CN111529459A

CN111529459A - Hair conditioner composition, silicone oil-free shampoo and preparation method thereof

Info

Publication number: CN111529459A
Application number: CN202010582240.2A
Authority: CN
Inventors: 牟维林; 邹鹏飞; 于建伟; 陶宇; 赵乐荣; 隋海松; 唐文金; 毕利顺; 杜可欣
Original assignee: Yantai New Era Health Industry Daily Chemical Co ltd
Current assignee: Yantai New Era Health Industry Daily Chemical Co ltd
Priority date: 2020-06-23
Filing date: 2020-06-23
Publication date: 2020-08-14

Abstract

The invention discloses a hair conditioner composition, which comprises 30-50 parts of mixed extract, 30-50 parts of walnut oil and 20-40 parts of hemp seed oil according to parts by weight; the mixed extract is the mixed extract of the green plum blossom and the pine pollen. The invention also discloses silicone oil-free shampoo containing the hair conditioner composition and a preparation method of the silicone oil-free shampoo. The conditioner composition is completely vegetable oil, has the characteristics of greenness and mildness, and has the effect of removing dandruff. The extracts of the green plum blossom and the pine pollen in the composition have a synergistic effect, and the shampoo prepared by taking the extracts as raw materials has no sticky feeling, has the characteristics of smoothness and luster of a silicone oil conditioner, and is an ideal silicone oil substitute containing plant components.

Description

Hair conditioner composition, silicone oil-free shampoo and preparation method thereof

Technical Field

The invention belongs to the technical field of daily chemicals, and relates to a hair conditioner composition, a silicone oil-free shampoo and a preparation method thereof.

Background

The silicone oil is widely applied to hair washing and caring products because the silicone oil can be adsorbed on the surface of hair, so that the hair is smoothed and glossy. However, more and more experts suspect that silicone oil may block pores, causing scalp irritation.

Therefore, the shampoo without silicone oil rises rapidly in recent years, and at present, polyethylene glycol, PPG-3 octyl ether or single vegetable oil is mostly adopted for the shampoo without silicone oil to replace the silicone oil, but the conditioning effect of the silicone oil cannot be achieved, and scalp itching can be caused. The daily industry is seeking better silicone oil substitutes.

Disclosure of Invention

Aiming at the defects in the prior art, the invention provides a hair conditioner composition, a silicone oil-free shampoo and a preparation method thereof. In the invention, plants rich in grease are screened, and the obtained hair conditioner composition is applied to shampoo to replace silicone oil through matching and combination, thereby playing the roles of smoothing hair scales and lubricating hair.

The specific technical scheme is as follows:

it is an object of the present invention to provide a hair conditioner composition.

A hair conditioner composition comprises, by weight, 30-50 parts of a mixed extract, 30-50 parts of walnut oil and 20-40 parts of hemp seed oil;

the mixed extract is the mixed extract of the green plum blossom and the pine pollen.

In the invention, the mixed extract of the green plum blossom and the pine pollen has the functions of smoothing hair and smoothing hair scales, and the efficacy of the mixed extract is obviously superior to that of a formula without the mixed extract.

The grease component of the walnut is as high as 65-70%, and the walnut oil is rich in squalene with excellent affinity with skin and essential fatty acid for human body, can be quickly absorbed by scalp, and effectively care and care hair.

As the original producing area of green plums, China has abundant green plum resources, but the utilization of green plums in China is mainly concentrated on the food industry, and the utilization market of non-fruit parts of green plums such as green plums is relatively lacked, so that the resource waste is caused in the flowering phase every year. The plum blossom is rich in lipids (mainly neutral lipids), and the plum blossom extract is found to have a good conditioning effect on hair in the earlier research of the invention.

Pollen pini is a pollen used as both medicine and food, is a traditional medicinal material which has been used for thousands of years, is rich in more than 200 nutrient components, and is known as a micro nutrient bank. The oil and fat components are also rich. In the earlier researches of the invention, the lipid component in the pine pollen has a good conditioning effect on hair.

The hemp seed oil is an oil squeezed from dry mature hemp seeds of a plant hemp of Moraceae, is an industrial hemp product which is popular in recent years, mainly contains monounsaturated fatty acid and polyunsaturated fatty acid, has excellent lubricating and conditioning effects, is very suitable for hair washing and caring products, has antibacterial and anti-inflammatory effects, and has a certain effect on inhibiting dandruff. In addition, there are history records, in famous physicians' book "long hair is used as bath medicine" and "simple and easy sanitary prescription" one liter of Ma Zi is used, and if the head is pressed, the hair grows gradually. It also has certain hair growth promoting effect.

Further, the preparation method of the mixed extract comprises the following steps:

(1) crushing the dried green plum blossom and the pine pollen;

(2) mixing the crushed dry flos mume and pollen Pini, performing ultrasonic reflux extraction, and filtering;

(3) and filtering again to obtain secondary filtrate.

Still further, the working conditions of the step (2) are as follows:

mixing the crushed dry green plum blossom flowers and pollen pini according to a mass ratio of 1: (3-6) mixing, and performing ultrasonic reflux extraction at 55-70 ℃; extracting twice by adopting GTCC as an extracting agent, wherein the dosage of the extracting agent is 5-8 times of the total weight of the plum blossom dry flower and the pine pollen each time; the two filtrates were combined.

GTCC is caprylic/capric triglyceride, INCI name: CAPRYLIC/CAPRIC TRIGLYCERIDE.

Still further, the working conditions of the step (1) are as follows:

grinding the dried green plum blossom into powder by using a grinder; breaking cell wall of pollen Pini with supersonic collision machine.

Still further, in the step (3), phenoxyethanol is added to the secondary filtrate in an amount of 0.2 to 0.5 wt% based on the mass thereof.

Another object of the present invention is to provide a silicone-free shampoo comprising the above hair conditioner composition, wherein the formulation comprises:

hair conditioner composition: 1-3 wt%, sodium methyl cocoyl taurate: 8-14 wt%, sodium laureth sulfate (AES): 5-10 wt%, lauryl glycoside: 3-6 wt%, cocamidopropyl betaine: 3 wt% -6 wt%, glycerin: 0.2 wt% -1 wt%, propylene glycol: 0.2 wt% -1 wt%, polyquaternium-10: 0.1 wt% -0.3wt guar hydroxypropyltrimonium chloride: 0.1 wt% -0.3 wt%, anhydrous citric acid: 0.01 wt% -0.05 wt%, sodium chloride: 0.1 wt% -0.8 wt%, hair conditioner: 1-3 wt%, preservative: 0.1 wt% -0.3 wt%, essence: 0.1 to 0.3 weight percent, and the balance of water.

The third purpose of the invention is to provide a preparation method of the silicone oil-free shampoo, which comprises the following steps:

adding polyquaternium-10, guar gum hydroxypropyl trimethyl ammonium chloride and anhydrous citric acid into water, stirring for 10-20min, adding sodium methyl cocoyl taurate and sodium laureth sulfate after swelling is complete, heating to 75-90 ℃, stirring for dissolving, keeping the temperature for 5-10min, sequentially adding cocamidopropyl betaine, lauryl glucoside, glycerol and propylene glycol, stirring for completely dissolving, keeping the temperature for 10-20min, cooling to below 45 ℃, and sequentially adding sodium chloride, a hair conditioner, a preservative and essence.

The water loss generated in the preparation process can be supplemented to the formula amount after cooling.

The invention has the following beneficial effects:

the conditioner composition is completely vegetable oil, has the characteristics of greenness and mildness, and has the effect of removing dandruff. The extracts of the green plum blossom and the pine pollen in the composition have a synergistic effect, and the shampoo prepared by taking the extracts as raw materials has no sticky feeling, has the characteristics of smoothness and luster of a silicone oil conditioner, and is an ideal silicone oil substitute containing plant components. GTCC is grease commonly used for washing and caring hair products, has the effect of nourishing hair, is used as an extracting agent to squeeze grease components in the plum blossom and the pollen pini, is simple to operate, and does not introduce other impurities. The composition can also be used in a hair washing and caring product of a silicone oil system, has a synergistic interaction effect, and has a better using effect.

Drawings

FIG. 1 shows the results of the wet combing performance test of each group in experiment 1;

FIG. 2 shows the results of the dry comb performance test of each group in experiment 1.

Detailed Description

The principles and features of this invention are described below in conjunction with examples, which are set forth to illustrate, but are not to be construed to limit the scope of the invention.

The GTCC manufacturers used in the examples were Heda chemical Co., Ltd;

example 1

1. Preparation of hair conditioner composition: a hair conditioner composition comprises 30 parts of mixed extract, 50 parts of walnut oil and 20 parts of hemp seed oil according to parts by weight; the mixed extract is the mixed extract of the green plum blossom and the pine pollen.

The preparation method of the mixed extract comprises the following steps:

(1) grinding the dried green plum blossom into powder by using a grinder; breaking cell wall of pollen Pini with supersonic collision machine.

(2) Mixing the crushed dry green plum blossom flowers and pollen pini according to a mass ratio of 1: 3 mixing, and performing ultrasonic reflux extraction at 60 ℃; extracting twice by adopting GTCC as an extracting agent for 2 hours each time, wherein the dosage of the extracting agent for each time is 8 times of the total weight of the plum blossom dry flower and the pine pollen; each extraction was followed by filtration through slow setting filter paper and the two filtrates were combined.

(3) Filtering the filtrate obtained in step (2) with slow qualitative filter paper to obtain secondary filtrate, and adding 0.2 wt% phenoxyethanol calculated by the secondary filtrate to obtain mixed solution extract.

(4) And mixing the mixed liquid extract with walnut oil and hemp seed oil according to a formula to obtain the hair conditioner composition.

2. Preparing a silicone oil-free shampoo containing the hair conditioner composition obtained in the step (3), wherein the formula is as follows:

hair conditioner composition: 3 wt%, sodium methyl cocoyl taurate: 14 wt%, sodium laureth sulfate: 5 wt%, lauryl glycoside: 3 wt%, cocamidopropyl betaine: 6 wt%, glycerin: 0.5 wt%, propylene glycol 0.5 wt%, polyquaternium-10: 0.1 wt%, guar gum hydroxypropyl trimethyl ammonium chloride: 0.3 wt%, anhydrous citric acid: 0.03 wt%, sodium chloride: 0.3 wt%, preservative: 0.1 wt%, essence: 0.1 wt%, and the balance being water.

The preparation method of the silicone oil-free shampoo comprises the following steps:

adding polyquaternium-10, guar gum hydroxypropyl trimethyl ammonium chloride and anhydrous citric acid into water, stirring for 15min, adding sodium methyl cocoyl taurate and sodium lauryl polyether sulfate after swelling is complete, heating to 85 ℃, stirring for dissolving, keeping the temperature for 10min, sequentially adding cocamidopropyl betaine, lauryl glucoside, glycerol and propylene glycol, stirring for completely dissolving, keeping the temperature for 15min, cooling to below 45 ℃, sequentially adding sodium chloride, a hair conditioner, a preservative and essence, and supplementing the water loss in the preparation.

Example 2

1. Preparation of hair conditioner composition: a hair conditioner composition comprises 40 parts of mixed extract, 30 parts of walnut oil and 30 parts of hemp seed oil according to parts by weight; the mixed extract is the mixed extract of the green plum blossom and the pine pollen.

The preparation method of the mixed extract comprises the following steps:

(2) Mixing the crushed dry green plum blossom flowers and pollen pini according to a mass ratio of 1: 5 mixing, and performing ultrasonic reflux extraction at 60 ℃; extracting twice by adopting GTCC as an extracting agent for 2 hours each time, wherein the dosage of the extracting agent for each time is 6 times of the total weight of the plum blossom dry flower and the pine pollen; each extraction was followed by filtration using slow qualitative filter paper and the two filtrates were combined.

(3) Filtering the filtrate obtained in step (2) with slow qualitative filter paper to obtain secondary filtrate, and adding 0.4 wt% phenoxyethanol calculated by the secondary filtrate to obtain mixed solution extract.

hair conditioner composition: 1 wt%, sodium methyl cocoyl taurate: 8 wt%, sodium laureth sulfate: 10 wt%, lauryl glycoside: 6 wt%, cocamidopropyl betaine: 3 wt%, glycerin: 1 wt%, propylene glycol 0.2 wt%, polyquaternium-10: 0.3 wt%, guar gum hydroxypropyl trimethyl ammonium chloride: 0.1 wt%, anhydrous citric acid: 0.01 wt%, sodium chloride: 0.6 wt%, preservative: 0.1 wt%, essence: 0.1 wt%, and the balance being water.

The preparation method of the silicone oil-free shampoo is the same as that of the example 1.

Comparative example 1

Comparative example 1 differs from example 1 in that no hair conditioner composition is added to the shampoo.

The remaining technical features are the same as those of example 1.

Comparative example 2

Comparative example 2 is different from example 1 in that the hair conditioner does not contain a mixed extract, i.e., the hair conditioner composition is formulated with 50 parts of walnut oil and 20 parts of hemp oil.

The remaining technical features are the same as those of example 1.

Comparative example 3

The difference between the comparative example 3 and the example 1 is that the mixed extract does not contain the plum blossom, only contains the pine pollen extract, the extraction method is the same as the example 1, and the dosage of the extracting agent is 8 times of the weight of the pine pollen each time; the content of the components of the mixed extract in the hair conditioner is not changed.

The remaining technical features are the same as those of example 1.

Comparative example 4

The difference between the comparative example 4 and the example 1 is that the mixed extract only contains the plum blossom extract without adding pine pollen, the extraction method is the same as the example 1, and the dosage of the extracting agent is 8 times of the weight of the pine pollen each time; the content of the components of the mixed extract in the hair conditioner is not changed.

The rest of the technical scheme is the same as that of the embodiment 1.

Experiment 1

A hair combing test was performed.

A testing instrument is a tensile testing machine Dia-Stron MTT-175;

the test object is a hair bundle dyed and ironed by Asian people, and the weight of the hair bundle is 10 grams;

a sample to be tested: commercial silicone oil-containing wash water a, example 1, comparative example 2, comparative example 3, comparative example 4;

the test method is as follows:

(1) wetting hair, washing with 5% ammonium lauryl sulfate solution, washing, and repeating for 3 times;

(2) testing the combing force of the wet hair by using a tension tester, repeating for 6 times, and averaging to obtain the maximum value F1 of the combing force of the wet hair and the total combing work W1 of the untreated hair;

(3) placing the hair bundle in a baking oven at 45 ℃ for 1 hour, naturally cooling at room temperature, and then testing the dry combing force to obtain the maximum value F2 and the total combing work W2 of the untreated hair;

(4) washing the same hair with 5% ammonium lauryl sulfate solution for 1 time, and washing with water;

(5) taking 1ml of a commercially available product in the sample to be detected by using a disposable syringe, uniformly spreading the commercially available product on a hair bundle, rubbing and washing the whole hair bundle (to the bottom end) for 30 seconds, standing for 15 seconds, and then washing for 30 seconds by using warm water at 35 ℃;

(6) the combing force test for wet hair was carried out to find the maximum value of the combing force for wet hair F3 and the total combing work W3 for hair using the commercial product A;

(7) the tresses were placed in an oven at 45 ℃ for 1 hour and cooled naturally at room temperature, and then subjected to a dry combing force test to obtain the maximum value of the dry combing force F4 and the total combing force W5 for the hair using the commercial product a;

(8) then using the same hair bundle, replacing the sample to be tested with the shampoo sample in the embodiment 1, the comparative example 2, the comparative example 3 and the comparative example 4 respectively, repeating the steps (4) to (7), and measuring the maximum carding force and the carding total work;

(9) data processing:

maximum combing force reduction,% (maximum combing force after treatment-maximum combing force of untreated hair)/maximum combing force of untreated hair

Total work reduction,% (total work of combing force of treated hair-total work of combing force of untreated hair)/total work of combing force of untreated hair

Negative numbers represent a decrease in the combing force of the hair tresses after treatment as compared to before, indicating that the hair is supple, so the lower the number, the better the effect.

The experimental data are shown in fig. 1 and 2. In fig. 1 and 2, the maximum carding force reduction (%) is shown on the left side and the total work reduction (%) is shown on the right side of each set of data.

FIG. 1 shows the results of various groups of wet combing performance tests;

FIG. 2 shows the results of the dry comb performance test of each group.

As can be seen from the data in the figure, the wet combing performance of the product A in the example 1 is similar to that of the product A in the market, and is obviously better than that of the comparative example 1, the dry combing performance of the product A in the market is slightly better than that of the example 1, and the wet combing performance and the dry combing performance of the product A in the market are obviously better than those of the comparative example 1. Comparative examples 2, 3 and 4, the wet combing and dry combing effects were slightly inferior to those of example 1, indicating that the hair conditioner composition of the present invention has a synergistic effect to significantly improve the conditioning of hair.

Experiment 2

Half head salon test

Sample 1: commercial silicon-containing oil washing water A; sample 2: example 1 sample.

10 hair dyeing and scalding volunteers, 5 men and 5 women, were screened, and the subjects were tried with two samples blindly, and the subjects were laid on a hair-washing deck chair, and half-head tested by professional teachers, according to the same hair-washing method and fixed hair-washing time, 2 minutes for men and 3 minutes for women. The test subject washed hair once at 9 am every day and then washed off with sufficient water, the test subject used sample 1 on the left half and sample 2 on the right half, the two samples were evaluated according to the items in table 1, and the results are summarized in table 2.

The scoring criteria for the effect of use are shown in table 1.

TABLE 1 Scoring standard for shampoo use effect

Table 2 comparison of the use of example 1 with commercially available silicone oil-containing shampoo a

From the results in Table 2, it is clear that the silicone-free shampoo formulation containing the hair conditioner of the present invention has similar effects to the commercially available silicone-containing shampoo formulation, and that the silicone-free shampoo containing the hair conditioner composition of the present invention can achieve the desired effects of smoothing, softening and polishing hair.

Experiment 2

Half head salon test

Sample 1: example 1 sample; sample 2: comparative example 1 sample.

The half-test was performed according to the test method of experiment 2 and scored according to table 1, and the scoring results are shown in table 3.

Table 3 comparison of the use effects of the shampoos of example 1 and comparative example 1

As can be seen from the results in Table 3, the silicone oil-free shampoo containing the hair conditioner of the present invention has a significantly better smooth conditioning performance than the shampoo containing no conditioner.

Experiment 3

Half head salon test

Sample 1: example 1 sample; sample 2: comparative example 2 sample. The half-test was performed as in experiment 2 and scored according to Table 1, with the results shown in Table 4.

Table 4 comparison of usage effects of shampoo of example 1 and comparative example 2

As can be seen from the results in Table 4, the silicone oil-free shampoo containing the hair conditioner of the present invention has a smooth conditioning property significantly superior to the shampoo made of the conditioner without the mixed extract.

Experiment 4

Half head salon test

Sample 1: example 1 sample; sample 2: comparative example 3 sample. The half-test was performed according to the test method of experiment 2 and scored according to table 1, and the scoring results are shown in table 5.

Table 5 comparison of the use effects of the shampoos of example 1 and comparative example 3

From the results in table 5, it can be seen that the smooth conditioning performance of the silicone oil-free shampoo containing the hair conditioner of the present invention is significantly better than the shampoo made with the mixed extract without the plum conditioner. And the conditioning agent without the plum blossom in the mixed extract is superior to the conditioning agent without the mixed extract in the conditioning of the shampoo.

Experiment 5

Half head salon test

Sample 1: example 1 sample; sample 2: comparative example 4 sample.

The half-test was performed according to the test method of experiment 2 and scored according to table 1, and the scoring results are shown in table 6.

Table 6 comparison of usage effects of shampoo of example 1 and comparative example 4

From the results in table 6, it can be seen that the smoothness conditioning performance of the silicone oil-free shampoo containing the hair conditioner of the present invention is significantly better than that of the shampoo prepared by the conditioner containing no pine pollen in the mixed extract. And the conditioning agent without pine pollen in the mixed extract is superior to the conditioning agent without the mixed extract in the conditioning of the shampoo.

The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that fall within the spirit and principle of the present invention are intended to be included therein.

Claims

1. A hair conditioner composition is characterized by comprising 30-50 parts of mixed extract, 30-50 parts of walnut oil and 20-40 parts of hemp seed oil according to parts by weight;

2. The hair conditioner composition according to claim 1, wherein the method for preparing the mixed extract comprises the steps of:

(1) crushing the dried green plum blossom and the pine pollen;

(3) and filtering again to obtain secondary filtrate.

3. The hair conditioner composition according to claim 2, wherein the working conditions of step (2) are:

4. The hair conditioner composition according to claim 2, wherein the working conditions of step (1) are:

5. The hair conditioner composition according to claim 2, wherein in the step (3), phenoxyethanol is added to the secondary filtrate in an amount of 0.2 to 0.5% by mass thereof.

6. A silicone oil-free shampoo comprising the hair conditioner composition of any of claims 1-5, wherein the formulation comprises:

hair conditioner composition: 1-3 wt%, sodium methyl cocoyl taurate: 8-14 wt%, sodium laureth sulfate: 5-10 wt%, lauryl glycoside: 3-6 wt%, cocamidopropyl betaine: 3 wt% -6 wt%, glycerin: 0.2 wt% -1 wt%, propylene glycol: 0.2 wt% -1 wt%, polyquaternium-10: 0.1 wt% -0.3 wt%, guar gum hydroxypropyl trimethyl ammonium chloride: 0.1 wt% -0.3 wt%, anhydrous citric acid: 0.01 wt% -0.05 wt%, sodium chloride: 0.1 wt% -0.8 wt%, hair conditioner: 1-3 wt%, preservative: 0.1 wt% -0.3 wt%, essence: 0.1 to 0.3 weight percent, and the balance of water.

7. The preparation method of the silicone-oil-free shampoo as defined in claim 6, comprising the following steps: