CN111655609A - 一种燃料化学链制氢系统和方法 - Google Patents

一种燃料化学链制氢系统和方法 Download PDF

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CN111655609A
CN111655609A CN201980007075.3A CN201980007075A CN111655609A CN 111655609 A CN111655609 A CN 111655609A CN 201980007075 A CN201980007075 A CN 201980007075A CN 111655609 A CN111655609 A CN 111655609A
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heat exchanger
fuel
chemical looping
hydrogen
oxygen carrier
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CN111655609B (zh
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苏庆泉
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Beijing Lianliyuan Technology Co Ltd
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    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
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    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
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    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/066—Integration with other chemical processes with fuel cells
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    • C01B2203/1041—Composition of the catalyst
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Abstract

提供一种燃料化学链制氢系统和方法，该系统包括两个完全相同的化学链燃烧反应器(10，20)，该反应器包括外管(11)和内管(12)，内管充填有第一载氧体(13)，内外之间的夹层充填有第二载氧体或催化燃烧催化剂(14)；内管上端连接有水蒸气导入管道(41)和燃料导入管道(42)，内管下端连接有气体导出管道，气体导出管道通过第3三通阀(53)与氢气导出管道(43)和还原反应产物气体连通管道(44)连接，还原反应产物气体连通管道的另一端与夹层下端连接；夹层上端连接有燃烧烟气的导出管道(46)，夹层下端连接有助燃空气导入管道(45)；两个反应器的水蒸气导入管道通过第1三通阀(51)相连接，燃料导入管道通过第2三通阀(52)相连接，助燃空气导入管道通过第5三通阀(55)相连接。当第一反应器(10)进行氧化反应时，第二反应器(20)进行还原反应。该系统简单、反应器紧凑且易于小型化，可高效率地从气态或者液态燃料制取。

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PCT国内申请，说明书已公开。

Claims (20)

  1. PCT国内申请，权利要求书已公开。
CN201980007075.3A 2018-02-24 2019-02-22 一种燃料化学链制氢系统和方法 Active CN111655609B (zh)

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PCT/CN2019/075792 WO2019161776A1 (zh) 2018-02-24 2019-02-22 一种燃料化学链制氢系统和方法

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114314509A (zh) * 2021-11-30 2022-04-12 西安交通大学 一种液态化学链气化/重整制备富氢合成气系统与工艺

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110803680B (zh) * 2019-12-16 2024-02-20 广东工业大学 一种循环回收反应副产物的化学链重整制氢的装置
CN110980644B (zh) * 2019-12-31 2021-10-22 中国科学院工程热物理研究所 水基化学链循环制氢系统及方法
CN112142491B (zh) * 2020-09-18 2022-02-22 西安交通大学 化学链制氢的整体式载氧体、制备方法、制氢系统和方法
CN214734510U (zh) * 2020-12-10 2021-11-16 广东醇氢新能源研究院有限公司 一种制氢系统
CN112803039A (zh) * 2020-12-30 2021-05-14 国网综合能源服务集团有限公司 一种热电联供装置及方法
CN113457444B (zh) * 2021-07-19 2023-02-28 重庆朗福环保科技有限公司 一种一氧化碳脱除系统
CN114477086B (zh) * 2022-01-27 2024-04-16 北京联力源科技有限公司 甲醇水蒸气重整制氢装置及其启动方法
CN114988362A (zh) * 2022-05-27 2022-09-02 东北电力大学 化学链制氢耦合燃料电池碳捕集制取甲酸系统及其方法
CN115111629A (zh) * 2022-06-10 2022-09-27 北京市燃气集团有限责任公司 一种零碳供热方法
CN115143510A (zh) * 2022-06-10 2022-10-04 北京市燃气集团有限责任公司 一种零碳供热系统
CN115386399A (zh) * 2022-08-29 2022-11-25 东南大学 一种基于生物质的连续制氢气装置及方法
CN115430288B (zh) * 2022-10-11 2023-12-22 太原理工大学 一种电厂烟气化学链脱氧方法
CN115535963A (zh) * 2022-10-11 2022-12-30 山东理工大学 一种生物质化学链循环制氢系统

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103113917A (zh) * 2013-02-18 2013-05-22 上海锅炉厂有限公司 一种固体燃料化学链气化制氢系统与方法
CN103552983A (zh) * 2013-10-25 2014-02-05 西南石油大学 一种CaO引导的甲烷蒸汽重整化学链燃烧制氢工艺
US9004911B1 (en) * 2012-11-29 2015-04-14 U.S. Department Of Energy Apparatus and method for solid fuel chemical looping combustion
CN105600747A (zh) * 2016-03-08 2016-05-25 东南大学 一种基于金属载氧体的化学链制氢装置及方法
CN106784936A (zh) * 2016-11-30 2017-05-31 宁波瑞翔新材料技术有限公司 一种基于化学链燃烧的氢气储能、热电联产及co2捕获的系统及方法
CN107539949A (zh) * 2016-06-23 2018-01-05 中国石油化工股份有限公司 一种化学链制氢的工艺装置和工艺方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101439844A (zh) * 2008-12-16 2009-05-27 中国科学院广州能源研究所 一种化学链耦合催化重整制氢的方法和装置
WO2011062728A1 (en) * 2009-11-19 2011-05-26 Conocophillips Company Liquid-phase chemical looping energy generator
CN202382432U (zh) * 2011-12-05 2012-08-15 北京科技大学 化学链燃烧系统
CN102865669B (zh) * 2012-10-15 2014-11-12 上海锅炉厂有限公司 一种切换式化学链燃烧装置和方法
CN106276794B (zh) * 2015-06-26 2019-03-08 韩国能量技术研究院 制氢反应器
CN105435599B (zh) * 2015-12-16 2018-12-25 北京科技大学 一种污染气体的处理系统及处理方法
CN107355766A (zh) * 2017-06-07 2017-11-17 北京市燃气集团有限责任公司 基于燃气锅炉的供能系统及方法
CN107804824B (zh) * 2017-11-09 2020-03-31 东南大学 一种复合型钙铁载氧体及其化学链制氢协同co2捕集方法
CN208700566U (zh) * 2018-02-24 2019-04-05 北京联力源科技有限公司 一种燃料化学链制氢系统

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9004911B1 (en) * 2012-11-29 2015-04-14 U.S. Department Of Energy Apparatus and method for solid fuel chemical looping combustion
CN103113917A (zh) * 2013-02-18 2013-05-22 上海锅炉厂有限公司 一种固体燃料化学链气化制氢系统与方法
CN103552983A (zh) * 2013-10-25 2014-02-05 西南石油大学 一种CaO引导的甲烷蒸汽重整化学链燃烧制氢工艺
CN105600747A (zh) * 2016-03-08 2016-05-25 东南大学 一种基于金属载氧体的化学链制氢装置及方法
CN107539949A (zh) * 2016-06-23 2018-01-05 中国石油化工股份有限公司 一种化学链制氢的工艺装置和工艺方法
CN106784936A (zh) * 2016-11-30 2017-05-31 宁波瑞翔新材料技术有限公司 一种基于化学链燃烧的氢气储能、热电联产及co2捕获的系统及方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114314509A (zh) * 2021-11-30 2022-04-12 西安交通大学 一种液态化学链气化/重整制备富氢合成气系统与工艺

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