CN103011603A - Low-corrosion microcrystal jade ware and manufacturing method thereof - Google Patents
Low-corrosion microcrystal jade ware and manufacturing method thereof Download PDFInfo
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- CN103011603A CN103011603A CN 201310001578 CN201310001578A CN103011603A CN 103011603 A CN103011603 A CN 103011603A CN 201310001578 CN201310001578 CN 201310001578 CN 201310001578 A CN201310001578 A CN 201310001578A CN 103011603 A CN103011603 A CN 103011603A
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Abstract
The invention provides a low-corrosion microcrystal jade ware and a manufacturing method thereof and belongs to the technical field of glass ceramics. The manufacturing method is characterized in that MgO-Al2O3-SiO2 series glass is used as a base, a main crystalline phase of the jade ware is cordierite, and the proportion of the main crystalline phase to the glass phase is controlled by adding other raw materials, so that the microcrystal jade ware is prepared out. In the production process, the raw materials are accurately weighed, fully mixed and then melted at a high temperature; the materials are selected manually or mechanically fed, and a mold is used for forming; then nucleation, crystallization and thermal treatment of annealing are carried out; and finally the steps of carving, drawing, decoration firing and the like are carried out. The microcrystal jade ware has the transparent or semitransparent character, moisture degree and wax feel of natural jades and resists high temperature; and compared with general glass wares, the low-corrosion microcrystal jade ware has high strength, is not easy to break and is attractive and practical.
Description
Technical field
A kind of low corrosion microcrystalline jade vessel and making method belong to the devitrified glass technical field.
Background technology
Glassware is indispensable necessary article in the people's lives, the huge market demand.Product category is various.Along with growth in the living standard, attractive and durable and the product that human body is safe from harm favored.
Jade stone glassware is mainly with Na in the market
2O-CaO-SiO
2To be that in addition high fluorine is low-phosphorous on the basis be the glassy product of milkiness thing to P series glass.There is wayward opacity aborning in this series products, and to the kiln seriously corroded, kiln is short work-ing life, and product cost is large, and high fluorin volatilization is serious, and human body is had injury, contaminate environment, the shortcoming such as product is easily crisp, and aberration is large.
In view of present jade glassware production status and the market requirement, the present invention has produced the transparent translucent beautiful matter shape of natural jade by new preparation method, moist degree and wax sense, higher than simple glass vessel intensity, high temperature resistant, difficult broken, both artistic and practical microcrystalline jade, and utilize this microcrystalline jade to produce the method for microcrystalline jade vessel.
Summary of the invention
The technical problem to be solved in the present invention is: overcome the technical deficiency of currently available products, when a kind of production is provided kiln is corroded light a kind of low corrosion microcrystalline jade vessel and making method.
The technical solution adopted for the present invention to solve the technical problems is: a kind of low corrosion microcrystalline jade vessel, it is characterized in that: adopt microcrystalline jade to make, the parts by weight of raw materials of described microcrystalline jade consists of: 45 ~ 68 parts raw mineral materials, 0 ~ 15 part aluminum oxide, 18 ~ 28 parts yellow soda ash, 5 ~ 6 parts magnesium oxide, 2 ~ 3 parts titanium oxide, 1 ~ 3 part zinc oxide and 2 parts SODIUMNITRATE.
Described raw mineral materials is one or more arbitrary proportion mixtures in quartz sand, albite, the alabaster.
The chemical constitution mass percent of microcrystalline jade is: SiO
245 ~ 55%, Na
2O 15 ~ 25%, Al
2O
315 ~ 25%, MgO 5 ~ 7%, TiO
22 ~ 4%, ZnO1 ~ 4%, trace impurity.
The parts by weight of raw materials of described microcrystalline jade forms with the contained chemical composition proportioning of component, and wherein albite mainly contains SiO
2, Na
2O, Al
2O
3, the alabaster raw mineral materials mainly contains SiO
2, Al
2O
3, raw mineral materials can add the requirement that aluminum oxide, yellow soda ash, magnesium oxide form the raw material composite chemical after selected during batching.
The volume fraction of trichroite crystalline phase is 40 ~ 50% in the described microcrystalline jade, and the volume fraction of glassy phase is 50 ~ 60%.
A kind of making method of low corrosion microcrystalline jade vessel is characterized in that, the concrete technology step is:
1, formulating of recipe: with above-mentioned raw materials, through accurate weighing, evenly be mixed with out mixing raw material;
2, fusing: the raw material that mixes is evenly dropped into smelting furnace, at 1460 ℃ ~ 1500 ℃ fusing 3 ~ 6h, form qualified glass metal by homogenizing, clarification;
3, work in-process moulding: qualified glass metal utilizes mould molding by manually choosing material or mechanical feed, prepares required vessel work in-process;
4, subsequent annealing: work in-process are carried out forming core, crystallization processing, and the microcrystalline jade vessel are prepared in short annealing again;
5, precision work: microcrystalline jade vessel engraving, drawing, decoration firing, manufacture multiple product.
The concrete operations of the described subsequent annealing of step 4 are: work in-process are carried out crystallization through the track type stove process, at 590 ~ 620 ℃ of forming cores, be warmed up to the highest 790 ~ 820 ℃ of crystallization by 3 ~ 5h again, be annealed to room temperature through 3 ~ 4h by 790 ~ 820 ℃ again, prepare the microcrystalline jade vessel.
[0013]This product is than Duoing upper nucleation, crystallization processing in the simple glass vessel production process, so that this product formation is with MgO-Al
2O
3-SiO
2P series glass is that the basis makes and contains main crystalline phase trichroite and be controlled at 40 ~ 50%, and glassy phase is controlled at 50 ~ 60% devitrified glass vessel.
The present invention by exclusive microcrystalline jade prescription and production technique, prepares Novel crystallite jade vessel product in conjunction with the glassware mode of production of maturation.With to compare the kiln extent of corrosion take the low-phosphorous milkiness jade glassware as emulsification of high fluorine little, cost is low, and volatilization is few, and is pollution-free to air.
Compared with prior art, the beneficial effect that a kind of low corrosion microcrystalline jade vessel of the present invention and making method have is: microcrystalline jade vessel of the present invention have the transparent translucent beautiful matter shape of natural jade, moist degree and wax sense; Higher, high temperature resistant than simple glass vessel intensity, difficult broken, both artistic and practical.Invention is with MgO-Al
2O
3-SiO
2P series glass is the basis, produces the common emulsion opal glass vessel of neutralization and compares, and not serious to the kiln corrosion, kiln lengthens work-ing life, and product cost reduces, good product quality, and the control no color differnece does not have fluorine to wave gas.
Embodiment
Below by implementation a kind of low corrosion microcrystalline jade vessel of the present invention and making method are described further, wherein embodiment 1 is most preferred embodiment.
Embodiment 1
1, formulating of recipe: select raw material (weight part): 64 parts of alabasters, 6 parts of aluminum oxide, 18 parts of yellow soda ash, 6 parts of magnesium oxide, 3 parts of titanium oxide, 1 part of zinc oxide, 2 parts of SODIUMNITRATE evenly are mixed with out raw material through accurate weighing;
2, fusing: will mix raw material and drop into smelting furnace, and at 1460 ℃ of fusing 4h, form qualified glass metal by homogenizing, clarification;
3, work in-process moulding: qualified glass metal utilizes mould molding by manually choosing material, prepares required tableware work in-process;
4, subsequent annealing: work in-process are carried out crystallization through the track type stove process, be warmed up to the highlyest 820 ℃ by 600 ℃ by 3h, prepare by annealing the microcrystalline jade vessel through 3h again;
5, precision work: microcrystalline jade vessel engraving, drawing, decoration firing, manufacture multiple product.
Getting the mass percent that the made microcrystalline jade vessel of the present embodiment detect its microcrystalline jade chemical constitution is: SiO
252%, Na
2O 21%, Al
2O
316%, MgO 6%, TiO
23%, ZnO1%, all the other are impurity.
Embodiment 2
1, formulating of recipe: according to its composition, select raw material (weight part): 45 parts of quartz sands, 15 parts of aluminum oxide, 28 parts of yellow soda ash, 5 parts of magnesium oxide, 2 parts of titanium oxide, 3 parts of zinc oxide, 2 parts of SODIUMNITRATE evenly are mixed with out raw material through accurate weighing;
2, fusing: will mix raw material and drop into smelting furnace, and at 1480 ℃ of fusing 5h, form qualified glass metal by homogenizing, clarification;
3, work in-process moulding: qualified glass metal utilizes mould molding by mechanical feed, prepares required vessel work in-process;
4, subsequent annealing: work in-process are carried out crystallization through the track type stove process, be warmed up to the highlyest 800 ℃ by 620 ℃ by 4h, prepare by annealing the microcrystalline jade vessel through 3h again;
5, precision work: as requested the microcrystalline jade vessel carved, drawing, decoration firing, produce multiple product.
Getting the mass percent that the made microcrystalline jade vessel of the present embodiment detect its microcrystalline jade chemical constitution is: SiO
245%, Na
2O 18%, Al
2O
325%, MgO 5%, TiO
22%, ZnO4%, all the other are impurity.
Embodiment 3
1, formulating of recipe: according to its composition, select raw material (weight part): 68 parts of albites, 20 parts of yellow soda ash, 5 parts of magnesium oxide, 3 parts of titanium oxide, 2 parts of zinc oxide, 2 parts of SODIUMNITRATE evenly are mixed with out raw material through accurate weighing;
2, fusing: will mix raw material and drop into smelting furnace, and at 1500 ℃ of fusing 6h, form qualified glass metal by homogenizing, clarification;
3, work in-process moulding: qualified glass metal utilizes mould molding by manually choosing material or mechanical feed, prepares required vessel work in-process;
4, subsequent annealing: work in-process are carried out crystallization through the track type stove process, be warmed up to by 5h by 590 ℃ the highest 790 ℃, again through preparing the microcrystalline jade vessel after the 3h annealing;
5, precision work: jade crystallite vessel are carved made finished product as requested.
Getting the mass percent that the made microcrystalline jade vessel of the present embodiment detect its microcrystalline jade chemical constitution is: SiO
254%, Na
2O 17%, Al
2O
315%, MgO 5%, TiO
24%, ZnO4%, all the other are impurity.
Embodiment 4
1, formulating of recipe: select raw material (weight part): 35 parts of albites, 20 parts of quartz sands, 10 parts of aluminum oxide, 23 parts of yellow soda ash, 6 parts of magnesium oxide, 3 parts of titanium oxide, 1 part of zinc oxide, 2 parts of SODIUMNITRATE evenly are mixed with out raw material through accurate weighing;
2, fusing: will mix raw material and drop into smelting furnace, and at 1460 ℃ of fusing 4h, form qualified glass metal by homogenizing, clarification;
3, work in-process moulding: qualified glass metal utilizes mould molding by manually choosing material, prepares required vessel work in-process;
4, subsequent annealing: work in-process are carried out crystallization through the track type stove process, be warmed up to the highlyest 820 ℃ by 600 ℃ by 3h, prepare by annealing the microcrystalline jade vessel through 4h again;
5, precision work: microcrystalline jade vessel engraving, drawing, decoration firing, manufacture multiple product.
Getting the mass percent that the made microcrystalline jade vessel of the present embodiment detect its microcrystalline jade chemical constitution is: SiO
245%, Na
2O 25%, Al
2O
318%, MgO 6%, TiO
23%, ZnO2%, all the other are impurity.
Embodiment 5
1, formulating of recipe: according to its composition, select raw material (weight part): 40 parts of alabasters, 20 parts of quartz sands, 8 parts of aluminum oxide, 20 parts of yellow soda ash, 5 parts of magnesium oxide, 3 parts of titanium oxide, 2 parts of zinc oxide, 2 parts of SODIUMNITRATE evenly are mixed with out raw material through accurate weighing;
2, fusing: will mix raw material and drop into smelting furnace, and at 1500 ℃ of fusing 6h, form qualified glass metal by homogenizing, clarification;
3, work in-process moulding: qualified glass metal utilizes mould molding by manually choosing material or mechanical feed, prepares required vessel work in-process;
4, subsequent annealing: work in-process are carried out crystallization through the track type stove process, be warmed up to by 5h by 590 ℃ the highest 790 ℃, again through preparing the microcrystalline jade vessel after the 3.5h annealing;
5, precision work: jade crystallite vessel are carved made finished product as requested.
Getting the mass percent that the made microcrystalline jade vessel of the present embodiment detect its microcrystalline jade chemical constitution is: SiO
250%, Na
2O 19%, Al
2O
320%, MgO 5%, TiO
23%, ZnO2%, all the other are impurity.
The above only is preferred embodiment of the present invention, is not to be the restriction of the present invention being made other form, and any those skilled in the art may utilize the technology contents of above-mentioned announcement to be changed or be modified as the equivalent example of equivalent variations.But every technical solution of the present invention content that do not break away from according to any simple modification, equivalent variations and the remodeling that technical spirit of the present invention is done above example, still belongs to the protection domain of technical solution of the present invention.
Claims (6)
1. one kind low corrodes the microcrystalline jade vessel, it is characterized in that: adopt microcrystalline jade to make, the parts by weight of raw materials of described microcrystalline jade consists of 45 ~ 68 parts raw mineral materials, 0 ~ 15 part aluminum oxide, 18 ~ 28 parts yellow soda ash, 5 ~ 6 parts magnesium oxide, 2 ~ 3 parts titanium oxide, 1 ~ 3 part zinc oxide and 2 parts SODIUMNITRATE.
2. a kind of low corrosion microcrystalline jade vessel according to claim 1, it is characterized in that: described raw mineral materials is one or more arbitrary proportion mixtures in quartz sand, albite, the alabaster.
3. a kind of low corrosion microcrystalline jade vessel according to claim 1, it is characterized in that: the chemical constitution mass percent of described microcrystalline jade is SiO
245 ~ 55%, Na
2O 15 ~ 25%, Al
2O
315 ~ 25%, MgO 5 ~ 7%, TiO
22 ~ 4%, ZnO1 ~ 4%, trace impurity.
4. each described a kind of low corrosion microcrystalline jade vessel according to claim 1 ~ 3, it is characterized in that: the volume fraction of trichroite crystalline phase is 40 ~ 50% in the described microcrystalline jade, the volume fraction of glassy phase is 50 ~ 60%.
5. a making method of utilizing each described a kind of low corrosion microcrystalline jade vessel of claim 1 ~ 4 is characterized in that, the concrete technology step is:
5.1, formulating of recipe: with described raw material accurate weighing in proportion, evenly mix;
5.2, fusing: the raw material that mixes is evenly dropped into smelting furnace, at 1460 ℃ ~ 1500 ℃ fusing 3 ~ 6h, forms qualified glass metal by homogenizing, clarification;
5.3, the work in-process moulding: qualified glass metal by manually choose the material or mechanical feed utilize mould molding, prepare required vessel work in-process;
5.4, subsequent annealing: work in-process are carried out nucleation, crystallization and anneal prepare low corrosion microcrystalline jade vessel;
5.5, precision work: to the microcrystalline jade vessel carve, the precision work such as drawing, decoration firing process.
6. the making method of a kind of low corrosion microcrystalline jade vessel according to claim 5, it is characterized in that: the concrete operations of the described subsequent annealing of step 5.4 are: work in-process are carried out crystallization through the track type stove process, at 590 ~ 620 ℃ of forming cores, be warmed up to the highest 790 ~ 820 ℃ of crystallization by 3 ~ 5h again, be annealed to room temperature through 3 ~ 4h by 790 ~ 820 ℃ again, prepare the microcrystalline jade vessel.
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|---|---|---|---|
| CN 201310001578 CN103011603A (en) | 2013-01-05 | 2013-01-05 | Low-corrosion microcrystal jade ware and manufacturing method thereof |
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|---|---|---|---|
| CN 201310001578 CN103011603A (en) | 2013-01-05 | 2013-01-05 | Low-corrosion microcrystal jade ware and manufacturing method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103641315A (en) * | 2013-12-06 | 2014-03-19 | 辽宁红山玉科技有限公司 | Preparation method of bowlder-like microcrystalline glass |
| CN103663968A (en) * | 2013-12-06 | 2014-03-26 | 辽宁红山玉科技有限公司 | Preparation method for jade-like microcrystalline glass |
| CN110040953A (en) * | 2019-06-04 | 2019-07-23 | 纪业 | A kind of imitation jade of glass vessel and formula and preparation method |
-
2013
- 2013-01-05 CN CN 201310001578 patent/CN103011603A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103641315A (en) * | 2013-12-06 | 2014-03-19 | 辽宁红山玉科技有限公司 | Preparation method of bowlder-like microcrystalline glass |
| CN103663968A (en) * | 2013-12-06 | 2014-03-26 | 辽宁红山玉科技有限公司 | Preparation method for jade-like microcrystalline glass |
| CN103641315B (en) * | 2013-12-06 | 2015-09-23 | 辽宁红山玉科技有限公司 | A kind of preparation method of bowlder-like devitrified glass |
| CN110040953A (en) * | 2019-06-04 | 2019-07-23 | 纪业 | A kind of imitation jade of glass vessel and formula and preparation method |
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Application publication date: 20130403 |