KR960009484B1 - Medicinal liquid composition for trees - Google Patents
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- KR960009484B1 KR960009484B1 KR1019930009112A KR930009112A KR960009484B1 KR 960009484 B1 KR960009484 B1 KR 960009484B1 KR 1019930009112 A KR1019930009112 A KR 1019930009112A KR 930009112 A KR930009112 A KR 930009112A KR 960009484 B1 KR960009484 B1 KR 960009484B1
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Abstract
Description
본 발명은 수목용 약액조성물에 관한 것으로서, 특히 선성비등의 오염원으로부터 수목을 보호해줄 수 있고 수목의 성장을 도울 수 있는 수목용 약액조성물에 관한 것이다.The present invention relates to a chemical composition for trees, and more particularly to a chemical composition for trees that can protect trees from contaminants such as sesame rain and help tree growth.
최근, 산업의 발달로 인하여 삼산화황(SO3), 이산화질소(NO2), 오존(O3), 이산화탄소(CO2), 에틸렌(ethylence; CH2=CH2), 메탄(CH4) 등의 유해가스가 대기중에 허용치 이상으로 존재하게 되어 농작물, 산림등에 커다란 피해를 주고 있다. 더구나 날로 증가하고 있는 자동차에서 배출되는 배기가스로 인하여 도로변에 있는 가로수가 고사(枯死)하는 현상이 현재 우라나라 뿐아니라 세계 각국에서 나타나고 있다. 이러한 공기오염은 인간에게서도 기관지염. 피부염 등의 형태로 피해가 나타나고 있으며, 특히 상기 오염원들로 인하여 비나 눈 등이 산성화되어 이로인한 피해도 날로 심각해지고 있는 실정이다.Recently, due to the development of the industry, such as sulfur trioxide (SO 3 ), nitrogen dioxide (NO 2 ), ozone (O 3 ), carbon dioxide (CO 2 ), ethylene (ethylence; CH 2 = CH 2 ), methane (CH 4 ) Gases are present in the atmosphere above acceptable levels, causing significant damage to crops and forests. In addition, the roadside death on the roadside due to the exhaust gas emitted from automobiles is increasing not only in Urana but also in other countries around the world. This air pollution is also bronchitis in humans. The damage is manifested in the form of dermatitis, and in particular, due to the pollutants, the rain or snow are acidified, and thus the damage caused by this is also serious.
상기 오염원들의 생성 원인과 이로 인한 산성비의 형성에 대하여 알아보면 다음과 같다.The causes of the generation of the pollutants and the resulting acid rain are as follows.
1) 일산화탄소는 자동차 연료의 불완전 연소로 인하여 발생되는 것으로 알려져 있으며, 이산화탄소 가스는 생활연료와 산업체 및 동, 식물의 호흡으로 인하여 발생되며, 대기중 이산화탄소 가스 농도는 매년 10%정도 증가하는 것으로 알려져 있다. 이산화탄소 가스는 수증기와 함께 지구에 온실효과를 주는데, 현재와 같은 추세로 이산화탄소가 증가한다면 2050년에 가서는 지구 평년기온이 약 1.5∼4.5 정도 상승할 것으로 예상되고 있다. 바로 이 이산화탄소 가스를 흡수할 수 있는 것이 수목인 것이다.1) Carbon monoxide is known to be caused by incomplete combustion of automobile fuels, and carbon dioxide gas is generated by the respiration of domestic fuel, industry, animal and plant, and the concentration of carbon dioxide gas in the atmosphere is known to increase by 10% every year. . Carbon dioxide gas has a greenhouse effect on the earth along with water vapor. If carbon dioxide is increased in the current trend, the average annual temperature of the earth is expected to increase by about 1.5 to 4.5 by 2050. It is the trees that can absorb this carbon dioxide gas.
2) 유황을 함유하는 연료의 연소에 의해, 또한 제련소 및 정유공장에서 황화수소와 유황산화물이 대기중으로 방출된다. 이 가스는 주로 기류를 타고 이동하면서 대기중에서 이산화황(SO2)과 삼산화황(SO3)으로 산화된 후 수분에 흡수되었다가 비나 눈의 형태로 지표면으로 돌아오게 된다.2) By the combustion of sulfur-containing fuels, hydrogen sulfide and sulfur oxides are also released into the atmosphere at smelters and refineries. The gas travels mainly in airflow, oxidized into sulfur dioxide (SO 2 ) and sulfur trioxide (SO 3 ) in the atmosphere, absorbed by moisture, and returned to the surface in the form of rain or snow.
상기한 메카니즘을 화석연료 속의 S가 연소된 경우를 예로하여 설명하면 다음과 같다.The mechanism described above will be described with an example in which S in fossil fuel is burned.
S+O2→SO2 S + O 2 → SO 2
SO2는 불 속에서 그 일부(약 1%)가 다음과 같이 반응하여 삼산화황(SO3)이 생성된다.SO 2 reacts with a part (about 1%) in the fire to produce sulfur trioxide (SO 3 ).
SO2+O→SO3 SO 2 + O → SO 3
SO2+1/202→SO3 SO 2 +1/20 2 → SO 3
SO3는 공기중의 수증기와 대단히 빨리 반응하여 황산을 생성한다.SO 3 reacts very quickly with water vapor in the air to produce sulfuric acid.
SO3+H2O→H2SO4 SO 3 + H 2 O → H 2S O 4
H2SO4는 증기압이 매우 낮으므로 빠른 속도로 기화 되어 황산 미스트를 생성하는데 이것이 산성비나 산성 안개의 한 요인이 된다.Since H 2 SO 4 has a very low vapor pressure, it vaporizes rapidly to produce sulfuric acid mist, which is one of the causes of acid rain and acid mist.
그 외에 자연의 습지에서 유기물이 세균에 의하여 분해된 황화수소(H2S)와 화산에서 방출된 SO2및 H2S가 대기중에서 변환되어 산성비의 원인이 되기도 한다.In addition, hydrogen sulfide (H 2 S), in which organic matter is decomposed by bacteria in natural wetlands, and SO 2 and H 2 S emitted from volcanoes, are converted into the atmosphere, causing acid rain.
3) 물질이 연소할 때 일산화질소(NO)와 이산화질소(NO2)가 발생되는데, NOx로 통칭되는 이들은 고온에서 질소와 산소가 반응하여 생성되는 열 NOx와, 본래 연료속에 함유되어 있던 CN화물, 피리딘, 퀴놀린등의 질소화합물이 산화되어 생성되는 연료 NOx로 크게 구분된다.3) When the material is burned, nitrogen monoxide (NO) and nitrogen dioxide (NO 2 ) are generated, which are collectively referred to as NOx, are thermal NOx produced by the reaction of nitrogen and oxygen at high temperature, CN cargo originally contained in fuel, Nitrogen compounds such as pyridine and quinoline are largely divided into fuel NOx produced by oxidation.
4)에틸렌, 메탄가스 등의 탄화수소물은 우리나라를 포함하여 전세계적으로 연간 최저 약 천이백만톤 이상이 방출되는 것으로 추산된다. 오염원은 주로 불완전 연소하거나 타지 않은 상태로 방출된 물질로서, 대기중에서 산화되어 개미산과 같은 유기산이 생성된다. 그 외에 습지나 광산에서는 메탄이 발생되고 침엽수림에서는 테르펜이 발생되는데, 이들이 대기중에서 산화되어 산성비의 한 요인이 된다.4) Hydrocarbons such as ethylene and methane gas are estimated to emit at least about 12 million tons annually, including Korea. Pollutants are mainly incompletely burned or unburned substances, which are oxidized in the atmosphere to produce organic acids such as formic acid. In addition, methane is produced in wetlands and mines, and terpenes are produced in coniferous forests, which are oxidized in the atmosphere and are a source of acid rain.
5) 또한 대기중에는 염화수소와 염소가 포함되어 있다. 석탄, 석유, 플라스틱 폐기물 등이 연소될 때 이속에 포함된 염소가 염산으로 방출되어 산성비의 원인이 된다.5) The atmosphere also contains hydrogen chloride and chlorine. When coal, petroleum and plastic wastes are combusted, chlorine in this stream is released into hydrochloric acid, causing acid rain.
우리나라에서 빗물의 산성도는 대도시 지역에서 더욱 높아 pH가 4.18 정도로서 정상빗물(pH dir 5.6) 보다 훨씬 높은 것으로 관찰된다.In Korea, the acidity of rainwater is higher in metropolitan areas, and the pH is about 4.18, which is much higher than that of normal rainwater (pH dir 5.6).
상기와 같은 여러가지 오염원, 특히 산성비로 인하여 피해를 받은 수목은 수종에 따라 그 영향이 다르게 나타나지만 공통된 점은 대기오염에 대한 자정(self-purification) 능력이 약화되고 보통 1 내지 3년 이내에 고사한다. 특히 대기오염 물질들은 기류를 타고 이동하기 때문에 저지대보다 고지대 에서 피해가 심각하게 나타나고 있다. 또한 도로변의 가로수 등은 차량 배기 가스의 분진에 의한 중금속 등으로 특히 광합성 작용에 장해를 받고 있다. 오염물질은 주로 기공을 통하여 수목의 내부로 침투되는데, 이들 오염물이 도관 내부에 머물게 되면 각종 영양분 및 수분의 공급이 차단되고 수목이 나이테 중심부로부터 썩기 시작하여 상단부로부터 조금씩 말라들어가 전체적으로 고사하게 된다.Trees affected by various pollutants such as acid rain, in particular, have different effects depending on the species, but the common point is that the self-purification ability to air pollution is weakened and usually dies within 1 to 3 years. In particular, air pollutants are more severely damaged in the highlands than in the lowlands because they travel by air currents. In addition, roadside trees and the like are heavy metals caused by dust of vehicle exhaust gas, and are particularly disturbed by photosynthesis. Pollutants are mainly penetrated into the trees through the pores. When these pollutants stay inside the conduit, the supply of various nutrients and water is blocked, and the trees start to rot from the center of the ring and dry out little by little from the upper end.
특히 산성비에 의해 수목에 나타나는 현상으로는 다음과 같은 것들이 있다.In particular, the phenomenon that occurs in trees due to acid rain includes the following.
(1) 조기 또는 부정기 낙엽(수목의 하부 보다 정상부가 일찍 낙엽되는 경향이 있음).(1) Early or irregular leaves (the tops tend to fall earlier than the bottom of the trees).
(2) 수명단축.(2) shorten the service life.
(3) 줄기의 비대생장과 새로운 가지에 있어서의 신장생장의 저하.(3) Hypertrophy of stem and fall of kidney growth in new branch.
(4) 뿌리끝이 직선으로 자라지 못하고 산호모양으로 뭉치게 된다.(4) The root tip does not grow in a straight line, but aggregates into corals.
(5) 뿌리가 토양면 가까이에 얕게 뻗는다.(5) The roots extend shallowly near the soil surface.
(6) 순생산량의 감소.(6) reduction in net production.
(7) 고사(枯死)(7) Examination
산성도가 높은 빗물에 적셔진 잎은 기공이나 털의 가까이에서 괴사(壞死)가 일어나는데, 그보다 앞서 표피를 덮고 있는 에피큐티큘라 왁스(epicuticular wax)가 침식되는 현상이 일어나는 것으로 보고되어 있다.Leaves soaked in high-acid rainwater have necrosis near the pores or hairs, and it has been reported that epipicicular wax, which covers the epidermis, erodes earlier.
깨끗한 환경에서는 왁스의 양이 변하지 않지만 산성도가 높은 빗물에 의해서는 왁스가 침식되고, 왁스가 두꺼운 잎에서는 빗방울이 빨리 떨어지지만 왁스가 얇고 털이 많은 부분에서는 빗물이 오래도록 머물게 되며 부착 면적이 넓기 때문에 수목에 대한 피해가 발생하는 것으로 이해되고 있다.In a clean environment, the amount of wax does not change, but the wax is eroded by acidic rainwater, the raindrops fall quickly on thick waxy leaves, but the rainwater stays long on thin, hairy areas, and because of the large attachment area, It is understood that the damage caused.
오염물질은 잎의 기공을 통하여 식물체내로 침입하여 흡수되는 것으로 보는 것이 통설이다. 실험에 의하면 잎이 이산화황 가스 처리를 하면 기공의 개도(開度)가 줄어들게 되고, 오존, 염소등의 가스를 처리하게 되면 가공이 폐경(閉鏡) 된다는 보고가 있다.It is common practice that pollutants are invaded and absorbed by plants through the pore of leaves. According to the experiment, when the leaves are treated with sulfur dioxide gas, the openings of pores are reduced, and when the gases such as ozone and chlorine are treated, the processing is reported to be menopause.
또한 산성비는 토양으로부터 양이온을 세탈(洗脫)시킨다. 토양 표면은 본래 음전하를 띠고 있으므로 그 표면에 양이온이 결합되어 있는데, 이들이 산성 빗물 속의 H+와 치환되는 것이다. 이는 결국 토양을 척박하게 만들어 수목의 영양분을 고갈시킨다는 의미이다.Acid rain also cites cations from the soil. Since the soil surface is inherently negatively charged, cations are bound to it, replacing them with H + in acid rain. This means that the soil is depleted, depleting tree nutrients.
상기에서 살펴본 여러가지를 염두에 둘 때, 오염된 대기를 정화시키는 작용을 하는 것으로 알려진 수목들이 지나친 오염으로 인하여 고사되는 것을 방지하고 보호하기 위한 대책 마련이 시급한 상황이라고 할 수 있겠다.With all of the above in mind, it is urgent to prepare measures to prevent and protect the trees known to act to purify the polluted atmosphere due to excessive pollution.
본 발명자는 상기한 수목에의 피해를 최대한 줄일 수 있는 방안을 지속적으로 연구하던 중 대기오염원, 특히 산성비로 인한 피해로부터 수목을 비호해주고, 성장을 도와줄 수 있는 수목용 약액을 개발하기에 이르러 이를 제공하고자 하는 것이다.The inventors of the present invention continue to study ways to reduce the damage to the trees as much as possible to protect the trees from damage caused by air pollution, especially acid rain, and to develop a tree chemical solution that can help growth. It is to provide.
상기 목적을 달성하기 위한 본 발명의 수목용 약액조성물은 기공개폐제 및 이물질 제거제를 포함하는 화합물을 용매를 녹이고 pH를 4.5 내지 8로 조절하여 얻어지는 점에 특징이 있다.The chemical composition for trees according to the present invention for achieving the above object is characterized in that the compound comprising a pore-closing agent and a foreign substance remover is dissolved by dissolving a solvent and adjusting the pH to 4.5 to 8.
기공개폐제로서는 리포비톡신, 안시미돌, 파클로부트라졸, 유니코나졸 등과 같은 안티지베레린제, 키네틴, ABA(Abscisic acid), 메발론산, 크산톡신, 베노밀, 아미노옥시아세테이트(AOA; aminooxyacetate), 티아벤다졸, 아스코르빈산 및 D-이소아스코르빈산으로 이루어진 군에서 선택되는 적어도 하나가 바람직하게 사용된다. 상기 기공개폐제를 수목에 주입하게 되면 대기중 오염원의 농도, 특히 산성비의 유무에 따라 이들이 기공의 개폐를 민감하게 조절하여 오염원의 흡수를 방지해 주는 것으로 생각된다. 즉, 대기중에 오염원이 많으면 기공을 닫아주어 오염원이 수목의 내부로 침투되는 것을 막아주고, 대기중에 오염원이 없을 때는 기공을 열어주는 작용을 하는 것이다.As pore-closing agents, anti-gibererins such as lipobittoxin, ancimidol, paclobutrazole, uniconazole, kinetin, ABA (Abscisic acid), mevalonic acid, xantoxin, benomil, aminooxyacetate (AOA), At least one selected from the group consisting of thiavenazole, ascorbic acid and D-isoascorbic acid is preferably used. When the pore-closing agent is injected into the trees, it is thought that they sensitively regulate the opening and closing of the pores according to the concentration of pollutants in the air, especially the presence of acid rain, thereby preventing the absorption of the pollutants. That is, if there are many pollutants in the air, the pores are closed to prevent the pollutants from penetrating into the inside of the tree, and when there are no pollutants in the air, the pores are opened.
상기 이물질 제거제로서는 에틸렌 가스, 황산가스등에 의한 피해로부터 수목을 보호해 줄 수 있는 염화코발트, 염화니켈 및 질산은중 적어도 하나가 사용될 수 있으며 라우릴황산나트륨, 슈퍼옥사이드 디스뮤타제, 에틸렌디우레아(EDU; ethlenediurea), 8-히드록시퀴놀린, 게르마늄 화합물, 퍼옥시다제(POD; peroxidase) 및 티오황산염 중 적어도 하나가 바람직하게 사용될 수 있다. 이물질 제거제는 수목내에 축적되어 존재하는 중금속 등의 이물질을 기공을 통하여 외부로 배출시켜 주는 역할을 하는데, 약액의 주입후 누런색의 액체 형태로 배출되는 것을 관찰할 수 있었다.As the foreign material remover, at least one of cobalt chloride, nickel chloride, and silver nitrate, which may protect trees from damage caused by ethylene gas, sulfuric acid gas, and the like, may be used, and sodium lauryl sulfate, superoxide dismutase, ethylenediurea (EDU; ethlenediurea), 8-hydroxyquinoline, germanium compound, peroxidase (POD; peroxidase) and thiosulfate may be preferably used. The foreign substance remover plays a role of discharging foreign substances such as heavy metals accumulated in the tree to the outside through the pores, and was discharged in the form of a yellowish liquid after injection of the chemical solution.
상기 약액조성물의 용매로서는 바람직하게는 알콜용매를 사용하고, 물, 또는 수산화칼륨 수용액, 수산화나트륨 수용액 등의 알칼리성 수용액을 사용할 수도 있다. 특히 침전물이 생성되는 경우에는 수산화나트륨, 수산화칼륨 등의 알칼리 화합물을 소량 가하면 대부분의 침전물이 용해된다.As a solvent of the chemical liquid composition, an alcohol solvent is preferably used, and an aqueous alkaline solution such as water or aqueous potassium hydroxide solution or aqueous sodium hydroxide solution may be used. In particular, when a precipitate is produced, most of the precipitate is dissolved by adding a small amount of an alkali compound such as sodium hydroxide or potassium hydroxide.
용매의 첨가량은 조성물의 각 성분이 용해될 수 있을 정도의 소량으로 하는 것이 바람직하나, 특별히 제한적이지는 않다. 농도가 짙으면 적은양의 액을 수목에 주입해도 되기 때문에 바람직한데, 농도가 옅어서 주입액의 양이 많아지게 되면 주입에 시간이 많이 걸리고 주입 용기 설정에 따르는 어려움은 있지만 약액이 수목에 주는 효과는 주입액중 약물의 농도에 영향을 받지 않는다. 또한 약액조성물에서 각 성분의 함량 및 혼합비는 수목의 크기, 수목의 오염 상태등에 따라 달라지기 때문에 특별히 제한적이지 않으며, 본 발명자의 관찰에 의하면 각 성분의 함량을 많이하여 수목에 투입할 경우, 그 효과가 장시간 지속되는 것을 확인할 수 있었다.The amount of the solvent added is preferably in a small amount such that each component of the composition can be dissolved, but is not particularly limited. If the concentration is high, a small amount of liquid may be injected into the tree, which is preferable.If the concentration is too light, the amount of infusion is increased, which requires a lot of time and the difficulty of setting the infusion container. Is not affected by the concentration of drug in the infusion. In addition, the content and mixing ratio of each component in the chemical liquid composition is not particularly limited because it depends on the size of the tree, the pollution state of the tree, etc. According to the inventors' observation, the effect of adding a lot of each component to the tree, the effect It could be confirmed that it lasts a long time.
상기 수목용 약액조성물의 pH는 바람직하게는 5.5 정도로 조절하는데, 이때 구연산을 사용하는 것이 바람직하다.The pH of the chemical composition for trees is preferably adjusted to about 5.5, in which case citric acid is preferably used.
또한 상기 약액조성물에는 칼륨화합물, 칼슘화합물, 인산화합물, 에틸렌디아민테트라아세테이트(ethylenediaminetetra-acetate; EDTA), 붕산화합물, 황산화합물 등과 같이 수목의 생장을 돕기 위하여 토양으로부터 흡수되게 되는 각종 영양소를 더 포함시키는 것이 바람직하다.In addition, the chemical liquid composition further includes various nutrients that are absorbed from the soil to help the growth of trees such as potassium compounds, calcium compounds, phosphate compounds, ethylenediaminetetra-acetate (EDTA), boric acid compounds, sulfate compounds, etc. It is preferable.
상기한 수목용 약액조성물을 본 출원인이 한국 특허 출원번호 제90-6840호(1990년 5월 14일)에 개시한 수목용 약액 주입방법에 따라 주입기에 주입하여 수목에 용이하게 주입할 수 있다. 특히 농도가 짙은 약액은 상기 주입기를 사용하여 주입하는 것이 바람직하다.The tree chemical liquid composition can be easily injected into the tree by injecting it into the injector according to the tree chemical liquid injection method disclosed in Korean Patent Application No. 90-6840 (May 14, 1990). In particular, it is preferable to inject the chemical liquid with a high concentration using the injector.
본 발명자는 다음과 같은 약액조성물이 수목에 대하여 우수한 효과를 제공해 준다는 것을 발견하였다. 하기의 각 조성물 성분비는 상기한 바와 같이 얼마든지 조절 가능한 것으로서, 바람직한 실시예의 개시를 위한 것이지 이로만 한정하는 것은 아니다.The present inventors have found that the following chemical composition provides excellent effects on trees. Each of the composition ratios described below can be adjusted as much as described above, but is not intended to limit the present invention to the disclosure of the preferred embodiment.
즉, 용매외의 주성분으로서 100 내지 500중량부의 질산칼륨, 0.01 내지 1중량부의 리포비톡시 및 1.0×10-2내지 4.0×10-3중량부의 라우릴 설페이트를 포함하여 이루어지는 약액조성물; 용매외의 주성분으로서 1 내지 10중량부의 키네틴, 1.0×103내지 1.0×105중량부의 염화코발트 및 5 내지 50중량부의 아스코르빈산을 포함하여 이루어지는 약액조성물; 용매외의 주성분으로서 10-15내지 500중량부의 ABA(abscisicacid), 100 내지 800중량부의 아스코르빈산, 1.25×104 내지 1.25×105중량부의 EDU(ethlenediurea), 10,000 내지 30,000 단위의 슈퍼옥사이드 디스뮤타제를 포함하여 이루어지는 약액조성물; 용매외의 주성분으로서 10 내지 500중량부의 안시미돌(ancymidol), 10 내지 100중량부의 질산은, 100 내지 400중량부의 티오 황산나트륨, 소량의 트윈 20을 포함하여 이루어지는 약액조성물; 용매외의 주성분으로서 1.0×103내지 5.0×105중량부의 파클로부트라졸, 10 내지 50중량부의 퍼옥시다제, 500 내지 1000단위의 슈퍼옥사이드 디스뮤타제를 포함하여 이루어지는 약액조성물; 용매외의 주성분으로서 0.5 내지 10중량부의 베노밀(benomy), 10 내지 100중량부의 염화니켈, 10 내지 50중량부의 퍼옥시다제 및 500 내지 1000단위의 슈퍼 옥사이드 스뮤타제를 포함하여 이루어지는 약액조성물; 용매외의 주성분으로서 0.1 내지 100중량부의 유니코나졸, 50 내지 500중량부의 D-이소아스코르빈산 및 5 내지 500중량부의 염화코발트를 포함하여 이루어지는 약액조성물; 용매외의 주성분으로서 0.1 내지 100중량부의 게르마늄 화합물, 5 내지 500중량부의 인산칼륨 화합물 및 3 내지 100중량부의 염화코발트를 포함하여 이루어지는 약액조성물; 용매외의 주성분으로서 1 내지 100중량부의 질산칼슘, 1 내지 100중량부의 티오황산, 1 내지 100중량부의 질산칼륨 및 1 내지 100중량부의 메발론산을 포함하여 이루어지는 약액조성물; 용매외의 주성분으로서 5 내지 500중량부의 티아벤다졸 및 10 내지 400중량부의 8-히드록시퀴놀린을 포함하여 이루어지는 약액조성물; 및 용매외의 주성분으로서 1 내지 500중량부의 아미노옥시아세테이트(AOA; amino-oxyacetic acid), 10 내지 500 중량부의 메발론산 및 소량의 싸이클로헥시미드를 포함하여 이루어지는 약액조성물 등이 수목에 우수한 효과를 제공해 준다는 것을 실험을 통해 발견할 수 있었다.Namely, a chemical composition comprising 100 to 500 parts by weight of potassium nitrate, 0.01 to 1 parts by weight of lipobitoxy and 1.0 × 10 -2 to 4.0 × 10 -3 parts by weight of lauryl sulfate as main components other than the solvent; A chemical composition comprising 1 to 10 parts by weight of kinetin, 1.0 × 10 3 to 1.0 × 10 5 parts by weight of cobalt chloride, and 5 to 50 parts by weight of ascorbic acid as a main component other than the solvent; 10-15 to 500 parts by weight of ABA (abscisicacid), 100 to 800 parts by weight of ascorbic acid, 1.25 × 104 to 1.25 × 10 5 parts by weight of ethlenediurea (EDU), 10,000 to 30,000 units of superoxide dismutase Chemical liquid composition comprising a; 10 to 500 parts by weight of ancymidol, 10 to 100 parts by weight of silver nitrate, as a main component other than the solvent, and a chemical liquid composition comprising 100 to 400 parts by weight of sodium thiosulfate and a small amount of Tween 20; A chemical liquid composition comprising 1.0 × 10 3 to 5.0 × 10 5 parts by weight of paclobutrazole, 10 to 50 parts by weight of peroxidase, and 500 to 1000 units of superoxide dismutase as main components other than the solvent; A chemical composition comprising 0.5 to 10 parts by weight of benomy, 10 to 100 parts by weight of nickel chloride, 10 to 50 parts by weight of peroxidase, and 500 to 1000 units of super oxide smistase as main components other than the solvent; A chemical liquid composition comprising 0.1 to 100 parts by weight of uniconazole, 50 to 500 parts by weight of D-isoascorbic acid and 5 to 500 parts by weight of cobalt chloride as main components other than the solvent; A chemical liquid composition comprising 0.1 to 100 parts by weight of germanium compounds, 5 to 500 parts by weight of potassium phosphate compounds and 3 to 100 parts by weight of cobalt chloride as main components other than the solvent; A chemical composition comprising 1 to 100 parts by weight of calcium nitrate, 1 to 100 parts by weight of thiosulfuric acid, 1 to 100 parts by weight of potassium nitrate, and 1 to 100 parts by weight of mevalonic acid as main components other than the solvent; A chemical liquid composition comprising 5 to 500 parts by weight of thiabendazole and 10 to 400 parts by weight of 8-hydroxyquinoline as a main component other than the solvent; And a chemical liquid composition comprising 1 to 500 parts by weight of amino-oxyacetic acid (AOA), 10 to 500 parts by weight of mevalonic acid and a small amount of cycloheximide as main components other than solvents to provide excellent effects to trees. Experiments to find out.
이하, 구체적인 실시예를 통하여 본 발명의 약액조성물을 그 제조방법과 함께 상세히 설명하기로 한다.Hereinafter, the pharmaceutical composition of the present invention will be described in detail with the preparation method through specific examples.
[실시예 1]Example 1
기공의 개폐를 조절해 주는 역할을 하는 안티지베레린제인 리포비톡신(rhippobitoxin; 분자량 190.2) 1×10-4g, 및 카드뮴, 납등의 이물질을 제거해주는 라우릴황산나트륨(C12H25O4SNa; 분자량 288.4) 288g을 최소량의 에틸알콜에 녹이고, 뿌리와 기공을 튼튼하게 해주는 것으로 알려진 질산칼륨(KNO3; 분자량 101) 315mg을 물 1ℓ에 녹인 후, 상기 두 용액을 혼합, 희석하고 구연산으로 pH가 5.5정도 되도록 조절하여 본 발명의 수목용 약액조성물을 제조한다.1 × 10 -4 g of rhippobitoxin (molecular weight 190.2), an anti-gibererin agent that controls the opening and closing of pores, and sodium lauryl sulfate (C 12 H 25 O 4) to remove foreign substances such as cadmium and lead SNa; Molecular weight 288.4) 288g is dissolved in a minimum amount of ethyl alcohol, 315mg of potassium nitrate (KNO 3 ; molecular weight 101), which is known to strengthen roots and pores, is dissolved in 1L of water, and the two solutions are mixed, diluted and diluted with citric acid. The pH is adjusted to about 5.5 to prepare a chemical composition for trees of the present invention.
[실시예 2]Example 2
시토킨(cytokin) 종류인 키네틴(C15H17N5O5; 분자량 347.3) 5mg을 물 1ℓ에 녹이고, 염화코발트(CoCl2; 분자량 237.9) 50g, 기공의 개폐에 관여는 비타민 C(ascorbic acid) 소량을 스테아린산 에스테르와 혼합한 후 pH를 약산성으로 조절하여 본 발명의 수목용 약액조성물을 제조한다. 5 mg of cytokine, kinetin (C 15 H 17 N 5 O 5 ; molecular weight 347.3) is dissolved in 1 liter of water, 50 g of cobalt chloride (CoCl 2 ; molecular weight 237.9), and vitamin C (ascorbic acid) involved in opening and closing of pores ) A small amount is mixed with stearic acid ester to adjust the pH to weak acid to prepare a chemical composition for trees of the present invention.
이때 비타민 C는 물과 빛에 의하여 쉽게 분해되므로 고농도로 제조한 후 단시간 내에 수목에 주입해야만 한다.At this time, since vitamin C is easily decomposed by water and light, it must be prepared in high concentration and then injected into trees within a short time.
[실시예 3]Example 3
ABA(abscisic acid; 분자량 264.3) 100mg을 증류수 250ml에 녹이고 아스코르빈산 500mg을 증류수 250ml에 녹인다. 약액의 흡수속도를 빠르게 해주는 슈퍼옥사이드디스뮤타제 15,000단위 에틸렌가스, 황산가스로부터 수목을 보호해 주는 에틸렌디우레아(EDU) 2.5g을 0.2% 트윈 20(Tween 20; polyethlene(20) sorbitan monolaurate)에 혼합한다. 구연산으로 상기 혼합액의 pH를 5.5로 조절한다. 상기 ABA는 오존 가스에 대하여 내성이 강한 수목일수록 내부에 많이 함유하고 있는 것으로 알려져 있는데, 이는 기공 개폐의 억제 호르몬인 것으로 알려져 있다. 즉, 오염물질이 많을수록 식물체내에서 ABA를 빨리 증가시킬 수 있어야 내성이 강한 수목이라고 할 수 있다.Dissolve 100 mg of ABA (abscisic acid; 264.3) in 250 ml of distilled water and dissolve 500 mg of ascorbic acid in 250 ml of distilled water. 15,000 units of superoxide dismutase ethylene gas to speed up the absorption of the chemical solution 2.5g of ethylene diurea (EDU) to protect trees from sulfuric acid gas in 0.2% Tween 20 (polyethlene (20) sorbitan monolaurate) Mix. The pH of the mixture is adjusted to 5.5 with citric acid. The ABA is known to contain more inside the more resistant wood to ozone gas, which is known to be a hormone inhibiting pore opening and closing. In other words, the more pollutants, the more resistant ABA can be to increase in plants.
[실시예 4]Example 4
안티지베레린제인 안시미돌(ancymidol; 분자량 256.3) 64.1g을 에틸알콜에 용해한 후 질산은(분자량 153.89) 39.5g을 증류수에 용해시키고 질산은과 동시에 사용하면 이물질을 제거해주는 역할을 하는 티오황산염(Na2S2O3; 분자량 158.13) 316g을 증류수 250ml에 용해시킨 용액을 혼합하여 0.2%의 트윈 20을 가하고 구연산으로 액의 pH를 조절하여 본 발명의 수목용 약액을 제조한다.After dissolving 64.1 g of antizibererin ancymidol (molecular weight 256.3) in ethyl alcohol, 39.5 g of silver nitrate (molecular weight 153.89) is dissolved in distilled water and used simultaneously with silver nitrate to remove foreign substances (Na 2). S 2 O 3 ; molecular weight 158.13) A solution of 316 g dissolved in 250 ml of distilled water was mixed, 0.2% Tween 20 was added, and the pH of the solution was adjusted with citric acid to prepare a tree chemical solution of the present invention.
[실시예 5]Example 5
안티지베레린제로서 파클로부트라졸(C15H20ClN3O; 분자량 293.50) 74g을 증류수 250ml에 용해시키고, 불활성 퍼옥시다제(POD) 25mg과 슈퍼옥사이드스뮤타제(SOD) 750 단위를 증류수 250ml에 용해시킨 후 파클로부트라졸 용액과 혼합한다. pH를 조절하여 수목용 약액을 제조한다.74 g of paclobutrazole (C 15 H 20 ClN 3 O; molecular weight 293.50) was dissolved in 250 ml of distilled water as an anti-gibererin agent, 25 mg of inert peroxidase (POD) and 750 units of superoxide stabilizer (SOD) 250 ml of distilled water. Dissolve in and mix with paclobutrazole solution. Adjust the pH to prepare a chemical for trees.
[실시예 6]Example 6
살균제인 베노밀[benomyl; (메틸 1-(부틸카바모일)베지미다졸-카바메이트; C14H18N4O3; 분자량 290.32)] 2.56g을 에틸알콜에 녹인 다음 증류수 250ml로 희석한다. 염화니켈(NiCl2; 분자량 129.61) 32g을 첨가한 다음, 실시예 5에서와 동량의 퍼옥시다제, 슈퍼옥사이드디스뮤타제를 증류수 250ml에 용해하고 혼합하여 수목용 약액을 제조한다.Beomyl, a fungicide; (Methyl 1- (butylcarbamoyl) benzimidazole-carbamate; C 14 H 18 N 4 O 3 ; molecular weight 290.32)] Dissolve 2.56 g in ethyl alcohol and dilute with 250 ml of distilled water. 32 g of nickel chloride (NiCl 2 ; molecular weight 129.61) was added, and the same amount of peroxidase and superoxide dismutase as in Example 5 were dissolved in 250 ml of distilled water and mixed to prepare a tree chemical solution.
[실시예 7]Example 7
안티지베레린제인 유니코나졸 4g 비타민 C의 일종인 D-이소아스코르빈산 100g, 염화코발트 50g을 에틸알콜에 용해시키고 pH를 5.5로 저절로 수목용 약액을 제조한다.Unigiazole 4g, an anti-gibererin agent, 100g of D-isoascorbic acid and 50g of cobalt chloride, a kind of vitamin C, are dissolved in ethyl alcohol and a pH of 5.5 is spontaneously prepared.
[실시예 8]Example 8
에틸알콜에 D-이소아스코르빈산 100g, 카르복시 에틸 게르마늄 32 산화물 5g, 꽃과 열매를 튼튼하게 해 주는 것으로 알려진 질산칼륨 100g, 인산이칼륨(K2HPO4) 200g, 분해 억제제인 글리신 75g을 가하여 용해시키고, 구연산 나트륨 및 염화코발트 50을 더 가하여 혼합한다.100 g of D-isoascorbic acid, 5 g of carboxyethyl germanium 32 oxide, 100 g of potassium nitrate known to strengthen flowers and fruits, 200 g of dipotassium phosphate (K 2 HPO 4 ) and 75 g of glycine, a degradation inhibitor, were added to ethyl alcohol. Dissolve and add sodium citrate and cobalt chloride 50 to mix.
[실시예 9]Example 9
알콜용매에 메발론산 50g, 티오황산 36g, 질산칼륨 36g, 질산칼슘 24g을 가하여 수산화나트륨 수용액에 용해하여 혼합한다.50 g of mevalonic acid, 36 g of thiosulfate, 36 g of potassium nitrate, and 24 g of calcium nitrate are added to an alcohol solvent, dissolved in an aqueous sodium hydroxide solution, and mixed.
[실시예 10]Example 10
에틸렌 억제제인 티아벤다졸(C10H2N3S; 분자량 201.2) 100g 8-히드록시퀴놀린 70g을 에틸알콜에 녹이고 pH를 5.5로 조절하여 본 발명의 수목용 약액조성물을 제조한다.Thiabenazole ethylene inhibitor (C 10 H 2 N 3 S; molecular weight 201.2) 100g 8-hydroxyquinoline 70g is dissolved in ethyl alcohol to adjust the pH to 5.5 to prepare a pharmaceutical composition for trees of the present invention.
[실시예 11]Example 11
AOA(aminoxyacetic acid) 100.3g, 메발론산[또는 8-메톡시프로마진(8-methoxypromazine; C19H22N2OS)] 130.1g 싸이클로헥시미드 2ppm을 에틸알콜에 용해시키고 구연산으로 pH를 조절하여 본 발명의 수목용 약액조성물을 제조한다.100.3 g of AOA (aminoxyacetic acid), 13 ppm of mevalonic acid (or 8-methoxypromazine (C 19 H 22 N 2 OS)] 13 ppm cycloheximide is dissolved in ethyl alcohol and the pH is adjusted with citric acid. To prepare a chemical composition for trees of the present invention.
상기 각 실시예에서 제조된 본 발명의 수목용 약액의 효과를 검증하기 위하여 각 실시예에서 제조된 약액조성물을 주입기에 넣고 다음과 같은 수목에 대하여 각각 투입한 후 결과를 관찰하였다. 실험 수목용의 수종, 크기 및 그루수는 다음 표1에 나타난 바와 같다.In order to verify the effect of the tree chemical solution of the present invention prepared in each of the above examples, the chemical composition was prepared in each of the injector and then put into each of the following trees and observed the results. Species, size and number of trees for experimental trees are shown in Table 1 below.
[표 1]TABLE 1
* 가지넓이는 나무의 가장 넓은 부분의 가로 넓이를 의미한다.Branch width means the width of the widest part of the tree.
* 직경은 원줄기의 가장 굵은 부분의 직경을 의미한다.* Diameter means the diameter of the thickest part of the stem.
* 쥐똥나무에는 본 발명의 약액조성물을 희석시켜 분무하였다.* Priest was sprayed by diluting the chemical composition of the present invention.
상기 표 1에 나타난 각종 수목에 대하여 상기 실시예 1 내지 11에서 제조한 약액조성물을 1987년에 투입하고 수목을 관찰한 결과, 1993년 4월말 현재까지 산성비로 인한 피해가 관찰되지 않았을 뿐아니라 오염된 수목의 경우에는 수목으로부터 중금속등의 오염물질등의 노폐물이 기공을 통해서 빠져나오는 것을 관찰할 수 있었다.As a result of observing the trees with the chemical liquid compositions prepared in Examples 1 to 11 for the various trees shown in Table 1 in 1987, the damage caused by acid rain was not observed until the end of April 1993, as well as contaminated. In the case of trees, waste products such as heavy metals and other contaminants can be observed from the trees through the pores.
Claims (8)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019930009112A KR960009484B1 (en) | 1993-05-25 | 1993-05-25 | Medicinal liquid composition for trees |
| GB9410140A GB2278347A (en) | 1993-05-25 | 1994-05-20 | Medicinal fluid composition for trees |
| CN94107975A CN1116045A (en) | 1993-05-25 | 1994-07-20 | Medicinal fluid composition for trees |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019930009112A KR960009484B1 (en) | 1993-05-25 | 1993-05-25 | Medicinal liquid composition for trees |
| GB9410140A GB2278347A (en) | 1993-05-25 | 1994-05-20 | Medicinal fluid composition for trees |
| CN94107975A CN1116045A (en) | 1993-05-25 | 1994-07-20 | Medicinal fluid composition for trees |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR960009484B1 true KR960009484B1 (en) | 1996-07-20 |
Family
ID=37076163
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019930009112A KR960009484B1 (en) | 1993-05-25 | 1993-05-25 | Medicinal liquid composition for trees |
Country Status (3)
| Country | Link |
|---|---|
| KR (1) | KR960009484B1 (en) |
| CN (1) | CN1116045A (en) |
| GB (1) | GB2278347A (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITPR20010061A1 (en) * | 2001-09-14 | 2003-03-14 | Bruno Corradi | PLANT PROTECTION PRODUCT, IN PARTICULAR FOR INJECTIONS INTO TREES, AND RELATED PROCEDURE. |
| CN100418930C (en) * | 2006-01-25 | 2008-09-17 | 北京华美天意科技开发有限公司 | SODM urea and its preparing process and application |
| CN102668906A (en) * | 2012-05-24 | 2012-09-19 | 广西大学 | Method for controlling abnormal-early flowering branch of longan by applying paclobutrazol on soil during longan flower bud physiological differentiation period |
| FR2999386B1 (en) * | 2012-12-17 | 2015-04-03 | Bionov | COMPOSITION FOR STIMULATING THE VITALITY OF PLANTS |
| CN111418417A (en) * | 2020-03-30 | 2020-07-17 | 华南农业大学 | Application of acid-base buffer system in improving acid rain resistance of plant leaves |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA966680A (en) * | 1972-04-12 | 1975-04-29 | Edwin V. Parups | Preservation of cut blooms |
| HU167787B (en) * | 1972-08-22 | 1975-12-25 | ||
| US3865569A (en) * | 1973-03-22 | 1975-02-11 | Canadian Patents Dev | Preservation of cut blooms |
| SU1025373A1 (en) * | 1981-03-10 | 1983-06-30 | Rozenberg Vijve R | Method of producing potato planting stock and medium for reproducing regenerated plants |
| SU1039963A1 (en) * | 1981-12-01 | 1983-09-07 | Ленинградский химико-фармацевтический институт | Culture medium for culturing tissue culture araliaceae producing glycozides |
| SU1127550A1 (en) * | 1982-02-18 | 1984-12-07 | Научно-производственное объединение "Биохимреактив" | Nutrient medium for growing carnations in vitro |
| JPS62138188A (en) * | 1985-12-12 | 1987-06-20 | Nissin Food Prod Co Ltd | Peroxidase and production thereof |
| JPS6323803A (en) * | 1986-07-16 | 1988-02-01 | Nippon Orin Kk | Seed disinfectant |
| JPS63181933A (en) * | 1987-01-24 | 1988-07-27 | 協和醗酵工業株式会社 | Increase of crops of grasses |
| JPS6430517A (en) * | 1987-07-27 | 1989-02-01 | Mitsui Petrochemical Ind | Tissue culture of plant of rubia family |
| HU206269B (en) * | 1990-03-13 | 1992-10-28 | Dezsoene Dr Feher | Process for producing solution or ointment suitable for relieving rheumatic pains |
| SU1706481A1 (en) * | 1990-05-15 | 1992-01-23 | Научно-исследовательский зональный институт садоводства Нечерноземной полосы | Nutrient medium for rooting bramble sprouts |
-
1993
- 1993-05-25 KR KR1019930009112A patent/KR960009484B1/en not_active IP Right Cessation
-
1994
- 1994-05-20 GB GB9410140A patent/GB2278347A/en not_active Withdrawn
- 1994-07-20 CN CN94107975A patent/CN1116045A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| GB2278347A (en) | 1994-11-30 |
| GB9410140D0 (en) | 1994-07-06 |
| CN1116045A (en) | 1996-02-07 |
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