CN103570219A - Production method of lead-free ceramic-simulating glass winebottles - Google Patents
Production method of lead-free ceramic-simulating glass winebottles Download PDFInfo
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- CN103570219A CN103570219A CN201210252376.2A CN201210252376A CN103570219A CN 103570219 A CN103570219 A CN 103570219A CN 201210252376 A CN201210252376 A CN 201210252376A CN 103570219 A CN103570219 A CN 103570219A
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- imitative porcelain
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/50—Glass production, e.g. reusing waste heat during processing or shaping
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Abstract
The invention discloses a production method of lead-free ceramic-simulating glass winebottles, and belongs to the field of glassmaking. The production method comprises following steps: cullet, quartz sand, sodium carbonate, albite, calcite, anhydrous sodium sulphate and sodium fluosilicate are taken as raw materials, and are subjected to mixing, fusing, moulding and annealing so as to obtain the lead-free ceramic-simulating glass winebottles. Advantages of the production method are that: recycled waste glass products are the principal raw material, quartz sand is locally produced, so that raw material cost is low; the ceramic-simulating glass winebottles are free of toxic elements such as lead, arsenic and chromium, and no harm on human bodies is caused; product modeling possesses diversity, and is as excellent as that of ceramic products; volume production can be realized, yield is high, quality is stable, the lead-free ceramic-simulating glass winebottles can be recycled after use, the production method is friendly to the environment, and no pollution is caused.
Description
Technical field
The invention belongs to glass manufacturing area, relate in particular to a kind of production method of unleaded imitative porcelain glass wine bottle.
Background technology
Glass is a kind of transparent or semitransparent solid matter, forms contiguous network structure when melting, and process of cooling medium viscosity increases and sclerosis and non crystallized silicates non-metallic material gradually.The sorting technique of glass is a lot, by main component, is divided into oxide glass and nonoxide glass, and nonoxide glass kind and quantity seldom, mainly contain chalcogenide glass and halide glass.Oxide glass is divided into again silicate glass, borate glass, phosphate glass etc., and wherein silicate glass refers to that basal component is the glass of silicon-dioxide, and it is wide in variety, output is large, purposes is wide.In silicate glass, output maximum is common soda-lime glass, the dioxide-containing silica of common soda-lime glass is between 55%-65%, also contain 15% sodium oxide, 15% calcium oxide and a certain amount of plumbous oxide, be characterized in low production cost, easy-formation, of many uses.Simple glass contains a certain amount of lead, if be directly used for manufacturing tea set, drinking utensils, bottle, lead just likely enters after human body, lead enters after human body except part is by ight soil, sweat excretion, all the other dissolve in blood after a few hours, hinder the synthetic of blood, cause human body anaemia, there are headache, dizzy, weak, sleepy, constipation and limb aching pain etc., cause the symptoms such as arteriosclerosis, digestive tract ulcer and retinal hemorrhage; There is hypoevolutism, poor appetite, inconvenient walking and constipation, insomnia in child's lead poisoning, also, with phenomenons such as many moving, dysacousis, absent minded, mental retardation, severe patient may cause permanent disbility; Lead enters in pregnant woman's body can pass through placental barrier, affects fetation, causes deformity etc.Along with the enhancing of people to environmental consciousness, use crown glass vessel to become people's common recognition.Crown glass has its following advantage than flint glass: 1. crown glass has better refractivity than flint glass, has more perfectly represented the refractive property of glass; 2. than flint glass, to knock sent metallic ring more melodized for crown glass, the good reputation of rich " music "; Crown glass than flint glass vessel more flexible be impact resistance performance; 4. than flint glass, to be used for making tea set, drinking utensils, kitchen vessel safer more reliable for crown glass.If being reprocessed into unleaded imitative porcelain glass, crown glass makes the vessel such as bottle, the new purposes of unleaded imitative porcelain glass will be opened up, unleaded imitative porcelain glass will be made bottle and have competitive power and need meet following two conditions: 1. product must be opaque or transparency is lower, so just has a ceramic texture; 2. tinting material and production cost are low.Practice discovery, the unleaded imitative porcelain glass wine bottle of production is compared and is had the following advantages with ceramic wine bottle: because production cost is low, can carry out price competition with ceramic wine bottle 1..2. ceramic wine bottle adopts casting, and oral area is just being difficult for rule, and wine liquid easily, from bottleneck volatilization, is also not suitable for making guarding against theft type bottleneck; Unleaded imitative porcelain glass wine bottle adopts die forming, mechanization production, efficiency is high, be applicable to making guarding against theft type bottleneck, thereby overcome the shortcoming of ceramic wine bottle bottleneck, the very not complicated low and middle-grade ceramic wine bottles of some appearance are identical by shape gradually for this reason, and the unleaded imitative porcelain glass wine bottle that color and luster is identical or close replaces.Product of the present invention is a kind of production method of unleaded imitative porcelain glass wine bottle, it is with glass cullet (purchase white glass and imitative porcelain glass), quartz sand (white sand, iron-holder 0.2≤‰), soda ash (Soda Ash Light 99.2min.), albite (iron-holder 0.3≤‰), calcite (iron-holder 0.2≤‰), Sodium sulfate anhydrous.min(99), Sodium Silicofluoride is raw material, first mix, melting, after moulding, annealing, make unleaded imitative porcelain glass wine bottle again.The advantage of product is: 1. discarded glass goods, the quartz sand that main raw material is recovery is that local Mineral resources, soda ash are that chemical industry is produced appurtenant, and raw material input cost is low; 2. the poisonous element such as not leaded in product, arsenic, chromium, harmless; 3. product-forming is various, can match in excellence or beauty with ceramic; 4. can be mass, output is high, steady quality; 5. product main Types is the fast-moving consumer goods packing materials such as white wine, yellow rice wine, product finish using after recoverable, environment friendly and pollution-free; The imitative ceramic effect of product is splendid, can partly replace ceramic wine bottle, can save scarce resource.
Summary of the invention:
The problem that the present invention mainly solves is to provide a kind of method that glass cullet and quartz sand is the unleaded imitative porcelain glass wine bottle of main raw material suitability for industrialized production of take, it is main raw material that the method be take glass cullet, quartz sand, take blending machine, boiler, kiln, forming machine, annealing box is equipment, the operations such as the high-temperature fusion by compound, formed product, annealing make finished product, and unleaded imitative porcelain glass wine bottle that the method is produced is exquisite in workmanship, specious, stable chemical performance, smooth surface are easy clean, not leaded.The raw material weight per-cent that the present invention uses is: glass cullet 29%-31%(purchase white glass and imitative porcelain glass respectively account for half), quartz sand 32%-34%(white sand, require iron-holder 0.2≤‰), soda ash 10% (Soda Ash Light 99.2min.), albite 15%(requires iron-holder 0.3≤‰), calcite 8%(requires iron-holder 0.2≤‰), Sodium sulfate anhydrous.min(99) 0.1%, Sodium Silicofluoride 3.9%.
The present invention can be achieved through the following technical solutions:
A method for the unleaded imitative porcelain glass wine bottle of suitability for industrialized production, is characterized in that consisting of following steps:
(1) glass cullet of formula ratio, quartz sand, soda ash, albite, calcite, Sodium sulfate anhydrous.min(99), Sodium Silicofluoride are sent into blending machine even blend and obtained compound, by transfer roller, compound is sent into kiln.
(2) coal is sent into boiler combustion, the coal gas of 540 ℃-560 ℃ that burning obtains is sent into kiln sealing combustion in kiln by coal gas gas transmission equipment, make the temperature of compound reach 1550 ℃-1560 ℃, keep this temperature 28-32 hour, make compound reach molten state, obtain unleaded imitative porcelain glass melt, the product porcelain degree of now measuring, if not, can suitably reduce the proportioning of quartz sand, the proportioning that increases Sodium Silicofluoride, meets the demands the porcelain degree of product.
(3) unleaded imitative porcelain glass melt is sent into forming machine, controlling moulding built-in temperature is 1000 ℃-1100 ℃, makes the unleaded imitative porcelain glass wine bottle of certain specification, mold temperature can not be too low, as too low difficult forming, mold temperature can not be too high, there will be thermal explosion phenomenon as too high.
(4) while the unleaded imitative porcelain glass wine bottle of moulding being cooled to 650 ℃ of left and right naturally, with transfer roller, send into annealing box, time by 2-2.5 hour in annealing box cools the temperature to 150 ℃ of left and right, now anneal complete, unleaded imitative porcelain glass wine bottle is sent in air, in air, naturally cool to normal temperature, obtain finished product.
(5) using method of plumbous imitative porcelain glass wine bottle is: as the packing material of low and middle-grade white wine, yellow rice wine.
Temperature of fusion in kiln described in above-mentioned steps (2) is about 1555 ℃.
Annealing time described in above-mentioned steps (4) is 2.25 hours.
The invention has the beneficial effects as follows: provide a kind of method of producing unleaded imitative porcelain glass wine bottle in batches, the feature that the method has that technique is simple, starting material convenient sources, production cost are low, pollution-free, be applicable to suitability for industrialized production; The unleaded imitative porcelain glass wine bottle of product can be used as the packing material of low and middle-grade white wine, yellow rice wine, and product is not leaded, recoverable after finishing using, and imitative ceramic effect is good, can partly replace ceramic wine bottle.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in further detail.
Embodiment 1
By accounting for total amount, be 29% glass cullet, to account for total amount be 34% quartz sand, account for total amount is 10% soda ash, account for total amount is 15% albite, account for total amount is 8% calcite, account for total amount is 0.1% Sodium sulfate anhydrous.min(99), account for total amount is that 3.9% Sodium Silicofluoride is sent into blending machine even blend and obtained compound, by transfer roller, compound sent into kiln; Coal is sent into boiler combustion, the coal gas of 540 ℃ that burning obtains is sent into kiln sealing combustion in kiln by coal gas gas transmission equipment, make the temperature of compound reach 1560 ℃, keep this temperature 28 hours, make compound reach molten state, obtain unleaded imitative porcelain glass melt, the product porcelain degree of now measuring, if not, can suitably reduce the proportioning of quartz sand, the proportioning that increases Sodium Silicofluoride, meets the demands the porcelain degree of product; Unleaded imitative porcelain glass melt is sent into forming machine, and controlling moulding built-in temperature is 1000 ℃, makes the unleaded imitative porcelain glass wine bottle of certain specification, mold temperature can not be too low, as too low difficult forming, mold temperature can not be too high, there will be thermal explosion phenomenon as too high; When being cooled to 650 ℃ of left and right naturally, the unleaded imitative porcelain glass wine bottle of moulding sends into annealing box with transfer roller, time by 2 hours in annealing box cools the temperature to 150 ℃ of left and right, now anneal complete, unleaded imitative porcelain glass wine bottle is sent in air, in air, naturally cool to normal temperature, obtain finished product; The using method of plumbous imitative porcelain glass wine bottle is: as the packing material of low and middle-grade white wine, yellow rice wine.
Embodiment 2
By accounting for total amount, be 30% glass cullet, to account for total amount be 33% quartz sand, account for total amount is 10% soda ash, account for total amount is 15% albite, account for total amount is 8% calcite, account for total amount is 0.1% Sodium sulfate anhydrous.min(99), account for total amount is that 3.9% Sodium Silicofluoride is sent into blending machine even blend and obtained compound, by transfer roller, compound sent into kiln; Coal is sent into boiler combustion, the coal gas of 550 ℃ that burning obtains is sent into kiln sealing combustion in kiln by coal gas gas transmission equipment, make the temperature of compound reach 1555 ℃, keep this temperature 30 hours, make compound reach molten state, obtain unleaded imitative porcelain glass melt, the product porcelain degree of now measuring, if not, can suitably reduce the proportioning of quartz sand, the proportioning that increases Sodium Silicofluoride, meets the demands the porcelain degree of product; Unleaded imitative porcelain glass melt is sent into forming machine, and controlling moulding built-in temperature is 1050 ℃, makes the unleaded imitative porcelain glass wine bottle of certain specification, mold temperature can not be too low, as too low difficult forming, mold temperature can not be too high, there will be thermal explosion phenomenon as too high; When being cooled to 650 ℃ of left and right naturally, the unleaded imitative porcelain glass wine bottle of moulding sends into annealing box with transfer roller, time by 2.25 hours in annealing box cools the temperature to 150 ℃ of left and right, now anneal complete, unleaded imitative porcelain glass wine bottle is sent in air, in air, naturally cool to normal temperature, obtain finished product; The using method of plumbous imitative porcelain glass wine bottle is: as the packing material of low and middle-grade white wine, yellow rice wine.
Embodiment 3
By accounting for total amount, be 31% glass cullet, to account for total amount be 32% quartz sand, account for total amount is 10% soda ash, account for total amount is 15% albite, account for total amount is 8% calcite, account for total amount is 0.1% Sodium sulfate anhydrous.min(99), account for total amount is that 3.9% Sodium Silicofluoride is sent into blending machine even blend and obtained compound, by transfer roller, compound sent into kiln; Coal is sent into boiler combustion, the coal gas of 560 ℃ that burning obtains is sent into kiln sealing combustion in kiln by coal gas gas transmission equipment, make the temperature of compound reach 1550 ℃, keep this temperature 32 hours, make compound reach molten state, obtain unleaded imitative porcelain glass melt, the product porcelain degree of now measuring, if not, can suitably reduce the proportioning of quartz sand, the proportioning that increases Sodium Silicofluoride, meets the demands the porcelain degree of product; Unleaded imitative porcelain glass melt is sent into forming machine, and controlling moulding built-in temperature is 1100 ℃, makes the unleaded imitative porcelain glass wine bottle of certain specification, mold temperature can not be too low, as too low difficult forming, mold temperature can not be too high, there will be thermal explosion phenomenon as too high; When being cooled to 650 ℃ of left and right naturally, the unleaded imitative porcelain glass wine bottle of moulding sends into annealing box with transfer roller, time by 2.5 hours in annealing box cools the temperature to 150 ℃ of left and right, now anneal complete, unleaded imitative porcelain glass wine bottle is sent in air, in air, naturally cool to normal temperature, obtain finished product; The using method of plumbous imitative porcelain glass wine bottle is: as the packing material of low and middle-grade white wine, yellow rice wine.
Claims (4)
1. the production method of a unleaded imitative porcelain glass wine bottle, its composition of raw materials counts by weight percentage: comprise that glass cullet 29%-31%(purchase white glass and imitative porcelain glass respectively account for half), quartz sand 32%-34%(white sand, require iron-holder 0.2≤‰), soda ash 10% (Soda Ash Light 99.2min.), albite 15%(requires iron-holder 0.3≤‰), calcite 8%(requires iron-holder 0.2≤‰), Sodium sulfate anhydrous.min(99) 0.1%, Sodium Silicofluoride 3.9%; It is characterized in that: step (1) is sent the glass cullet of formula ratio, quartz sand, soda ash, albite, calcite, Sodium sulfate anhydrous.min(99), Sodium Silicofluoride into blending machine even blend and obtained compound, by transfer roller, compound is sent into kiln; Step (2) is sent coal into boiler combustion, the coal gas of 540 ℃-560 ℃ that burning obtains is sent into kiln sealing combustion in kiln by coal gas gas transmission equipment, make the temperature of compound reach 1550 ℃-1560 ℃, keep this temperature 28-32 hour, make compound reach molten state, obtain unleaded imitative porcelain glass melt, now measure the porcelain degree of product, if not, can suitably reduce the proportioning of quartz sand, the proportioning that increases Sodium Silicofluoride, meets the demands the porcelain degree of product; Step (3) is sent unleaded imitative porcelain glass melt into forming machine, and controlling moulding built-in temperature is 1000 ℃-1100 ℃, makes the unleaded imitative porcelain glass wine bottle of certain specification, mold temperature can not be too low, as too low difficult forming, mold temperature can not be too high, there will be thermal explosion phenomenon as too high; When being cooled to 650 ℃ of left and right naturally by the unleaded imitative porcelain glass wine bottle of moulding, step (4) sends into annealing box with transfer roller, time by 2-2.5 hour in annealing box cools the temperature to 150 ℃ of left and right, now anneal complete, unleaded imitative porcelain glass wine bottle is sent in air, in air, naturally cool to normal temperature, obtain finished product.
2. the production method of a kind of unleaded imitative porcelain glass wine bottle according to claim 1, its step (1) feature is: the temperature of fusion in described kiln is 1555 ℃, fusing time is 30 hours.
3. the production method of a kind of unleaded imitative porcelain glass wine bottle according to claim 1, its step (4) feature is: described annealing time is total up to 2.25 hours.
4. the production method of a kind of unleaded imitative porcelain glass wine bottle according to claim 1, unleaded imitative porcelain glass wine bottle using method is: as the packing material of low and middle-grade white wine, yellow rice wine.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210252376.2A CN103570219A (en) | 2012-07-20 | 2012-07-20 | Production method of lead-free ceramic-simulating glass winebottles |
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| CN201210252376.2A CN103570219A (en) | 2012-07-20 | 2012-07-20 | Production method of lead-free ceramic-simulating glass winebottles |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107348765A (en) * | 2017-08-04 | 2017-11-17 | 安徽宽居电器有限公司 | A kind of glass flower pot and its manufacturing process for meeting water discoloration |
| CN107382060A (en) * | 2017-08-14 | 2017-11-24 | 重庆昊晟玻璃股份有限公司 | The preparation method of bottle |
| CN109761490A (en) * | 2019-03-18 | 2019-05-17 | 江苏新奥得玻璃制品股份有限公司 | A kind of colored glaze cut glass vase and its manufacturing method |
| CN111484246A (en) * | 2020-05-07 | 2020-08-04 | 山东景耀玻璃集团有限公司 | Formula and preparation method of cobalt blue porcelain-like glass bottle |
-
2012
- 2012-07-20 CN CN201210252376.2A patent/CN103570219A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107348765A (en) * | 2017-08-04 | 2017-11-17 | 安徽宽居电器有限公司 | A kind of glass flower pot and its manufacturing process for meeting water discoloration |
| CN107382060A (en) * | 2017-08-14 | 2017-11-24 | 重庆昊晟玻璃股份有限公司 | The preparation method of bottle |
| CN109761490A (en) * | 2019-03-18 | 2019-05-17 | 江苏新奥得玻璃制品股份有限公司 | A kind of colored glaze cut glass vase and its manufacturing method |
| CN109761490B (en) * | 2019-03-18 | 2019-09-13 | 江苏新奥得玻璃制品股份有限公司 | A kind of colored glaze cut glass vase and its manufacturing method |
| CN111484246A (en) * | 2020-05-07 | 2020-08-04 | 山东景耀玻璃集团有限公司 | Formula and preparation method of cobalt blue porcelain-like glass bottle |
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Application publication date: 20140212 |