CN106242279A - Crack preventing glass and preparation method thereof - Google Patents
Crack preventing glass and preparation method thereof Download PDFInfo
- Publication number
- CN106242279A CN106242279A CN201610806157.2A CN201610806157A CN106242279A CN 106242279 A CN106242279 A CN 106242279A CN 201610806157 A CN201610806157 A CN 201610806157A CN 106242279 A CN106242279 A CN 106242279A
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- China
- Prior art keywords
- consumption
- parts
- glass
- preparation
- crack preventing
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
Abstract
The invention discloses a kind of crack preventing glass and preparation method thereof, the method includes: the stirring of arsenicum sablimatum, carborundum, decolorising agent, grinding aid, corrosion inhibiter, adhesive, silicon dioxide, sodium carbonate and Pulvis Talci is mixed to prepare powder；Described powder is carried out heating again and makes the molten slurry of glass；Then by mechanical-moulded for molten for described glass slurry；Described crack preventing glass is made in finally annealing；Wherein, in parts by weight, relative to 200 parts of Pulvis Talci, the consumption of described arsenicum sablimatum is 10 25 parts, and the consumption of carborundum is 10 30 parts, the consumption of decolorising agent is 10 30 parts, the consumption of grinding aid is 10 15 parts, and the consumption of corrosion inhibiter is 25 40 parts, and the consumption of adhesive is 10 20 parts, the consumption of silicon dioxide is 10 30 parts, and the consumption of sodium carbonate is 10 25 parts.The crack preventing glass prepared by the method has the mechanical mechanics property of excellence.
Description
Technical field
The present invention relates to glass, be specifically related to crack preventing glass and preparation method thereof.
Background technology
Glass is with Pulvis Talci, soda, Anhydrite and limestone etc. as raw material, through mixing, high-temperature fusion, homogenize after, processing
Shape, more annealed and silicates nonmetallic materials.Glass forms contiguous network structure when melted, in cooling procedure
Viscosity is gradually increased and hardens final molding.The main component of simple glass is silicate double salt, is a kind of random structure
Non-crystalline solids.Separately have and be mixed into the oxide of some metal or salt and show the coloured glass of color, and pass through thing
The safety glass etc. that the method for reason or chemistry prepares.Glass is because having good perspective, light transmission, high compressive strength and relatively
The excellent specific properties such as high chemical stability and be widely used in the fields such as building, daily, medical, chemical, electronics, instrument, nuclear engineering.
Wherein, there is the defect easily broken in the such as glass of the glass for daily field.
Summary of the invention
An object of the present invention is to provide mild condition, the preparation method of crack preventing glass simple to operate.
It is a further object of the present invention to provide the shatter-resistant with excellent mechanical mechanical property being prepared from by said method
Split glass.
The preparation method of the crack preventing glass that the present invention provides includes: by arsenicum sablimatum, carborundum, decolorising agent, grinding aid, delay
Erosion agent, adhesive, silicon dioxide, sodium carbonate and Pulvis Talci stirring are mixed to prepare powder；Again described powder is carried out heating to make
The molten slurry of glass；Then by mechanical-moulded for molten for described glass slurry；Described crack preventing glass is made in finally annealing；Wherein, with weight
Part meter, relative to 200 parts of Pulvis Talci, the consumption of described arsenicum sablimatum is 10-25 part, and the consumption of carborundum is 10-30 part, decolorising agent
Consumption is 10-30 part, and the consumption of grinding aid is 10-15 part, and the consumption of corrosion inhibiter is 25-40 part, and the consumption of adhesive is 10-20
Part, the consumption of silicon dioxide is 10-30 part, and the consumption of sodium carbonate is 10-25 part.
In above-mentioned preparation method, the concrete kind of decolorising agent can select in wide scope, but prevents for improving this
Break the permeability of glass, it is preferable that one or more in sodium hypochlorite, potassium permanganate and ozone of decolorising agent.
In above-mentioned preparation method, the concrete kind of grinding aid can select in wide scope, taking cost into account, excellent
Selection of land, one or more in sodium soap, calcium chloride and sodium chloride of grinding aid.
In above-mentioned preparation method, the concrete kind of corrosion inhibiter can select in wide scope, but prevents for improving this
Break the hardness of glass, it is preferable that corrosion inhibiter one or many in zinc naphthenate, petroleum sodium sulfonate and barium mahogany sulfonate
Kind.
In above-mentioned preparation method, the concrete kind of adhesive can select in wide scope, but prevents for improving this
Break the toughness of glass, it is preferable that adhesive is selected from polyvinyl acetate, polyvinyl alcohol and the one of Vinylidene Chloride or many
Kind.
In above-mentioned preparation method, the temperature and time of high-temperature heating can select in wide scope, but in order to enter
One step improves the intensity of this crack preventing glass, it is preferable that the temperature of high-temperature heating is 1605-1710 DEG C, and the time is 100-
130min。
In above-mentioned preparation method, mechanical-moulded concrete grammar can select in wide scope, but, should for improving
The preparation precision of crack preventing glass and efficiency, it is preferable that the method pressing of mechanical-moulded employing.
In above-mentioned preparation method, at a temperature of annealing, reduction of speed rate and time can select in wide scope, but are
The intensity of this crack preventing glass of further raising, it is preferable that at a temperature of annealing, reduction of speed rate is 5-15 DEG C/min, annealing
Time is 80-100min.
Present invention also offers crack preventing glass, this crack preventing glass is to be prepared from by above-mentioned method.
By technique scheme, the present invention, by first by the raw material mixed grinding of each weight portion, then adds heat fusing, connects
Molding, described crack preventing glass is made in finally annealing.The method be a kind of with low cost, mild condition, environmental protection and
Mixed sintering method simple to operate, prepared crack preventing glass has the mechanical mechanics property of excellence.
Other features and advantages of the present invention will be described in detail in detailed description of the invention part subsequently.
Detailed description of the invention
Hereinafter the detailed description of the invention of the present invention is described in detail.It should be appreciated that described herein specifically
Embodiment is merely to illustrate and explains the present invention, is not limited to the present invention.
Embodiment 1
In parts by weight, by 12 parts of arsenicum sablimatums, 15 parts of carborundums, 15 parts of sodium hypochlorite, 10 parts of sodium soaps, 25 parts of aphthenic acids
Zinc, 11 parts of polyvinyl acetate, 15 parts of silicon dioxide, 10 parts of sodium carbonate and 200 parts of Pulvis Talci stirrings are mixed to prepare powder；Then at
At a temperature of 1610 DEG C, powder heating 105min is prepared the molten slurry of glass；Mechanical-moulded followed by pressing；Finally with 5 DEG C/
At a temperature of min, reduction of speed rate annealing 82min makes crack preventing glass A1.
Embodiment 2
In parts by weight, by 25 parts of arsenicum sablimatums, 30 parts of carborundums, 25 parts of potassium permanganate, 14 parts of calcium chloride, 38 parts of mahogany acids
Sodium, 20 parts of polyvinyl alcohol, 25 parts of silicon dioxide, 24 parts of sodium carbonate and 200 parts of Pulvis Talci stirrings are mixed to prepare powder；Then at 1710
At a temperature of DEG C, powder heating 130min is prepared the molten slurry of glass；Mechanical-moulded followed by pressing；Last with 15 DEG C/min
At a temperature of reduction of speed rate annealing 100min make crack preventing glass A2.
Embodiment 3
In parts by weight, by 17 parts of arsenicum sablimatums, 20 parts of carborundums, 20 parts of ozone, 12 parts of sodium chloride, 32 parts of barium mahogany sulfonates,
15 parts of Vinylidene Chloride, 20 parts of silicon dioxide, 17 parts of sodium carbonate and 200 parts of Pulvis Talci stirrings are mixed to prepare powder；Then at 1655 DEG C
At a temperature of powder heating 120min is prepared the molten slurry of glass；Mechanical-moulded followed by pressing；Last with 10 DEG C/min's
Temperature fall off rate annealing 90min makes crack preventing glass A3.
Comparative example 1
Preparing glass B1 according to the method for embodiment 1, except for the difference that, the consumption adding carborundum is 0.5 weight portion, two
The consumption of silicon oxide is 80 weight portions.
Comparative example 2
Preparing glass B2 according to the method for embodiment 1, except for the difference that, the consumption adding arsenicum sablimatum is 5 weight portions, sodium carbonate
Consumption be 0.5 weight portion.
Detection example 1
Universal testing machine is utilized the glass that above-described embodiment and comparative example prepare to be carried out the mensuration of mechanical performance, specifically
The results are shown in Table 1.
Table 1
| Toughness/MPa | Tensile strength/MPa | Elongation percentage/% | |
| A1 | 650 | 760 | 7 |
| A2 | 670 | 750 | 6.5 |
| A3 | 654 | 760 | 6.8 |
| B1 | 320 | 480 | 2 |
| B2 | 350 | 500 | 3.5 |
By above-mentioned detection example, the crack preventing glass prepared by above-described embodiment has that toughness is big, tensile strength
Greatly, the characteristic that elongation percentage is big.Being learnt by the testing result of above-described embodiment, the crack preventing glass that the present invention provides has excellent
Different mechanical mechanics property.Additionally, from preparation method provided by the present invention it can be seen that the present invention provide crack preventing glass
The preparation method of cup is simple and safe.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited in above-mentioned embodiment
Detail, in the technology concept of the present invention, technical scheme can be carried out multiple simple variant, this
A little simple variant belong to protection scope of the present invention.
It is further to note that each the concrete technical characteristic described in above-mentioned detailed description of the invention, at not lance
In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to various can
The compound mode of energy illustrates the most separately.
Additionally, combination in any can also be carried out between the various different embodiment of the present invention, as long as it is without prejudice to this
The thought of invention, by material mixing reheats molding, crack preventing glass is made in finally annealing, and it should be considered as this equally
Invention disclosure of that.
Claims (9)
1. the preparation method of a crack preventing glass, it is characterised in that by arsenicum sablimatum, carborundum, decolorising agent, grinding aid, inhibition
Agent, adhesive, silicon dioxide, sodium carbonate and Pulvis Talci stirring are mixed to prepare powder；Again described powder is carried out heating and make glass
The molten slurry of glass；The most mechanical-moulded；Then by mechanical-moulded for molten for described glass slurry；Described crack preventing glass is made in finally annealing；
Wherein, in parts by weight, relative to 200 parts of Pulvis Talci, the consumption of described arsenicum sablimatum is 10-25 part, and the consumption of carborundum is
10-30 part, the consumption of decolorising agent is 10-30 part, and the consumption of grinding aid is 10-15 part, and the consumption of corrosion inhibiter is 25-40 part, glue
The consumption of glutinous agent is 10-20 part, and the consumption of silicon dioxide is 10-30 part, and the consumption of sodium carbonate is 10-25 part.
Preparation method the most according to claim 1, wherein, described decolorising agent is selected from sodium hypochlorite, potassium permanganate and ozone
In one or more.
Preparation method the most according to claim 1, wherein, described grinding aid is selected from sodium soap, calcium chloride and sodium chloride
In one or more.
Preparation method the most according to claim 1, wherein, described corrosion inhibiter is selected from zinc naphthenate, petroleum sodium sulfonate and stone
One or more in oil barium sulfonate.
Preparation method the most according to claim 1, wherein, described adhesive selected from polyvinyl acetate, polyvinyl alcohol and
One or more of Vinylidene Chloride.
6. according to the preparation method according to any one of claim 1-5, wherein, the temperature of described heating is 1605-1710 DEG C,
Time is 100-130min.
Preparation method the most according to claim 6, wherein, described mechanical-moulded method is pressing.
Preparation method the most according to claim 6, wherein, at a temperature of described annealing, reduction of speed rate is 5-15 DEG C/min, institute
The time stating annealing is 80-100min.
9. a crack preventing glass, it is characterised in that described crack preventing glass is by any one institute in claim 1-8
The method stated is prepared from.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610806157.2A CN106242279A (en) | 2016-09-07 | 2016-09-07 | Crack preventing glass and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610806157.2A CN106242279A (en) | 2016-09-07 | 2016-09-07 | Crack preventing glass and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106242279A true CN106242279A (en) | 2016-12-21 |
Family
ID=57599519
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610806157.2A Pending CN106242279A (en) | 2016-09-07 | 2016-09-07 | Crack preventing glass and preparation method thereof |
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| Country | Link |
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| CN (1) | CN106242279A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114409255A (en) * | 2022-02-10 | 2022-04-29 | 淄博泰康轻工制品有限公司 | Breakage-proof glass cup |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4615987A (en) * | 1985-04-15 | 1986-10-07 | Corning Glass Works | Reinforcement of alkaline earth aluminosilicate glass-ceramics |
| CN85108524A (en) * | 1985-04-15 | 1986-10-15 | 康宁玻璃厂 | Enhanced alkaline-earth aluminosilicate glass |
| CN103043909A (en) * | 2012-12-29 | 2013-04-17 | 青岛崂山玻璃有限公司 | Fabrication method of beer bottle |
| CN104386914A (en) * | 2014-10-30 | 2015-03-04 | 泸州观宇玻璃制品有限公司 | Method for preparing glass cup |
| CN104445942A (en) * | 2014-12-09 | 2015-03-25 | 新沂市新奥特玻璃制品有限公司 | Lead-free porcelain imitation glass wine bottle and manufacture process thereof |
-
2016
- 2016-09-07 CN CN201610806157.2A patent/CN106242279A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4615987A (en) * | 1985-04-15 | 1986-10-07 | Corning Glass Works | Reinforcement of alkaline earth aluminosilicate glass-ceramics |
| CN85108524A (en) * | 1985-04-15 | 1986-10-15 | 康宁玻璃厂 | Enhanced alkaline-earth aluminosilicate glass |
| CN103043909A (en) * | 2012-12-29 | 2013-04-17 | 青岛崂山玻璃有限公司 | Fabrication method of beer bottle |
| CN104386914A (en) * | 2014-10-30 | 2015-03-04 | 泸州观宇玻璃制品有限公司 | Method for preparing glass cup |
| CN104445942A (en) * | 2014-12-09 | 2015-03-25 | 新沂市新奥特玻璃制品有限公司 | Lead-free porcelain imitation glass wine bottle and manufacture process thereof |
Non-Patent Citations (1)
| Title |
|---|
| 田英良等主编: "《新编玻璃工艺学》", 30 June 2009 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114409255A (en) * | 2022-02-10 | 2022-04-29 | 淄博泰康轻工制品有限公司 | Breakage-proof glass cup |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161221 |
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