CN111603430B - Hair dye for physically dyeing hair by using plant extracts and natural pigments and preparation method thereof - Google Patents
Hair dye for physically dyeing hair by using plant extracts and natural pigments and preparation method thereof Download PDFInfo
- Publication number
- CN111603430B CN111603430B CN202010577475.2A CN202010577475A CN111603430B CN 111603430 B CN111603430 B CN 111603430B CN 202010577475 A CN202010577475 A CN 202010577475A CN 111603430 B CN111603430 B CN 111603430B
- Authority
- CN
- China
- Prior art keywords
- hair
- extract
- dyeing
- carbon black
- natural
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9789—Magnoliopsida [dicotyledons]
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9794—Liliopsida [monocotyledons]
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/805—Corresponding aspects not provided for by any of codes A61K2800/81 - A61K2800/95
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/82—Preparation or application process involves sonication or ultrasonication
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Engineering & Computer Science (AREA)
- Biotechnology (AREA)
- Botany (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Inorganic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a hair dye for physically dyeing hair by utilizing plant extracts and natural pigments, which is prepared from raw materials such as mulberry leaves, natural carbon black, scutellaria baicalensis, Pu-erh ripe tea, bletilla striata, scutellaria baicalensis, prepared polygonum multiflorum and the like. The invention also provides an application method of the hair dye. According to the hair dye, the hair scales are opened through the mulberry leaf extract, the natural carbon black is adsorbed on the hair scales and clamped between the hair scales, then the extracts of the scutellaria baicalensis and the polygonum multiflorum are adopted to close the surface scales of the hair, so that the natural carbon black is firmly clamped in the hair scales, the color fastness of the chemical hair dye is achieved, the surface of the hair presents a smooth surface effect, high fish scale-like brightness is generated, and the blackened hair becomes dark and bright. The hair dye disclosed by the invention adopts natural raw materials, does not contain chemical substances, is safe and nontoxic, does not hurt hair and scalp, does not generate side effects on human health, is a good sound for pregnant women, patients and weak people, and has a good market application prospect.
Description
Technical Field
The invention relates to the technical field of daily chemical articles, in particular to a hair dye for physically dyeing hair by utilizing plant extracts and natural pigments and a preparation method thereof.
Background
With the gradual increase of people with silver hair class and the change of aesthetic concepts of people, the market demands of hair dyeing and color fixing products are increasing day by day. With the increasing health importance, carcinogenic and strongly sensitizing chemical dyeing components (such as phenylenediamine and aminophenol) and some harmful components (such as hydrogen peroxide and ammonia water) contained in the chemically synthesized hair dye are receiving more and more attention. For this reason, natural, harmless, safer hair coloring materials have been sought. For example, although plant pigment hair dyes have achieved a certain level of performance, there are still many problems, and such products are still unable to avoid the addition of harmful substances such as phenols and hydrogen peroxide to hair dyes, and are lacking in mature pigment refining techniques. At present, most natural plant direct hair dyeing products have room for improvement in terms of dyeing effect and retention time.
In some of the old hair dyes, black hair is dyed by reacting lead salts with sulfur-containing keratin in the hair to form black fine particles of lead sulfide. In carbon-based black dyeing materials, carbon black has good colorability and chemical stability, is safe, non-toxic and low in price, is widely applied to the fields of rubber, plastics, coatings and the like, and is also reported to be applied to hair dyes. If the problems of uneven coloring, insufficient color fastness and the like of the carbon black hair dye can be solved, the carbon black hair dye is an ideal permanent hair dye colorant.
Disclosure of Invention
The invention aims to overcome the defects in the prior art and provide the hair dye for physically dyeing hair by utilizing the plant extract and the natural pigment.
In order to achieve the purpose, the technical scheme adopted by the invention is as follows:
a hair dye for physically dyeing hair by utilizing plant extracts and natural pigments comprises the following components in percentage by mass:
dyeing assistant: 5-10%, coloring agent: 50-85%, and the balance of hair care agent;
the dyeing auxiliary is mulberry leaf extract.
Preferably, the preparation method of the dyeing assistant is as follows:
pulverizing folium Mori, adding 50-80% ethanol solution 4-8 times by volume, reflux extracting at 45-60 deg.C for 2-3 times (each time for 1-4 hr), mixing extractive solutions, and concentrating at 60-65 deg.C to obtain fluid extract with alcohol content not more than 30% and relative density of 1.15-1.25.
Preferably, the colorant is natural carbon black.
Preferably, the coloring agent also comprises cooked puerh tea extract accounting for 40-70% of the mass percentage of the coloring agent besides the natural carbon black.
Preferably, the coloring agent comprises bletilla striata extract besides natural carbon black and Pu-erh ripe tea extract, and the specific mass percentages of the components are as follows:
natural carbon black: 1-20 percent of the extract of the cooked puerh tea, 40-70 percent of the extract of the cooked puerh tea and the balance of the extract of the bletilla striata.
Preferably, the preparation method of the coloring agent is as follows: grinding natural carbon black until the particle size is not more than 100nm, and uniformly mixing with the rest coloring agent raw materials.
Preferably, when the natural carbon black is ground, a mixture of the natural carbon black and 40-50% ethanol solution in volume fraction is ground by a ball mill until the particle size of the natural carbon black is not more than 100 μm, then the material in the ball mill is transferred to a high-speed shearing machine, the material is sheared at the rotating speed of 60000-120000rpm until the particle size of the natural carbon black is not more than 100nm, and then the natural carbon black is obtained by low-temperature rotary evaporation of ethanol and drying.
Preferably, the preparation method of the Pu-Er ripe tea extract comprises the following steps: pulverizing dried Pu-Er ripe tea, adding 5-10 times of water, extracting at 50-75 deg.C for 2-3 times (each time for 2-3 hr), mixing extractive solutions, centrifuging, standing, collecting supernatant, and concentrating to relative density of 1.05-1.10.
Preferably, the preparation method of the bletilla striata extract comprises the following steps: soaking rhizoma bletilla powder in 45-60 deg.C deionized water for 1-3 hr, filtering, and concentrating the filtrate to gel.
The hair conditioner comprises the following components in percentage by mass:
20-80% of radix scutellariae extract and the rest of radix polygoni multiflori preparata extract.
Preferably, the hair conditioner is prepared by the following method:
mixing Scutellariae radix extract and radix Polygoni Multiflori Preparata extract, adding lemon juice to adjust pH to 6.0-6.5.
Preferably, the preparation method of the scutellaria baicalensis extract comprises the following steps: pulverizing Scutellariae radix, sieving with 30 mesh sieve, adding 10-20 times of 70% ethanol solution, ultrasonic extracting at 50-60kHz ultrasonic frequency for 2-3 times (each time for 40-80 min), mixing extractive solutions, centrifuging, standing, collecting supernatant, and concentrating to obtain fluid extract with relative density of 1.08-1.15.
Preferably, the preparation method of the prepared fleece flower root extract comprises the following steps: pulverizing radix Polygoni Multiflori Preparata, sieving with 100-8 times of 80% ethanol, soaking at 40-60 deg.C for 2-5 hr, sieving with 250-300 meshes sieve, and collecting the sieved material; adding 2-3 times of 60-80 deg.C deionized water into the oversize product, soaking for 50-100min, filtering, mixing the filtrate with undersize product, and rotary evaporating ethanol in the mixture at low temperature.
The method also provides an application method of the hair dye: cleaning hair, smearing dyeing assistant on hair, hot compressing for at least 10min, washing, smearing dyeing agent, hot compressing for at least 20min, washing, supplementing dyeing agent for 0-3 times, washing hair after each time of supplementing, smearing hair caring agent after dyeing, massaging scalp for 3-10min, washing hair, and blowing hair to seven dry with hot air along hair scale direction.
Due to the adoption of the technical scheme, the invention has the following beneficial effects:
1. the mulberry leaf extract is used as the dyeing assistant, the pH value of the mulberry leaf extract is 7.5-8.0, the mulberry leaf extract is alkalescent, and when the mulberry leaf extract acts on hair, the multi-layer scales on the surface of the hair can be opened at a large angle, so that the dyeing agent can be adsorbed in the hair scales. Meanwhile, the strong adsorbability of alkaline substances in the mulberry leaf extract and rich carboxyl and amino groups on the surface of hair fibers enables the coloring agent to be implanted into the surface layer or scales of the hair and not easy to wash off.
The natural carbon black is used as a main component for deepening the color in the coloring agent, is dark in color, has small particle size after being ground and sheared, can be uniformly dispersed in the coloring agent, and is more beneficial to being clamped in hair scales. The cooked puerh tea extract has the effects of absorbing and isolating ultraviolet rays and fixing color and protecting hair, the bletilla striata extract has the effects of fixing color and nourishing hair, and the bletilla striata extract has special viscosity characteristic and can be used as an auxiliary emulsifier to improve the retention time of natural carbon black on hair and enhance the dyeing effect.
The hair conditioner utilizes lemon juice to adjust the pH value to enable the hair conditioner to be weakly acidic, so that the scales on the surface layer of the hair are closed, the natural carbon black is firmly clamped in the scales of the hair, and the color fastness of the chemical hair dye is achieved. The Scutellariae radix extract has inhibitory effect on various gram-positive bacteria, gram-negative bacteria, and pathogenic dermatophytes, and baicalein has stronger effect than glycoside in resisting allergy. The Scutellariae radix extract can also be used as antiinflammatory agent, sebum secretion inhibitor and humectant, and has good softening effect on hair, and baicalin can absorb ultraviolet ray, scavenge oxygen free radical, prevent hair from sunburn, and prolong hair dyeing time of hair dye. The prepared fleece-flower root has rich nutrition, integrates various nutrients required by hair, promotes the blood microcirculation of scalp, supplements the nutrition of hair, and repairs the bifurcation damage. In addition, due to the closure of the scales on the hair surface, the hair surface presents a smooth effect, high fish-scale brightness is generated, and the blackened hair becomes dark and bright.
2. The invention adopts different extraction processes aiming at the characteristics of different raw materials and the function of the baicalin in the hair dye, the baicalin is not dissolved in cold water, is easy to dissolve in hot water, and can be precipitated after being cooled, so the extraction is carried out by adopting a mode of combining ethanol extraction and ultrasonic extraction, the nutrient components in the baical skullcap root are extracted as far as possible, and the hair is moistened.
The hair dye disclosed by the invention has the advantages that the phenomenon that the hair becomes withered due to alkaline components in the dyeing auxiliary can be avoided, the hair care agent is used after dyeing is finished, the frizziness is smoothed, and the hair is soft, bright and glossy. Tests prove that the hair dye has uniform color and good washing fastness after dyeing, and the color fixing time is 1-3 months. The hair dye disclosed by the invention adopts natural raw materials, does not contain chemical substances, is safe and nontoxic, does not hurt hair and scalp, does not generate side effects on human health, is a good sound for pregnant women, patients and weak people, and has a good market application prospect.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention will be described in further detail below with reference to preferred embodiments. It should be noted, however, that the numerous details set forth in the description are merely for the purpose of providing the reader with a thorough understanding of one or more aspects of the present invention, which may be practiced without these specific details.
Example 1
A hair dye for physically dyeing hair by utilizing plant extracts and natural pigments comprises the following components in percentage by mass:
dyeing assistant: 5%, coloring agent: 50%, hair conditioner: 45 percent;
the hair conditioner comprises the following components in percentage by mass:
20% of radix scutellariae extract and 80% of radix polygoni multiflori preparata extract.
The preparation method of the hair dye comprises the following steps:
(1) preparing an auxiliary dyeing agent: pulverizing folium Mori, adding 8 times and 4 times of 80% ethanol solution, extracting under reflux at 60 deg.C for 2 times (4 hr and 2 hr each time), mixing extractive solutions, and concentrating at 60 deg.C to obtain fluid extract with alcohol content of 30% and relative density of 1.15.
(2) Preparing a coloring agent: adding 50% ethanol solution into natural carbon black according to the material-liquid ratio of 1:1, placing in a ball mill, grinding until the particle size of the natural carbon black is 100 μm, transferring the material into a high-speed shearing machine, shearing at the rotating speed of 60000rpm until the particle size of the natural carbon black is 100nm, then rotationally evaporating ethanol in the mixture at 40 ℃, and drying to obtain the natural carbon black.
(3) Preparing a hair conditioner:
(3-1) crushing scutellaria baicalensis, sieving by a 30-mesh sieve, respectively adding ethanol solutions with volume fractions of 20 times and 10 times of 70%, ultrasonically extracting for 2 times at the ultrasonic frequency of 50kHz, wherein the extraction time is 80min and 40min each time, combining the extracting solutions, centrifuging for 5min at the rotating speed of 1500rpm, standing for 1h, taking the supernatant, and concentrating to obtain clear paste with the relative density of 1.08, so as to obtain the scutellaria baicalensis extract for later use;
(3-2) taking prepared polygonum multiflorum, crushing, sieving with a 100-mesh sieve, adding 8 times of 80% ethanol, soaking at 60 ℃ for 2 hours, and sieving with a 250-mesh sieve to obtain undersize for later use; adding 2 times of deionized water of 80 deg.C into the oversize product, soaking for 50min, filtering, mixing the filtrate with the undersize product, and rotary evaporating ethanol in the mixture at 45 deg.C to obtain radix Polygoni Multiflori Preparata extract;
(3-3) uniformly mixing the scutellaria baicalensis extract in the step (3-1) and the prepared polygonum multiflorum extract in the step (3-2) according to the proportion, and adding lemon juice to adjust the pH value of the mixture to 6.0 to obtain the hair care agent.
When the hair care product is used, after the hair is cleaned, the dyeing assistant is uniformly coated on the hair, the hair is wrapped by the hot towel for hot compress for 10min, the hair is washed clean, then the dyeing agent is uniformly coated, the hot compress is continued for 20min, the dyeing agent is used for supplementing 2 times after the hair is washed clean, the hair is washed clean after each supplementing, the hair care agent is coated after the dyeing is finished, the scalp is massaged for 3min, the hair is washed clean, and the hair is blown to be seven dry along the direction of hair scales by hot air at 50 ℃.
Example 2
A hair dye for physically dyeing hair by utilizing plant extracts and natural pigments comprises the following components in percentage by mass:
dyeing assistant: 10%, coloring agent: 85%, hair conditioner: 5 percent;
the hair conditioner comprises the following components in percentage by mass:
80% of radix scutellariae extract and 20% of radix polygoni multiflori preparata extract.
The preparation method of the hair dye comprises the following steps:
(1) preparing an auxiliary dyeing agent: pulverizing folium Mori, adding 8 times and 6 times of 50% ethanol solution, extracting under reflux at 45 deg.C for 2 times (4 hr and 3 hr each time), mixing extractive solutions, and concentrating at 61 deg.C to obtain fluid extract with alcohol content of 28% and relative density of 1.17.
(2) Preparing a coloring agent: adding 40% ethanol solution into natural carbon black according to the material-liquid ratio of 1:1.5, placing in a ball mill, grinding until the particle size of the natural carbon black is 90 μm, transferring the material into a high-speed shearing machine, shearing at the rotation speed of 70000rpm until the particle size of the natural carbon black is 80nm, then rotationally evaporating ethanol in the mixture at 45 ℃, and drying to obtain the natural carbon black.
(3) Preparing a hair conditioner:
(3-1) crushing scutellaria baicalensis, sieving by a 30-mesh sieve, respectively adding ethanol solutions with volume fractions of 18 times and 12 times of 70%, ultrasonically extracting for 2 times at the ultrasonic frequency of 52kHz, wherein the extraction time is 70min and 50min each time, combining extracting solutions, centrifuging for 3min at the rotating speed of 1800rpm, standing for 1.5h, taking supernatant, and concentrating to obtain clear paste with the relative density of 1.10 to obtain a scutellaria baicalensis extract for later use;
(3-2) taking prepared polygonum multiflorum, crushing, sieving with a 120-mesh sieve, adding 7.5 times of 80% ethanol, soaking at 56 ℃ for 2.6 hours, and sieving with a 250-mesh sieve to obtain undersize for later use; adding 2.2 times of deionized water of 75 deg.C into the oversize product, soaking for 65min, filtering, mixing the filtrate with undersize product, and rotary evaporating ethanol in the mixture at 42 deg.C to obtain radix Polygoni Multiflori Preparata extract;
(3-3) uniformly mixing the scutellaria baicalensis extract in the step (3-1) and the prepared polygonum multiflorum extract in the step (3-2) according to the proportion, and adding lemon juice to adjust the pH value of the mixture to 6.1 to obtain the hair care agent.
When the hair care product is used, after the hair is cleaned, the dyeing assistant is uniformly coated on the hair, the hair is wrapped by a hot towel for hot compress for 12min, the hair is washed clean, then the dyeing agent is uniformly coated, the hot compress is continued for 22min, the dyeing agent is used for 1 time after the hair is washed clean, the hair is washed clean after each time of hair supplement, the hair care agent is coated after the dyeing is finished, the scalp is massaged for 5min, the hair is washed clean, and the hair is blown to be seven dry along the direction of hair scales by hot air at 55 ℃.
Example 3
A hair dye for physically dyeing hair by utilizing plant extracts and natural pigments comprises the following components in percentage by mass:
dyeing assistant: 8%, coloring agent: 60%, hair conditioner: 32 percent;
the coloring agent comprises the following components in percentage by mass: 30% of natural carbon black and 70% of Pu-Er ripe tea extract;
the hair conditioner comprises the following components in percentage by mass: 50% of radix scutellariae extract and 50% of radix polygoni multiflori preparata extract.
The preparation method of the hair dye comprises the following steps:
(1) preparing an auxiliary dyeing agent: pulverizing folium Mori, adding 8 times, 5 times, and 4 times of 56% ethanol solution, extracting under reflux at 48 deg.C for 3 times (3 hr, and 2 hr each time), mixing extractive solutions, and concentrating at 62 deg.C to obtain fluid extract with alcohol content of 25% and relative density of 1.20.
(2) Preparing a coloring agent:
(2-1) adding a 45% ethanol solution into natural carbon black according to a feed-liquid ratio of 1:1.8, placing the mixture into a ball mill, grinding the mixture until the particle size of the natural carbon black is 80 microns, transferring the material into a high-speed shearing machine, shearing the material at the rotating speed of 80000rpm until the particle size of the natural carbon black is 70nm, then rotationally evaporating ethanol in the mixture at 48 ℃, and drying the mixture for later use;
(2-2) taking dry tea leaves of cooked puerh tea, crushing, adding 10 times and 5 times of water respectively, extracting for 2 times at 75 ℃, wherein the extraction time is 3 hours and 2 hours respectively, combining the extracting solutions, centrifuging for 10min at the rotating speed of 1000rpm, standing for 2 hours, taking the supernatant, concentrating until the relative density is 1.05, and obtaining the concentrated solution, namely the cooked puerh tea extract for later use;
and (2-3) uniformly mixing the material in the step (2-1) and the Pu-Er ripe tea extract in the step (2-2) according to a proportion to obtain the coloring agent.
(3) Preparing a hair conditioner:
(3-1) crushing scutellaria baicalensis, sieving by a 30-mesh sieve, respectively adding ethanol solutions with volume fractions of 15 times, 12 times and 10 times of 70%, ultrasonically extracting for 3 times at the ultrasonic frequency of 54kHz, wherein the extraction time is 70min, 50min and 45min each time, combining the extracting solutions, centrifuging at the rotating speed of 2000rpm for 8min, standing for 2h, taking upper clear liquid, and concentrating to obtain clear paste with the relative density of 1.12 to obtain a scutellaria baicalensis extract for later use;
(3-2) taking prepared polygonum multiflorum, crushing, sieving with a 140-mesh sieve, adding 7 times of 80% ethanol, soaking at 52 ℃ for 3.2h, and sieving with a 250-mesh sieve to obtain undersize for later use; adding 2.4 times of deionized water of 70 deg.C into the oversize product, soaking for 80min, filtering, mixing the filtrate with undersize product, and rotary evaporating ethanol in the mixture at 40 deg.C to obtain radix Polygoni Multiflori Preparata extract;
(3-3) uniformly mixing the scutellaria baicalensis extract in the step (3-1) and the prepared polygonum multiflorum extract in the step (3-2) according to the proportion, and adding lemon juice to adjust the pH value of the mixture to 6.2 to obtain the hair care agent.
When in use, the hair is cleaned, the dyeing assistant is uniformly coated on the hair, the hair is wrapped by a hot towel for hot compress for 10min, washed and then uniformly coated with the dyeing agent, the hot compress is continued for 20min, the hair is washed and cleaned, the hair conditioner is coated, the scalp is massaged for 6min, the hair is washed and cleaned, and the hair is blown to be seven dry along the direction of hair scales by using hot air at 48 ℃.
Example 4
A hair dye for physically dyeing hair by utilizing plant extracts and natural pigments comprises the following components in percentage by mass:
dyeing assistant: 6%, coloring agent: 80%, hair conditioner: 14 percent;
the coloring agent comprises the following components in percentage by mass: 60% of natural carbon black and 40% of Pu-Er ripe tea extract;
the hair conditioner comprises the following components in percentage by mass: 38% of radix scutellariae extract and 62% of radix polygoni multiflori preparata extract.
The preparation method of the hair dye comprises the following steps:
(1) preparing an auxiliary dyeing agent: pulverizing folium Mori, adding 7 times, 6 times, 4 times of 62% ethanol solution, extracting at 51 deg.C under reflux for 3 times (each time for 3 hr, 2 hr, 1 hr), mixing extractive solutions, and concentrating at 63 deg.C to obtain fluid extract with alcohol content of 24% and relative density of 1.22.
(2) Preparing a coloring agent:
(2-1) adding an ethanol solution with the volume fraction of 46% into natural carbon black according to the feed-liquid ratio of 1:1.2, placing the mixture into a ball mill, grinding the mixture until the particle size of the natural carbon black is 100 mu m, transferring the material into a high-speed shearing machine, shearing the material at the rotating speed of 90000rpm until the particle size of the natural carbon black is 50nm, then rotationally evaporating the ethanol in the mixture at 42 ℃, and drying the mixture for later use;
(2-2) taking dry tea leaves of cooked puerh tea, crushing, adding 8 times and 6 times of water respectively, extracting for 2 times at 68 ℃, wherein the extraction time is 3 hours and 2 hours respectively, combining the extracting solutions, centrifuging for 8min at the rotating speed of 1500rpm, standing for 1.5 hours, taking the supernatant, concentrating until the relative density is 1.06, and obtaining the concentrated solution, namely the cooked puerh tea extract for later use;
and (2-3) uniformly mixing the material in the step (2-1) and the Pu-Er ripe tea extract in the step (2-2) according to a proportion to obtain the coloring agent.
(3) Preparing a hair conditioner:
(3-1) crushing scutellaria baicalensis, sieving by a 30-mesh sieve, respectively adding ethanol solutions with volume fractions of 70% 16 times, 14 times and 12 times, ultrasonically extracting for 3 times at the ultrasonic frequency of 56kHz, wherein the extraction time is respectively 50min, 45min and 40min each time, combining the extracting solutions, centrifuging for 5min at the rotating speed of 2500rpm, standing for 1h, taking upper clear liquid, and concentrating to obtain clear paste with the relative density of 1.14 to obtain a scutellaria baicalensis extract for later use;
(3-2) taking prepared polygonum multiflorum, crushing, sieving with a 160-mesh sieve, adding 6.5 times of 80% ethanol, soaking at 48 ℃ for 3.8h, and sieving with a 300-mesh sieve to obtain undersize for later use; adding 2.6 times of deionized water of 65 deg.C into the oversize product, soaking for 90min, filtering, mixing the filtrate with undersize product, and rotary evaporating ethanol in the mixture at 43 deg.C to obtain radix Polygoni Multiflori Preparata extract;
(3-3) uniformly mixing the scutellaria baicalensis extract in the step (3-1) and the prepared polygonum multiflorum extract in the step (3-2) according to the proportion, and adding lemon juice to adjust the pH value of the mixture to 6.3 to obtain the hair care agent.
When in use, the hair is cleaned, the dyeing assistant is uniformly coated on the hair, the hair is wrapped by a hot towel for hot compress for 15min, washed and then uniformly coated with the dyeing agent, the hot compress is continued for 25min, the hair is washed and cleaned, the hair conditioner is coated, the scalp is massaged for 7min, the hair is washed and cleaned, and the hair is blown to be seven dry along the direction of hair scales by hot air at 60 ℃ to obtain the hair conditioner.
Example 5
A hair dye for physically dyeing hair by utilizing plant extracts and natural pigments comprises the following components in percentage by mass:
dyeing assistant: 9%, coloring agent: 70%, hair conditioner: 21 percent;
the coloring agent comprises the following components in percentage by mass: 20% of natural carbon black, 45% of Pu-Er ripe tea extract and 35% of bletilla striata extract;
the hair conditioner comprises the following components in percentage by mass: 46% of radix scutellariae extract and 54% of radix polygoni multiflori preparata extract.
The preparation method of the hair dye comprises the following steps:
(1) preparing an auxiliary dyeing agent: pulverizing folium Mori, adding ethanol solution with volume fraction of 68% 6 times, and 4 times respectively, reflux-extracting at 54 deg.C for 3 times (each time for 4 hr, 2 hr, and 1 hr), mixing extractive solutions, and concentrating at 64 deg.C to obtain fluid extract with alcohol content of 27% and relative density of 1.24.
(2) Preparing a coloring agent:
(2-1) adding 48% ethanol solution by volume fraction into natural carbon black according to the feed-liquid ratio of 1:1.4, placing the mixture into a ball mill, grinding the mixture until the particle size of the natural carbon black is 100 mu m, transferring the material into a high-speed shearing machine, shearing the material at the rotating speed of 100000rpm until the particle size of the natural carbon black is 60nm, then rotationally evaporating ethanol in the mixture at the temperature of 40 ℃, and drying the mixture for later use;
(2-2) taking dry tea leaves of cooked puerh tea, crushing, adding 10 times, 7 times and 5 times of water respectively, extracting for 3 times at 60 ℃, wherein the extraction time is 3 hours, 2.5 hours and 2 hours respectively, combining extracting solutions, centrifuging for 5min at the rotating speed of 2000rpm, standing for 2.5 hours, taking supernatant, concentrating to the relative density of 1.08, and obtaining concentrated solution, namely cooked puerh tea extract for later use;
(2-3) taking bletilla striata powder, adding deionized water with the temperature of 60 ℃ for soaking for 1h, filtering, and concentrating the filtrate to be gelatinous to obtain a bletilla striata extract for later use;
and (2-4) uniformly mixing the materials in the step (2-1), the Pu-Er ripe tea extract in the step (2-2) and the bletilla striata extract in the step (2-3) according to a proportion to obtain the coloring agent.
(3) Preparing a hair conditioner:
(3-1) crushing scutellaria baicalensis, sieving by a 30-mesh sieve, respectively adding 17-fold and 15-fold ethanol solutions with volume fraction of 70%, ultrasonically extracting for 2 times at ultrasonic frequency of 57kHz, wherein the extraction time is 65min and 45min each time, combining extracting solutions, centrifuging for 12min at the rotating speed of 1200rpm, standing for 2h, taking supernatant, and concentrating to obtain clear paste with relative density of 1.15 to obtain a scutellaria baicalensis extract for later use;
(3-2) taking prepared polygonum multiflorum, crushing, sieving with a 180-mesh sieve, adding 6 times of 80% ethanol, soaking at 45 ℃ for 4.5 hours, and sieving with a 300-mesh sieve to obtain undersize for later use; adding 2.8 times of 60 deg.C deionized water into the oversize product, soaking for 100min, filtering, mixing the filtrate with undersize product, and rotary evaporating ethanol in the mixture at 40 deg.C to obtain radix Polygoni Multiflori Preparata extract;
(3-3) uniformly mixing the scutellaria baicalensis extract in the step (3-1) and the prepared polygonum multiflorum extract in the step (3-2) according to the proportion, and adding lemon juice to adjust the pH value of the mixture to 6.4 to obtain the hair care agent.
When in use, the hair is cleaned, the dyeing assistant is uniformly coated on the hair, the hair is wrapped by a hot towel for hot compress for 15min, washed and then uniformly coated with the dyeing agent, the hot compress is continued for 25min, the hair is washed and cleaned, the hair conditioner is coated, the scalp is massaged for 8min, the hair is washed and cleaned, and the hair is blown to be seven dry along the direction of hair scales by hot air at 50 ℃.
Example 6
A hair dye for physically dyeing hair by utilizing plant extracts and natural pigments comprises the following components in percentage by mass:
dyeing assistant: 7%, coloring agent: 70%, hair conditioner: 23 percent;
the coloring agent comprises the following components in percentage by mass: 15% of natural carbon black, 42% of Pu-Er ripe tea extract and 43% of bletilla striata extract;
the hair conditioner comprises the following components in percentage by mass: 60% of radix scutellariae extract and 40% of radix polygoni multiflori preparata extract.
The preparation method of the hair dye comprises the following steps:
(1) preparing an auxiliary dyeing agent: pulverizing folium Mori, adding 7 times and 5 times of 74% ethanol solution, extracting under reflux at 57 deg.C for 2 times (4 hr and 2 hr each time), mixing extractive solutions, and concentrating at 65 deg.C to obtain fluid extract with alcohol content of 25% and relative density of 1.25.
(2) Preparing a coloring agent:
(2-1) adding a 45% ethanol solution into natural carbon black according to a feed-liquid ratio of 1:1.6, placing the mixture into a ball mill, grinding the mixture until the particle size of the natural carbon black is 100 microns, transferring the material into a high-speed shearing machine, shearing the material at a rotating speed of 120000rpm until the particle size of the natural carbon black is 65nm, then rotationally evaporating ethanol in the mixture at a temperature of 43 ℃, and drying the mixture for later use;
(2-2) crushing dry tea leaves of cooked puerh tea, adding 9 times, 7 times and 6 times of water respectively, extracting for 3 times at 50 ℃, wherein the extraction time is 3h, 2h and 2h respectively, combining extracting solutions, centrifuging for 10min at the rotation speed of 1800rpm, standing for 2h, taking supernatant, concentrating to the relative density of 1.10, and obtaining concentrated solution, namely cooked puerh tea extract for later use;
(2-3) taking bletilla striata powder, adding deionized water with the temperature of 45 ℃ for soaking for 3 hours, filtering, and concentrating the filtrate to be gelatinous to obtain a bletilla striata extract for later use;
and (2-4) uniformly mixing the materials in the step (2-1), the Pu-Er ripe tea extract in the step (2-2) and the bletilla striata extract in the step (2-3) according to a proportion to obtain the coloring agent.
(3) Preparing a hair conditioner:
(3-1) crushing scutellaria baicalensis, sieving by a 30-mesh sieve, respectively adding ethanol solutions with volume fractions of 15 times and 12 times of 70%, ultrasonically extracting for 2 times at the ultrasonic frequency of 60kHz, wherein the extraction time is 80min and 60min each time, combining extracting solutions, centrifuging for 10min at the rotating speed of 1600rpm, standing for 1.5h, taking supernatant, and concentrating to obtain clear paste with the relative density of 1.15 to obtain a scutellaria baicalensis extract for later use;
(3-2) taking prepared polygonum multiflorum, crushing, sieving with a 200-mesh sieve, adding 6 times of 80% ethanol, soaking at 40 ℃ for 5 hours, and sieving with a 300-mesh sieve to obtain undersize for later use; adding 3 times of 60 deg.C deionized water into the oversize product, soaking for 100min, filtering, mixing the filtrate with undersize product, and rotary evaporating ethanol at 42 deg.C to obtain radix Polygoni Multiflori Preparata extract;
(3-3) uniformly mixing the scutellaria baicalensis extract in the step (3-1) and the prepared polygonum multiflorum extract in the step (3-2) according to the proportion, and adding lemon juice to adjust the pH value of the mixture to 6.5 to obtain the hair care agent.
When in use, the hair is cleaned, the dyeing assistant is uniformly coated on the hair, the hair is wrapped by a hot towel for hot compress for 14min, washed and then uniformly coated with the dyeing agent, the hot compress is continued for 30min, the hair is washed and cleaned, the hair conditioner is coated, the scalp is massaged for 10min, the hair is washed and cleaned, and the hair is blown to be seven dry along the direction of hair scales by hot air at 50 ℃.
Hair dyeing effect of each example
120 white-haired volunteers were selected, randomly divided into 6 groups of 20 (no significant difference in each group), and the hair dyes of examples 1 to 6 were used, respectively, and were dyed according to the hair dye application methods described in the corresponding examples, and the dyeing effects are shown in table 1.
| Examples | 1 | 2 | 3 | 4 | 5 | 6 |
| Hair color before dyeing | White hair | White hair | White hair | White hair | White hair | White hair |
| Color of dyed hair | Black colour | Black colour | Black colour | Black colour | Black colour | Black colour |
| Number of washing times per first fading | 21 | 27 | 26 | 29 | 33 | 35 |
| Complete fade time/day | 40 | 38 | 79 | 70 | 91 | 89 |
TABLE 1
As can be seen from the data in Table 1, the first fade times of examples 1-6 of the present invention ranged from 21 to 35, which is due to the difference in hair dye composition, the frequency of shampooing, the different hair quality of each person, and the different environment in the normal environment (e.g., the hair of field workers is often exposed to the sun and easily discolored). But the fading condition begins to appear after 21 times of water washing, which shows that the coloring agent of the invention has better color fastness and good washing fastness.
Claims (7)
1. A hair dye for physically dyeing hair by utilizing plant extracts and natural pigments is characterized by comprising the following components in percentage by mass:
dyeing assistant: 5-10%, coloring agent: 50-85%, and the balance of hair care agent;
the dyeing auxiliary is a mulberry leaf extract;
the coloring agent comprises the following components in percentage by mass:
natural carbon black: 1-20 percent of cooked puerh tea extract, 40-70 percent of cooked puerh tea extract and the balance of bletilla extract;
the hair conditioner comprises the following components in percentage by mass:
20-80% of radix scutellariae extract and the balance of radix polygoni multiflori preparata extract;
the preparation method of the coloring agent comprises the following steps:
grinding natural carbon black until the particle size is not more than 100nm, and mixing with cooked Pu-Er tea extract and rhizoma Bletillae extract;
when the natural carbon black is ground, a mixture of the natural carbon black and 40-50% ethanol solution in volume fraction is ground by a ball mill until the particle size of the natural carbon black is not more than 100 mu m, then the material in the ball mill is transferred to a high-speed shearing machine, the material is sheared at the rotating speed of 60000-120000rpm until the particle size of the natural carbon black is not more than 100nm, and then the ethanol is rotationally evaporated at low temperature and dried, thus obtaining the natural carbon black;
the preparation method of the hair conditioner comprises the following steps:
mixing Scutellariae radix extract and radix Polygoni Multiflori Preparata extract, adding lemon juice to adjust pH to 6.0-6.5.
2. The hair dye for physically dyeing hair by using plant extracts and natural pigments according to claim 1, wherein the dyeing auxiliary is prepared by the following method:
pulverizing folium Mori, adding 50-80% ethanol solution 4-8 times by volume, reflux extracting at 45-60 deg.C for 2-3 times (each time for 1-4 hr), mixing extractive solutions, and concentrating at 60-65 deg.C to obtain fluid extract with alcohol content not more than 30% and relative density of 1.15-1.25.
3. The hair dye using plant extracts and natural pigments for physical hair dyeing according to claim 1, wherein the preparation method of the pu-er ripe tea extract comprises the following steps:
pulverizing dried Pu-Er ripe tea, adding 5-10 times of water, extracting at 50-75 deg.C for 2-3 times (each time for 2-3 hr), mixing extractive solutions, centrifuging, standing, collecting supernatant, and concentrating to relative density of 1.05-1.10.
4. The hair dye for physically dyeing hair by using plant extracts and natural pigments according to claim 1, wherein the preparation method of the bletilla striata extract comprises the following steps:
soaking rhizoma bletilla powder in 45-60 deg.C deionized water for 1-3 hr, filtering, and concentrating the filtrate to gel.
5. The hair dye using plant extracts and natural pigments for physical hair dyeing according to claim 1, wherein the scutellaria baicalensis extract is prepared by the following method:
pulverizing Scutellariae radix, sieving with 30 mesh sieve, adding 10-20 times of 70% ethanol solution, ultrasonic extracting at 50-60kHz ultrasonic frequency for 2-3 times (each time for 40-80 min), mixing extractive solutions, centrifuging, standing, collecting supernatant, and concentrating to obtain fluid extract with relative density of 1.08-1.15.
6. The hair dye using plant extracts and natural pigments for physical hair dyeing according to claim 1, wherein the prepared polygonum multiflorum thumb extract is prepared by the following method:
pulverizing radix Polygoni Multiflori Preparata, sieving with 100-8 times of 80% ethanol, soaking at 40-60 deg.C for 2-5 hr, sieving with 250-300 meshes sieve, and collecting the sieved material; adding 2-3 times of 60-80 deg.C deionized water into the oversize product, soaking for 50-100min, filtering, mixing the filtrate with undersize product, and rotary evaporating ethanol in the mixture at low temperature.
7. The hair dye for physically dyeing hair using plant extracts and natural pigments according to any one of claims 1 to 6, which is applied by:
cleaning hair, smearing dyeing assistant on hair, hot compressing for at least 10min, washing, smearing dyeing agent, hot compressing for at least 20min, washing, supplementing dyeing agent for 0-3 times, washing hair after each time of supplementing, smearing hair caring agent after dyeing, massaging scalp for 3-10min, washing hair, and blowing hair to seven dry with hot air along hair scale direction.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010577475.2A CN111603430B (en) | 2020-06-23 | 2020-06-23 | Hair dye for physically dyeing hair by using plant extracts and natural pigments and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010577475.2A CN111603430B (en) | 2020-06-23 | 2020-06-23 | Hair dye for physically dyeing hair by using plant extracts and natural pigments and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN111603430A CN111603430A (en) | 2020-09-01 |
| CN111603430B true CN111603430B (en) | 2021-08-24 |
Family
ID=72200548
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010577475.2A Active CN111603430B (en) | 2020-06-23 | 2020-06-23 | Hair dye for physically dyeing hair by using plant extracts and natural pigments and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111603430B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115414304B (en) * | 2022-07-01 | 2023-06-09 | 广东诗华莎化学材料有限公司 | Bi-component hair dye composition and preparation method thereof |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1062652A (en) * | 1990-12-24 | 1992-07-15 | 战永胜 | The Chinese herbal medicine hair dyed agent |
| CN101889968A (en) * | 2009-05-22 | 2010-11-24 | 李哲 | Hair blacking medicine for combing |
| CN102166173B (en) * | 2011-03-08 | 2012-11-28 | 贵州阿斯科科技开发有限公司 | Ecological plant hair dye and preparation method thereof |
| CN109431934B (en) * | 2018-11-28 | 2021-11-09 | 山东师范大学 | Pricklyash seed hair sun-screening agent and preparation method thereof |
| CN109674732A (en) * | 2019-03-07 | 2019-04-26 | 宋子奎 | A kind of indigo darkener and hair dyeing technique |
| CN109984989A (en) * | 2019-05-16 | 2019-07-09 | 杨灼银 | A kind of Chinese medicine compound prescription hair dye and preparation method thereof and application method |
-
2020
- 2020-06-23 CN CN202010577475.2A patent/CN111603430B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN111603430A (en) | 2020-09-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110420143B (en) | A gel containing herba seu radix Clerodenri Cyrtophylli extract and its preparation method | |
| CN111821238A (en) | Moisturizing cream capable of relieving, repairing and brightening | |
| CN110664650A (en) | Multi-effect skin care composition and essence and preparation method thereof | |
| CN104586727A (en) | Anti-radiation plant-tea oil water replenishing liquid | |
| CN111603430B (en) | Hair dye for physically dyeing hair by using plant extracts and natural pigments and preparation method thereof | |
| CN110946797A (en) | Abelmoschus manihot sun repair gel sleeping mask and preparation method thereof | |
| CN110613676A (en) | Chitosan marine peptide crystal facial mask | |
| CN101032456B (en) | Hairdressing combination made of natural vegetable and preparing method thereof | |
| CN113662890A (en) | Antioxidant whitening composition and preparation method thereof | |
| CN111012684B (en) | Anti-allergic hair dye and preparation method thereof | |
| CN107823004A (en) | Plant composition with anti-sunlight function and its application in sunscreen product | |
| CN112426399A (en) | Plant shampoo and preparation method thereof | |
| CN108014056A (en) | Skin relaxes liquid living and method | |
| CN104825359A (en) | Method for preparing natural hair dye from black plum peels | |
| CN111603427A (en) | Whitening and relieving mask | |
| CN113069383A (en) | Collagen needle self-repairing medical mask and preparation method thereof | |
| CN114569523A (en) | Anti-wrinkle skin care product containing double-extraction protein and using method | |
| CN112870141A (en) | Edible natural plant skin-care mask lotion and preparation method thereof | |
| CN110090193B (en) | Acne-removing moisturizing essence with fat-reducing effect and preparation method thereof | |
| CN106819280A (en) | Health tea formula prepared by a kind of use Tongkat Ali, Momordica grosvenori | |
| CN112545969A (en) | Compound traditional Chinese medicine mask for moisturizing and removing acne and preparation method thereof | |
| CN110974748A (en) | Hair nourishing liquid and preparation method thereof | |
| CN109331074B (en) | Traditional Chinese medicine composition with anti-aging effect and preparation method and application thereof | |
| CN110638730A (en) | Moistening and nourishing essence and preparation method thereof | |
| CN108703924A (en) | A kind of plant Shu Min Essences and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |