CN1116045A - Medicinal fluid composition for trees - Google Patents
Medicinal fluid composition for trees Download PDFInfo
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- CN1116045A CN1116045A CN94107975A CN94107975A CN1116045A CN 1116045 A CN1116045 A CN 1116045A CN 94107975 A CN94107975 A CN 94107975A CN 94107975 A CN94107975 A CN 94107975A CN 1116045 A CN1116045 A CN 1116045A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G7/00—Botany in general
- A01G7/06—Treatment of growing trees or plants, e.g. for preventing decay of wood, for tingeing flowers or wood, for prolonging the life of plants
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing within the same carbon skeleton a carboxylic group or a thio analogue, or a derivative thereof, and a carbon atom having only two bonds to hetero atoms with at the most one bond to halogen, e.g. keto-carboxylic acids
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
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- A—HUMAN NECESSITIES
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
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- A01N63/50—Isolated enzymes; Isolated proteins
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- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
- C05F11/10—Fertilisers containing plant vitamins or hormones
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- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
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Abstract
The invented composite is mainly composed of stoma closed-open agent, foreign substance remover and solvent, the pH value range is 4.5-8. When said drug is injected into the tree by liquid composite, it can control the close-open of the stoma of the leaves, thus it can prevent the harm caused by particles of pollution substances and can induce the particles of pollution substance to be expelled from the tree.
Description
The present invention relates to a pharmaceutical composition for trees, and more particularly, to a composition for protecting trees from a pollution source such as acid rain, thereby accelerating the growth of trees.
At present, the industry has developed atmospheric pollutants such as sulfur trioxide (SO)3) Nitrogen dioxide (NO)2) Ozone (O)3) Carbon dioxide (CO)2) Diene (CH)2＝CH2) And methane (CH)4) Exceeding the allowable standards. As a result, crops and plants are being severely damaged. In addition, the exhaust gas emitted from automobiles is increasing continuously. Thus, the global impact of these pollutants is drying out trees from place to place. Such contaminants also induce bronchitis and dermatitis in humans, and in particular rain and snow are acidified by the above contaminants, causing an increasing hazard.
The factors that generate these contaminants and form acid rain are detailed below.
1) The release of carbon dioxide gas is associated with the consumption of domestic fuel, the operation of plants and the respiration of animals and plants. The concentration of carbon dioxide gas in the atmosphere is known to increase at a rate of about 10% per year. Carbon dioxide and atmospheric water vapor contribute to the greenhouse effect of the earth, so if carbon dioxide continues to increase at the present rate, it can be expected that the annual average temperature of the earth will increase by about 1.5-4.5 ℃ by 2050. Here, trees play an important role in absorbing carbon dioxide gas.
2) By combustion of sulfur-containing fuels, sulphidationHydrogen and sulfur-containing compounds are released into the atmosphere from smelters and refineries. The exhaust gases generally move along the air flow and are thus acidified in the air to sulphur dioxide (SO)2) Or sulfur trioxide (SO)3) Subsequently absorbed by water vapor, with the result thatThey then fall to the ground as rain and snow.
The above mechanism is described below in connection with an example of combustion of sulfur in fossil fuels.
By burning, some sulfur dioxide (about 1% SO)2) In a flame, SO that sulfur trioxide (SO) is formed therein3)。
The sulfur trioxide then reacts very rapidly with atmospheric moisture, with the result that sulfuric acid (H) is formed2SO4)。
The vapor pressure of sulfuric acid is so low that it vaporizes at a high rate to form sulfuric acid moisture, which is a factor in the formation of acid rain or acid mist.
In addition, when organic substances are decomposed by bacteria in the naturally moist soil to generate hydrogen sulfide (H)2S), acid rain may also form. And sulfur dioxide (SO) emitted from volcanoes2) And hydrogen sulfide may also be transferred to the air.
3) When nitrogen-containing compounds are combusted, nitrogen monoxide (NO) and nitrogen dioxide (NO) are generated2). These two nitrogen-containing compounds, generally denoted as NOx, can be divided into two classes: thermal NOx is generated when nitrogen reacts with oxygen at high temperatures, and fuel NOx is generated when nitrogen-containing compounds, such as nitrile compounds, pyridine, and quinoline, originally contained in fuel, are oxidized.
4) It is estimated that more than about 1200 million tons of hydrocarbon gases such as ethylene and methane are released worldwide each year. Generally, the source of pollution is due to incomplete combustion of the product and unburned compounds, which are acidified in air to form organic acids such as formic acid. In addition, methane is also produced in moist soils and in pits, alkenes are produced in conifers, which are acidified in the air and are also factors in the formation of acid rain.
5) Also, hydrogen chloride and chlorine are present in the air. When coal, petroleum and plastic wastes are burned, chlorine contained therein is converted into hydrochloric acid to be discharged, which is another factor causing acid rain.
Due to these pollution sources, the number of areas affected by acid rain is increasing, and the acidity of rain is higher in large cities. It was observed that the pH of rain was about 4.18. So its acidity is much higher than that of normal raindrops (the pH of normal raindrops is about 5.6).
When rainwater of high acidity is absorbed through the leaves, the portions close to the stomata and its hairs are dried up, thus causing the leaves to die. Before the leaf dies, the epicuticular wax covering the outer coating of the leaf is said to be attacked. In a clean environment, the amount of wax is constant, but wax soaked in rain of high acidity is eroded. Raindrops fall rapidly from the leaves with thick wax, while they stay longer on the parts of the leaves with thin wax and on the hair. Trees are easily damaged due to the enlargement of the damaged area in this part.
The trees damaged by various pollutants, particularly the trees damaged by acid rain, have different influences according to the types of the trees, but the common influence is that the self-purification capacity of the trees to air pollution is weakened, and the trees are dehydrated and die within 1-3 years. In particular, because air pollutants move with the air flow, damage to trees in hilly areas is more severe in depressions. Also, in the case of trees on both sides of a highway, heavy metals in dust of gas discharged from automobiles particularly hinder photosynthesis. Contaminants often infiltrate the trees through the pores of the leaves, and when the contaminants remain inside the screens and water pipes of the trees, the supply of various nutrients and water is blocked and the trees near the center of the growth wheel begin to decay. Thus, as the upper portion dries up a bit, the entire tree begins to dry up and dies.
It is well known that such contaminants are absorbed into the interior of the tree through the pores of the leaves. According to various experiments, the rate of stomata opening decreased when the leaves were treated with sulfur dioxide, and the stomata closed when the leaves were treated with ozone and chloride gas.
Also, acid rain can separate cations from the soil. The surface charge of natural soil is negative, so that various cations are bonded to the surface of soil, and the bonded cations are bound by H in acid rain+And (4) substitution. As a result, the soil is wasted and nutrients useful for trees are consumed.
In view of the foregoing, there is a need for a method of protecting trees that are generally known to purify contaminated air from drying out due to excessive contamination.
The object of the present invention is to provide a medicinal liquid composition for trees, which can protect trees from air pollutants, particularly acid rain, thereby accelerating the growth of trees.
In order to achieve the purpose, the liquid composition for the tree medicine mainly comprises an air hole opening and closing agent, an external substance removing agent and a solvent, wherein the pH value of the composition is in a range of 4.5-8.
As the stomatal shutter, at least one selected from the group consisting of antimitomyces (e.g., rhiptobiotine, ancymidol, chloroconazole, and uniconazole), kinetin, defoliating acid (ABA), 3, 5-dihydroxy-3-methylvaleric acid, xanthosine, benomyl, aminoxyacetic acid (AOA), sesamozole, ascorbic acid, and D-erythorbic acid is desirably used. It is considered that when the above-mentioned air hole shutter is injected into trees depending on the concentration of an air pollution source, particularly depending on the presence or absence of acid rain, the opening and closing of the air holes are remarkably controlled. Thus, the source of contamination is prevented from being absorbed into the tree. That is, when a source of contamination is present in the air, the air holes are closed, thereby preventing the source of contamination from being absorbed into the tree. When there is no source of contamination in the air, the air vent is opened.
As for the foreign substance removing agent mentioned above, it is also desirable to use, which makes trees not damaged by the generation of ethylene gas and sulfide gas, at least one selected from the group consisting of cobalt chloride, nickel chloride, silver nitrate, sodium lauryl sulfate, superoxide dismutase (SOD), Ethylene Diurea (EDU), 8-hydroxyquinoline, germanium compound, Peroxidase (POD) and thiosulfate. The foreign substance remover serves to release foreign substances such as heavy metals accumulated in the tree through pores outside the tree. It was observed that the medicinal compound released yellow liquid-like foreign substances through the pores after injection into the trees.
As the solvent for the present pharmaceutical liquid composition, alcohols are generally used. Here, water or an alkali solution, such as a potassium hydroxide solution or a sodium hydroxide solution, can also be used. In particular, when a precipitate is formed in the composition, a small amount of an alkaline compound such as sodium hydroxide or potassium hydroxide may be added to dissolve the precipitate.
It is desirable to add as little solvent as possible, provided that it is sufficient to solubilize each of the components of the composition. However, there is no particular limitation thereto. It is preferred that the concentration of the composition should be as high as possible, since in this case it is easy to inject a small amount of the composition. However, if the concentration of the composition is low, the injection amount is large, so the time required to inject these solutions into trees becomes long, and a suitable injection tool should be selected. In either case, the effect of the pharmaceutical liquid composition on the trees is not altered by changes in the concentration of the pharmaceutical composition contained in the infusion solution. Also, the content and mixing ratio of each component in the pharmaceutical liquid composition vary depending on the size of trees and contamination conditions, and thus are not particularly limited. According to the observation of the present inventors, the detectable effect of each component can be maintained for a longer period of time as the amount of each component injected into the tree increases.
It is desirable to control the pH of the arborescent liquid pharmaceutical composition to about 5.5. And it is desirable to adjust the pH with citric acid.
In addition, in order to accelerate the growth of trees, it is desirable to include various nutrients, such as potassium-containing compounds, calcium-containing compounds, phosphoric acid compounds, ethylenediaminetetraacetic acid (EDTA), boric acid compounds, and sulfuric acid compounds, in the pharmaceutical liquid composition in order to promote the growth of trees, which are generally absorbed from soil.
The above medicinal liquid composition for tree is injected by conventional method. The composition can be easily injected into the water of trees using a medical liquid injector for injection into the water of trees corresponding to korean patent No. 90-6840 (filed on 14.5.1990 by the present applicant). In particular, when a high concentration of the pharmaceutical liquid composition is used, it is preferable to use such a syringe as described above.
The inventors of the present invention have found, through repeated experiments and observations, that the pharmaceutical liquid composition described below has excellent effects on various trees. As described above, the content ratio of the respective compounds can be controlled in a variety of ways. This ratio is set forth in the disclosure of the preferred embodiment for convenience, but is not intended to be limiting.
That is, it has been found through experimentation that many compositions have excellent medicinal effects on trees. These compositions are liquid pharmaceutical compositions comprising: 100-500 parts of potassium nitrate, 0.01-1 part of rhippobitoxine and 1.0 multiplied by 10-6～4.0×10-3Parts by weight of lauryl sulfate as the main component excluding the solvent. 1 to 10 parts by weight of kinetin and 1.0X 103～1.0×105Cobalt chloride and 5-50 parts by weight of ascorbic acid are used as main components except the solvent; 10-15500 parts by weight of defoliating acid (ABA), 100-800 parts by weight of ascorbic acid and 1.25 multiplied by 104～1.25×105Parts by weight of glycoluril and 10000-30000 units of superoxide dismutase are used as main components except a solvent; 10-500 parts by weight of ancymidol, 10-100 parts by weight of silver nitrate, 100-400 parts by weight of sodium thiosulfate and a small amount of a nonionic active agent 20 as main components except a solvent; 10 x 103～5.0×105Parts by weight of chlorobutyl azole, 10-50 parts by weight of peroxidase and 500-100 parts by weight of superoxide dismutase as main components except a solvent; 0.5 to 10 parts by weight of benomyl and 10 to 100 parts by weight of chlorineNickel oxide, 10-50 parts by weight of peroxidase and 500-1000 parts by weight of superoxide dismutase are used as main components except a solvent; 0.1 to 100 parts by weight of uniconazole compound, 50 to 500 parts by weight of D-isoascorbic acid and 50 to 500 parts by weight of cobalt chloride as main components except for the solvent, and 1 to 100 parts by weight of calcium nitrate, 1 to 100 parts by weight of thiosulfate, 1 to 100 parts by weight of potassium nitrate and 1 to 100 parts by weight of 3.5-dihydroxy-3-methylvaleric acid as main components except for the solvent; 5 to 500 parts by weight of thiabendazole and 10400 parts by weight of 8-hydroxyquinoline as a main component other than the solvent; and 1 to 500 parts by weight of aminoxyacetic acid (AOA), 10 to 500 parts by weight of 3, 5-dihydroxy-3-methylpentanoic acid and a small amount of cyclohexylimine as main components excluding a solvent.
The pharmaceutical liquid composition of the present invention and the process for producing the same are described in more detail below with reference to examples.
Example 1
Will be 1 × 10-4Kripipopibidoxine (molecular weight 190.2), 288 mg sodium dodecyl sulfate (C)12H25O4SNa, molecular weight 288.4) was dissolved in the minimum amount of ethanol required to dissolve the above components, and 315 mg potassium nitrate (KNO)3Molecular weight 101.1) dissolved in 1 liter of water. rhiptobiotoxin is an anti-gibberellin (anti-GA) which acts to control the opening and closing of stomata, sodium lauryl sulfate is used to remove foreign substances such as cadmium and lead from trees, and potassium nitrate is known to strengthen roots and stomata of trees. The two solutions were then mixed and diluted and citric acid was added thereto to adjust the pH of the composition to 5.5 to prepare the arborescent pharmaceutical composition of the present invention.
Example 2
Mixing 5 mg kinetin (C)15H17N5O5Molecular weight 347.3), a cytokinin, was dissolved in 1 liter of water, and 50 g of cobalt chloride (CoCl) was added2Molecular weight of 237.9) and a small amount of vitamin C (i.e., L-ascorbic acid) associated with stomatal opening and closing, were mixed with stearate, and then pH thereof was controlled to a weak acid range to prepare the arborescent medicinal liquid composition of the present invention. Here, vitamin C is very muchIs easily decomposed by water and light, so that it must be prepared in high concentration and injected into trees in a short time.
Example 3
100 mg of defoliated acid (ABA, molecular weight 264.3) were dissolved in 250 ml of distilled water, and 500 mg of ascorbic acid were dissolved in 250 mg of distilled water. 15000 units of superoxide dismutase to accelerate the rate of absorption of the pharmaceutical composition, 2.5 grams of Ethylenediamine (EDU) to protect the tree from ethylene and sulfide gases, and 0.2% of a non-ionic active agent 20 (i.e., polyethylene (20) sorbitan monolaurate). The pH of the compound was controlled to 5.5 by adding citric acid to prepare the arborescent liquid pharmaceutical composition of the present invention. Ozone gas-resistant trees contain a large amount of ABA as described above. (ABA is a strong hormone). Here, the ozone-resistant tree is a tree in which ABA increases more rapidly in the tree when pollutant particles become more abundant.
Example 4
64.1 g of ancymidol (an anti-gibberellin with a molecular weight of 256.3) was dissolved in ethanol, 39.5 g of silver nitrate with a molecular weight of 153.89 was dissolved in distilled water, and 316 g of sodium thiosulfate (Na) for removing foreign substances in the presence of silver nitrate was added2S2O3Molecular weight 158.13) was dissolved in 250 ml of distilled water. The above solutions were then mixed and 0.2% of the non-ionic active agent 20 was added to the mixture. The pH of the compound is controlled with citric acid to prepare the arborescent liquid pharmaceutical composition of the present invention.
Example 5
74 g of chlorobutyl azole (C)15H20ClN3O, molecular weight of 293.50, manufactured by c.i.c. company, uk) was dissolved in 250 ml of distilled water as an anti-gibberellin, and 25 mg of an unactivated peroxidase (POD, manufactured by SIGMA company) and 750 units of superoxide dismutase (SOD, manufactured by SIGMA company) were dissolved in 250 ml of distilled water. The two solutions are mixed and the PH of the composition is then controlled to prepare the arborescent liquid composition of the present invention.
Example 6
2.56 g benomyl (C)14H18N4O3Methyl-1- (butylcarbamoyl) -2-benzimidazolecarbamate, having a molecular weight of 290.32, a fungicide) is usedIn ethanol diluted with 250 ml of distilled water, 32 g of nickel chloride (NiCl) are then added2Molecular weight 129.61) was added to the solution. The peroxidase and the same amount of superoxide dismutase as in example 5 were then dissolved in 250 ml of distilled water. The above solutions were then mixed to prepare a liquid pharmaceutical composition for trees of the present invention.
Example 7
4 grams of uniconazole (which is an anti-gibberellin), 100 grams of D-erythorbic acid (as a vitamin C source), and 50 grams of cobalt chloride were dissolved in ethanol. The PH of the composition was then controlled to 5.5 to prepare a arborescent liquid pharmaceutical composition of the present invention.
Example 8
100 g of D-erythorbic acid, 5 g of carboxyethylgermanium 32 oxide, 100 g of potassium nitrate known for strengthening flowers and fruits, 200 g of dipotassium hydrogen phosphate and 75 g of glycine (a decomposition inhibitor) were dissolved in ethanol. Sodium citrate and 50 grams of cobalt chloride were then added to the solution and mixed to provide the pharmaceutical liquid composition of the present invention.
Example 9
50 g of 3, 5-dicarboxy-3-methylpentanoic acid, 36 g of thiosulfate, 36 g of potassium nitrate and 24 g of calcium nitrate were added to the alcoholic solution. Then, the above solution was mixed with an aqueous sodium hydroxide solution.
Example 10
100 g of thiabendazole (C)10H7N3S, molecular weight 201.2, manufactured by SIGMA company, an ethylene inhibitor) and 70 g of 8-hydroxyquinoline were dissolved in ethanol. The PH of the composition was controlled to 5.5 to prepare the arborescent pharmaceutical solution composition of the present invention.
Example 11
100.3 g of aminooxyacetic acid (AOA), 130.1 g of 3, 5-dihydroxy-3-Methylpentanoic acid (or 8-hydroxy 10- (3-dimethylaminopropyl) phenothiazine (C)18H22N2OS)) and 2ppm of cyclohexylimine were dissolved in ethanol.Citric acid is used to control the pH of the composition.
In order to determine the effect of the pharmaceutical liquid compositions of the present invention prepared in the above examples, the pharmaceutical liquid compositions prepared in each example were filled in a syringe, injected into trees of the size and number shown in Table 1, and then the results of the experiment were observed.
TABLE 1
| Tree species | Tree size | Number of trees | ||
| Height of (Rice) | Width of branch (Rice) | Diameter of (cm) | ||
| Pine tree | 5.6 | 4.2 | 20 | 3,600 |
| Zelkova serrata | 6.5 | 5.5 | 25 | 800 |
| Maple tree | 3.5 | 2.6 | 10 | 500 |
| European willow | 12 | 6 | 30 | 300 |
| Oak tree | 8.5 | 4.8 | 30 | 50 |
| 4.2 | 2.5 | 10 | 300 | |
| Hornbeam | 6.0 | 4.0 | 15 | 60 |
| Quercus mongolica (L.) Merr | 4.5 | 3.2 | 10 | 25 |
| Quercus trees | 4.5 | 3.2 | 10 | 25 |
| Sophora japonica | 7.0 | 2.8 | 12 | 20 |
| Sugar machine | 6.2 | 3.3 | 15 | 50 |
| Chamaecyparis obtusa | 5.5 | 3.1 | 20 | 41 |
| Arborvitae | 3.2 | 1.5 | 10 | 200 |
| Big ash tree | 1.2 | 0.4 | - | 13,000 |
| Sabina chinensis | 5.2 | 3.5 | 25 | 255 |
| Norway spruce | 8 | 3.5 | 20 | 13 |
| All-grass of firm pine | 6.2 | 2.5 | 15 | 3,250 |
| Big fruit pine | 7.2 | 3.3 | 20 | 2,361 |
| Cherry tree | 4.5 | 3.6 | 20 | 350 |
Here, the branch width corresponds to the width of the widest part of the tree, and the diameter is the diameter of the thickest part of the trunk of the tree. In the case of large ash trees, the pharmaceutical liquid composition of the present invention is diluted for spraying. Also, the amount of the medicinal liquid to be injected is controlled according to the size of the tree and the conditions under which it is injected.
The inventors of the present invention injected the pharmaceutical liquid compositions prepared in examples 1 to 11 into the trees of Table 1, which were grown at Seoul national university, in 1987, and observed them. According to the data at the end of 4 months in 1993, no harm due to acid rain was observed. It was also observed that in the case of contaminated trees, the waste of the trees, i.e. the pollutant particles (heavy metals), exude through the pores.
Claims (8)
1. A pharmaceutical liquid composition consisting essentially of a pore opener, a foreign substance remover and a solvent, wherein said composition hasa pH of 4.5 to 8.
2. The liquid pharmaceutical composition according to claim 1, wherein the stomatal opening and closing agent is at least one selected from the group consisting of gibberellin, kinetin, defoliating acid (ABA), D-isoascorbic acid, 3, 5-dihydroxy-3-methylpentanoic acid, xanthosine, benomyl, aminoxyacetic acid (AOA), ascorbic acid and thiabendazole.
3. The liquid pharmaceutical composition according to claim 2, wherein the anti-gibberellin is at least one selected from the group consisting of rhiptobutoxine, ancymidol, chlorobutadiene and uniconaz-ole.
4. The liquid pharmaceutical composition according to claim 1, wherein the solvent is at least one selected from the group consisting of an alcohol, an aqueous potassium hydroxide solution and an aqueous sodium hydroxide solution.
5. The liquid pharmaceutical composition according to claim 1, further comprising a base compound.
6. The pharmaceutical liquid composition according to claim 1, wherein the foreign substance-removing agent is at least one selected from the group consisting of cobalt chloride, nickel chloride, silver nitrate, sodium lauryl sulfate, superoxide dismutase (SOD), Ethylene Diurea (EDU), Peroxidase (POD), 8-hydroxyquinoline, germanium compounds and thiosulfate.
7. The pharmaceutical liquid composition according to claim 1, further comprising at least one nutrient selected from the group consisting of a potassium-containing compound, a calcium-containing compound, a phosphate compound, ethylenediaminetetraacetic acid (EDTA), a boric acid compound, and asulfur-containing compound.
8. The liquid pharmaceutical composition according to claim 1, wherein the composition has a PH of 5.5.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019930009112A KR960009484B1 (en) | 1993-05-25 | 1993-05-25 | Medicinal liquid composition for trees |
| GB9410140A GB2278347A (en) | 1993-05-25 | 1994-05-20 | Medicinal fluid composition for trees |
| CN94107975A CN1116045A (en) | 1993-05-25 | 1994-07-20 | Medicinal fluid composition for trees |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019930009112A KR960009484B1 (en) | 1993-05-25 | 1993-05-25 | Medicinal liquid composition for trees |
| GB9410140A GB2278347A (en) | 1993-05-25 | 1994-05-20 | Medicinal fluid composition for trees |
| CN94107975A CN1116045A (en) | 1993-05-25 | 1994-07-20 | Medicinal fluid composition for trees |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1116045A true CN1116045A (en) | 1996-02-07 |
Family
ID=37076163
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN94107975A Pending CN1116045A (en) | 1993-05-25 | 1994-07-20 | Medicinal fluid composition for trees |
Country Status (3)
| Country | Link |
|---|---|
| KR (1) | KR960009484B1 (en) |
| CN (1) | CN1116045A (en) |
| GB (1) | GB2278347A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111418417A (en) * | 2020-03-30 | 2020-07-17 | 华南农业大学 | Application of acid-base buffer system in improving acid rain resistance of plant leaves |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITPR20010061A1 (en) * | 2001-09-14 | 2003-03-14 | Bruno Corradi | PLANT PROTECTION PRODUCT, IN PARTICULAR FOR INJECTIONS INTO TREES, AND RELATED PROCEDURE. |
| CN100418930C (en) * | 2006-01-25 | 2008-09-17 | 北京华美天意科技开发有限公司 | SODMUrea and preparation method and application thereof |
| CN102668906A (en) * | 2012-05-24 | 2012-09-19 | 广西大学 | Method for controlling abnormal-early flowering branch of longan by applying paclobutrazol on soil during longan flower bud physiological differentiation period |
| FR2999386B1 (en) * | 2012-12-17 | 2015-04-03 | Bionov | COMPOSITION FOR STIMULATING THE VITALITY OF PLANTS |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA966680A (en) * | 1972-04-12 | 1975-04-29 | Edwin V. Parups | Preservation of cut blooms |
| HU167787B (en) * | 1972-08-22 | 1975-12-25 | ||
| US3865569A (en) * | 1973-03-22 | 1975-02-11 | Canadian Patents Dev | Preservation of cut blooms |
| SU1025373A1 (en) * | 1981-03-10 | 1983-06-30 | Rozenberg Vijve R | Method of producing potato planting stock and medium for reproducing regenerated plants |
| SU1039963A1 (en) * | 1981-12-01 | 1983-09-07 | Ленинградский химико-фармацевтический институт | Culture medium for culturing tissue culture araliaceae producing glycozides |
| SU1127550A1 (en) * | 1982-02-18 | 1984-12-07 | Научно-производственное объединение "Биохимреактив" | Nutrient medium for growing carnations in vitro |
| JPS62138188A (en) * | 1985-12-12 | 1987-06-20 | Nissin Food Prod Co Ltd | Peroxidase and production thereof |
| JPS6323803A (en) * | 1986-07-16 | 1988-02-01 | Nippon Orin Kk | Seed disinfectant |
| JPS63181933A (en) * | 1987-01-24 | 1988-07-27 | 協和醗酵工業株式会社 | Increase of crops of grasses |
| JPS6430517A (en) * | 1987-07-27 | 1989-02-01 | Mitsui Petrochemical Ind | Tissue culture of plant of rubia family |
| HU206269B (en) * | 1990-03-13 | 1992-10-28 | Dezsoene Dr Feher | Process for producing solution or ointment suitable for relieving rheumatic pains |
| SU1706481A1 (en) * | 1990-05-15 | 1992-01-23 | Научно-исследовательский зональный институт садоводства Нечерноземной полосы | Nutrient medium for rooting bramble sprouts |
-
1993
- 1993-05-25 KR KR1019930009112A patent/KR960009484B1/en not_active IP Right Cessation
-
1994
- 1994-05-20 GB GB9410140A patent/GB2278347A/en not_active Withdrawn
- 1994-07-20 CN CN94107975A patent/CN1116045A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111418417A (en) * | 2020-03-30 | 2020-07-17 | 华南农业大学 | Application of acid-base buffer system in improving acid rain resistance of plant leaves |
Also Published As
| Publication number | Publication date |
|---|---|
| KR960009484B1 (en) | 1996-07-20 |
| GB9410140D0 (en) | 1994-07-06 |
| GB2278347A (en) | 1994-11-30 |
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