CN104445942B - A kind of unleaded imitative porcelain glass wine bottle and manufacturing process thereof - Google Patents
A kind of unleaded imitative porcelain glass wine bottle and manufacturing process thereof Download PDFInfo
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- CN104445942B CN104445942B CN201410741629.1A CN201410741629A CN104445942B CN 104445942 B CN104445942 B CN 104445942B CN 201410741629 A CN201410741629 A CN 201410741629A CN 104445942 B CN104445942 B CN 104445942B
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- unleaded
- wine bottle
- imitative porcelain
- glass wine
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/04—Opacifiers, e.g. fluorides or phosphates; Pigments
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/004—Refining agents
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/02—Pretreated ingredients
- C03C1/022—Purification of silica sand or other minerals
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Glass Compositions (AREA)
Abstract
The present invention relates to a kind of unleaded imitative porcelain glass wine bottle and preparation method thereof.Its raw material composition is by weight: quartz sand 45-50 part, soda ash 10-12 part, calcite 10-11 part, superfine talcum powder 5-8 part, magnesium chloride 2-4 part, finings 2-3 part, opacifying agent 4-6 part, solidifying agent 1-2 part, coupling agent 1-2 part.Unleaded imitative porcelain glass wine bottle provided by the invention is high temperature resistant, pure white, safety non-toxic, printing opacity, refractivity are strong, homogeneous.Recoverable, with low cost, environmental protection and energy saving.
Description
Technical field
The invention belongs to glass manufacturing area, be specifically related to a kind of unleaded imitative porcelain glass wine bottle and manufacturing process thereof.
Background technology
Glass has application widely in daily life.General glass contains a certain amount of plumbous oxide because the reasons such as materials cause in finished product.Plumbous major determinant neural system, Digestive tract, hemopoietic system and kidney.In recent years, the impact of Effects of Lead Exposure Endocrine, reproductive system also draws attention.But glass is a kind of renewable resources, can repeat to melt down use.Its main raw material is quartz sand.Pottery safety is attractive in appearance, but generally adopts casting, easily causes oral area irregular positive.
Imitative porcelain glass is the novel material of rising in recent years, and industrial scale progressively expands in recent years, has good market development prospect.The production of imitative porcelain glass at present mainly makes opacifying agent with fluorochemical, in glass melt process of cooling, separate out a large amount of CaF
2with NaF crystal, and then cause " devitrification " of glasswork.When the advantage of this Fluoride Opal Glass is glass melt cooling, the temperature of crystallization is lower, be conducive to the forming operation of glasswork, in process of production due to the existence of fluorochemical, the problems such as the serious and environmental pollution of glass furnace refractory corrosion can be caused, limit its range of application.So using other raw materials to replace fluorochemical is a very important problem.
The material that porcelain imitation material of the prior art adds is scarcely non-toxic material, can cause certain injury to human body, is not suitable for the utensil making splendid attire food.
Patent 201210593455X discloses a kind of imitative porcelain tableware and preparation method thereof.Processing step comprises batch mixing, baking, compression molding, sanding and polishing etc., but wherein containing melamine and tripolycyanamide, this material is thermo-labile, at high temperature easily decomposes, and causes damage to health.
Patent 2012102620724 discloses a kind of manufacture method of colored fluoride-free ceramic imitation azure stone.The method that the present invention is blown by melt jacking, dips according to the order of bright material, white material, bright material, colorant, bright material the colored fluoride-free ceramic imitation azure stone that material is blow molded into five layers.Do not use finings in invention, the effect that body reaches penetrating can not be made.
Summary of the invention
A kind of unleaded imitative porcelain glass wine bottle, it is characterized in that, its raw material composition is by weight: quartz sand 45-50 part, soda ash 10-12 part, calcite 10-11 part, superfine talcum powder 5-8 part, magnesium chloride 2-4 part, finings 2-3 part, opacifying agent 4-6 part, solidifying agent 1-2 part, coupling agent 1-2 part.
Described finings is sodium sulfate, SODIUMNITRATE, sodium-chlor.
Described opacifying agent is stannic oxide, aluminum oxide.
Described solidifying agent is phenylformic acid or silicon phosphate.
Described coupling agent is dioxolane, vinyl three tert-butyl peroxide silane or butadienyl triethoxyl silane.
The production method of described unleaded imitative porcelain glass wine bottle, is characterized in that comprising the following steps:
(1) quartz sand, soda ash, calcite, superfine talcum powder, magnesium chloride, finings, opacifying agent are sent into blending machine and mixed.
(2) enter burner hearth by travelling belt, heating makes the temperature of compound to 1150-1200 DEG C, continues 10-12 hour;
(3) add solidifying agent and coupling agent in former compound, make temperature of charge reach 1300 DEG C, continue 30-60 minute, degas bubble;
(4) by moulding press compression molding, molding temperature is 650-800 DEG C, and pressure is 4-4.5Mpa, and the time is 8-10 minute.
(5) shaping unleaded imitative porcelain glass wine bottle is sent into annealing furnace, annealing 1-1.5 hour.
(6) utilize sander to carry out sanding and polishing, obtain finished product.
Unleaded imitative porcelain glass wine bottle provided by the invention is high temperature resistant, pure white, safety non-toxic.Make containing finings and opacifying agent in product that bottle is homogeneous, bubble-free, printing opacity, refractivity are strong, and body is penetrating attractive in appearance.And there will not be striped and the uneven situation of milkiness.And can recycle, manufacture craft is simple, and environmental protection and energy saving, are suitable for scale operation.Unleaded imitative porcelain glass wine bottle provided by the invention employs the raw material such as quartz sand, calcite, and with the addition of solidifying agent and coupling agent, very sturdy and durable, non-friable, is convenient to transport and sells.
Embodiment
Embodiment 1
(1) get quartz sand 50 parts by weight, soda ash 12 parts, 11 parts, calcite, superfine talcum powder 5 parts, 3 parts, magnesium chloride, SODIUMNITRATE 2 parts, 5 parts, stannic oxide mixes.
(2) enter burner hearth by travelling belt, heating makes the temperature to 1150 DEG C of compound, continues 12 hours;
(3) add 2 parts, phenylformic acid, dioxolane 2 parts in former compound, make temperature of charge reach 1300 DEG C, continue 35 minutes, degas bubble;
(4) by moulding press compression molding, molding temperature is 800 DEG C, and pressure is 4.5Mpa, and the time is 10 minutes;
(5) shaping unleaded imitative porcelain glass wine bottle is sent into annealing furnace, anneal 1.5 hours.
(6) utilize sander to carry out sanding and polishing, obtain finished product.
Embodiment 2
(1) get quartz sand 47 parts by weight, soda ash 11 parts, 10 parts, calcite, superfine talcum powder 6 parts, 2 parts, magnesium chloride, 3 parts, sodium sulfate, 5 parts, aluminum oxide, 2 parts, stannic oxide, coupling agent 2 parts mix.
(2) enter burner hearth by travelling belt, heating makes the temperature to 1200 DEG C of compound, continues 10 hours;
(3) add silicon phosphate 1 part with 1 part, vinyl three tert-butyl peroxide silane in former compound, make temperature of charge reach 1300 DEG C, continue 45 minutes, degas bubble;
(4) by moulding press compression molding, molding temperature is 700 DEG C, and pressure is 4Mpa, and the time is 8-10 minute.
(5) shaping unleaded imitative porcelain glass wine bottle is sent into annealing furnace, anneal 1 hour.
(6) utilize sander to carry out sanding and polishing, obtain finished product.
Embodiment 3
(1) get quartz sand 35 parts by weight, soda ash 9 parts, 8 parts, calcite, superfine talcum powder 5 parts, 2 parts, magnesium chloride, 3 parts, sodium sulfate, 4 parts, stannic oxide mixes.
(2) enter burner hearth by travelling belt, heating makes the temperature to 1000 DEG C of compound, continues 10 hours;
(3) add silicon phosphate 0.5 part with dioxolane 0.5 part in former compound, make temperature of charge reach 1300 DEG C, continue 20 minutes, degas bubble;
(4) by moulding press compression molding, molding temperature is 600 DEG C, and pressure is 3Mpa, and the time is 8-10 minute.
(5) shaping unleaded imitative porcelain glass wine bottle is sent into annealing furnace, anneal 0.5 hour.
(6) utilize sander to carry out sanding and polishing, obtain finished product.
Below measure embodiment 1, embodiment 3, patent 201210593455X(comparative example 1), patent 2012102620724(comparative example 2) parameter:
Embodiment 1 have employed the data in limited range of the present invention, transparence and bending strength higher be respectively 71% and 198mpa be significantly greater than embodiment 3 at the outer setup parameter of limited range of the present invention, and comparative example 1 and comparative example 2.Meanwhile, the hot pressing temperature of embodiment 1 is high, high temperature resistant, stable in properties.
Above-mentioned detailed description is illustrating for one of them possible embodiments of the present invention, and this embodiment is also not used to limit the scope of the claims of the present invention, and the equivalence that all the present invention of disengaging do is implemented or changed, and all should be contained in the scope of technical solution of the present invention.
Claims (1)
1. a production method for unleaded imitative porcelain glass wine bottle, is characterized in that, comprise the following steps:
(1) get quartz sand 50 parts by weight, soda ash 12 parts, 11 parts, calcite, superfine talcum powder 5 parts, 3 parts, magnesium chloride, SODIUMNITRATE 2 parts, 5 parts, stannic oxide mixes;
(2) enter burner hearth by travelling belt, heating makes the temperature to 1150 DEG C of compound, continues 12 hours;
(3) add 2 parts, phenylformic acid, dioxolane 2 parts in former compound, make temperature of charge reach 1300 DEG C, continue 35 minutes, degas bubble;
(4) by moulding press compression molding, molding temperature is 800 DEG C, and pressure is 4.5Mpa, and the time is 10 minutes;
(5) shaping unleaded imitative porcelain glass wine bottle is sent into annealing furnace, anneal 1.5 hours;
(6) utilize sander to carry out sanding and polishing, obtain finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410741629.1A CN104445942B (en) | 2014-12-09 | 2014-12-09 | A kind of unleaded imitative porcelain glass wine bottle and manufacturing process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410741629.1A CN104445942B (en) | 2014-12-09 | 2014-12-09 | A kind of unleaded imitative porcelain glass wine bottle and manufacturing process thereof |
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| Publication Number | Publication Date |
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| CN104445942A CN104445942A (en) | 2015-03-25 |
| CN104445942B true CN104445942B (en) | 2015-07-29 |
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| CN201410741629.1A Active CN104445942B (en) | 2014-12-09 | 2014-12-09 | A kind of unleaded imitative porcelain glass wine bottle and manufacturing process thereof |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106630600A (en) * | 2016-09-07 | 2017-05-10 | 安徽金生金世电子科技有限公司 | Color-changing glass cup and preparation method thereof |
| CN106365445A (en) * | 2016-09-07 | 2017-02-01 | 安徽金生金世电子科技有限公司 | Explosion-proof glass and preparation method thereof |
| CN106242279A (en) * | 2016-09-07 | 2016-12-21 | 安徽金生金世电子科技有限公司 | Crack preventing glass and preparation method thereof |
| CN110357417A (en) * | 2019-08-02 | 2019-10-22 | 翔实光电科技(昆山)有限公司 | The self-cleaning processing method of touched panel glass |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102775064A (en) * | 2012-02-16 | 2012-11-14 | 湖北晶彩玻璃有限公司 | Production recipe of purple true color glass bottle |
| CN103043909A (en) * | 2012-12-29 | 2013-04-17 | 青岛崂山玻璃有限公司 | Fabrication method of beer bottle |
| CN103408258A (en) * | 2013-07-15 | 2013-11-27 | 刘兰芳 | Manufacturing method for porcelain-imitated colorized floor tile |
-
2014
- 2014-12-09 CN CN201410741629.1A patent/CN104445942B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102775064A (en) * | 2012-02-16 | 2012-11-14 | 湖北晶彩玻璃有限公司 | Production recipe of purple true color glass bottle |
| CN103043909A (en) * | 2012-12-29 | 2013-04-17 | 青岛崂山玻璃有限公司 | Fabrication method of beer bottle |
| CN103408258A (en) * | 2013-07-15 | 2013-11-27 | 刘兰芳 | Manufacturing method for porcelain-imitated colorized floor tile |
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| Publication number | Publication date |
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| CN104445942A (en) | 2015-03-25 |
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Address after: 221424 Jiangsu city of Xuzhou province Xinyi city town board Glass Industrial Park City North Street Gang Yi City oder glass products Co. Patentee after: JIANGSU XINAODE GLASS PRODUCTS LIMITED COMPANY Address before: 221424 Jiangsu city of Xuzhou province Xinyi city town board glass industrial park city street gang Bei Xin Yi Xinaote glass products Co. Patentee before: Xinyi Xinaote Glass Products Co., Ltd. |