GB2278347A - Medicinal fluid composition for trees - Google Patents
Medicinal fluid composition for trees Download PDFInfo
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- GB2278347A GB2278347A GB9410140A GB9410140A GB2278347A GB 2278347 A GB2278347 A GB 2278347A GB 9410140 A GB9410140 A GB 9410140A GB 9410140 A GB9410140 A GB 9410140A GB 2278347 A GB2278347 A GB 2278347A
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- medicinal fluid
- fluid composition
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- trees
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G7/00—Botany in general
- A01G7/06—Treatment of growing trees or plants, e.g. for preventing decay of wood, for tingeing flowers or wood, for prolonging the life of plants
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing within the same carbon skeleton a carboxylic group or a thio analogue, or a derivative thereof, and a carbon atom having only two bonds to hetero atoms with at the most one bond to halogen, e.g. keto-carboxylic acids
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
- A01N63/50—Isolated enzymes; Isolated proteins
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
- C05F11/10—Fertilisers containing plant vitamins or hormones
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
- C05G5/23—Solutions
Abstract
A medicinal fluid corn position which can protect trees from contaminating particles, comprises a stomata opening and closing agent, a foreign substance removing agent and a solvent, and has a pH from 4.5 to 8. When the medicinal fluid composition is injected into a tree, the opening and closing of the stomata of a leaf is controlled. Consequently, the injuries resulting from the contaminating particles are impeded, and the extraction of contaminating particles from the tree is induced. The composition may also comprise a nutrient.
Description
MEDICINAL FLUID COMPOSITION FOR TREES
The present invention relates to a medicinal fluid composition for trees and more particularly, to the composition for protecting trees from contaminating sources, e.g., acid rain, and for accelerating their growth.
Recently, industrial developments have resulted in the polluting gases e.g., sulfur trioxide (SO3), nitrogen dioxide (NO2), ozone (03), carbon dioxide (CO2), ethylene (CH2 = CH2), and methane (CH4), over permissible standards for the atmosphere. Consequently. crops and plants are being heavily damaged. In addition, exhaust gas emitted by automobiles is increasing perennially. Accordingly, the worldwide effects of these contaminants are drying up trees everywhere. Such air pollution also induces bronchial inflammation and dermatitis in human beings, and especially rain and snow are acidified by the above pollutants. and the resulting injuries are getting more and more serious.
The factor for generating the pollutants and the formation of acid rain are described in more detail as follows.
1) The release of carbonic acid gas is associated with domestic fuel consumption. industrial factory operation. and the respiration of animals and plants. It is known that the concentration of the carbonic acid gas in the atmosphere increases about 10% per year. Carbon dioxide with water vapor in the atmosphere builds up the earth's greenhouse effect. so that if carbon
dioxide continues to increase at the current rate, it has been predicted that in
the year 2050, the yearly mean temperature of the earth will have increased
about 1.5-4.5 C. Here, the trees play important roles in absorbing the
carbonic acid gas.
2) By the combustion of fuels including sulphur, hydrogen sulfide and
sulfurized compounds are introduced to the atmosphere from smelters and oil
refineries. The emitted gases usually move along air currents. thereby being acidified into sulfur dioxide (SO2) or sulfur trioxide (SO3) in the air, and then to be absorbed by moisture. so that they finally fall to the ground. as rain and snow.
The above mechanisms are described below, associated with the example of the combustion of sulfur in fossil fuels.
S + O2 # SO2
By the combustion. some of sulfur dioxide (about 1% SO2) reacts in fire as follows, so that sulfur trioxide (S03) is produced therein.
S 2 + 0 < S03 502 + 1/2 2 # S03 Then, sulfur trioxide reacts with the moisture in the air very rapidly, so that sulfuric acid (H2SO4) is formed.
S03 + H20 ~ H2S 4 The steam pressure of sulfuric acid is so low as to be vaporized at high speed. producing a sulfuric acid mist that is one factor for forming acid rain or acid fog.
In addition, the acid rain is formed when hydrogen sulfide (H2S) generated when organisms are decomposed by bacteria in naturally damp grounds. Also. sulfur dioxide (SO2) and hydrogen sulfide which are discharged from volcanos are transformed in the air.
3) When the compounds including nitrogen are burned, nitrogen monoxide (NO) and nitrogen dioxide (NO2) are produced. The above nitrogen compounds generally expressed as NOx, are classified into two groups: heat NOX produced when nitrogen reacts with oxygen at high temperatures. and fuel NOX produced when the nitrogen compounds included originally in fuels, e.g., CN compounds, pyridine, and quinoline. are oxidized.
4) It is estimated that in excess of approximately twelve million tons of hydrocarbons. e.g., ethylene and methane gas. are released yearly worldwide.
The contaminating sources are usually due to the incomplete combustion of products and the unburned compounds, which are acidified in the air to form organic acids. e.g., formic acid. In addition. methane is generated in the damp grounds and in mines, and terpene is generated in coniferous forests, which are acidified in the air as factors forming acid rain.
5) Also. hydrogen chloride and chlorine exist in the air. When coal, coal oil, and plastic wastes burn. the chlorine included therein is transformed into hydrochloric acid to be emitted which is another factor contributing to acid rain.
Due to the contaminating sources described above, the areas affected by acid rain is increasing, with the acidity of the rain being higher in large cities. It is observed that the pH of the rain is about 4.18, and accordingly its acidity is far higher as compared with the normal rain droplets (whose pH is about 5.6).
When the rain of high acidity soaks through a leaf. the portions near the stomata and the leaf hairs thereof dry up. thereby cause the death of the leaf. Before the death of the leaf, it is reported that the epicuticular wax covering the exterior coating of the leaf is eroded. The amount of the wax is constant in clean circumstances, but the wax soaked in the rain of the high acidity is eroded. Rain drops fall from the leaf having thick wax rapidly, while they stay long in the portions of the leaf having thin wax and shaggy hairs, and since the attaching area is broad at this portion, the trees are liable to be injured.
The trees injured by the above various pollutants, and especially by the acid rains show different effects according to the tree type but the common effect is that the capacity of self-purification against air pollution is lessened, and the trees die from dehydration usually within one to three years.
Especially, since the air pollutants move along air currents. the injuries of trees in hilly areas are more serious that in lowlands. Also. in the case of roadside trees, photosynthesis is particularly hindered by the heavy metals among the dusts of the emitted gas from the automobiles. The pollutants usually pass through the stomata of the leaves to infiltrate the trees, and when the pollutants stay in the interior of sieve tubes and water tubes of trees, the supply of several nutrients and water is blocked and the tree starts to decay from near the center of the growth rings. Then. as the upper portions thereof dry up bit by bit the whole tree dries up and dies.
It is known that the above pollutants pass through the stomata of the leaves to be absorbed into the interior of the tree. According to the experiments, when the leaves are treated with sulfur dioxide, the rate of opening the stomata decreases. and when they are treated with ozone and chloride gas. the stomata become closed.
Also. the acid rain isolates cations from soils. The surface charge of soil is negative naturally, so that the cations are bonded with the surface of the soil and the bonded cations are replaced with H+ in the acid rain.
Consequently, the soil becomes barren and the nutrients useful for the trees are depleted.
In view of the above. a method to prevent the trees which are generally known to purify the polluted air from dying due to excessive pollution and to protect the trees is needed.
The object of the present invention is to provide a medicinal fluid composition for trees, that protects trees from injuries resulting from air pollutants and especially from acid rain, and accelerates the growth of the trees.
To accomplish the object, the medicinal fluid composition for trees according to the present invention comprises a stomata opening and closing agent, a foreign substance removing agent and a solvent. and wherein the pH of the composition ranges from 4.5 to 8.
As for the stomata opening and closing agent. at least one selected from the group consisting of antigibberellins (e.g., rhippobitoxine, ancymidol, paclobutrazol and uniconazole), kinetin, abscisic acid (ABA), mevalonic acid, xanthosine. benomyl, aminooxyacetate (AOA), thiabendazole, ascorbic acid, and D-isoascorbic acid. is desirably used. It is thought that when the above stomata opening and closing agent is injected into a tree, according to the concentration of the contaminating sources in the air. and especially to the presence or the absence of the acid rain, the opening and closing of the stomata is controlled significantly. Accordingly, the contaminating sources are prevented from being absorbed into the tree. That is, when the contaminating sources exist in the air. the stomata is closed and consequently blocks the contaminating sources from being absorbed into the tree.When there is no polluting source in the air, the stomata is opened.
As for the above foreign substance removing agent. at least one selected from the group consisting of cobalt chloride, nickel chloride, silver nitrate. sodium laurylsulfate, superoxide dismutase (SOD). ethylenediurea (EDU), 8-hydroxvquinoline. a germanium compound, peroxidase (POD), and thiosulfate is desirably adapted. which protects the trees from injury resulting from ethylene gas and sulfide gas. The foreign substance removing agent plays the role of releasing the foreign substances, e.g., the heavy metals which are accumulated in the trees, via the stomata outside the tree It is observed that after injecting the medicinal compound into the tree, a yellowcolored fluid-type foreign substances are released through the stomata.
As for the solvent of the medicinal fluid composition, alcohol is usually adapted. Here, water or an alkaline solution, such as potassium hydroxide solution or sodium hydroxide solution, can be used as well. Particularly, when precipitates are formed therein, a small amount of an alkaline compound, such as sodium hydroxide or potassium hydroxide, can be added to dissolve the precipitates.
It is desired that the added amount of the solvent is small enough to dissolve each element of the composition. However, no critical limit thereof is suggested. It is preferred that the concentration of the composition is high, because in this case, a small amount may be injected into the trees easily.
However, if the concentration thereof is low and the injecting amount is great, the time required for injecting the solution into the tree becomes longer and an appropriate injecting tool should be selected. In both cases, the effect of the medicinal fluid composition on the trees does not vary depending on the change~of the concentration of the medicinal composition included in the injecting solution. Also. the content and the mixture ratio of each element in the medicinal fluid composition vary depending on the size of the tree and the contaminating condition thereof, so as not to be limited specifically.
According to the observations of the inventor of the present invention, when an increased amount of each element is injected into the tree, the detected effects of the elements are maintained for a longer duration.
The pH of the medicinal fluid composition for trees is controlled to be about 5.5 desirably. Also. it is desired that the pH is adjusted using citric acid.
Also. in order to accelerate the growth of the tree, it is desired that all sorts of nutrients. e.g., potassium compound. calcium compound, phosphoric acid compound. ethylenediaminetetraacetate (EDTA), boracic acid compound, and sulfuric acid compound. are included in the medicinal fluid composition to help the growth of the trees which are normally absorbed from the soil.
The above medicinal fluid composition for the trees is injected according to a conventional method. Using a medicinal fluid injector for the water in trees corresponding to Korean Patent No. 90-6840 (14 May 1990 by the present applicant), the composition can be easily injected into the water in a tree. Particularly, the above injector is preferably used when the medicinal fluid composition of high concentration is employed.
The inventor of the present invention has discovered through repeated experiments and observations that the medicinal fluid composition described below has an excellent effect on the trees. The content ratio of each compound can be controlled in many ways as described above, and the content ratio is suggested for convenience, in the disclosure of the desirable embodiments, and is not limited.
That is, through experimentation, it has been discovered that many compositions have excellent medicinal effects on the trees. These are a medicinal fluid composition including 100 to 500 weight parts of potassium nitrate, 0.01 to 1 weight parts of rhippobitoxine. and 1.0x 10-6 to 4.0x 10-3 weight parts of laurylsulfate as the predominant constituents excluding the solvent; a medicinal fluid composition including 1 to 10 weight parts of kinetin, 1.0 x 103 to 1.0 x 105 weight parts of cobalt chloride, and 5 to 50 weight parts of ascorbic acid as the predominant constituents except the solvent; a medicinal fluid composition including 10-15 to 500 weight parts of abscisic acid (ABA), 100 to 800 weight parts of ascorbic acid, 1.25 x 104 to 1.25 x 105 weight parts of ethylenediurea, and 10,000 to 30,000 units of superoxide dismutase as the predominant constituents excluding the solvent; a medicinal fluid composition including 10 to 500 weight parts of ancymidol, 10 to 100 weight parts of silver nitrate, 100 to 400 weight parts of sodium thiosulfate and a small amount of tween 20 as the predominant constituents excluding the solvent; a medicinal fluid composition including 1.0 x 103 to 5.0 x 105 weight parts of paclobutrazol, 10 to 50 weight parts of peroxidase, and 500 to 1000 units of superoxide dismutase as the predominant constituents excluding the solvent: a medicinal fluid composition including 0.5 to 10 weight parts of benomyl, 10 to 100 weight parts of nickel chloride, 10 to 50 weight parts of peroxidase. and 500 to 1000 units of superoxide dismutase as the predominant constituents excluding the solvent; a medicinal fluid composition including 0.1 to 100 weight parts of uniconazole compound, 50 to 500 weight parts of D-isoascorbic acid. 5 to 500 weight parts of cobalt chloride as the predominant constituents except the solvent: a medicinal fluid composition including 1 to 100 weight parts of germanium compound, 5 to 500 weight parts of potassium phosphate and 3 to 100 weight parts of cobalt chloride as the predominant constituents excluding the solvent; a medicinal fluid composition including 1 to 100 weight parts of calcium nitrate, 1 to 100 weight parts of thiosulfate, 1 to 100 weight parts of potassium nitrate, and 1 to 100 weight parts of mevalonic acid as the predominant constituents excluding the solvent; a medicinal fluid composition including 5 to 500 weight parts of thiabendazole and 10 to 400 weight parts of 8-hydroxyquinoline as the predominant constituents excluding the solvent; and a medicinal fluid composition including 1 to 500 weight parts of amino-oxyacetic acid (AOA), 10 to 500 weight parts of mevalonic acid, and a small amount of cycloheximide as the predominant constituents excluding the solvent.
Hereinafter. the medicinal fluid composition of the present invention and the manufacturing method are explained. by referring to examples thereof in more detail.
Example 1
1 X l0-4g of rhippobitoxine (whose molecular weight is 190.2). that is one of antigibberellins (anti-GA) which plays the role of controlling the opening and closing of the stomata, 288,ug of sodium laurylsulfate (Cl2HsO4SNa whose molecular weight is 288.4) for removing the foreign substances, such as cadmium lead in a tree, were dissolved in the leastrequired amount of ethyl alcohol for dissolving the above constituents and, 315mg of potassium nitrate (KNO3 whose molecular weight is 101.1) is dissolved in one liter of water, which was known to strengthen the roots of the trees and the stomata thereof.Then both solutions were mixed to be diluted, and the citric acid was added therein to adjust the pH of the composition as 5.5 to prepare a medicinal composition for trees according to the present invention.
Example 2
Smg of kinetin (C,sH17N505 whose molecular weight is 347.3), i.e., one sort of cytokinins was dissolved in one liter of water. and 50g of cobalt chloride (CoCl2 whose molecular weight is 237.9) and a small amount of vitamin C (that is. L-ascorbic acid) associated with the opening and closing of the stomata. were mixed with stearic acid ester. and then the pH thereof was controlled as weak acid to prepare a medicinal fluid composition for trees according to the present invention. Here. vitamin C is decomposed easily by water and light, so that it has to be manufactured in high concentrations so as to be injected into the tree in a short time.
Example 3
100mg of abscisic acid (ABA whose molecular weight is 264.3) was dissolved in 250ml of distilled water and 500mg of ascorbic acid was dissolved in 250mg of distilled water. 15,000 units of superoxide dismutase which accelerates the absorption rate of the medicinal composition, 2.5g of ethylenediurea (EDU) which protects the trees from ethylene gas and sulfide gas, were mixed with 0.2rye of tween 20 (that is. polyethylene(20) sorbitan monolaurate). By adding the citric acid, the pH of the compound was controlled as 5.5 to prepare a medicinal fluid composition for trees according to the present invention.As the trees which are resistant to ozone gas, the above ABA is included in large quantities. (The ABA is a strong hormone.)
Here, a resistant tree is one in which the ABA is increased more rapidly as the contaminating particles become more prevalent.
Example 4
64. lg of ancymidol (whose molecular weight is 256.3), a kind of antigibberellins. was dissolved in ethyl alcohol, and 39.5g of silver nitrate (whose molecular weight is 153.89) was dissolved in distilled water, and 31 6g of sodium thiosulfate (Na252O3 whose molecular weight is 158.13) for removing foreign substances in a tree in the presence of silver nitrate, was dissolved in 250ml of distilled water. Thus, the above solutions were mixed, and 0.2% of tween 20 was added to the mixture. The pH of the compound was controlled by the citric acid to prepare a medicinal fluid composition for trees according to the present invention.
Example 5
74g of paclobutrazol (CisH2oClN3O whose molecular weight is 293.50 and manufactured by C.I.C. of Britain) as an antigibberellin, was dissolved in 250ml of distilled water. and 25mg of peroxidase inactivated (POD made by
SIGMA) and 750 units of superoxide dismutase (SOD made by SIGMA) were dissolved in 250ml of distilled water. The two solutions were mixed and then the pH of the composition was controlled to prepare a medicinal fluid composition for trees according to the present invention.
Example 6 2. 56g of benomyl (Cl4Hl8N403, i.e., methyl-I -(butylcarbamoyl)-2- benzimidazole carbamate. whose molecular weight is 290.32, a germicidal agent) was dissolved in ethyl alcohol to be diluted with 250 ml of distilled water1 and 32g of nickel chloride (NiCl2 whose molecular weight is 129.61) was added to the solution. Then, the peroxidase and the same amount of superoxide dismutase as in Example 5 were dissolved in 250ml of distilled water. The above solutions were then mixed up to prepare a medicinal fluid composition for trees according to the present invention.
Example 7
4g of uniconazole. which is antigibberellin, 100g of D-isoascorbic acid as a source of vitamin C. and 50g of cobalt chloride were dissolved in ethyl alcohol. Then. the pH of the composition was controlled as 5.5 to prepare a medicinal fluid composition for tree according to the present invention.
Example 8
In ethyl alcohol, 100g of D-isoascorbic acid. 5g of carboxyl ethyl germanium 32 oxide. 1 00g of potassium nitrate known to strengthen flowers and fruits, 200g of phosphate dipotassium (K2HPO4), and 75g of glycine. a decomposition inhibiting agent, were dissolved. Then. sodium citrate and 50g of cobalt chloride were added to the solution and mixed to give a medicinal fluid composition according to the present invention.
Example 9
50g of mevalonic acid. 36g of thiosulfate, 36g of potassium nitrate, and 24g of calcium nitrate were added to an alcoholic solvent. Then, the above solution was mixed with an aqueous sodium hydroxide solution.
Example 10
100g of thiabendazole (CloH,N3S whose molecular weight is 201.2 and made by SIGMA), an ethylene repressing agent, and 70g of 8hydroxyquinoline were dissolved in ethyl alcohol. The pH of the composition was controlled as 5.5 to prepare a medicinal fluid composition for trees according to the present invention.
Example 11
100.3g of aminooxyacetic acid (AOA), 130. 1g of mevalonic acid, [or 8-methoxypromazine (C,8H22N2OS)], and 2ppm of cycloheximide were dissolved in ethyl l alcohol. The pH of the composition was controlled using citric acid.
In order to detect the effects of the medicinal fluid compositions of the present invention manufactured by the above examples, the medicinal fluid compositions manufactured in each example were filled in an injector for injection into trees of Table 1 showing tree sizes and quantity, and then the results were observed.
Table 1
tree species tree size tree number height | branch width diameter (m) (m) (cm) Pine tree 5.6 4.2 20 3.600 Zelkova tree 6.5 5.5 25 800 Maple tree 3.5 2.6 10 500 Red osier L 12 6 30 300 Acorn 8.5 4.8 30 50 4.2 2.5 10 300 Hornbeam 6.0 4.0 15 60 Mongolian oak 4.5 3.2 10 25 Oak tree 4.5 3.2 10 25 Pagoda tree 7.0 2.8 12 20 Sugar maple 6.2 3.3 15 50 Japanese cypress 5.5 3.1 20 41 Oriental arborvitae 3.2 1.5 10 200 Wax tree 1.2 0.4 - 13,000 Chinese juniper 5.2 3.5 25 255 Norway spruce 8 3.5 20 13 Rigida pine tree 6.2 2.5 15 3,250 Big cone tree 7.2 3.3 20 2,361 Cherrv tree 4.5 3.6 20 350 Here. the branch width corresponds to the width at the widest portion of the tree, and the above diameter is that of the thickest portion of the main trunk of the tree. In the case of the wax tree. the medicinal fluid composition of the present invention was diluted to be sprayed thereto. Also, the injecting amount of the medicinal fluid was controlled according to the size of the tree and the condition thereof to be injected.
The inventor of the present invention injected the medicinal fluid compositions manufactured in Examples 1 to 11 into the trees in Table 1, which existed at Seoul National University in 1987, and then has observed them. As a result, as of the end of April 1993, the injuries resulting from acid rain have not been observed. Also, it was observed that in the case of the contaminated trees, the tree' waste matter, i.e., the contaminating particles (heavy metals) leaked out via the stomata.
Claims (8)
1. A medicinal fluid composition comprising a stomata opening and closing agent, a foreign substance removing agent and a solvent, wherein the pH of said composition ranges from 4.5 to 8.
2. A medicinal fluid composition as claimed in claim 1, wherein said stomata opening and closing agent is at least one selected from the group consisting of antlgibberellins kinetin. abscisic acid (ABA). D-isoascorbic acid, mevalonic acid, xanthosine, benomyl. amino-oxyacetate (AOA), ascorbic acid and thiabendazole.
3. A medicinal fluid composition as claimed in claim 2, wherein said antigibberellin is at least one selected from the group consisting of rhippobitoxine, ancymidol. paclobutrazol and uniconazole.
4. A medicinal fluid composition as claimed in claim 1, wherein said solvent is at least one selected from the group consisting of alcohol.
aqueous potassium hydroxide solution and aqueous sodium hydroxide solution.
5. A medicinal fluid composition as claimed in claim 1, further comprising an alkaline compound.
6. A medicinal fluid composition as claimed in claim 1, wherein said foreign substance removing agent is at least one selected from the group consisting of cobalt chloride. nickel chloride. silver nitrate. sodium laurylsulfate, superoxide dismutase (SOD), ethylenediurea (EDU), peroxidase (POD), 8-hydroxyquinoline, a germanium compound and thiosulfate.
7. A medicinal fluid composition as claimed in claim 1. further comprising at least one nutrient selected from the group consisting of a potassium compound, a calcium compound. a phosphate compound, ethylenediaminetetraacetate (EDTA), boracic acid compound and a sulfur compound.
8. A medicinal fluid composition as claimed in claim 1, wherein the pH of said composition is 5.5.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019930009112A KR960009484B1 (en) | 1993-05-25 | 1993-05-25 | Medicinal liquid composition for trees |
| GB9410140A GB2278347A (en) | 1993-05-25 | 1994-05-20 | Medicinal fluid composition for trees |
| CN94107975A CN1116045A (en) | 1993-05-25 | 1994-07-20 | Medicinal fluid composition for trees |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019930009112A KR960009484B1 (en) | 1993-05-25 | 1993-05-25 | Medicinal liquid composition for trees |
| GB9410140A GB2278347A (en) | 1993-05-25 | 1994-05-20 | Medicinal fluid composition for trees |
| CN94107975A CN1116045A (en) | 1993-05-25 | 1994-07-20 | Medicinal fluid composition for trees |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB9410140D0 GB9410140D0 (en) | 1994-07-06 |
| GB2278347A true GB2278347A (en) | 1994-11-30 |
Family
ID=37076163
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB9410140A Withdrawn GB2278347A (en) | 1993-05-25 | 1994-05-20 | Medicinal fluid composition for trees |
Country Status (3)
| Country | Link |
|---|---|
| KR (1) | KR960009484B1 (en) |
| CN (1) | CN1116045A (en) |
| GB (1) | GB2278347A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1293122A1 (en) * | 2001-09-14 | 2003-03-19 | Bruno Corradi | A plant protection product, in particular for injections in arboreal plants, and the relative process |
| CN100418930C (en) * | 2006-01-25 | 2008-09-17 | 北京华美天意科技开发有限公司 | SODM urea and its preparing process and application |
| CN102668906A (en) * | 2012-05-24 | 2012-09-19 | 广西大学 | Method for controlling abnormal-early flowering branch of longan by applying paclobutrazol on soil during longan flower bud physiological differentiation period |
| FR2999386A1 (en) * | 2012-12-17 | 2014-06-20 | Bionov | COMPOSITION FOR STIMULATING THE VITALITY OF PLANTS |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111418417A (en) * | 2020-03-30 | 2020-07-17 | 华南农业大学 | Application of acid-base buffer system in improving acid rain resistance of plant leaves |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1293122A1 (en) * | 2001-09-14 | 2003-03-19 | Bruno Corradi | A plant protection product, in particular for injections in arboreal plants, and the relative process |
| CN100418930C (en) * | 2006-01-25 | 2008-09-17 | 北京华美天意科技开发有限公司 | SODM urea and its preparing process and application |
| CN102668906A (en) * | 2012-05-24 | 2012-09-19 | 广西大学 | Method for controlling abnormal-early flowering branch of longan by applying paclobutrazol on soil during longan flower bud physiological differentiation period |
| FR2999386A1 (en) * | 2012-12-17 | 2014-06-20 | Bionov | COMPOSITION FOR STIMULATING THE VITALITY OF PLANTS |
| WO2014095900A1 (en) * | 2012-12-17 | 2014-06-26 | Bionov | Composition for stimulating plant vitality |
| US9854808B2 (en) | 2012-12-17 | 2018-01-02 | Bionov | Composition for stimulating plant vitality |
Also Published As
| Publication number | Publication date |
|---|---|
| KR960009484B1 (en) | 1996-07-20 |
| GB9410140D0 (en) | 1994-07-06 |
| CN1116045A (en) | 1996-02-07 |
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