CN112424396B - 用于可持续产生氢气的连续方法 - Google Patents

用于可持续产生氢气的连续方法 Download PDF

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Publication number
CN112424396B
CN112424396B CN201980047876.2A CN201980047876A CN112424396B CN 112424396 B CN112424396 B CN 112424396B CN 201980047876 A CN201980047876 A CN 201980047876A CN 112424396 B CN112424396 B CN 112424396B
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zinc
tin
hydroxide
metal
solution
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CN112424396A (zh
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巴赫曼·阿米尼霍瑞
顾赛
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University of Surrey
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University of Surrey
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/06Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents
    • C01B3/08Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents by reaction of inorganic compounds with metals
    • C01B3/10Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents by reaction of inorganic compounds with metals by reaction of water vapour with metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/2455Stationary reactors without moving elements inside provoking a loop type movement of the reactants
    • B01J19/2465Stationary reactors without moving elements inside provoking a loop type movement of the reactants externally, i.e. the mixture leaving the vessel and subsequently re-entering it
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/14Methods for preparing oxides or hydroxides in general
    • C01B13/20Methods for preparing oxides or hydroxides in general by oxidation of elements in the gaseous state; by oxidation or hydrolysis of compounds in the gaseous state
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01DCOMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D1/00Oxides or hydroxides of sodium, potassium or alkali metals in general
    • C01D1/02Oxides
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G1/00Methods of preparing compounds of metals not covered by subclasses C01B, C01C, C01D, or C01F, in general
    • C01G1/02Oxides
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G9/00Compounds of zinc
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G9/00Compounds of zinc
    • C01G9/02Oxides; Hydroxides
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/14Electrolytic production, recovery or refining of metals by electrolysis of solutions of tin
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/16Electrolytic production, recovery or refining of metals by electrolysis of solutions of zinc, cadmium or mercury
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Metallurgy (AREA)
  • Combustion & Propulsion (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Electrolytic Production Of Metals (AREA)
CN201980047876.2A 2018-07-19 2019-07-18 用于可持续产生氢气的连续方法 Active CN112424396B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB1811785.3A GB201811785D0 (en) 2018-07-19 2018-07-19 A continuous process for sustainable production of hydrogen
GB1811785.3 2018-07-19
PCT/GB2019/052002 WO2020016580A2 (en) 2018-07-19 2019-07-18 A continuous process for sustainable production of hydrogen

Publications (2)

Publication Number Publication Date
CN112424396A CN112424396A (zh) 2021-02-26
CN112424396B true CN112424396B (zh) 2024-12-24

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US (1) US12391547B2 (https=)
EP (1) EP3824116A2 (https=)
JP (1) JP7464996B2 (https=)
CN (1) CN112424396B (https=)
CA (1) CA3106028A1 (https=)
GB (1) GB201811785D0 (https=)
WO (1) WO2020016580A2 (https=)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2631304A (en) * 2023-06-27 2025-01-01 Clean Hydrogen Ltd Hydrogen and Battery Storage
GB2632092A (en) * 2023-06-27 2025-01-29 Clean Hydrogen Ltd Multi-phase reactor for hydrogen production
DE102024107523B3 (de) * 2024-03-15 2025-03-06 Forschungszentrum Jülich GmbH Verfahren und eine Anlage zur Wasserstoffgewinnung
US20250320118A1 (en) * 2024-04-12 2025-10-16 Peregrine Hydrogen Inc. Steam sulfurous material reforming and thermochemical cycles related thereto
EP4711476A1 (en) * 2024-09-16 2026-03-18 Energy 13 GmbH Process for preparing iron metal by reduction of iron oxide with hydrogen and device for implementing this process
WO2026074433A1 (en) 2024-10-01 2026-04-09 Fabio Ruggeri Process and system for producing hydrogen and/or syngas

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101746724A (zh) * 2009-12-25 2010-06-23 昆明理工大学 一种同时制取氢气与氧化锌粉体的方法
WO2013181261A2 (en) * 2012-05-31 2013-12-05 Marine Power Products Incorporated Method of and device for optimizing a hydrogen generating system
CN104919088A (zh) * 2012-09-19 2015-09-16 液体光有限公司 由二氧化碳生产羧酸的综合方法
JP2017190275A (ja) * 2016-04-15 2017-10-19 株式会社Ksf 副生水素生成装置

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3928550A (en) * 1974-09-12 1975-12-23 Sun Ventures Inc Process for making hydrogen
US4332650A (en) 1981-01-21 1982-06-01 Gas Research Institute Thermoelectrochemical process using copper oxide for producing hydrogen and oxygen from water
JP2001270701A (ja) * 2000-03-28 2001-10-02 Yutaka Tamaura 水の分解方法
JP2004529056A (ja) 2001-03-06 2004-09-24 アルケミックス・コーポレーション 水素の製造方法およびその用途
JP2005255505A (ja) 2004-03-15 2005-09-22 Kurita Water Ind Ltd 水素供給方法
JP5124728B2 (ja) 2005-03-18 2013-01-23 国立大学法人東京工業大学 水素生成装置、レーザ還元装置、エネルギー変換装置、水素生成方法および発電システム
US9415363B2 (en) 2009-02-20 2016-08-16 Marine Power Products Corporation Method and apparatus for efficient on-demand production of H2 and O2 from water using waste heat and environmentally safe metals
FR2948654B1 (fr) * 2009-07-30 2015-01-16 Gerkaro Cogeneration d'energie electrique et d'hydrogene
KR20140016921A (ko) * 2011-04-05 2014-02-10 블랙라이트 파워 인코포레이티드 H2o 기반의 전기화학적 수소-촉매 전력 시스템
JP5820928B2 (ja) 2011-07-08 2015-11-24 インスティテュート・オブ・ケミカル・テクノロジーInstitute of Chemical Technology 多工程の銅−塩素熱化学サイクルによる水素の製造方法
US10208384B2 (en) 2011-08-11 2019-02-19 Toyota Motor Engineering & Manufacturing North America, Inc. Efficient water oxidation catalysts and methods of oxygen and hydrogen production by photoelectrolysis
TW201504477A (zh) 2013-07-17 2015-02-01 Industrie De Nora Spa 電解電池和鹼溶液電解槽以及在電池內之電解方法
WO2016066571A1 (en) * 2014-10-28 2016-05-06 Shell Internationale Research Maatschappij B.V. Process for producing liquid hydrogen
JP6040511B2 (ja) 2015-03-31 2016-12-07 株式会社エクォス・リサーチ 太陽光利用システム
ITUB20159792A1 (it) * 2015-12-30 2017-06-30 Federico Longhini Sistema e procedimento per la generazione di idrogeno gassoso a richiesta
JP2017155315A (ja) 2016-03-04 2017-09-07 株式会社東芝 光電気化学反応装置

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101746724A (zh) * 2009-12-25 2010-06-23 昆明理工大学 一种同时制取氢气与氧化锌粉体的方法
WO2013181261A2 (en) * 2012-05-31 2013-12-05 Marine Power Products Incorporated Method of and device for optimizing a hydrogen generating system
CN104919088A (zh) * 2012-09-19 2015-09-16 液体光有限公司 由二氧化碳生产羧酸的综合方法
JP2017190275A (ja) * 2016-04-15 2017-10-19 株式会社Ksf 副生水素生成装置

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
A highly efficient hydrogen generation electrolysis system using alkaline zinc hydroxide solution;Bahman Amini Horri et al.;《INTERNATIONAL JOURNAL OF HYDROGEN ENERGY》;第44卷;第72-81页 *

Also Published As

Publication number Publication date
EP3824116A2 (en) 2021-05-26
JP7464996B2 (ja) 2024-04-10
US12391547B2 (en) 2025-08-19
JP2021531407A (ja) 2021-11-18
WO2020016580A2 (en) 2020-01-23
WO2020016580A3 (en) 2020-03-12
CN112424396A (zh) 2021-02-26
CA3106028A1 (en) 2020-01-23
GB201811785D0 (en) 2018-09-05
US20210261407A1 (en) 2021-08-26

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