CN103318507A - Method for producing lead-free low-temperature embossed decoration-fired glass wine bottles - Google Patents
Method for producing lead-free low-temperature embossed decoration-fired glass wine bottles Download PDFInfo
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- CN103318507A CN103318507A CN2013102304149A CN201310230414A CN103318507A CN 103318507 A CN103318507 A CN 103318507A CN 2013102304149 A CN2013102304149 A CN 2013102304149A CN 201310230414 A CN201310230414 A CN 201310230414A CN 103318507 A CN103318507 A CN 103318507A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
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Abstract
The invention discloses a method for producing lead-free low-temperature embossed decoration-fired glass wine bottles and belongs to the field of glass manufacturing. According to the method, lead-free white broken glass, white quartz sand, sodium carbonate, albites, calcites, anhydrous sodium sulphate, cobalt powder, 2mm-thick pattern paper and removable films are used as raw materials. A water washer, a mixing machine, a boiler, a kiln, a forming machine, an annealing box, an adapter sticking box, a gas glass decoration firing furnace and a film removing box serve as equipment. The method comprises the steps of water washing of the lead-free white broken glass, raw material mixing, fusing, forming, annealing, film sticking, decoration firing and film tearing off to obtain the lead-free low-temperature embossed decoration-fired glass wine bottles. The method has the advantages of being simple in process, capable of obtaining raw materials conveniently, low in production cost, pollution-free and applicable to industrial production. The product lead-free low-temperature embossed decoration-fired glass wine bottles can be used as packaging materials for high-grade white spirits and are lead-free and recyclable after usage.
Description
Technical field
The invention belongs to glass manufacturing area, relate in particular to a kind of production method of lead-free low-temperature embossment decoration firing glass wine bottle.
Background technology
Glass types is various, principal item is silicate glass, the composition of silicate glass is: the content of silicon dioxide is between 55%-65%, the content of sodium oxide molybdena is 15%, the content of calcium oxide is 15%, also contain a certain amount of lead-oxide, because it contains lead, if directly be used for making tea set, drinking utensils, bottle, the people is plumbous in the process of drink tea or wine just might to enter human body, there is part can pass through ight soil although enter the lead of human body, sweat is drained, but still have the lead of part will dissolve in blood, hinder the synthetic of blood, cause the human body anaemia, headache occurs, dizzy, weak, sleepy, constipation and limb aching pain etc., and then cause artery sclerosis, symptom such as digestive tract ulcer and fundus hemorrhage.Along with the enhancing of people's environmental consciousness, use the crown glass vessel to become people's common recognition.Crown glass has its following advantage than flint glass: it is more melodized that crown glass knocks the metallic sound that sends than flint glass; Crown glass than flint glass vessel more flexible be the impact resistance performance; It is nontoxic that crown glass is used for making tea set, drinking utensils, kitchen vessel than flint glass.Variation along with the propensity to consume, the high-grade wine kind of China is more and more, requirement to packing material is also more and more higher, single colourless bottle has been difficult to adapt to high-grade wine packing requirements, therefore then follow-up synchronously of manufacture, the decoration firing glass wine bottle has been come into people's the visual field gradually, the image color of decoration firing glass wine bottle is gorgeous, graceful magnificent, never fade, water-fast, anti-wine, wear-resisting, firmness is high, hardness is high, becomes the first-selection of high-grade wine-bottle.So-called decoration firing is a kind of decoration firing technology of glass wine bottle, characteristics are that exquisite colored glaze pattern directly is attached on the good glasswork of blowing, sent in the oven by belt conveyor, through heating up, high temperature, behind the cooling supervisor, multicolour pattern is bonded on the glass surface, and demonstrate gloss, make pigment be combined with the glass face and be fixed up, make the glasswork that has exquisite multicolour pattern, along with the development of decoration firing technique, the embossment decoration firing is used again gradually, and so-called embossment decoration firing is exactly that the pattern hand that bakes has been touched concave-convex sense, looked and made its exterior design fuller by three-dimension effect.Decoration firing has leaded and not leaded branch, and unleaded decoration firing ratio has plumbous decoration firing to be used for making the bottle safety and reliability; But the paster that decoration firing is used divides dyestripping and dyestripping not, but the advantage of dyestripping is: the decoration firing temperature only needs 180-200 ℃, but has copied the need dyestripping; Dyestripping is not easy and simple to handle, but higher and technology difficulty is big to raw-material requirements for quality, and the decoration firing temperature needs more than 600 ℃.The present invention is a kind of production method of lead-free low-temperature embossment decoration firing glass wine bottle, but this method is at first selected unleaded dyestripping for use, and adopts the temperature below 200 ℃ to carry out low-temperature bake, and operation easier is lower.The raw material that the present invention uses is: but the pattern marble paper of no lead white cullet, white quarz sand, soda ash, albite, calc spar, glauber salt, cobalt powder, two millimeters thick and dyestripping are raw material, pasting case, combustion gas glass decoration firing kiln, striping case with rinsing machine, blending machine, boiler, kiln, make-up machine, annealing box, commentaries on classics is equipment, makes lead-free low-temperature embossment decoration firing glass wine bottle behind the washing by no lead white cullet, the mixing of raw material, fusion, moulding, annealing, pad pasting, decoration firing, the dyestripping.The combustion gas glass decoration firing kiln that uses is a kind of of decoration firing kiln, can be used for the decoration firing of multiple glass ware, the burner hearth active volume: 6 cubic meters, car-type, serviceability temperature is between 150 ℃-650 ℃ and adjustable, and temperature control method is manually and automatically to regulate, temperature-controlled precision ± 3 ℃.The major advantage of this production method is: the waste and old crown glass goods of primary raw material for reclaiming, and cheap; Quarz sand is that the real estate resources source is abundant; Poisonous elements such as not leaded in the product, arsenic, chromium, harmless; Product-forming is various, and decoration firing pattern solid is attractive in appearance; Product is mainly as the packing material of high-grade liquor, and the product recyclable utilization in back of finishing using is environment friendly and pollution-free.
Summary of the invention:
It is the method for primary raw material batch manufacturing lead-free low-temperature embossment decoration firing glass wine bottle with the no lead white cullet of purchase, white quarz sand that the problem that the present invention mainly solves provides a kind of, the plumbous low temperature embossment decoration firing glass wine bottle that this method is produced is exquisite in workmanship, decoration firing pattern solid is attractive in appearance, stable chemical performance, not leaded, and product is mainly as the packing material of high-grade liquor.The raw material weight proportioning that the present invention uses is: no lead white cullet 34%-36%, real estate quarz sand 38%-40%, soda ash 9%, albite 12%, calc spar 4.6%, glauber salt 0.2%, cobalt powder 0.2%; But the pattern marble paper dyestripping of two millimeters thick and system bottle do not belong to same reaction, and its consumption is one pair every bottle.
The present invention can be achieved through the following technical solutions:
A kind of production method of lead-free low-temperature embossment decoration firing glass wine bottle is characterized in that being made of following steps:
(1) will purchase no lead white cullet and send into rinsing machine and wash repeatedly with high pressure water, dry naturally the flushing back.
(2) no lead white cullet, real estate quarz sand, soda ash, albite, calc spar, glauber salt, the cobalt powder cleaned of formula ratio are sent into the blending of blending machine and evenly obtain mixture, by conveyer mixture is sent into kiln.
(3) coal is sent into boiler combustion, 540 ℃-560 ℃ the coal gas that burning obtains is sent into kiln sealing combustion in kiln by the coal gas gas line, make the temperature of mixture reach 1550 ℃-1560 ℃, kept this temperature 26-28 hour, make mixture reach molten condition, obtain the crown glass molten mass.
(4) the crown glass molten mass is sent into make-up machine, control moulding built-in temperature is 1020 ℃-1080 ℃, makes the crown glass bottle of certain specification.
Send into annealing box with conveyer when (5) the crown glass bottle of moulding being cooled to 700 ℃ naturally, annealing the temperature inside the box is 680-700 ℃, 2.5-3.0 hour time of process cools the temperature to about 150 ℃ then, this moment, annealing finished, the crown glass bottle is sent in the air, in air, naturally cooled to normal temperature.
(6) the crown glass bottle is sent into commentaries on classics and pasted case: the pattern marble paper of two millimeters thick that will design is put into water and is soaked after 30 seconds, the whole pattern that is connected by front cover oil can strip down from base stock, the pattern that strips down directly is attached on the glass bottle, but after to be dried pattern is fixed with dyestripping.
(7) but will be pinup picture case and sent into combustion gas glass decoration firing kiln with conveyer by the fixing glass bottle of dyestripping, temperature is between 185 ℃-195 ℃ in the input fuel gas buring control combustion gas glass decoration firing kiln, the sight pinkeye of reserving in the time of can be by banking is observed in the stove and is burnt till situation, bottle is along with the rising pattern of temperature is slowly thickened by clear, turned to again when clear by fuzzy again, can stop to heat, be cooled to discharging behind the normal temperature naturally, obtain finished product but cooled bottle is thrown off dyestripping.
(8) using method of this lead-free low-temperature embossment decoration firing glass wine bottle is: as the packing material of high-grade liquor.
The fusion temperature of mixture is 1555 ℃ in the kiln described in the above-mentioned steps (3).
Annealing time in the annealing box described in the above-mentioned steps (5) is 2.75 hours.
Temperature in the combustion gas glass decoration firing kiln described in the above-mentioned steps (7) is 190 ℃.
The invention has the beneficial effects as follows: provide a kind of production method of lead-free low-temperature embossment decoration firing glass wine bottle, the characteristics that this method has that technology is simple, raw MAT'L convenient sources, productive costs are low, pollution-free, be fit to suitability for industrialized production; Product lead-free low-temperature embossment decoration firing glass wine bottle can be used as the packing material of high-grade liquor, and product is not leaded, the recyclable utilization in back of finishing using.
The specific embodiment
Below in conjunction with specific embodiment, the present invention is described in further detail.
Embodiment 1
The no lead white cullet of purchase are sent into rinsing machine wash repeatedly with high pressure water, dry naturally the flushing back.
Be 34% no lead white cullet of cleaning with accounting for total amount, to account for total amount be 40% real estate quarz sand, account for total amount is 9% soda ash, account for total amount is 12% albite, account for total amount is 4.6% calc spar, account for total amount is 0.2% glauber salt, account for total amount is that 0.2% cobalt powder is sent into the blending of blending machine and evenly obtained mixture, by conveyer mixture sent into kiln.Coal is sent into boiler combustion, 540 ℃-560 ℃ the coal gas that burning obtains is sent into kiln sealing combustion in kiln by the coal gas gas line, makes the temperature of mixture reach 1550 ℃, keeps this temperature 28 hours, make mixture reach molten condition, obtain the crown glass molten mass.The crown glass molten mass is sent into make-up machine, and control moulding built-in temperature is 1020 ℃-1080 ℃, makes the crown glass bottle of certain specification.When being cooled to 700 ℃ naturally, the crown glass bottle of moulding sends into annealing box with conveyer, annealing the temperature inside the box is 680 ℃, cools the temperature to about 150 ℃ through time of 2.5 hours then, and this moment, annealing finished, the crown glass bottle is sent in the air, in air, naturally cooled to normal temperature.The crown glass bottle is sent into commentaries on classics paste case: the pattern marble paper of two millimeters thick that will design was put into the water immersion after 30 seconds, the whole pattern that is connected by front cover oil can strip down from base stock, the pattern that strips down directly is attached on the glass bottle, but after to be dried pattern is fixed with dyestripping.With but pinup picture case and the fixing glass bottle of quilt dyestripping are sent into combustion gas glass decoration firing kiln with conveyer, temperature is 185 ℃ in the input fuel gas buring control combustion gas glass decoration firing kiln, the sight pinkeye of reserving in the time of can be by banking is observed in the stove and is burnt till situation, bottle is along with the rising pattern of temperature is slowly thickened by clear, turned to again when clear by fuzzy again, can stop to heat, be cooled to discharging behind the normal temperature naturally, obtain finished product but cooled bottle is thrown off dyestripping.
Embodiment 2
The no lead white cullet of purchase are sent into rinsing machine wash repeatedly with high pressure water, dry naturally the flushing back.
Be 35% no lead white cullet of cleaning with accounting for total amount, to account for total amount be 39% real estate quarz sand, account for total amount is 9% soda ash, account for total amount is 12% albite, account for total amount is 4.6% calc spar, account for total amount is 0.2% glauber salt, account for total amount is that 0.2% cobalt powder is sent into the blending of blending machine and evenly obtained mixture, by conveyer mixture sent into kiln.Coal is sent into boiler combustion, 540 ℃-560 ℃ the coal gas that burning obtains is sent into kiln sealing combustion in kiln by the coal gas gas line, makes the temperature of mixture reach 1555 ℃, keeps this temperature 27 hours, make mixture reach molten condition, obtain the crown glass molten mass.The crown glass molten mass is sent into make-up machine, and control moulding built-in temperature is 1020 ℃-1080 ℃, makes the crown glass bottle of certain specification.When being cooled to 700 ℃ naturally, the crown glass bottle of moulding sends into annealing box with conveyer, annealing the temperature inside the box is 690 ℃, cool the temperature to about 150 ℃ through time of 2.75 hours then, this moment, annealing finished, the crown glass bottle is sent in the air, in air, naturally cooled to normal temperature.The crown glass bottle is sent into commentaries on classics paste case: the pattern marble paper of two millimeters thick that will design was put into the water immersion after 30 seconds, the whole pattern that is connected by front cover oil can strip down from base stock, the pattern that strips down directly is attached on the glass bottle, but after to be dried pattern is fixed with dyestripping.With but pinup picture case and the fixing glass bottle of quilt dyestripping are sent into combustion gas glass decoration firing kiln with conveyer, temperature is 190 ℃ in the input fuel gas buring control combustion gas glass decoration firing kiln, the sight pinkeye of reserving in the time of can be by banking is observed in the stove and is burnt till situation, bottle is along with the rising pattern of temperature is slowly thickened by clear, turned to again when clear by fuzzy again, can stop to heat, be cooled to discharging behind the normal temperature naturally, obtain finished product but cooled bottle is thrown off dyestripping.
Embodiment 3
The no lead white cullet of purchase are sent into rinsing machine wash repeatedly with high pressure water, dry naturally the flushing back.
Be 36% no lead white cullet of cleaning with accounting for total amount, to account for total amount be 38% real estate quarz sand, account for total amount is 9% soda ash, account for total amount is 12% albite, account for total amount is 4.6% calc spar, account for total amount is 0.2% glauber salt, account for total amount is that 0.2% cobalt powder is sent into the blending of blending machine and evenly obtained mixture, by conveyer mixture sent into kiln.Coal is sent into boiler combustion, 540 ℃-560 ℃ the coal gas that burning obtains is sent into kiln sealing combustion in kiln by the coal gas gas line, makes the temperature of mixture reach 1560 ℃, keeps this temperature 26 hours, make mixture reach molten condition, obtain the crown glass molten mass.The crown glass molten mass is sent into make-up machine, and control moulding built-in temperature is 1020 ℃-1080 ℃, makes the crown glass bottle of certain specification.When being cooled to 700 ℃ naturally, the crown glass bottle of moulding sends into annealing box with conveyer, annealing the temperature inside the box is 700 ℃, cools the temperature to about 150 ℃ through time of 3.0 hours then, and this moment, annealing finished, the crown glass bottle is sent in the air, in air, naturally cooled to normal temperature.The crown glass bottle is sent into commentaries on classics paste case: the pattern marble paper of two millimeters thick that will design was put into the water immersion after 30 seconds, the whole pattern that is connected by front cover oil can strip down from base stock, the pattern that strips down directly is attached on the glass bottle, but after to be dried pattern is fixed with dyestripping.With but pinup picture case and the fixing glass bottle of quilt dyestripping are sent into combustion gas glass decoration firing kiln with conveyer, temperature is 195 ℃ in the input fuel gas buring control combustion gas glass decoration firing kiln, the sight pinkeye of reserving in the time of can be by banking is observed in the stove and is burnt till situation, bottle is along with the rising pattern of temperature is slowly thickened by clear, turned to again when clear by fuzzy again, can stop to heat, be cooled to discharging behind the normal temperature naturally, obtain finished product but cooled bottle is thrown off dyestripping.
Claims (5)
1. the production method of a lead-free low-temperature embossment decoration firing glass wine bottle, its composition of raw materials is counted by weight percentage, and comprising: no lead white cullet 34%-36%, real estate quarz sand 38%-40%, soda ash 9%, albite 12%, calc spar 4.6%, glauber salt 0.2%, cobalt powder 0.2%; But the pattern marble paper dyestripping of two millimeters thick and system bottle do not belong to same reaction, and its consumption is one pair every bottle; It is characterized in that:
Step (1) will be purchased no lead white cullet and be sent into rinsing machine and wash repeatedly with high pressure water, and dry naturally the flushing back;
No lead white cullet, real estate quarz sand, soda ash, albite, calc spar, glauber salt, the cobalt powder cleaned of step (2) formula ratio are sent into the blending of blending machine and are evenly obtained mixture, by conveyer mixture are sent into kiln;
Step (3) is sent coal into boiler combustion, 540 ℃-560 ℃ the coal gas that burning obtains is sent into kiln sealing combustion in kiln by the coal gas gas line, make the temperature of mixture reach 1550 ℃-1560 ℃, kept this temperature 26-28 hour, make mixture reach molten condition, obtain the crown glass molten mass;
Step (4) is sent the crown glass molten mass into make-up machine, and control moulding built-in temperature is 1020 ℃-1080 ℃, makes the crown glass bottle of certain specification;
When being cooled to 700 ℃ naturally with the crown glass bottle of moulding, step (5) sends into annealing box with conveyer, annealing the temperature inside the box is 680-700 ℃, 2.5-3.0 hour time of process cools the temperature to about 150 ℃ then, this moment, annealing finished, the crown glass bottle is sent in the air, in air, naturally cooled to normal temperature;
Step (6) is sent into the crown glass bottle to change and pasted case: the pattern marble paper of two millimeters thick that will design was put into the water immersion after 30 seconds, the whole pattern that is connected by front cover oil can strip down from base stock, the pattern that strips down directly is attached on the glass bottle, but after to be dried pattern is fixed with dyestripping;
Step (7) but will be pinup picture case and sent into combustion gas glass decoration firing kiln with conveyer by the fixing glass bottle of dyestripping, temperature is between 185 ℃-195 ℃ in the input fuel gas buring control combustion gas glass decoration firing kiln, the sight pinkeye of reserving in the time of can be by banking is observed in the stove and is burnt till situation, bottle is along with the rising pattern of temperature is slowly thickened by clear, turned to again when clear by fuzzy again, can stop to heat, be cooled to discharging behind the normal temperature naturally, obtain finished product but cooled bottle is thrown off dyestripping.
2. the production method of a kind of lead-free low-temperature embossment decoration firing glass wine bottle according to claim 1, its step (3) feature is: the fusion temperature of mixture is 1555 ℃ in the described kiln.
3. the production method of a kind of lead-free low-temperature embossment decoration firing glass wine bottle according to claim 1, its step (5) feature is: the annealing time in the described annealing box is 2.75 hours.
4. the production method of a kind of lead-free low-temperature embossment decoration firing glass wine bottle according to claim 1, its step (7) feature is: the temperature in the described combustion gas glass decoration firing kiln is 190 ℃.
5. the using method of this lead-free low-temperature embossment decoration firing glass wine bottle is: as the packing material of high-grade liquor.
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| CN2013102304149A CN103318507A (en) | 2013-06-12 | 2013-06-12 | Method for producing lead-free low-temperature embossed decoration-fired glass wine bottles |
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| CN2013102304149A CN103318507A (en) | 2013-06-12 | 2013-06-12 | Method for producing lead-free low-temperature embossed decoration-fired glass wine bottles |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104445941A (en) * | 2014-12-08 | 2015-03-25 | 新沂市新奥特玻璃制品有限公司 | Production method and decoration firing process of lead-free glass bottle |
| CN109399923A (en) * | 2018-11-22 | 2019-03-01 | 重庆市笙建玻璃有限公司 | A kind of production technology of lead-free high-temperature decoration firing glass container |
| CN110066110A (en) * | 2019-04-30 | 2019-07-30 | 武汉龙族药号生物医药科技有限公司 | The method of the imitative ceramic leakproof glass body of preparation and imitative ceramic leakproof vial |
| CN110255899A (en) * | 2019-06-17 | 2019-09-20 | 江苏双兴工贸有限公司 | A kind of formula and its production method of high temperature decoration firing glass container |
-
2013
- 2013-06-12 CN CN2013102304149A patent/CN103318507A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104445941A (en) * | 2014-12-08 | 2015-03-25 | 新沂市新奥特玻璃制品有限公司 | Production method and decoration firing process of lead-free glass bottle |
| CN104445941B (en) * | 2014-12-08 | 2016-04-13 | 新沂市新奥特玻璃制品有限公司 | A kind of making method of crown glass bottle and enamel firing process |
| CN109399923A (en) * | 2018-11-22 | 2019-03-01 | 重庆市笙建玻璃有限公司 | A kind of production technology of lead-free high-temperature decoration firing glass container |
| CN110066110A (en) * | 2019-04-30 | 2019-07-30 | 武汉龙族药号生物医药科技有限公司 | The method of the imitative ceramic leakproof glass body of preparation and imitative ceramic leakproof vial |
| CN110255899A (en) * | 2019-06-17 | 2019-09-20 | 江苏双兴工贸有限公司 | A kind of formula and its production method of high temperature decoration firing glass container |
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Application publication date: 20130925 |