CN111545034A - 一种硫化氢清洗除臭剂及其制备、使用方法 - Google Patents
一种硫化氢清洗除臭剂及其制备、使用方法 Download PDFInfo
- Publication number
- CN111545034A CN111545034A CN202010406751.9A CN202010406751A CN111545034A CN 111545034 A CN111545034 A CN 111545034A CN 202010406751 A CN202010406751 A CN 202010406751A CN 111545034 A CN111545034 A CN 111545034A
- Authority
- CN
- China
- Prior art keywords
- cleaning
- hydrogen sulfide
- agent
- deodorant
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 113
- 239000002781 deodorant agent Substances 0.000 title claims abstract description 69
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title claims abstract description 59
- 229910000037 hydrogen sulfide Inorganic materials 0.000 title claims abstract description 59
- 238000000034 method Methods 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 238000005260 corrosion Methods 0.000 claims abstract description 28
- 230000007797 corrosion Effects 0.000 claims abstract description 28
- 239000002738 chelating agent Substances 0.000 claims abstract description 24
- 239000003112 inhibitor Substances 0.000 claims abstract description 24
- 239000002270 dispersing agent Substances 0.000 claims abstract description 23
- 239000012459 cleaning agent Substances 0.000 claims abstract description 21
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 20
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 18
- 230000003009 desulfurizing effect Effects 0.000 claims abstract description 17
- 239000007788 liquid Substances 0.000 claims abstract description 17
- 238000007670 refining Methods 0.000 claims description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 238000007599 discharging Methods 0.000 claims description 7
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- 238000007865 diluting Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 6
- 238000005303 weighing Methods 0.000 claims description 6
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 4
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 239000000344 soap Substances 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims description 3
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 3
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 3
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 3
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 3
- 229940048086 sodium pyrophosphate Drugs 0.000 claims description 3
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 3
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- DDAQLPYLBPPPRV-UHFFFAOYSA-N [4-(hydroxymethyl)-2-oxo-1,3,2lambda5-dioxaphosphetan-2-yl] dihydrogen phosphate Chemical compound OCC1OP(=O)(OP(O)(O)=O)O1 DDAQLPYLBPPPRV-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 14
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 abstract description 8
- 239000000126 substance Substances 0.000 abstract description 7
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 abstract description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract description 3
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 abstract description 3
- 150000001412 amines Chemical class 0.000 abstract description 3
- 230000003115 biocidal effect Effects 0.000 abstract description 3
- 229910052804 chromium Inorganic materials 0.000 abstract description 3
- 239000011651 chromium Substances 0.000 abstract description 3
- 238000002485 combustion reaction Methods 0.000 abstract description 3
- 239000003344 environmental pollutant Substances 0.000 abstract description 3
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 3
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- 239000010802 sludge Substances 0.000 abstract description 3
- 230000002269 spontaneous effect Effects 0.000 abstract description 3
- 241000894006 Bacteria Species 0.000 abstract description 2
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- 230000001804 emulsifying effect Effects 0.000 abstract description 2
- 239000002699 waste material Substances 0.000 abstract description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 239000011572 manganese Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 10
- 239000000049 pigment Substances 0.000 description 4
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000003446 ligand Substances 0.000 description 3
- 231100000252 nontoxic Toxicity 0.000 description 3
- 230000003000 nontoxic effect Effects 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000007667 floating Methods 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- 238000002798 spectrophotometry method Methods 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 208000006069 Corneal Opacity Diseases 0.000 description 1
- 206010011224 Cough Diseases 0.000 description 1
- 208000004232 Enteritis Diseases 0.000 description 1
- 206010019280 Heart failures Diseases 0.000 description 1
- 206010029216 Nervousness Diseases 0.000 description 1
- 206010029240 Neuritis Diseases 0.000 description 1
- 206010034829 Pharyngeal oedema Diseases 0.000 description 1
- 206010034960 Photophobia Diseases 0.000 description 1
- 206010036105 Polyneuropathy Diseases 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 206010006451 bronchitis Diseases 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 230000009920 chelation Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000010668 complexation reaction Methods 0.000 description 1
- 231100000269 corneal opacity Toxicity 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 208000035475 disorder Diseases 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 206010014801 endophthalmitis Diseases 0.000 description 1
- 125000005313 fatty acid group Chemical group 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229960000907 methylthioninium chloride Drugs 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 208000019629 polyneuritis Diseases 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/361—Phosphonates, phosphinates or phosphonites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/362—Phosphates or phosphites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/02—Compositions of detergents based essentially on soap on alkali or ammonium soaps
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/06—Inorganic compounds
- C11D9/08—Water-soluble compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/06—Inorganic compounds
- C11D9/08—Water-soluble compounds
- C11D9/10—Salts
- C11D9/14—Phosphates; Polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/30—Organic compounds, e.g. vitamins containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/34—Organic compounds, e.g. vitamins containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/20—Industrial or commercial equipment, e.g. reactors, tubes or engines
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
本发明公开了一种硫化氢清洗除臭剂，所述清洗除臭剂包括下述原料：分散剂、螯合剂、有机缓蚀剂、脱硫剂、清洗剂、乳化剂和水。本发明的有益效果为：本发明所述硫化氢清洗除臭剂可有效清除硫化氢、氨氮、硫醇、有机胺等污染物，能有效防止硫化亚铁自燃，具有良好的除油效果，轻油乳化能力大于50g/l，解决了一般硫化亚铁清洗钝化剂不能除油垢的难题，本发明所述清洗除臭剂具有良好的除臭钝化效果，可避免对需清洗装置和环境的破坏。所述硫化氢清洗除臭剂不含铬、锰等重金属元素，不存在杀生性物质，在清洗过程对环境不会造成污染，排出的清洗废液不会杀灭或抑制污水处理单元活性菌的活性，且对活性污泥安全，易于降解对环境无污染。
Description
技术领域
本发明涉及石油化工技术领域，具体涉及一种高效、环保、无毒、清洗效果好且对装备和环境无损害的硫化氢清洗除臭剂及其制备、使用方法。
背景技术
炼油装置长周期运行后，在塔、换热器、容器、管线等设备的表面会沉积大量油泥、油浆、渣油、催化剂粉尘及FeS、H2S等有毒有害有味物质，在装置停工吹扫及检修打开设备时会散发出恶臭，有时会发生硫化亚铁自燃，即污垢的存在不仅容易引发安全事故和设备事故，给以后的生产和现场安全施工留下隐患，因此应定期对装置进行清洗。
硫化氢是具有臭鸡蛋气味的气体，低浓度时，它能引起眼炎、眼部分泌物增多，角膜混浊畏光，易发生支气管炎、咳嗽甚至咽部水肿；如长期吸硫化氢会导致人体质变弱、抵抗力下降，易发生肠炎、心脏衰弱、神经紊乱、多发性神经炎症等，目前对单台设备清洗应用较多，但关于系统清洗的研究报道比较少；常用的炼油装置清洗方法为蒸汽吹扫法，蒸汽吹扫法费用低，对设备无腐蚀作用，但是清洗时间较长效果较差。
发明内容
本发明的目的是提供一种高效、环保、无毒、清洗效果好且对装备和环境无损害的硫化氢清洗除臭剂及其制备、使用方法。
一种硫化氢清洗除臭剂，包括分散剂、螯合剂、有机缓蚀剂、脱硫剂、清洗剂、乳化剂和水，其中分散剂的重量百分比为5％-10％、螯合剂的重量百分比为10％-15％、有机缓蚀剂的重量百分比为10％-15％、脱硫剂的重量百分比为20％-25％、清洗剂的重量百分比为10％-15％、乳化剂的重量百分比为5％-10％、余量为水。
优选地，分散剂的重量百分比为6％-8％、螯合剂的重量百分比为12％-14％、有机缓蚀剂的重量百分比为12％-14％、脱硫剂的重量百分比为22％-24％、清洗剂的重量百分比为12％-14％、乳化剂的重量百分比为6％-8％、余量为水。
优选地，分散剂的重量百分比为7％、螯合剂的重量百分比为13％、有机缓蚀剂的重量百分比为13％、脱硫剂的重量百分比为23％、清洗剂的重量百分比为13％、乳化剂的重量百分比为7％、余量为水。
本发明所述硫化氢清洗除臭剂所含各原料可与硫化氢、硫化亚铁、氨氮、硫醇、有机胺等污染物发生中和、鳌合、络合等反应，达到清除污染、恶臭、清除硫化亚铁，且不会腐蚀设备，起到保护环境及设备、人身安全的效果。
优选地，所述分散剂为六偏磷酸钠、三聚磷酸钠、焦磷酸钠的至少一种。
优选地，所述螯合剂为柠檬酸、乙二胺四乙酸的至少一种。
优选地，所述有机缓蚀剂为羟基乙叉二磷酸HEDP、膦酸的至少一种。
优选地，所述脱硫剂为碳酸钠、N-甲基二乙醇胺的至少一种；所述清洗剂为乙醇胺、工业酒精、片碱的至少一种；所述乳化剂为十二烷基苯磺酸钠、十二烷基硫酸钠、脂肪酸钾皂的至少一种。
分散剂具有较好的分散性和优异的高温稳定性。其作用是使用润湿分散剂减少完成分散过程所需要的时间和能量，稳定所分散的颜料分散体，改性颜料粒子表面性质，调整颜料粒子的运动性，具体体现在以下几个方面：缩短分散时间，提高光泽，提高着色力和遮盖力，改善展色性和调色性，防止浮色发花，防止絮凝，防止沉降。
螯合剂又称螯合配体、螯合集团或多齿配体，配体中有两个或两个以上配位原子，且同时与一个中心原子形成螯合环。在化学工业和工业生产过程中，加入螯合剂使金属离子生成性质完全不同的螯合物，是降低和控制金属离子浓度的主要方法。
有机缓蚀剂，缓蚀剂是常见的保护金属材料不被腐蚀的产品，按照化学成分划分，缓蚀剂主要有效成分为有机物，因此称之为有机缓蚀剂。
脱硫剂一般指脱除燃料、原料或其他物料中的游离硫或硫化合物的药剂。
清洗剂由表面活性剂和各种助剂、辅助剂配制成的，在洗涤物体表面上的污垢时，能降低水溶液的表面张力，提高去污效果的物质。
所述硫化氢清洗除臭剂的制备方法为：按上述重量百分比称取各原料混合搅拌均匀，得所述硫化氢清洗除臭剂。
所述硫化氢清洗除臭剂的使用方法，包括以下步骤：
(1)用水稀释所述除臭剂，得清洗液；
(2)在需被清洗的炼油装置上连接临时管路，使其成为循环体系；按照需清洗装置的原物料运转流程将清洗液依次运送到各个反应装置对炼油装置进行清洗，待清洗完毕，拆除临时管路，排出清洗液。
将清洗液注入待清洗装置，按照需清洗装置的原物料运转流程对装置设备进行清洗，待流转完毕，收集由装置出料口流出的清洗液，在循环泵的作用下，将收集所得清洗液再次注入待清洗装置，对需清洗装置进行循环清洗。
因循环清洗后的清洗液不含有锰、铬等重金属离子，不含有杀生性物质，且无毒无害，此外本发明所述除臭剂易于生物降解，待使用后可直接排放，对环境不会造成污染。
优选地，步骤(1)中，所用水的量与所述除臭剂的重量比为10-12:1；步骤(2)中，清洗液在炼油装置中循环清洗的时间为8-12h。
本发明的有益效果：
本发明所述硫化氢清洗除臭剂,可有效清除硫化氢、氨氮、硫醇、有机胺等污染物，能有效防止硫化亚铁自燃，具有良好的除油效果，轻油乳化能力大于50g/l，解决了一般硫化亚铁清洗钝化剂不能除油垢的难题，本发明所述清洗除臭剂具有良好的除臭钝化效果，可避免对需清洗装置和环境的破坏。
本发明所述硫化氢清洗除臭剂不含铬、锰等重金属元素，不存在杀生性物质，在清洗过程对环境不会造成污染，排出的清洗废液不会杀灭或抑制污水处理单元活性菌的活性，且对活性污泥安全，易于降解对环境无污染。
本发明所述硫化氢清洗除臭剂的使用较安全。使用所述清洗除臭剂清洗施工过程中不产生有毒有害物质，不会发生暴沸或突沸现象；对设备的腐蚀率较低，使用时对碳钢设备腐蚀率小于2.0g/m2·h，对不锈钢设备腐蚀率小于1.0g/m2·h。
本发明所述硫化氢清洗除臭剂使用较方便，在使用时，无需改动待清洗装置的工艺流程，便可实现对整个装置设备的清洗，且集清洗钝化一体，减少了清洗液的使用量、缩短了清洗时间、保证了检修时间统筹。
具体实施方式
为使本发明的目的、技术方案和优点更加清楚，下面将对本发明的技术方案进行详细的描述。显然，所描述的实施例仅仅是本发明的一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动的前提下所得到的所有其它实施方式，都属于本发明所保护的范围。
实施例1
一种硫化氢清洗除臭剂，包括分散剂、螯合剂、有机缓蚀剂、脱硫剂、清洗剂、乳化剂和水，其中分散剂的重量百分比为5％、螯合剂的重量百分比为10％、有机缓蚀剂的重量百分比为10％、脱硫剂的重量百分比为20％、清洗剂的重量百分比为10％、乳化剂的重量百分比为5％、余量为水。
所述硫化氢清洗除臭剂的制备方法为：按上述重量百分比称取各原料混合搅拌均匀，得所述硫化氢清洗除臭剂。
所述硫化氢清洗除臭剂的使用方法，包括以下步骤：
(1)用水稀释所述除臭剂得清洗液，所用水的量与所述除臭剂的重量比为：10:1；
(2)在需被清洗的炼油装置上连接临时管路，使其成为循环体系；按照需清洗装置的原物料运转流程将清洗液依次运送到各个反应装置对炼油装置清洗8h，待清洗完毕，拆除临时管路，排出清洗液。
实施例2
一种硫化氢清洗除臭剂，包括分散剂、螯合剂、有机缓蚀剂、脱硫剂、清洗剂、乳化剂和水，其中分散剂的重量百分比为6％、螯合剂的重量百分比为12％、有机缓蚀剂的重量百分比为12％、脱硫剂的重量百分比为22％、清洗剂的重量百分比为12％、乳化剂的重量百分比为6％、余量为水；
本实施例中，所用分散剂为六偏磷酸钠；所用螯合剂为柠檬酸；所用有机缓蚀剂为羟基乙叉二磷酸HEDP；所用脱硫剂为碳酸钠；所用清洗剂为乙醇胺；所用乳化剂为十二烷基苯磺酸钠。
所述硫化氢清洗除臭剂的制备方法为：按上述重量百分比称取各原料混合搅拌均匀，得所述硫化氢清洗除臭剂。
所述硫化氢清洗除臭剂的使用方法，包括以下步骤：
(1)用水稀释所述除臭剂得清洗液，所用水的量与所述除臭剂的重量比为：11:1；
(2)在需被清洗的炼油装置上连接临时管路，使其成为循环体系；按照需清洗装置的原物料运转流程将清洗液依次运送到各个反应装置对炼油装置清洗9h，待清洗完毕，拆除临时管路，排出清洗液。
实施例3
一种硫化氢清洗除臭剂，包括分散剂、螯合剂、有机缓蚀剂、脱硫剂、清洗剂、乳化剂和水，其中分散剂的重量百分比为8％、螯合剂的重量百分比为14％、有机缓蚀剂的重量百分比为14％、脱硫剂的重量百分比为24％、清洗剂的重量百分比为14％、乳化剂的重量百分比为8％、余量为水；
本实施例中，所用分散剂为焦磷酸钠；所用螯合剂为乙二胺四乙酸；所用有机缓蚀剂为膦酸；所用脱硫剂为N-甲基二乙醇胺；所用清洗剂为工业酒精、；所用乳化剂为十二烷基硫酸钠。
所述硫化氢清洗除臭剂的制备方法为：按上述重量百分比称取各原料混合搅拌均匀，得所述硫化氢清洗除臭剂。
所述硫化氢清洗除臭剂的使用方法，包括以下步骤：
(1)用水稀释所述除臭剂得清洗液，所用水的量与所述除臭剂的重量比为：10:1；
(2)在需被清洗的炼油装置上连接临时管路，使其成为循环体系；按照需清洗装置的原物料运转流程将清洗液依次运送到各个反应装置对炼油装置清洗10h，待清洗完毕，拆除临时管路，排出清洗液。
实施例4
一种硫化氢清洗除臭剂，包括分散剂、螯合剂、有机缓蚀剂、脱硫剂、清洗剂、乳化剂和水，其中分散剂的重量百分比为10％、螯合剂的重量百分比为15％、有机缓蚀剂的重量百分比为15％、脱硫剂的重量百分比为25％、清洗剂的重量百分比为15％、乳化剂的重量百分比为10％、余量为水；
本实施例中，所用分散剂为三聚磷酸钠；所用螯合剂为乙二胺四乙酸；所用有机缓蚀剂为羟基乙叉二磷酸HEDP；所用脱硫剂为N-甲基二乙醇胺；所用清洗剂为片碱；所用乳化剂为脂肪酸钾皂。
所述硫化氢清洗除臭剂的制备方法为：按上述重量百分比称取各原料混合搅拌均匀，得所述硫化氢清洗除臭剂。
所述硫化氢清洗除臭剂的使用方法，包括以下步骤：
(1)用水稀释所述除臭剂得清洗液，所用水的量与所述除臭剂的重量比为：12:1；
(2)在需被清洗的炼油装置上连接临时管路，使其成为循环体系；按照需清洗装置的原物料运转流程将清洗液依次运送到各个反应装置对炼油装置清洗12h，待清洗完毕，拆除临时管路，排出清洗液。
对比例1
对比例1所述硫化氢清洗除臭剂，所用螯合剂的重量百分比为8％，其余原料、重量份及制备和使用方法均与实施例2相同。
对比例2
对比例2所述硫化氢清洗除臭剂，所用螯合剂的重量百分比为18％，其余原料、重量份及制备和使用方法均与实施例2相同。
对比例3
对比例3所述硫化氢清洗除臭剂，所用分散剂的重量百分比为3％，其余原料、重量份及制备和使用方法均与实施例2相同。
本发明所述硫化氢清洗除臭剂的技术指标如表1所示：
表1硫化氢清洗除臭剂的技术指标
本发明所述硫化氢清洗除臭剂符合国家标准和行业标准的要求。
本发明所述硫化氢清洗除臭剂的清洗效果研究：
检测方法：在污染程度相当需被清洗的6台设备中补充一定量的水，再把该除臭剂加入到被清洗设备中，根据设备内硫化氢、硫化亚铁和氨氮的量使其浓度维持在5％～10％，用外部清洗泵或设备本身动力使清洗液循环运行，8～12小时后停止清洗，将清洗液排放到污水井中，用水清洗。
检测方法参见：GBT-16489-1996-水质-硫化物的测定-亚甲基蓝分光光度法；HJ535-2009氨氮的测定-纳氏试剂分光光度法
表2硫化氢清洗除臭剂的清洗效果研究
| 项目 | 清洗效果 |
| 实施例1 | 系统表面清洁、无异味、无恶臭味 |
| 实施例2 | 系统表面清洁、无明显异味、无恶臭味 |
| 实施例3 | 系统表面清洁、无异味、无恶臭味 |
| 实施例4 | 系统表面清洁、无明显异味、无恶臭味 |
| 对比例1 | 系统表面清洁、有明显异味 |
| 对比例2 | 系统表面有少量污垢、有明显异味 |
| 对比例3 | 系统表面有少量污垢、有明显恶臭味 |
从表2可以看出，本申请实施例1-4所述硫化氢清洗除臭剂的清洗效果优于对比例1-3所述硫化氢清洗除臭剂的清洗效果。
本发明不局限于上述最佳实施方式，任何人在本发明的启示下都可得出其他各种形式的产品，但不论在其细节上作任何变化，凡是具有与本申请相同或相近似的技术方案，均落在本发明的保护范围之内。
Claims (10)
1.一种硫化氢清洗除臭剂，其特征在于，包括分散剂、螯合剂、有机缓蚀剂、脱硫剂、清洗剂、乳化剂和水，其中分散剂的重量百分比为5％-10％、螯合剂的重量百分比为10％-15％、有机缓蚀剂的重量百分比为10％-15％、脱硫剂的重量百分比为20％-25％、清洗剂的重量百分比为10％-15％、乳化剂的重量百分比为5％-10％、余量为水。
2.根据权利要求1所述硫化氢清洗除臭剂，其特征在于，分散剂的重量百分比为6％-8％、螯合剂的重量百分比为12％-14％、有机缓蚀剂的重量百分比为12％-14％、脱硫剂的重量百分比为22％-24％、清洗剂的重量百分比为12％-14％、乳化剂的重量百分比为6％-8％、余量为水。
3.根据权利要求1所述硫化氢清洗除臭剂，其特征在于，分散剂的重量百分比为7％、螯合剂的重量百分比为13％、有机缓蚀剂的重量百分比为13％、脱硫剂的重量百分比为23％、清洗剂的重量百分比为13％、乳化剂的重量百分比为7％、余量为水。
4.根据权利要求1所述硫化氢清洗除臭剂，其特征在于，所述分散剂为六偏磷酸钠、三聚磷酸钠、焦磷酸钠的至少一种。
5.根据权利要求1所述硫化氢清洗除臭剂，其特征在于，所述螯合剂为柠檬酸、乙二胺四乙酸的至少一种。
6.根据权利要求1所述硫化氢清洗除臭剂，其特征在于，所述有机缓蚀剂为羟基乙叉二磷酸HEDP、膦酸的至少一种。
7.根据权利要求1所述硫化氢清洗除臭剂，其特征在于，所述脱硫剂为碳酸钠、N-甲基二乙醇胺的至少一种；所述清洗剂为乙醇胺、工业酒精、片碱的至少一种；所述乳化剂为十二烷基苯磺酸钠、十二烷基硫酸钠、脂肪酸钾皂的至少一种。
8.权利要求1-7任一项所述硫化氢清洗除臭剂的制备方法，其特征在于，按上述重量百分比称取各原料混合搅拌均匀，得所述硫化氢清洗除臭剂。
9.权利要求1-7任一项所述硫化氢清洗除臭剂的使用方法，其特征在于，包括以下步骤：
(1)用水稀释所述除臭剂，得清洗液；
(2)在需被清洗的炼油装置上连接临时管路，使其成为循环体系；按照需清洗装置的原物料运转流程将清洗液依次运送到各个反应装置对炼油装置进行清洗，待清洗完毕，拆除临时管路，排出清洗液。
10.根据权利要求9所述硫化氢清洗除臭剂的使用方法，其特征在于，步骤(1)中，所用水的量与所述除臭剂的重量比为10-12:1；步骤(2)中，清洗剂在炼油装置中循环清洗的时间为8-12h。
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