate in cholesterol biosynthesis. Dissolving in chloroform, ethanol, and diethyl ether. Lanosterol is a tetracyclic triterpene compound, and can be prepared from chain squalene. Molecular formula C30H50O, CAS number 79-63-0.
When the lanosterol is used for moistening the magic body lotion, the structure of the lanosterol is similar to that of hydrogenated polyisobutene, the smearing property of the product is optimized, the skin moistening and anti-aging properties are strong, the lanosterol and the hydrogenated polyisobutene act together, more than 1% of solid particles are suspended at the viscosity of 200cps, the smearing feeling is good, the skin feeling is fresh, and the lanosterol is transparent and beautiful.
When the liquid oily composition is used in whitening milk, the anti-aging actives include bisabolol, vitamin E acetate.
(vitamin E acetate)
In one embodiment, the vitamin E acetate is present in an amount of 4 to 6 wt%; preferably, the vitamin E acetate is present in an amount of 5 wt%.
In the invention, the vitamin E acetate, CAS No. 7695-91-2, is light yellow viscous liquid, is easily soluble in chloroform, diethyl ether, acetone and vegetable oil, is soluble in alcohol and is insoluble in water. Has good heat resistance, can be oxidized when being exposed to light, and has dark color.
The vitamin E acetate and wax-coated VC can improve the whitening effect and keep stable luster for a long time under the action of the red powder alcohol and the dibutyl hydroxy toluene.
Antioxidant agent
In one embodiment, the antioxidant is selected from one or more of dibutyl hydroxy toluene, butyl hydroxy anisole, citric acid, sodium sulfite, sodium bisulfite, sodium metabisulfite; preferably, the antioxidant is dibutylhydroxytoluene.
In the invention, the molecular formula of the dibutyl hydroxy toluene, namely 2, 6-di-tert-butyl-p-cresol (BHT for short) is C15H24O, relative molecular mass 220.36, CAS number 128-37-0. The dibutyl hydroxy toluene is white crystal or crystalline powder, basically odorless and tasteless, has a melting point of 69.5-71.5 ℃, a boiling point of 265 ℃, and is quite stable to heat. The antioxidant effect of dibutylhydroxytoluene is realized by autoxidation of dibutylhydroxytoluene.
When the liquid oily composition is used in body milk, sun milk, etc., the liquid oily composition further comprises 0.1 wt% of a perfume.
Essence
In one embodiment, the fragrance is a synthetic floral fragrance, purchased from international fragrance company, usa.
The second aspect of the present invention provides a method for producing the above liquid oily composition, comprising the steps of:
(1) heating polar oil or oil solution, antiaging active substance and antioxidant to 60-80 deg.C, and stirring for 15-30 min;
(2) stirring and cooling to 20-30 ℃, and measuring the refractive index;
(3) adding hydrophilic fumed silica, and rapidly stirring for 60-120 min;
(4) the refractive index was measured.
(5) Adding the rest filler, and stirring for 20-40min to obtain the liquid oily composition.
In one embodiment, the method for preparing the liquid oily composition comprises the following steps:
(1) heating polar oil or oil solution, antiaging active substance and antioxidant to 70 deg.C, and stirring for 20 min;
(2) stirring and cooling to 25 ℃, and measuring the refractive index;
(3) adding hydrophilic fumed silica, and rapidly stirring for 90 min;
(4) the refractive index was measured.
(5) Adding the rest filler and the rest raw materials, and stirring for 30min to obtain the liquid oily composition.
In a third aspect, the invention provides an application of the liquid oily composition in body milk, sun-block milk, whitening milk, foundation liquid and makeup removing milk.
The present invention will be specifically described below by way of examples. It should be noted that the following examples are only for illustrating the present invention and should not be construed as limiting the scope of the present invention, and that the insubstantial modifications and adaptations of the present invention by those skilled in the art based on the above disclosure are still within the scope of the present invention.
In addition, the starting materials used are all commercially available, unless otherwise specified.
Examples
Example 1
Example 1 provides a liquid oily composition, which specifically comprises, by mass: 0.1% of hydrophilic fumed silica, 17% of caprylic/capric glyceride, 5% of olive oil, 3% of grape seed oil, 7.5% of hydrogenated polyisobutene, 0.2% of fustin, 0.1% of dibutyl hydroxy toluene, 0.1% of fluorescent white pearly-lustre powder, 0.1% of essence and the balance of ethylhexyl palmitate;
the hydrophilic fumed silica is N20, purchased from Wake International group, Inc., Germany;
the caprylic/capric glycerides were purchased from debo, france;
the olive oil was purchased from northern Star, UK;
the grape seed oil was purchased from northern star, uk;
the grain size of the pearl fluorescent powder is 0.05 micron; the fluorescent white pearl powder was purchased from merck, germany;
the essence is a synthetic floral essence purchased from international perfume company of the united states.
The preparation method of the liquid oily composition comprises the following steps:
(1) heating ethylhexyl palmitate, caprylic/capric glyceride, olive oil, grape seed oil, hydrogenated polyisobutene, pinoxanol and dibutyl hydroxy toluene to 70 deg.C, and stirring for 20 min;
(2) stirring and cooling to 25 ℃, and measuring the refractive index;
(3) adding hydrophilic fumed silica, and rapidly stirring for 90 min;
(4) the refractive index was measured.
(5) Adding pearl essence and essence, and stirring for 30min to obtain the liquid oily composition.
The liquid oily composition is used for a body lotion.
Example 2
Example 2 provides a liquid oily composition, which is the same as example 1 except that the hydrophilic fumed silica is V15, and the specific surface area is 130-179m2(ii)/g, purchased from Wake International group, Inc., Germany. The adding amount is 0.1 percent
The liquid oily composition was prepared in the same manner as in example 1.
The liquid oily composition is used for a body lotion.
Example 3
Example 3 provides a liquid oily composition, similar to example 1, except that 0.1% of the hydrophilic fumed silica is replaced by 0.5% of hydrophilic fumed silica.
The liquid oily composition was prepared in the same manner as in example 1.
The liquid oily composition is used for a body lotion.
Example 4
Example 4 provides a liquid oily composition, similar to example 1, except that 0.1% hydrophilic fumed silica is replaced by 1.0%.
The liquid oily composition was prepared in the same manner as in example 1.
The liquid oily composition is used for a body lotion.
Example 5
Example 5 provides a liquid oily composition, similar to example 1, except that the glyceryl caprylate/caprate is replaced with glyceryl tristearate having a CAS number of 555-43-1.
Example 6
Example 6 provides a liquid oily composition, which specifically comprises, by mass: 0.5% of hydrophilic fumed silica, 17% of caprylic/capric glyceride, 5% of olive oil, 3% of grape seed oil, 1% of lanosterol, 7.5% of hydrogenated polyisobutene, 0.2% of pinoxanthin, 0.1% of dibutyl hydroxy toluene, 0.3% of colorful pearl powder, 0.1% of essence and the balance of ethylhexyl palmitate;
the hydrophilic fumed silica is N20, purchased from Wake International group, Inc., Germany;
the caprylic/capric glycerides were purchased from debo, france;
the olive oil was purchased from northern Star, UK;
the grape seed oil was purchased from northern star, uk;
the grain size of the colorful pearl powder is 0.2 micron; the colorful pearl powder is purchased from Merck of Germany;
the essence is a florescent essence purchased from International flavors corporation of America.
The preparation method of the liquid oily composition comprises the following steps:
(1) heating ethylhexyl palmitate, caprylic/capric glyceride, olive oil, grapeseed oil, hydrogenated polyisobutene, pinoxanol, lanosterol and dibutyl hydroxy toluene to 70 deg.C, and stirring for 20 min;
(2) stirring and cooling to 25 ℃, and measuring the refractive index;
(3) adding hydrophilic fumed silica, and rapidly stirring for 90 min;
(4) the refractive index was measured.
(5) Adding colorful pearl essence and essence, and stirring for 30min to obtain the liquid oily composition.
The liquid oily composition is used for moistening magic body lotion.
Example 7
Example 7 provides a liquid oily composition, which specifically comprises, by mass: 3% of hydrophilic fumed silica, 17% of caprylic/capric glyceride, 5% of olive oil, 3% of grape seed oil, 9.5% of hydrogenated polyisobutene, 0.2% of creosol, 0.1% of dibutyl hydroxy toluene, 5% of walnut shell grinding sand, 0.1% of essence and the balance of ethylhexyl palmitate;
the hydrophilic fumed silica is N20, purchased from Wake International group, Inc., Germany;
the caprylic/capric glycerides were purchased from debo, france;
the olive oil was purchased from northern Star, UK;
the grape seed oil was purchased from northern star, uk;
the grain size of the walnut shell abrasive grains is 0.5 micron; the walnut shell grit particles were purchased from shanghai puren company;
the essence is a synthetic floral essence purchased from international perfume company of the united states.
The preparation method of the liquid oily composition comprises the following steps:
(1) heating ethylhexyl palmitate, caprylic/capric glyceride, olive oil, grape seed oil, hydrogenated polyisobutene, pinoxanol and dibutyl hydroxy toluene to 70 deg.C, and stirring for 20 min;
(2) stirring and cooling to 25 ℃, and measuring the refractive index;
(3) adding hydrophilic fumed silica, and rapidly stirring for 90 min;
(4) the refractive index was measured.
(5) Adding walnut shell frosted particles and essence, and stirring for 30min to obtain the liquid oily composition.
The liquid oily composition is used for rubbing massage body lotion.
Example 8
Embodiment 8 provides a liquid oily composition, which comprises the following specific components in percentage by mass: 0.3% of hydrophilic gas-phase silicon dioxide, 17% of caprylic/capric glyceride, 8% of methoxy ethylhexyl laurate, 4% of octocrylene, 2% of UVinal apple, 15% of hydrogenated polyisobutene, 0.2% of pinoxapol, 0.1% of dibutyl hydroxy toluene, 0.2% of silvery white powder, 0.1% of essence and the balance of ethylhexyl palmitate;
the hydrophilic fumed silica is N20, purchased from Wake International group, Inc., Germany;
the caprylic/capric glycerides were purchased from debo, france;
the UVinal apple is purchased from Pasteur, Germany;
the particle size of the silver white powder is 0.7 micron; the silver white powder was purchased from merck, netherlands;
the essence is a synthetic floral essence purchased from international perfume company of the united states.
The preparation method of the liquid oily composition comprises the following steps:
(1) heating ethylhexyl palmitate, caprylic/capric glyceride, ethylhexyl methoxylaurate, octocrylene, UVinal apple, hydrogenated polyisobutene, bisabolol and dibutylhydroxytoluene to 70 ℃ and stirring for 20 min;
(2) stirring and cooling to 25 ℃, and measuring the refractive index;
(3) adding hydrophilic fumed silica, and rapidly stirring for 90 min;
(4) the refractive index was measured.
(5) Adding silver white powder and essence, and stirring for 30min to obtain the liquid oily composition.
The liquid oily composition is used for sun protection cream.
Example 9
Example 9 provides a liquid oily composition, which specifically comprises, by mass: 0.7% of hydrophilic fumed silica, 17% of caprylic/capric glyceride, 5% of olive oil, 5% of vitamin E acetate, 15% of hydrogenated polyisobutene, 0.2% of creosol, 0.1% of dibutyl hydroxy toluene, 5% of wax-coated VC and the balance of ethylhexyl palmitate;
the hydrophilic fumed silica is N20, purchased from Wake International group, Inc., Germany;
the caprylic/capric glycerides were purchased from debo, france;
the olive oil was purchased from northern Star, UK;
the grain size of the wax-coated VC is 0.1 micrometer; the wax-wrapped VC was purchased from Shanghai Puen.
The preparation method of the liquid oily composition comprises the following steps:
(1) heating ethylhexyl palmitate, caprylic/capric glyceride, olive oil, hydrogenated polyisobutene, vitamin E acetate, bisabolol and dibutyl hydroxy toluene to 70 deg.C, and stirring for 20 min;
(2) stirring and cooling to 25 ℃, and measuring the refractive index;
(3) adding hydrophilic fumed silica, and rapidly stirring for 90 min;
(4) the refractive index was measured.
(5) Adding VC wrapped by wax, and stirring for 30min to obtain the liquid oily composition.
The liquid oily composition is used for whitening milk.
Example 10
Example 10 provides a liquid oily composition, which specifically comprises, by mass: 5% of hydrophilic fumed silica, 17% of caprylic/capric glyceride, 5% of olive oil, 3% of macadamia nut oil, 10% of hydrogenated polyisobutene, 0.2% of fustin, 0.1% of dibutyl hydroxy toluene, 1% of silicone oil-coated iron yellow pigment, 1% of silicone oil-coated iron red pigment, 2% of silicone oil-coated titanium dioxide and the balance of ethylhexyl palmitate;
the hydrophilic fumed silica is N20, purchased from Wake International group, Inc., Germany;
the caprylic/capric glycerides were purchased from debo, france;
the olive oil was purchased from northern Star, UK;
the macadamia nut oil was purchased from northern Star, UK;
the particle size of the silicone oil coated iron yellow pigment is 1.5 microns; the silicone oil-coated iron yellow pigment was purchased from france senxin;
the particle size of the silicone oil-coated iron red pigment is 1.5 microns; the silicone oil-coated ferrirubin was purchased from france senxin;
the particle size of the titanium dioxide wrapped by the silicone oil is 1.5 microns; the silicone oil-coated titanium dioxide was purchased from the company forest, france.
The preparation method of the liquid oily composition comprises the following steps:
(1) heating ethylhexyl palmitate, caprylic/capric glyceride, olive oil, hydrogenated polyisobutene, vitamin E acetate, bisabolol and dibutyl hydroxy toluene to 70 deg.C, and stirring for 20 min;
(2) stirring and cooling to 25 ℃, and measuring the refractive index;
(3) adding hydrophilic fumed silica, and rapidly stirring for 90 min;
(4) the refractive index was measured.
(5) Adding VC wrapped by wax, and stirring for 30min to obtain the liquid oily composition.
The liquid oily composition is used for foundation liquid.
Performance testing
1. Viscosity: the liquid oily compositions described in examples 1 to 10 were tested for viscosity at 25 ℃ using a Brook Field viscometer, the results of which are given in table 1.
2. Appearance: the appearance of the liquid oily compositions described in examples 1 to 10 was visually observed for clarity, and the test results are shown in Table 1.
3. Suspension force: the liquid oily compositions described in examples 1 to 10 were tested for suspending power by the method of measuring elastic modulus using a rheometer, and the results are shown in Table 1.
4. Smearing feeling: the liquid oily compositions described in examples 1 to 10 were tested for spreadability using the person's spreadability method, and the test results are shown in table 1.
5. Skin feel: the liquid oily compositions described in examples 1 to 10 were tested for suspending power using the evaluation method by a person, and the test results are shown in Table 1.
TABLE 1
The foregoing examples are merely illustrative and serve to explain some of the features of the method of the present invention. The appended claims are intended to claim as broad a scope as is contemplated, and the examples presented herein are merely illustrative of selected implementations in accordance with all possible combinations of examples. Accordingly, it is applicants' intention that the appended claims are not to be limited by the choice of examples illustrating features of the invention. Also, where numerical ranges are used in the claims, subranges therein are included, and variations in these ranges are also to be construed as possible being covered by the appended claims.
Claims (10)
1. A liquid oily composition, characterized in that it comprises at least a polar oil or oil-soluble substance, a filler; the polar oil or oil soluble substance is selected from one or more of liquid vegetable oil, liquid animal oil, and oil soluble ultraviolet absorbent.
2. The liquid oily composition according to claim 1, wherein the liquid vegetable oil or fat is selected from one or more of ethylhexyl palmitate, caprylic/capric glycerides, olive oil, grape seed oil, macadamia nut oil.
3. The liquid oily composition according to claim 2, wherein the saponification value of the glyceryl caprylate/caprate is 325-345 mg/g.
4. The liquid oily composition according to any one of claims 1 to 3, characterized in that it further comprises an anti-ageing active and an antioxidant.
5. The liquid oily composition according to claim 4, wherein the anti-ageing active is selected from one or more of bisabolol, vitamin A, vitamin E, cholesterol, lanosterol, vitamin E acetate.
6. The liquid oily composition according to claim 4, characterized in that the filler comprises hydrophilic fumed silica.
7. The liquid oily composition according to claim 6, wherein the hydrophilic fumed silica has a specific surface area of 170-230m2(ii)/g; the pH value of the hydrophilic fumed silica is 3.8-4.3.
8. The liquid oily composition according to claim 6, characterized in that the filler further comprises one or more of mica, pearlescence, zinc oxide, titanium dioxide, silicon oxide, nylon powder, talc, silvery white powder, walnut shell grits, wax-coated VC, silicone oil-coated iron yellow pigment, silicone oil-coated iron red pigment.
9. A process for the preparation of a liquid oily composition according to any one of claims 6 to 8, characterized by comprising the following steps:
(1) heating polar oil or oil solution, antiaging active substance and antioxidant to 60-80 deg.C, and stirring for 15-30 min;
(2) stirring and cooling to 20-30 ℃, and measuring the refractive index;
(3) adding hydrophilic fumed silica, and rapidly stirring for 60-120 min;
(4) the refractive index was measured.
(5) Adding the rest filler, and stirring for 20-40min to obtain the liquid oily composition.
10. Use of the liquid oily composition according to any one of claims 1 to 8 in body milks, sun screens, whitening milks, liquid foundations, make-up removers.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011613355.XA CN112569127A (en) | 2020-12-30 | 2020-12-30 | Liquid oily composition and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011613355.XA CN112569127A (en) | 2020-12-30 | 2020-12-30 | Liquid oily composition and preparation method and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112569127A true CN112569127A (en) | 2021-03-30 |
Family
ID=75145195
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202011613355.XA Pending CN112569127A (en) | 2020-12-30 | 2020-12-30 | Liquid oily composition and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112569127A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023222116A1 (en) * | 2022-05-20 | 2023-11-23 | 广州润尔眼科生物科技有限公司 | Use of steroid compound |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005063190A1 (en) * | 2003-03-18 | 2005-07-14 | Johnson & Johnson Industrial Ltda. | Sunscreen composition comprising a mixture of silicas |
| CN104940033A (en) * | 2014-03-28 | 2015-09-30 | 强生消费者公司 | Method of making an anhydrous, pigmented composition |
| WO2018153555A1 (en) * | 2017-02-27 | 2018-08-30 | Beiersdorf Ag | Cosmetic or dermatological preparations having a content of inorganic pigments, which are coated with hydrophilic silica, and having one or more stabilizers |
| US20190298623A1 (en) * | 2018-03-30 | 2019-10-03 | L'oreal | Anhydrous Cosmetic Composition |
| CN112057366A (en) * | 2020-08-28 | 2020-12-11 | 浙江美蜜科技有限公司 | Glittering colorful massage oil and preparation method thereof |
-
2020
- 2020-12-30 CN CN202011613355.XA patent/CN112569127A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005063190A1 (en) * | 2003-03-18 | 2005-07-14 | Johnson & Johnson Industrial Ltda. | Sunscreen composition comprising a mixture of silicas |
| CN104940033A (en) * | 2014-03-28 | 2015-09-30 | 强生消费者公司 | Method of making an anhydrous, pigmented composition |
| WO2018153555A1 (en) * | 2017-02-27 | 2018-08-30 | Beiersdorf Ag | Cosmetic or dermatological preparations having a content of inorganic pigments, which are coated with hydrophilic silica, and having one or more stabilizers |
| US20190298623A1 (en) * | 2018-03-30 | 2019-10-03 | L'oreal | Anhydrous Cosmetic Composition |
| CN112057366A (en) * | 2020-08-28 | 2020-12-11 | 浙江美蜜科技有限公司 | Glittering colorful massage oil and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023222116A1 (en) * | 2022-05-20 | 2023-11-23 | 广州润尔眼科生物科技有限公司 | Use of steroid compound |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR102229247B1 (en) | Cosmetic composition for improving wrinkles containing zipenoside isolated from Chilgyeopdam | |
| CN107550771A (en) | Salubrious camellia makeup remover of quality and preparation method thereof | |
| JP2012502020A5 (en) | ||
| CN113081906B (en) | Astaxanthin composition and preparation method and application thereof | |
| KR101917774B1 (en) | A preservative composition of cosmetics comprising Nigella sativa seed extract as an active ingredient | |
| CN113057902A (en) | Camellia seed oil cream containing hydrolyzed vegetable protein and preparation method thereof | |
| CN110721120A (en) | Multifunctional skin care cream and preparation method thereof | |
| KR101184427B1 (en) | Cosmetic composition for improving skin using Gombo-Baechu and manufacturing method thereof | |
| KR101732906B1 (en) | Skin care and atopic dermatitis cosmetic compositions containing asiatic pennywort extract, magnolia bark extract, hiba arborvitae branch extract, eucalyptus oil and borage seed oil | |
| CN112569127A (en) | Liquid oily composition and preparation method and application thereof | |
| JP2008100963A (en) | Cosmetic | |
| US5037641A (en) | Beauty preparations having anti-fading effect and a process for preparing the same | |
| CN112353705A (en) | Cosmetic composition, preparation method thereof and cosmetic with wrinkle removing and aging delaying effects | |
| JP5701480B2 (en) | Antioxidant | |
| KR20180065166A (en) | Cosmetic composition for skin whitening containing pancratium maritimum extract and blue lotus extract | |
| CN111973501A (en) | Ceramide activation milk and preparation method thereof | |
| JP7016500B1 (en) | Waterproof eye pencil cosmetic composition and method for manufacturing waterproof eye pencil cosmetic using the same | |
| KR101934976B1 (en) | Composition for enhancing skin barrier comprising mixture of Diospyros lotus leaf extract and Curcuma longa extract as effective component | |
| KR101462491B1 (en) | Cosmetic Compositions for Moisturizing Lips | |
| KR20220118059A (en) | A method for increasing antioxidation capacity of purple tea leaves | |
| CN112545914A (en) | Safflower rich velvet nourishing lipstick | |
| KR101363029B1 (en) | The cosmetic composition for anti-oxident and anti-aging of the skin comprising the Gelidium amansii, Undaria pinnatifida, wheat bud and Monarda horsemint | |
| KR20100045691A (en) | Cosmetic composition for inhibiting inflammation comprising the extract of euphoria longan as active ingredient | |
| JP2006282536A (en) | Super oxide-eliminating agent, free radical-eliminating agent, hydrogen peroxide-eliminating agent and external preparation for skin | |
| KR20080038482A (en) | Cosmetic composition for protecting skin aging comprising the extract of root from rhododendron mucronulatum as active ingredient |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20210330 |
|
| RJ01 | Rejection of invention patent application after publication |