CA1092969A - Insecticidal composition containing cis-9-tricosene and methomyl - Google Patents
Insecticidal composition containing cis-9-tricosene and methomylInfo
- Publication number
- CA1092969A CA1092969A CA292,007A CA292007A CA1092969A CA 1092969 A CA1092969 A CA 1092969A CA 292007 A CA292007 A CA 292007A CA 1092969 A CA1092969 A CA 1092969A
- Authority
- CA
- Canada
- Prior art keywords
- tricosene
- methomyl
- cis
- composition
- sugar
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/002—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits
- A01N25/006—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits insecticidal
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Food Science & Technology (AREA)
- Toxicology (AREA)
- Insects & Arthropods (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
NOVEL COMPOSITION
Abstract of the Disclosure Novel insecticidal composition for the control of Diptera such as Musca domestica comprising cis-9-tricosene, methomyl, and a carrier substance.
Abstract of the Disclosure Novel insecticidal composition for the control of Diptera such as Musca domestica comprising cis-9-tricosene, methomyl, and a carrier substance.
Description
lO~Z969 This invention is directed to highly effective insecticidal compositions for Diptera, especially Musca domestica.
More particularly,~ this invention relates to a novel composition comprising cis-9-tricosene r methomyl, and a suitable carrier substance, which is unusually effective for combatting Dipteran insects.
Although the art knows that cis-9-tricosene is a sex pheromone of Musca domestica [Carlson et al., Science 17~, 76 (1971~] and has been used in combination with insecticides, as in our Canadian Patent 1,012,058 for the control of Dipteran insects, the superior effectiveness of the compositions of the present invention over prior art compos-itions is unexpected and could not have been predicted.
In the practice of the present invention, cis-9-tricosene is mixed with methomyl together with a suitable carrier substance to prepare the novel compositions of the present invention which are then applied in the usual way for control. One suitable method of preparing the compositions of :.
the present invention is to mix methomyl, with or without sol-
More particularly,~ this invention relates to a novel composition comprising cis-9-tricosene r methomyl, and a suitable carrier substance, which is unusually effective for combatting Dipteran insects.
Although the art knows that cis-9-tricosene is a sex pheromone of Musca domestica [Carlson et al., Science 17~, 76 (1971~] and has been used in combination with insecticides, as in our Canadian Patent 1,012,058 for the control of Dipteran insects, the superior effectiveness of the compositions of the present invention over prior art compos-itions is unexpected and could not have been predicted.
In the practice of the present invention, cis-9-tricosene is mixed with methomyl together with a suitable carrier substance to prepare the novel compositions of the present invention which are then applied in the usual way for control. One suitable method of preparing the compositions of :.
the present invention is to mix methomyl, with or without sol-
2~ vent or diluent, with a suitable carrier substance and then mix -~ the resulting composition with cis-9-tricosene with or without ~; solvent.
- The novel insecticidal compositions of the present inventions can include conventional pest control adjuvants, diluents, modifiers or conditioning agents, herein included in the term "suitable carrier substance", to provide compositions in the form of solutions, emulsions, dispersions, powders, dusts, granules, pellets, and the like. Thus, the insecticidal composi- `~
tions can be liquid or solid. The liquid compositions can contain one or more surface active agents as a conditioning agent to render the composition readily dispersable in water. The term 32 "surface active agents" includes wetting agents, dispersing X `'~
,:~, : ,,, , . : - , , ` `` ~0~2~69 agents, emulsifying agents, and the like. The solid formulations of the present invention in the form of powder, dust, pellets or granules can be prepared using such substances as talc, natural clay, pyrophyllite, diatomaceous earth, walnut shells, corn cobs, sugar and the like.
The amount of active ingredient in the compositions of the present invention will vary according to the manner in which the composition is to be applied but, in general, will be from about 0.25% to 95~ by weight of the total composition. Usually, the amount of active ingredient will be about 0.50% to 10~.
Active ingredient as used herein means cis-9-tricosene and methomyl. The ratio of cis-9-tricosene to methomyl is generally from about 1:50 to 25:1 parts by weight. A sugar granule formu- ~;
lation of 1% methomyl and containing cis-9-tricosene within the ratio of 1:25 to 2:1 of cis-9-tricosene to methomyl provides an increase in effectiveness of a few hundred percent to several hundred percent over the same granule formulation containing other insecticides such as propoxur. A comparison of a sugar granule formulation of methomyl and propoxur in the absence of cis-9-tricosene shows substantially equal effectiveness.
~ Methomyl is the common name for methyl N-[~methyl-`~ carbamoyl)oxy]thioacetamide, described in U.S. Patent 3,576,834.
As described in U.S. Patent 3,576,834, other pesticides can be used in mixture with methomyl. It is important, however, that within the practice of the present invention the ratio-~ of cis-9-tricosene to methomyl remain within the ratios described herein even though other pesticide(s) may be present in the composition.
,'
- The novel insecticidal compositions of the present inventions can include conventional pest control adjuvants, diluents, modifiers or conditioning agents, herein included in the term "suitable carrier substance", to provide compositions in the form of solutions, emulsions, dispersions, powders, dusts, granules, pellets, and the like. Thus, the insecticidal composi- `~
tions can be liquid or solid. The liquid compositions can contain one or more surface active agents as a conditioning agent to render the composition readily dispersable in water. The term 32 "surface active agents" includes wetting agents, dispersing X `'~
,:~, : ,,, , . : - , , ` `` ~0~2~69 agents, emulsifying agents, and the like. The solid formulations of the present invention in the form of powder, dust, pellets or granules can be prepared using such substances as talc, natural clay, pyrophyllite, diatomaceous earth, walnut shells, corn cobs, sugar and the like.
The amount of active ingredient in the compositions of the present invention will vary according to the manner in which the composition is to be applied but, in general, will be from about 0.25% to 95~ by weight of the total composition. Usually, the amount of active ingredient will be about 0.50% to 10~.
Active ingredient as used herein means cis-9-tricosene and methomyl. The ratio of cis-9-tricosene to methomyl is generally from about 1:50 to 25:1 parts by weight. A sugar granule formu- ~;
lation of 1% methomyl and containing cis-9-tricosene within the ratio of 1:25 to 2:1 of cis-9-tricosene to methomyl provides an increase in effectiveness of a few hundred percent to several hundred percent over the same granule formulation containing other insecticides such as propoxur. A comparison of a sugar granule formulation of methomyl and propoxur in the absence of cis-9-tricosene shows substantially equal effectiveness.
~ Methomyl is the common name for methyl N-[~methyl-`~ carbamoyl)oxy]thioacetamide, described in U.S. Patent 3,576,834.
As described in U.S. Patent 3,576,834, other pesticides can be used in mixture with methomyl. It is important, however, that within the practice of the present invention the ratio-~ of cis-9-tricosene to methomyl remain within the ratios described herein even though other pesticide(s) may be present in the composition.
,'
- 3 -, ~ ,, -;
~09Z969 The following examples are provided to illustrate the practice of the present invention and not as a limitation - of the scope thereo. All parts and percentages are by weight.
- ,10 , .; . ' ' IO~Z969 E~AMPLE 1 - The formulations below were prepared by dissolving the active ingredient, methomyl or propoxur, in methylene chloride and blending with fine grain beet sugar of relatively uniform particle size until homogenous. The formulations - containing cis-9-tricosene were prepared by dissolving the cis-9-tricosene in methylene chloride and then thoroughly blending with the formulation of sugar and active ingredient until dry and flowable.
Formulation Parts A) propoxur sugar 10 B) methomyl sugar 10 C) propoxur sugar 10 cis-9-tricosene 0.1 ) methomyl sugar 10 cis-9-tricosene 0.1 Formulations A, B, C and D were tested in a large swine house, using the formulations as a scatter bait. The results are tabulated in Table 1. The superior effectiveness of formulation D, a composition of the present invention, is evident. Trials were ended after 30 minutes. The number of dead flies were counted at 15 minutes and 30 minutes. For convenience, the mean fly count is given as a ratio. In each test, 0.8 grams per four square feet of each formulation was used.
.. . . - - ,-, . . .~ , . . .
3L09Z96~
Table 1 Formulation Mean Fly Count (ratio) A 1.0 B 1.0 C 2.2 - D 4.6 Trials were made using formulations A-D at a large poultry house. The formulations were scattered using 0.8 grams lQ per four square feet. Counts were made after 15 and 25 minutes and the trial terminated.
; Table 2 Mean Fly Count Formulation (ratio) A 2.0 B 1.0 C 6.0 D 14.4 ; .. ' .
At a second site of the large poultry house, formulations C and D were tested using Q.8 grams per four square feet ground area. Two replicates of each test were made and counts were made after 30 minutes.
Table 3 Mean Fly Count Formulation (ratio) C
D 7.3 EXA*~LE 2 Formulation E was prepared using the procedure of Example 1 and containing 1% methomyl and 0.04% cis-9-tricosene 10~296~
with fine granule sugar as the carrier. Formulations B, D
and E were tested using equal quantities of each in a scatter test at an egg ranch. The tests were terminated after 4 hours.
Table 4 Mean Fly Count Formulation (ratio?
B 1.0 D 7.5 E 4.6 Formulations utilizing diatomaceous earth of about 8 mesh or less particle size, methomyl and cis-9-tricosene are prepared as-in Examples 1 and 2. The formulations are useful for Musca domestica control around stockyards, patios, chicken houses, etc., by scattering.
~09Z969 The following examples are provided to illustrate the practice of the present invention and not as a limitation - of the scope thereo. All parts and percentages are by weight.
- ,10 , .; . ' ' IO~Z969 E~AMPLE 1 - The formulations below were prepared by dissolving the active ingredient, methomyl or propoxur, in methylene chloride and blending with fine grain beet sugar of relatively uniform particle size until homogenous. The formulations - containing cis-9-tricosene were prepared by dissolving the cis-9-tricosene in methylene chloride and then thoroughly blending with the formulation of sugar and active ingredient until dry and flowable.
Formulation Parts A) propoxur sugar 10 B) methomyl sugar 10 C) propoxur sugar 10 cis-9-tricosene 0.1 ) methomyl sugar 10 cis-9-tricosene 0.1 Formulations A, B, C and D were tested in a large swine house, using the formulations as a scatter bait. The results are tabulated in Table 1. The superior effectiveness of formulation D, a composition of the present invention, is evident. Trials were ended after 30 minutes. The number of dead flies were counted at 15 minutes and 30 minutes. For convenience, the mean fly count is given as a ratio. In each test, 0.8 grams per four square feet of each formulation was used.
.. . . - - ,-, . . .~ , . . .
3L09Z96~
Table 1 Formulation Mean Fly Count (ratio) A 1.0 B 1.0 C 2.2 - D 4.6 Trials were made using formulations A-D at a large poultry house. The formulations were scattered using 0.8 grams lQ per four square feet. Counts were made after 15 and 25 minutes and the trial terminated.
; Table 2 Mean Fly Count Formulation (ratio) A 2.0 B 1.0 C 6.0 D 14.4 ; .. ' .
At a second site of the large poultry house, formulations C and D were tested using Q.8 grams per four square feet ground area. Two replicates of each test were made and counts were made after 30 minutes.
Table 3 Mean Fly Count Formulation (ratio) C
D 7.3 EXA*~LE 2 Formulation E was prepared using the procedure of Example 1 and containing 1% methomyl and 0.04% cis-9-tricosene 10~296~
with fine granule sugar as the carrier. Formulations B, D
and E were tested using equal quantities of each in a scatter test at an egg ranch. The tests were terminated after 4 hours.
Table 4 Mean Fly Count Formulation (ratio?
B 1.0 D 7.5 E 4.6 Formulations utilizing diatomaceous earth of about 8 mesh or less particle size, methomyl and cis-9-tricosene are prepared as-in Examples 1 and 2. The formulations are useful for Musca domestica control around stockyards, patios, chicken houses, etc., by scattering.
Claims (9)
1. An insecticidal composition comprising a mixture of cis-9-tricosene, methomyl and a suitable carrier substance, wherein the ratio of cis-9-tricosene and methomyl is from about 1:50 to 25:1.
2. A composition according to Claim 1 wherein said carrier substance is sugar.
3. A composition according to Claim 2 wherein said mixture contains cis-9-tricosene and methomyl in the total amount of from 0.25% to 95%, by weight, of the composition.
4. A composition according to Claim 3 wherein said ratio is from about 1:25 to 2:1.
5. A composition according to Claim 1, 2 or 4 wherein the total amount of cis-9-tricosene and methomyl is from about 0.50% to 10%.
6. A composition-according to Claim 3 wherein the sugar is granulated sugar, and wherein the total amount of cis-9-tricosene and methomyl is from about 0.50% to 10%.
7. A method of destroying Diptera insects which comprises applying to the locus to be protected a mixture containing cis-9-tricosene, methomyl and a suitable carrier substance, wherein the ratio of cis-9-tricosene and methomyl is from about 1:50 to 25:1.
8. The method according to Claim 7 wherein the carrier substance is granulated sugar.
9. The method according to claim 7 or 8 wherein said mixture contains cis-9-tricosene and methomyl in the total amount of from 0.25% to 95%, by weight, of the composition.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/833,402 US4122165A (en) | 1977-09-15 | 1977-09-15 | Insecticidal composition containing cis-9-tricosene and methomyl |
| US833,402 | 1977-09-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1092969A true CA1092969A (en) | 1981-01-06 |
Family
ID=25264315
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA292,007A Expired CA1092969A (en) | 1977-09-15 | 1977-11-29 | Insecticidal composition containing cis-9-tricosene and methomyl |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US4122165A (en) |
| JP (1) | JPS5444020A (en) |
| AR (1) | AR218662A1 (en) |
| AU (1) | AU506197B1 (en) |
| BE (1) | BE870517A (en) |
| BR (1) | BR7804447A (en) |
| CA (1) | CA1092969A (en) |
| CH (1) | CH638373A5 (en) |
| DE (1) | DE2816275A1 (en) |
| ES (1) | ES471642A1 (en) |
| FR (1) | FR2403026A1 (en) |
| GB (1) | GB1575169A (en) |
| GR (1) | GR66166B (en) |
| IL (1) | IL54978A (en) |
| IT (1) | IT1158696B (en) |
| NL (1) | NL7807669A (en) |
| NZ (1) | NZ187354A (en) |
| TR (1) | TR20232A (en) |
| ZA (1) | ZA783237B (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5141744A (en) * | 1974-10-08 | 1976-04-08 | Ishikawa Takashi | Taika tainetsuseigoseijushi |
| LU78277A1 (en) * | 1977-10-10 | 1979-06-01 | Airwick Ag | ATTRACTIVE BATS FOR USE IN THE CONTROL OF SYNANTHROPIC FLIES |
| US4692468A (en) * | 1980-08-01 | 1987-09-08 | Eli Lilly And Company | Control of colonial insects employing o-phenylenediamines |
| NZ215991A (en) * | 1985-05-01 | 1988-10-28 | Johnson & Son Inc S C | Method of controlling wasps |
| US4851218A (en) * | 1985-05-01 | 1989-07-25 | S. C. Johnson & Son, Inc. | Method for controlling insects of the family vespidae utilizing interspecific insecticidal bait |
| US4775534A (en) * | 1986-02-05 | 1988-10-04 | Fermone Chemicals, Inc. | Miticidal composition and method for controlling spider mite populations |
| JPH01106801A (en) * | 1987-10-19 | 1989-04-24 | H Edward Lowe | Agricultural granule and manufacture |
| US5008107A (en) * | 1990-01-31 | 1991-04-16 | Farnam Companies, Inc. | Attractant composition for synanthropic flies |
| IL113447A (en) * | 1994-04-22 | 1999-01-26 | Us Agriculture | Attractant for controlling insects and apparatus containing the same |
| US5766617A (en) * | 1996-08-23 | 1998-06-16 | The United States Of America As Represented By The Secretary Of Agriculture | Trapping system for mediterranean fruit flies |
| GB2370775A (en) * | 2001-01-04 | 2002-07-10 | Nimrod Israely | Insecticidal composition based on attractant, insecticide and stabilizer, the outer surface of which expands & loses viscosity on contact with humidity |
| EP1504664A1 (en) * | 2003-07-29 | 2005-02-09 | Novartis AG | Organic compounds |
| JP5656286B2 (en) * | 2009-12-28 | 2015-01-21 | 住友化学株式会社 | Fly attractant and method for attracting and controlling flies |
| BE1024239B1 (en) * | 2016-05-30 | 2018-01-09 | Globachem Nv | USE OF 9-TRICOSEEN TO COMBAT DROSOPHILA SUZUKII (SUZUKI'S FRUIT FLY) |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3824320A (en) * | 1967-08-31 | 1974-07-16 | Du Pont | Substituted o-carbamylhydroxamate insecticides |
| US3576834A (en) * | 1967-08-31 | 1971-04-27 | Du Pont | Substituted o-carbamylhydroxamates |
| DE2357799A1 (en) * | 1972-11-27 | 1974-06-06 | Thuron Industries | INSECTICIDAL PREPARATIONS |
-
1977
- 1977-09-15 US US05/833,402 patent/US4122165A/en not_active Expired - Lifetime
- 1977-11-29 CA CA292,007A patent/CA1092969A/en not_active Expired
-
1978
- 1978-03-29 GB GB12303/78A patent/GB1575169A/en not_active Expired
- 1978-04-14 DE DE19782816275 patent/DE2816275A1/en not_active Ceased
- 1978-04-18 AR AR271817A patent/AR218662A1/en active
- 1978-04-27 IT IT7822778A patent/IT1158696B/en active
- 1978-05-23 FR FR7815288A patent/FR2403026A1/en active Granted
- 1978-05-24 NZ NZ187354A patent/NZ187354A/en unknown
- 1978-06-06 ZA ZA00783237A patent/ZA783237B/en unknown
- 1978-06-22 IL IL54978A patent/IL54978A/en unknown
- 1978-07-04 CH CH728478A patent/CH638373A5/en not_active IP Right Cessation
- 1978-07-07 BR BR7804447A patent/BR7804447A/en unknown
- 1978-07-12 ES ES471642A patent/ES471642A1/en not_active Expired
- 1978-07-18 JP JP8765278A patent/JPS5444020A/en active Granted
- 1978-07-18 NL NL7807669A patent/NL7807669A/en not_active Application Discontinuation
- 1978-07-20 AU AU38217/78A patent/AU506197B1/en not_active Expired
- 1978-08-04 TR TR20232A patent/TR20232A/en unknown
- 1978-08-20 GR GR57095A patent/GR66166B/el unknown
- 1978-09-15 BE BE190515A patent/BE870517A/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| IT1158696B (en) | 1987-02-25 |
| JPS6242881B2 (en) | 1987-09-10 |
| IL54978A (en) | 1981-10-30 |
| TR20232A (en) | 1980-11-07 |
| FR2403026B1 (en) | 1983-02-18 |
| FR2403026A1 (en) | 1979-04-13 |
| AU506197B1 (en) | 1979-12-13 |
| NZ187354A (en) | 1980-03-05 |
| GB1575169A (en) | 1980-09-17 |
| GR66166B (en) | 1981-01-20 |
| BR7804447A (en) | 1979-04-10 |
| ZA783237B (en) | 1979-09-26 |
| CH638373A5 (en) | 1983-09-30 |
| BE870517A (en) | 1979-03-15 |
| IL54978A0 (en) | 1978-08-31 |
| US4122165A (en) | 1978-10-24 |
| JPS5444020A (en) | 1979-04-07 |
| IT7822778A0 (en) | 1978-04-27 |
| AR218662A1 (en) | 1980-06-30 |
| NL7807669A (en) | 1979-03-19 |
| ES471642A1 (en) | 1979-02-01 |
| DE2816275A1 (en) | 1979-03-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |