CN111484246A - Formula and preparation method of cobalt blue porcelain-like glass bottle - Google Patents
Formula and preparation method of cobalt blue porcelain-like glass bottle Download PDFInfo
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- CN111484246A CN111484246A CN202010378682.5A CN202010378682A CN111484246A CN 111484246 A CN111484246 A CN 111484246A CN 202010378682 A CN202010378682 A CN 202010378682A CN 111484246 A CN111484246 A CN 111484246A
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- 239000011521 glass Substances 0.000 title claims abstract description 72
- 239000010941 cobalt Substances 0.000 title claims abstract description 31
- 229910017052 cobalt Inorganic materials 0.000 title claims abstract description 31
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title claims abstract description 31
- 238000009472 formulation Methods 0.000 title claims description 7
- 238000002360 preparation method Methods 0.000 title abstract description 17
- 239000000463 material Substances 0.000 claims abstract description 84
- 239000000843 powder Substances 0.000 claims abstract description 56
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 27
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 22
- 238000000137 annealing Methods 0.000 claims abstract description 22
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 16
- 239000006004 Quartz sand Substances 0.000 claims abstract description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910000428 cobalt oxide Inorganic materials 0.000 claims abstract description 16
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000010459 dolomite Substances 0.000 claims abstract description 15
- 229910000514 dolomite Inorganic materials 0.000 claims abstract description 15
- 238000002844 melting Methods 0.000 claims abstract description 15
- 230000008018 melting Effects 0.000 claims abstract description 15
- 238000004806 packaging method and process Methods 0.000 claims abstract description 15
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 14
- 239000010445 mica Substances 0.000 claims abstract description 14
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 14
- 239000011734 sodium Substances 0.000 claims abstract description 14
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 13
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 13
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 12
- 235000017550 sodium carbonate Nutrition 0.000 claims abstract description 12
- 238000002156 mixing Methods 0.000 claims abstract description 9
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000005751 Copper oxide Substances 0.000 claims abstract description 8
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 8
- 229910000431 copper oxide Inorganic materials 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 8
- 239000006060 molten glass Substances 0.000 claims description 8
- 230000001590 oxidative effect Effects 0.000 claims description 7
- 238000005507 spraying Methods 0.000 claims description 7
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 229910052573 porcelain Inorganic materials 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 5
- 238000009826 distribution Methods 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- YMLFYGFCXGNERH-UHFFFAOYSA-K butyltin trichloride Chemical compound CCCC[Sn](Cl)(Cl)Cl YMLFYGFCXGNERH-UHFFFAOYSA-K 0.000 claims description 4
- 238000000465 moulding Methods 0.000 claims description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 4
- 235000011152 sodium sulphate Nutrition 0.000 claims description 4
- 229910004014 SiF4 Inorganic materials 0.000 claims description 3
- -1 sodium fluorosilicate Chemical compound 0.000 claims description 3
- 230000005587 bubbling Effects 0.000 claims description 2
- 239000000919 ceramic Substances 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 6
- 230000007547 defect Effects 0.000 abstract description 4
- 239000010977 jade Substances 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 description 10
- 241000227425 Pieris rapae crucivora Species 0.000 description 5
- 238000005265 energy consumption Methods 0.000 description 5
- 235000013361 beverage Nutrition 0.000 description 4
- 239000005022 packaging material Substances 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 241001391944 Commicarpus scandens Species 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 2
- 235000013405 beer Nutrition 0.000 description 2
- NPAIMXWXWPJRES-UHFFFAOYSA-N butyltin(3+) Chemical compound CCCC[Sn+3] NPAIMXWXWPJRES-UHFFFAOYSA-N 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000000156 glass melt Substances 0.000 description 2
- 238000009776 industrial production Methods 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052629 lepidolite Inorganic materials 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000000038 blue colorant Substances 0.000 description 1
- 239000003034 coal gas Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000004031 devitrification Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 239000005392 opalescent glass Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 235000012736 patent blue V Nutrition 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 235000015192 vegetable juice Nutrition 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/11—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen
- C03C3/112—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B25/00—Annealing glass products
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
- C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B7/00—Distributors for the molten glass; Means for taking-off charges of molten glass; Producing the gob, e.g. controlling the gob shape, weight or delivery tact
- C03B7/02—Forehearths, i.e. feeder channels
- C03B7/06—Means for thermal conditioning or controlling the temperature of the glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/001—General methods for coating; Devices therefor
- C03C17/003—General methods for coating; Devices therefor for hollow ware, e.g. containers
- C03C17/005—Coating the outside
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/112—Deposition methods from solutions or suspensions by spraying
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a formula and a preparation method of a cobalt blue porcelain-imitating glass bottle, wherein the formula comprises main materials and auxiliary materials, and the main materials comprise: 49-54% of common quartz sand powder, 7-12% of lithium mica powder, 18-19% of soda ash, 9-13% of calcite powder and 4-8% of dolomite powder; the auxiliary materials comprise: barite powder 0.20%, sodium fluosilicate 1.6-1.65%, anhydrous sodium sulfate 0.6-1.3%, cobalt oxide 0.1-0.4%, copper oxide 0.1-0.4%; the preparation process comprises the steps of mixing main materials and auxiliary materials, melting glass, mechanically forming, annealing products, inspecting and packaging. The cobalt blue porcelain-imitating glass bottle prepared by the invention gives people a mild, elegant, comfortable and light blue jade feeling, has the characteristics of good chemical stability, ultraviolet irradiation resistance, physical impact resistance and the like, avoids the defects of easy breakage, easy leakage and the like of a ceramic bottle, and effectively ensures the safety and sanitation of the contents in the bottle.
Description
Technical Field
The invention relates to the technical field of glass bottle manufacturing, in particular to a cobalt blue porcelain-like glass bottle formula and a preparation method thereof.
Background
The glass bottle is a packaging container for food, beverage and many products, is widely used, is a traditional beverage packaging container in China, is a historical packaging material, and still occupies an important position in beverage packaging under the condition that many packaging materials are introduced into the market, which is not distinguished from the packaging characteristics that other packaging materials cannot replace.
Glass packaging materials and containers have many advantages:
1. the glass material has good barrier property, can well prevent invasion of gases such as oxygen and the like to contents, and can prevent volatile components of the contents from volatilizing into the atmosphere;
2. the glass bottle can be used repeatedly, so that the packaging cost can be reduced;
3. the glass can be easily changed in color and transparency;
4. the glass bottle is safe and sanitary, has good corrosion resistance and acid corrosion resistance, and is suitable for packaging acidic substances (such as vegetable juice beverages);
the existing glass bottle preparation method is mature, but most of the produced glass bottles are white or transparent, the sense and vision of people are single, and the existing glass bottles have the problems of poor chemical stability, fragility, easy explosion and the like.
Disclosure of Invention
The invention aims to provide a formula and a preparation method of a cobalt blue porcelain-imitating glass bottle, and the prepared cobalt blue porcelain-imitating glass bottle gives people a mellow, elegant, comfortable and light-blue jade feeling, has the characteristics of good chemical stability, ultraviolet irradiation resistance, physical impact resistance and the like, and avoids the defects of easy breakage, easy leakage and the like of a ceramic bottle.
In order to achieve the purpose, the invention provides the following technical scheme:
a formula of a cobalt blue porcelain-imitating glass bottle, which comprises a main material and an auxiliary material,
the main material consists of the following raw materials in percentage by mass: 49-54% of common quartz sand powder, 7-12% of lithium mica powder, 18-19% of soda ash, 9-13% of calcite powder and 4-8% of dolomite powder;
the auxiliary materials comprise the following raw materials in percentage by mass: barite powder 0.20%, sodium fluosilicate 1.6-1.65%, anhydrous sodium sulfate 0.6-1.3%, cobalt oxide 0.1-0.4%, and copper oxide 0.1-0.4%.
Furthermore, the main material comprises the following raw materials in percentage by mass: 53.89% of common quartz sand powder, 7.67% of lithium mica powder, 18.40% of soda ash, 12.60% of calcite powder and 4.30% of dolomite powder;
the auxiliary materials comprise the following raw materials in percentage by mass: barite powder 0.20%, sodium fluorosilicate 1.60%, anhydrous sodium sulfate 0.60%, cobalt oxide 0.40%, and copper oxide 0.40%. .
Furthermore, the main material comprises the following raw materials in percentage by mass: 49.5 percent of common quartz sand powder, 11.8 percent of lithium mica powder, 18.44 percent of soda ash, 9.83 percent of calcite powder and 7.42 percent of dolomite powder;
the auxiliary materials comprise the following raw materials in percentage by mass: 1.62 percent of sodium fluosilicate, 1.26 percent of anhydrous sodium sulphate and 0.13 percent of cobalt oxide.
Furthermore, in the raw material formula: SiO in common quartz sand powder2The content of (1) is 99.17%, Fe2O3The content of (A) is 0.02%;
al in lithium mica powder2O3Content of (b) 22%, L i2The content of O accounts for 3.5 percent;
na in soda ash2CO3The content of (A) is 99.2%;
the content of CaO in the calcite powder is 55 percent, and Fe2O3The content of (A) is 0.02%;
the dolomite powder contains 30 percent of CaO and 19 percent of MgO;
na in sodium fluosilicate2SiF4The content of (A) is 99.0%;
na in anhydrous sodium sulphate2SO4The content of (A) is 99%;
the content of CoO in the cobalt oxide was 75.0%.
The invention provides another technical scheme: a preparation method of a cobalt blue porcelain-imitating glass bottle formula comprises the following steps:
s1: mixing main materials and auxiliary materials: adding the auxiliary materials into the main material in turn according to 15kg as a batch, and uniformly mixing;
s2: melting glass: feeding the mixed raw and auxiliary materials into a kiln for heating, wherein the highest furnace temperature of the kiln is controlled within 1550-1555 ℃, and the inside of the kiln is controlled according to the oxidizing atmosphere;
s3: mechanical forming: cooling the molten glass to 1160-1260 ℃ through a material channel, a distribution material channel and a material supply system, and introducing the molten glass into a glass mold through a material guide system for molding treatment;
s4: uniformly spraying atomized monobutyl tin chloride on the outer surface of a molded product at the temperature of about 400 ℃ by a hot end spraying machine;
s5: annealing the product: putting the cooled glass bottle into an annealing furnace for annealing treatment, wherein the annealing temperature is 380-600 ℃, and the annealing time is 60 min;
s6: and (3) inspecting and packaging: and (5) inspecting the cooled glass bottles, and packaging the qualified glass bottles.
Furthermore, the control of the kiln temperature in the S2 is determined according to the temperature conditions of the regenerators, wherein the temperature of the air regenerator is not more than 1350 ℃, the temperature of the coal gas regenerator is not more than 1150 ℃, the melting temperature of the raw material is 1550 ℃, and the melting rate is 1.5-1.6t/m2And d, bubbling for 12 times/min, and controlling the kiln atmosphere according to the oxidizing atmosphere.
Compared with the prior art, the invention has the beneficial effects that:
according to the formula and the preparation method of the cobalt blue porcelain-imitating glass bottle, the prepared cobalt blue porcelain-imitating glass bottle has a mild, elegant, smooth and light-blue jade feeling, has the characteristics of good chemical stability, ultraviolet irradiation resistance, physical impact resistance and the like, avoids the defects that a ceramic bottle is easy to break and leak and the like, and effectively guarantees the safety and the sanitation of a content in the bottle.
According to the formula and the preparation method of the cobalt blue porcelain-imitating glass bottle, provided by the invention, the production efficiency is improved by about 10 times compared with that of a semi-artificial porcelain bottle by adopting mechanical forming, and continuous industrial production is realized.
Compared with the prior art, the formula of the cobalt blue porcelain-like glass bottle and the preparation method thereof provided by the invention have the advantages that the formula uses lepidolite, the goal of reducing energy consumption can be realized while the glass melting rate is improved, and the formula has the remarkable advantages of strong transparency, low production cost, low energy consumption and the like.
The formula of the cobalt blue porcelain-like glass bottle and the preparation method thereof provided by the invention have the advantages that the raw material formula has wide source, the purchase is easy, and the cost is low.
The formula and the preparation method of the cobalt blue porcelain-like glass bottle provided by the invention can be used for remelting and remelting all blue waste products, so that the glass melting rate is improved, the glass material property is enhanced, and the energy consumption is reduced.
Detailed Description
The following examples will explain the present invention in detail, however, the present invention is not limited thereto. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
A formula of a cobalt blue porcelain-imitating glass bottle, which comprises a main material and an auxiliary material,
the main material consists of the following raw materials in percentage by mass: 49-54% of common quartz sand powder, 7-12% of lithium mica powder, 18-19% of soda ash, 9-13% of calcite powder and 4-8% of dolomite powder;
the auxiliary materials comprise the following raw materials in percentage by mass: barite powder 0.20%, sodium fluosilicate 1.6-1.65%, anhydrous sodium sulfate 0.6-1.3%, cobalt oxide 0.1-0.4%, and copper oxide 0.1-0.4%.
In the formula of the raw materials: the sodium fluosilicate accounts for 1.6-1.65 percent, can be completely melted in glass components during actual production, and is not enough to cause the problems of serious corrosion of refractory materials of a glass kiln, environmental pollution and the like.
In the formula of the raw materials: SiO in common quartz sand powder2The content of (1) is 99.17%, Fe2O3The content of (A) is 0.02%;
al in lithium mica powder2O3Content of (b) 22%, L i2The content of O accounts for 3.5 percent;
na in soda ash2CO3The content of (A) is 99.2%;
the content of CaO in the calcite powder is 55 percent, and Fe2O3The content of (A) is 0.02%;
the dolomite powder contains 30 percent of CaO and 19 percent of MgO;
na in sodium fluosilicate2SiF4The content of (A) is 99.0%;
na in anhydrous sodium sulphate2SO4The content of (A) is 99%;
the content of CoO in the cobalt oxide was 75.0%.
Based on the above raw material composition, in order to further explain the present invention better, the following specific examples are also provided:
the first embodiment is as follows:
the main materials are mixed according to the following mass fractions: 53.89% of common quartz sand powder, 7.67% of lithium mica powder, 18.40% of soda ash, 12.60% of calcite powder and 4.30% of dolomite powder;
the auxiliary materials are mixed according to the following mass fraction: barite powder 0.20%, sodium fluorosilicate 1.60%, anhydrous sodium sulfate 0.60%, cobalt oxide 0.40%, and copper oxide 0.40%.
According to the raw materials in the mass fraction ratio, the following raw materials in parts by weight are sequentially weighed:
main materials: common quartz sand powder: 274.2kg, lithium mica powder: 39kg, 93.6kg of soda ash, 64.1kg of calcite powder and 21.9kg of dolomite powder;
auxiliary materials: 1kg of barite powder, 8kg of sodium fluosilicate, 3kg of anhydrous sodium sulfate, 2kg of cobalt oxide and 2kg of copper oxide.
The preparation method of the cobalt blue porcelain-imitating glass bottle formula comprises the following steps of:
the first step is as follows: mixing main materials and auxiliary materials: adding the auxiliary materials into the main material in turn according to 15kg as a batch, and uniformly mixing;
the second step is that: melting glass: feeding the mixed raw and auxiliary materials into a kiln for heating, wherein the highest furnace temperature of the kiln is controlled within 1550-1555 ℃, and the inside of the kiln is controlled according to the oxidizing atmosphere;
the third step: mechanical forming: cooling the molten glass to 1160-1260 ℃ through a material channel, a distribution material channel and a material supply system, and introducing the molten glass into a glass mold through a material guide system for molding treatment;
the fourth step: the formed product with the temperature of about 400 ℃ passes through a hot end spraying machine, and atomized monobutyl tin chlorideUniformly spraying the coating on the outer surface of the product; the monobutyl tin chloride reacts at high temperature to generate SnO which replaces partial Na2O, compensating microcracks generated in the product forming process, thereby improving the strength of the glass bottle;
the fifth step: annealing the product: putting the cooled glass bottle into an annealing furnace for annealing treatment, wherein the annealing temperature is 380-600 ℃, and the annealing time is 60 min;
and a sixth step: and (3) inspecting and packaging: and (5) inspecting the cooled glass bottles, and packaging the qualified glass bottles.
Example two:
the main materials are mixed according to the following mass fractions: 49.5 percent of common quartz sand powder, 11.8 percent of lithium mica powder, 18.44 percent of soda ash, 9.83 percent of calcite powder and 7.42 percent of dolomite powder;
the auxiliary materials are mixed according to the following mass fraction: 1.62 percent of sodium fluosilicate, 1.26 percent of anhydrous sodium sulphate and 0.13 percent of cobalt oxide.
According to the raw materials in the mass fraction ratio, the following raw materials in parts by weight are sequentially weighed:
549 kg of white quartz sand, 130.9 kg of lithionite, 204.5 kg of soda ash, 109 kg of calcite, 82.3 kg of dolomite, 18 kg of sodium fluosilicate, 14 kg of anhydrous sodium sulphate and 1.4 kg of cobalt oxide.
The preparation method of the cobalt blue porcelain-imitating glass bottle formula comprises the following steps of:
the first step is as follows: mixing main materials and auxiliary materials: adding the auxiliary materials into the main material in turn according to 15kg as a batch, and uniformly mixing;
the second step is that: melting glass: feeding the mixed raw and auxiliary materials into a kiln for heating, wherein the highest furnace temperature of the kiln is controlled within 1550-1555 ℃, and the inside of the kiln is controlled according to the oxidizing atmosphere;
the third step: mechanical forming: cooling the molten glass to 1160-1260 ℃ through a material channel, a distribution material channel and a material supply system, and introducing the molten glass into a glass mold through a material guide system for molding treatment;
the fourth step: the formed product with the temperature of about 400 ℃ passes through a hot end spraying machine to uniformly atomize the monobutyl tin chlorideSpraying on the outer surface of the product; the monobutyl tin chloride reacts at high temperature to generate SnO which replaces partial Na2O, compensating microcracks generated in the product forming process, thereby improving the strength of the glass bottle;
the fifth step: annealing the product: putting the cooled glass bottle into an annealing furnace for annealing treatment, wherein the annealing temperature is 380-600 ℃, and the annealing time is 60 min;
and a sixth step: and (3) inspecting and packaging: and (5) inspecting the cooled glass bottles, and packaging the qualified glass bottles.
Based on the description of the first embodiment and the second embodiment, the formula of the cobalt blue porcelain-imitating glass bottle is used in actual production:
changing the furnace burden in the kiln from a common white material to a cobalt blue porcelain imitation material:
the formula is changed on the basis of the existing common white material in the original workshop, the low-iron raw material is replaced, the cobalt oxide colorant is used, and when the common white material is changed into the cobalt blue colorant, the existing common white material glass in the original workshop is stopped to be added, the limestone is changed into calcite, and the low-iron common white quartz sand is used.
In the actual production process: because the cobalt blue material glass has poor transmission and is difficult to melt, the cobalt blue material is produced according to the highest temperature of the kiln, the temperature range of the kiln is controlled to be 1550-1555 ℃, and the temperature range is determined according to the temperature condition of the regenerator, wherein the temperature of the air regenerator does not exceed 1350 ℃, the temperature of the gas regenerator does not exceed 1150 ℃, the melting temperature of the blue material is 1550 ℃, and the melting rate is 1.5-1.6t/m2Bubbling for more than 12 times/min, and controlling the kiln atmosphere according to the oxidizing atmosphere.
The discharge amount of the cobalt blue material is reduced from 135 tons/day to 130 tons/day, after the furnace temperature reaches 1550 ℃, the discharge amount condition is determined according to the material pile and the melting condition in the furnace, and the discharge amount starts to be gradually reduced after the material color is changed conventionally and is controlled according to 97.5 tons/day; and a natural gas gun is arranged on the distribution material channel, heating is carried out according to the material temperature, the temperature of the rising channel is more than 1150 ℃, and the annealing time is controlled to be 1 hour.
The sky blue porcelain-imitating glass bottle prepared by the method has the advantages that the impact resistance is more than or equal to 0.8J, the internal pressure resistance is more than or equal to 1.6MPa, and the internal stress is less than or equal to 4 grades through the detection of physical performance indexes, so that the method can be known as follows: the method can completely prepare beer bottles with strict requirements on quality standards, and the currently produced cobalt blue porcelain-like glass beer bottles are supplied in batches by quality detection of domestic famous breweries.
In summary, the following steps: the invention provides a formula and a preparation method of a cobalt blue porcelain-like glass bottle, wherein porcelain-like glass is a new material which is made up in recent years, and the porcelain-like glass at present mainly takes fluoride as an opacifier, and a large amount of CaF can be separated out in the cooling process of a glass melt2And NaF crystal, make the glass semitransparent to have hazy porcelain, but can see the content clearly, but the ceramic bottle is not feasible, and the advantage of the opalescent glass of fluoride is that the temperature of devitrification is lower when the glass melt is cooled, the shaping operation favorable to glass product; the prepared cobalt blue porcelain-imitating glass bottle gives people a mild, elegant, comfortable and light-blue jade feeling, has the characteristics of good chemical stability, ultraviolet irradiation resistance, physical impact resistance and the like, and avoids the defects that a ceramic bottle is easy to break and leak and the like; secondly, the preparation method adopts mechanical forming, improves the production efficiency by about 10 times compared with the manufacturing production efficiency of semi-artificial ceramic bottles, and realizes continuous industrial production; in addition, compared with the prior art, the formula using the lepidolite can realize the purposes of improving the glass melting rate and reducing the energy consumption, and has the remarkable advantages of strong transparency, low production cost, low energy consumption and the like.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be able to cover the technical solutions and the inventive concepts of the present invention within the technical scope of the present invention.
Claims (6)
1. A formula of a cobalt blue porcelain-imitating glass bottle, which comprises a main material and an auxiliary material and is characterized in that,
the main material consists of the following raw materials in percentage by mass: 49-54% of common quartz sand powder, 7-12% of lithium mica powder, 18-19% of soda ash, 9-13% of calcite powder and 4-8% of dolomite powder;
the auxiliary materials comprise the following raw materials in percentage by mass: barite powder 0.20%, sodium fluosilicate 1.6-1.65%, anhydrous sodium sulfate 0.6-1.3%, cobalt oxide 0.1-0.4%, and copper oxide 0.1-0.4%.
2. The cobalt blue porcelain imitating glass bottle formulation as claimed in claim 1,
the main material consists of the following raw materials in percentage by mass: 53.89% of common quartz sand powder, 7.67% of lithium mica powder, 18.40% of soda ash, 12.60% of calcite powder and 4.30% of dolomite powder;
the auxiliary materials comprise the following raw materials in percentage by mass: barite powder 0.20%, sodium fluorosilicate 1.60%, anhydrous sodium sulfate 0.60%, cobalt oxide 0.40%, and copper oxide 0.40%.
3. The cobalt blue porcelain imitating glass bottle formulation as claimed in claim 1,
the main material consists of the following raw materials in percentage by mass: 49.5 percent of common quartz sand powder, 11.8 percent of lithium mica powder, 18.44 percent of soda ash, 9.83 percent of calcite powder and 7.42 percent of dolomite powder;
the auxiliary materials comprise the following raw materials in percentage by mass: 1.62 percent of sodium fluosilicate, 1.26 percent of anhydrous sodium sulphate and 0.13 percent of cobalt oxide.
4. The formulation of any one of claims 1 to 3, wherein the formulation comprises: SiO in common quartz sand powder2The content of (1) is 99.17%, Fe2O3The content of (A) is 0.02%;
al in lithium mica powder2O3Content of (b) 22%, L i2The content of O accounts for 3.5 percent;
na in soda ash2CO3The content of (A) is 99.2%;
the content of CaO in the calcite powder is 55 percent, and Fe2O3The content of (A) is 0.02%;
the dolomite powder contains 30 percent of CaO and 19 percent of MgO;
na in sodium fluosilicate2SiF4In the content of99.0％；
Na in anhydrous sodium sulphate2SO4The content of (A) is 99%;
the content of CoO in the cobalt oxide was 75.0%.
5. A method of preparing the cobalt blue porcelain imitating glass bottle formulation as claimed in claim 1, comprising the steps of:
s1: mixing main materials and auxiliary materials: adding the auxiliary materials into the main material in turn according to 15kg as a batch, and uniformly mixing;
s2: melting glass: feeding the mixed raw and auxiliary materials into a kiln for heating, wherein the highest furnace temperature of the kiln is controlled within 1550-1555 ℃, and the inside of the kiln is controlled according to the oxidizing atmosphere;
s3: mechanical forming: cooling the molten glass to 1160-1260 ℃ through a material channel, a distribution material channel and a material supply system, and introducing the molten glass into a glass mold through a material guide system for molding treatment;
s4: uniformly spraying atomized monobutyl tin chloride on the outer surface of a molded product at the temperature of about 400 ℃ by a hot end spraying machine;
s5: annealing the product: putting the cooled glass bottle into an annealing furnace for annealing treatment, wherein the annealing temperature is 380-600 ℃, and the annealing time is 60 min;
s6: and (3) inspecting and packaging: and (5) inspecting the cooled glass bottles, and packaging the qualified glass bottles.
6. The method of claim 5, wherein the temperature of the furnace in S2 is controlled according to the temperature of the regenerators, wherein the temperature of the air regenerator is not more than 1350 ℃, the temperature of the gas regenerator is not more than 1150 ℃, the melting temperature of the raw material is 1550 ℃, and the melting rate is 1.5-1.6t/m2And d, bubbling for 12 times/min, and controlling the kiln atmosphere according to the oxidizing atmosphere.
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