CN1120303A - Insecticidal compositions - Google Patents
Insecticidal compositions Download PDFInfo
- Publication number
- CN1120303A CN1120303A CN 94191668 CN94191668A CN1120303A CN 1120303 A CN1120303 A CN 1120303A CN 94191668 CN94191668 CN 94191668 CN 94191668 A CN94191668 A CN 94191668A CN 1120303 A CN1120303 A CN 1120303A
- Authority
- CN
- China
- Prior art keywords
- composition
- insect
- insecticidal components
- active insecticidal
- particle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/002—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits
- A01N25/006—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits insecticidal
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Food Science & Technology (AREA)
- Agronomy & Crop Science (AREA)
- Insects & Arthropods (AREA)
- Plant Pathology (AREA)
- Toxicology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention provides a solid insecticidal composition which comprises a mixture of two insecticidally active ingredients in association with an insect-attracting bait substance characterised in that the first insecticidally active ingredient is an insect growth regulator active against larval stages, and the second insecticidally active ingredient is a direct toxicant having knock-down and lethal effects on adult stages, the insect-attracting bait substance being attractive to both adult and larval stages of the insect.
Description
Invention relates to new Pesticidal combination, and is particularly related to the harmful insect that is used to prevent and treat adult and larval phase, particularly with spread disease relevant and to the healthy composition that has the Diptera pest that endangers of humans and animals.
Knew already, the flying insect of some type can be used as the vector of propagation to the healthy disease that is harmful to of human or animal.Special example comprises dipteral insect such as housefly (Musca domestica), and they are with leftovers, excreta, and spoils etc. are food, and they are by microbial contaminations such as bacteriums for this reason, and some microorganisms can then be transferred to the human or animal and will get on the food of food; And chrysomyia megacephala (Chrysomya meqacephala), they follow the domestic animal of raising as food production, for example ox, sheep, goat, pig, poultry are relevant, particularly survive in enclose block or animal house in domestic animal.
Up to the present prevent and treat above-mentioned insect and typically comprise the adult of handling especially with the elimination mission phase, spray insecticide or to getting food place (for example rubbish heap) spraying as space, or hang the band (killing fly paper) that scribbles sticker in dwelling and animal house to the place.Above-mentioned processing is bad to the above-mentioned insect effect of eliminating larval phase, this be because during these larval feedings often be hide and be difficult for contacting with the sprayed deposit thing.The control of larval phase for example can use so-called insect growth to transfer long agent (IGRs), it insect larvae from an age to next age, finally transform the process of normally casting off a skin of interference insect in the pupa and the process in adult stage., above-mentioned processing is invalid fully to the insect in adult stage.
The invention relates to a kind of novel formulations, wherein contain the combination of active insecticidal components, and it can prevent and treat and control larva and the adult of these diptera harmful insects.
Therefore, the invention provides a kind of solid Pesticidal combination, it includes the two kinds of active insecticidal components and the mixture of the bait of luring insect of combination with it, it is characterized in that first kind of active insecticidal components is a kind of to activated insect growth regulator, IGR of larval phase, with second kind of active insecticidal components is a kind of the adult stage to be had the contact toxic agent of knocking down with lethal effect, and the erbium material of luring insect all has attracting action to the insect of adult and larval phase.
The granular above-mentioned composition of preferred use, this composition are suitable for spreading fertilizer over the fields in the place of needs control harmful insect.
In composition of the present invention, can use the active insecticidal components of numerous species.The active component that is fit to as insect growth regulator, IGR (IGRs) that uses in composition comprises that its Chinese common name is grand as flufenoxuron, desinsection, fly eradication amine, methamidophos, fluorine bell urea, diflubenzuron, pyriproxyfen, ABG-6215, UC 62644, Hydramethylnon Bait, methoxy protect that the children is plain, the medicament of hydroprene.Spendable suitable contact toxic agent comprises carbamate insecticide such as unden, carbofuran and bendiocarb; Organophosphorus insecticide such as fenthion, azamethiphos, basudin, chlopyrifos, Methomyl, propetamphos, methyl Actellic and Folithion; And pyrethroid insecticides, as permethrin, cypermethrin, α-cypermethrin, ζ-cypermethrin, decis, tralomethrin, cyfloxylate, β-cyfloxylate, Cyhalothrin, λ-Cyhalothrin, flucythrinate, sumicidin, esfenvalerate and taufluvalinate.Above-mentioned list illustration the type of the active component that comprises in the present composition, but those skilled in the art can replace above-mentioned medicament to prepare other embodiment of the present composition with other active component
The material that the preferred a kind of IGR that uses is an ISO approval called after pyriproxyfen (pyriproxifen) in the present composition, its chemical name is 2[1-methyl-2-(4-phenoxy group phenoxy group) ethyoxyl] pyridine.Preferred toxic agent comprises cypermethrin, permethrin, sumicidin, decis, λ-Cyhalothrin, methyl Actellic and chlorpyrifos-methyl.
Lure the erbium material of insect to be preferably sucrose or other has the crystal sugar of allure to insect.
When IGR is a pyriproxyfen, toxic agent is λ-Cyhalothrin or methyl Actellic and erbium material when being sucrose, can obtain particularly preferred composition.
Composition of the present invention be solid pulvis or, be preferably granule.If carefully control the glycosyl granule of two kinds of active component ratios, just can provide with single application dosage and to have best effectiveness.What this granule not only can be used as imago feeding well lure the erbium material, and provide after a while can disintegration the solvable holder of active component.
Except active insecticidal components and erbium material, also can there be other composition, for example can improves steroids attractant and the dyestuff of composition the target insect attracting action.Therefore, also can add the hormone attractant Z-9-tricosene of luring target insect to the composition that is used for preventing and treating housefly (Musca domestica), and yellow or red colouring agent, for example oil-soluble dyes that provides with trade name " Waxoline " yellow (" Waxoline " is the registration mark of ZENECA Co., Ltd).
Can contain bitters in the composition in addition,, comprise that the mankind's accident is got this particle of food with birds and the mammal that stops non-target.The denatonium benzoate of the bitters that is fit to for selling with trade name " Bifex " (registration mark) raw silk.
In preparation process, for the processing that is beneficial to each composition and the preparation of composition, can add that specific help is flowed and the composition of hybrid technique, as solid diluent and filler, surfactant and solvent.Surfactant can be cloudy from, nonionic or cationic surfactant.Useful especially is long-chain phenylbenzimidazole sulfonic acid salt, as calcium dodecyl benzene sulfonate (phenylbenzimidazole sulfonic acid salt CALX).Solid diluent and filler for example comprise powdered silica, and diatomite and clay if you would take off soil.Spendable solvent comprises that those solubilized active insecticidal components and other compound are to obtain the even coating of holder.Found when active component is pyriproxyfen and pyrethroid, used the ethylene glycol diester, effective especially as propylene-glycol diacetate.
Particulate composition of the present invention can be about to each composition by the mechanical mixing method preparation of routine and insert in the equipment, produces granule by the method for agglomeration.The equipment that is fit to that is used for said method comprises pan-type pelletizer, rolls drum granulator and blender such as ∑ blender, Lodige blender, Fielder matrix blender (matrix mixer) and Shugi blender.Can for example use fluidized bed pelletizer by the using gases stirring means in addition, or for example comprise in flakes or pelleting equipment, or prepare this particulate composition by the method for extruding such as the method for hammer, spiral or marumeriser extruding by the method for pressurization.
The typical method of granule composite produced according to the invention is the agglomeration technique by comprising the steps: (1) is by active component and solid diluent or carrier with required ratio, as silica
Powder is mixed together preparation and concentrates powder, and (2) prilling process mixing dry ingredients by as above being recommended adds toward doing to mix in the thing simultaneously
Enough water is to cause agglomeration, and (3) are proceeded stirring technique and anhydrated to remove up to obtaining required size particles and (4) dried particles.
In the process of the effectiveness of carrying out the test determination present composition, be surprisingly found out that when composition is particle form preferably most of particles are in specific particle size range.This scope is by as a kind of food source, and insect is lured by this food source and gets food with the sufficiently long time thereon, determines with the acceptability of the final composition that absorbs lethal dose.The particle grain size scope can change by the method for normalizing of having known in the granulating technique in the composition.
Therefore, the preferred particle of producing the stronger specified particle diameter scope of housefly allure.Particle size range can change according to the harmful elder brother's who is attracted kind.For the preferred particle size range of adult housefly is 500 μ m to 10000 μ m, and particularly preferred particle is in 2500 μ m to 3500 mu m ranges.
Following embodiment provides the composition of special concern of the present invention.
Use this composition that the adult and the larva of harmful insect such as housefly (Musca domestica) and chrysomyia megacephala (Chrysomya megacephala) are all produced effect.
On the other hand, the invention provides a kind of method of the diptera harmful insect of eliminating larval phase and adult stage, comprising using the above-mentioned insect of compositions-treated according to the present invention vegetatively.
This composition can be incorporated in the governing project of housefly, as disperseing the erbium material, is positioned over erbium material level point or soluble in water and be coated in the target surface.Owing to there is saccharide matrix, housefly can attracted on the composition, and by using vision (color) or chemistry hint, as housefly sex hormone Z-9-tricosene, this attracting action can be enhanced.Red and yellow preparation is effective especially.
After contacting or get the food composition, adult housefly can be gone down and be killed very soon.Particle dissolving after after a while makes active component be distributed to and wherein finds to have in the medium of larva, and kills them or disturb its growth.In the test of granule of the present invention, when with 100mg ai/m
2Dosage when on muck matrix, using composition based on pyriproxyfen and λ-Cyhalothrin, can in two months, keep the inhibition fully that housefly and chrysomyia megacephala are grown.
By the following further illustration of embodiment the present invention, wherein various compositions " part " expression weight portion.
Embodiment 1
The present embodiment illustration according to the present invention the preparation of compositions of coating particle agent form.
With propylene-glycol diacetate (24 parts), calcium dodecyl benzene sulfonate (1 part), the mixture of pyriproxyfen (5 parts) and λ-Cyhalothrin (1 part) is heated to 50 ℃, up to obtaining limpid solution.Then it is joined lentamente in the granular sugar (2Kg) in a rotation rotary drum.Rotation is up to the particle of observing even coating, to obtain required particulate composition continuously.
Embodiment 2
The present embodiment illustration contain the composition of insect hormone according to the present invention.Except before coating particle, Z-9-tricosene (0.5 part) being joined in the mixture, prepare this composition according to illustrative method among the embodiment 1.
Embodiment 3
The present embodiment illustration in particle, be filled with the composition that contains dyestuff of yellow colorants according to the present invention.Except before coating particle, " Waxoline " yellow GFW (0.1 part, registration mark is " Waxoline ") being joined in the mixture, prepare this composition according to illustrative method among the embodiment 1.
Embodiment 4
The present embodiment illustration contain the composition of bitters according to the present invention, eat this composition by mistake with the birds and the mammal that prevent non-target.
Except before adding other composition, at room temperature denatonium benzoate is dissolved in the propylene-glycol diacetate (0.025 part), prepare this composition according to illustrative method among the embodiment 1.
Embodiment 5
The present embodiment illustration contain the composition of organic phosphorus compound according to the present invention.Prepare composition according to embodiment 1 illustrative method except replacing λ-Cyhalothrin with methyl Actellic (10 parts).
Embodiment 6
The present embodiment illustration preparation of particulate composition according to the present invention.
To mix by sucrose (8967 parts) by the pre-composition that λ-Cyhalothrin (5 parts), pyriproxyfen (25 parts) and silica FK320 (1000 parts) form in formula mixing and Z-9-tricosene (2.5 parts), denatonium benzoate (0.1 part), " Monolyte " yellow GNV (0.5 part, " Monolyte " is registration mark) and meticulous separation the (rock sugar level).Sparsely add entry and make disc spins to the mixture on pan-type pelletizer then, in 2800 to 3350m scope, after this particle is carried out drying to remove fine grained except that anhydrating and sieving up to most particle grain size.
Claims (12)
1. solid Pesticidal combination, the mixture that wherein comprises two kinds of active insecticidal components that combine with the bait of luring insect, it is characterized in that first kind of active insecticidal components is to activated insect growth regulator, IGR of insect larvae phase, with second kind of active insecticidal components be to the adult stage insect have the contact toxic agent of knocking down with lethal effect, the bait of luring insect all has allure to the insect of adult stage and larval phase.
2. according to the composition of claim 1, first kind of active insecticidal components pyriproxyfen wherein.
3. according to the composition of claim 1, wherein second kind of active insecticidal components is chrysanthemum ester or organic phosphorus compound.
4. according to the composition of claim 3, chrysanthemum ester wherein is λ-Cyhalothrin.
5. according to the composition of claim 1, the bait of luring insect wherein is sucrose.
6. according to the composition of claim 5, sucrose wherein is granular.
7. according to the composition of claim 6, wherein particle grain size is in 2500 μ m to 3500 mu m ranges.
8. according to the composition of claim 1, also contain a kind of hormone attractant of luring insect in addition.
9. composition according to Claim 8, hormone attractant wherein is that Z-9-23 carbon are rare.
10. according to the composition of claim 1, wherein comprise a kind of composition that makes and become redness or yellow dyestuff.
11. preparation method according to the particulate composition of claim 1, wherein comprise step: (a) first and second kinds of active insecticidal components are mixed with pulverous solid diluent or carrier with required ratio, to prepare concentrated powder, (b) concentrated powder is mixed with the bait of luring insect and other composition, to add enough water during mixing makes the dried thing that mixes cause agglomeration, (c) proceed this technology and make particle drying except that anhydrating up to the particle that obtains required particle size range with (d).
12. eliminate the method for the diptera harmful insect of adult stage and larval phase, wherein comprise vegetatively with the above-mentioned insect of the compositions-treated according to claim 1 of insecticidal effective dose.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9306769.2 | 1993-03-31 | ||
| GB939306769A GB9306769D0 (en) | 1993-03-31 | 1993-03-31 | Insecticidal compositions |
| GB939312207A GB9312207D0 (en) | 1993-06-14 | 1993-06-14 | Insecticidal compositions |
| GB9312207.5 | 1993-06-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1120303A true CN1120303A (en) | 1996-04-10 |
Family
ID=26302682
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 94191668 Pending CN1120303A (en) | 1993-03-31 | 1994-03-18 | Insecticidal compositions |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0691809A1 (en) |
| JP (1) | JPH08508287A (en) |
| CN (1) | CN1120303A (en) |
| AU (1) | AU6217394A (en) |
| BR (1) | BR9406243A (en) |
| CA (1) | CA2158069A1 (en) |
| CZ (1) | CZ252595A3 (en) |
| HU (1) | HUT72027A (en) |
| WO (1) | WO1994022299A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102246806A (en) * | 2011-04-30 | 2011-11-23 | 江西海科瑞特作物科学有限公司 | Insecticidal composition containing pyriproxyfen and lambda-cyhalothrin |
| CN106259419A (en) * | 2015-05-20 | 2017-01-04 | 江苏扬农化工股份有限公司 | One kills fly compositions and application thereof |
| CN113598163A (en) * | 2021-09-10 | 2021-11-05 | 姜兆伟 | Mosquito-repellent incense liquid for preventing children from eating by mistake and application of bitter essence as raw material |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4677676B2 (en) * | 2001-02-23 | 2011-04-27 | 凸版印刷株式会社 | Food packaging container with pest repellent function |
| EP1504664A1 (en) * | 2003-07-29 | 2005-02-09 | Novartis AG | Organic compounds |
| DE102004001271A1 (en) * | 2004-01-08 | 2005-08-04 | Bayer Cropscience Ag | Drug combinations with insecticidal properties |
| KR100840197B1 (en) | 2007-06-26 | 2008-06-23 | 퀀틴 패트릭 | A materials for mothproof and method of manufacturing the same |
| LU91484B1 (en) * | 2008-10-10 | 2010-04-12 | Jeyes Deutschland Gmbh | Bait |
| CN102883611B (en) * | 2010-05-19 | 2015-01-21 | 住友化学株式会社 | Pest control material |
| EP2446742A1 (en) * | 2010-10-28 | 2012-05-02 | Bayer CropScience AG | Insecticide or acaricide compositions containing mono- or disaccharides as activity enhancers |
| CN101971803B (en) * | 2010-11-03 | 2013-11-20 | 沈阳师范大学 | Dye mixed liquid for killing houseflies |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5428824A (en) * | 1977-08-05 | 1979-03-03 | Nissan Chem Ind Ltd | Insecticidal composition |
| JPS6036403A (en) * | 1983-08-08 | 1985-02-25 | Sumitomo Chem Co Ltd | Mixed insecticidal composition |
| AU576034B2 (en) * | 1984-12-10 | 1988-08-11 | R & C Products Pty Limited | Non-crumbly solid edible insect bait |
| BR8606797A (en) * | 1985-07-18 | 1987-10-13 | Earth Chemical Co | FLY ATTRACTION COMPOSITION |
| JP2771193B2 (en) * | 1988-10-20 | 1998-07-02 | アース製薬株式会社 | Pest poison composition |
| ZA917192B (en) * | 1990-10-23 | 1992-05-27 | Ciba Geigy Proprietary Limited | A pesticidal composition |
| HU9201745D0 (en) * | 1991-06-11 | 1992-08-28 | Sandoz Ag | Ant lure |
-
1994
- 1994-03-18 JP JP6521785A patent/JPH08508287A/en active Pending
- 1994-03-18 HU HU9502718A patent/HUT72027A/en unknown
- 1994-03-18 WO PCT/GB1994/000555 patent/WO1994022299A1/en not_active Application Discontinuation
- 1994-03-18 CZ CZ952525A patent/CZ252595A3/en unknown
- 1994-03-18 CN CN 94191668 patent/CN1120303A/en active Pending
- 1994-03-18 BR BR9406243A patent/BR9406243A/en not_active Application Discontinuation
- 1994-03-18 AU AU62173/94A patent/AU6217394A/en not_active Abandoned
- 1994-03-18 EP EP94909259A patent/EP0691809A1/en not_active Ceased
- 1994-03-18 CA CA 2158069 patent/CA2158069A1/en not_active Abandoned
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102246806A (en) * | 2011-04-30 | 2011-11-23 | 江西海科瑞特作物科学有限公司 | Insecticidal composition containing pyriproxyfen and lambda-cyhalothrin |
| CN106259419A (en) * | 2015-05-20 | 2017-01-04 | 江苏扬农化工股份有限公司 | One kills fly compositions and application thereof |
| CN113598163A (en) * | 2021-09-10 | 2021-11-05 | 姜兆伟 | Mosquito-repellent incense liquid for preventing children from eating by mistake and application of bitter essence as raw material |
Also Published As
| Publication number | Publication date |
|---|---|
| AU6217394A (en) | 1994-10-24 |
| CA2158069A1 (en) | 1994-10-13 |
| BR9406243A (en) | 1996-01-09 |
| JPH08508287A (en) | 1996-09-03 |
| EP0691809A1 (en) | 1996-01-17 |
| HU9502718D0 (en) | 1995-11-28 |
| WO1994022299A1 (en) | 1994-10-13 |
| HUT72027A (en) | 1996-03-28 |
| CZ252595A3 (en) | 1996-01-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |