CN109369218A - A kind of low temperature gloss marzacotto powder composition and preparation method thereof - Google Patents
A kind of low temperature gloss marzacotto powder composition and preparation method thereof Download PDFInfo
- Publication number
- CN109369218A CN109369218A CN201811407609.5A CN201811407609A CN109369218A CN 109369218 A CN109369218 A CN 109369218A CN 201811407609 A CN201811407609 A CN 201811407609A CN 109369218 A CN109369218 A CN 109369218A
- Authority
- CN
- China
- Prior art keywords
- glaze
- marzacotto
- low temperature
- gloss
- powder composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Dental Preparations (AREA)
Abstract
The invention discloses a kind of low temperature gloss marzacotto powder compositions, including following component: the pink mud of 30-40wt% potassium feldspar, 5-10wt%, 5-10wt% talcum, 25-30wt% quartz, 2-5wt%Al2O3, 15-20wt% calcite, 3-5wt%ZnO.The low temperature gloss marzacotto powder composition can be reduced to the firing temperature of glaze 1150 DEG C, and firing period is 3 hours or so；Sintered Ceramic glaze is flat and smooth, glossiness is good, hardness is high, water absorption rate is low, thermal stability, chemical stability are good, and ensure that glaze firing after glaze paint appearance property it is good, glossiness, light transmittance and hardness meet national Glaze for chinaware standard.
Description
Technical field
The present invention relates to the technical field of powder body material preparation process more particularly to a kind of low temperature gloss marzacotto powders
Formula and preparation method thereof.
Background technique
Gloss clear frit largely can be such that ceramic process effect highlights, the exquisiter beauty in surface.As compared with
A kind of common glaze, the main problem of gloss marzacotto are crystallizations.If with the presence of crystal, light warp in the glaze of firing
Repeatedly refraction and scattering will make glaze that milkiness color be presented, and frit glass body crystallization is that nucleus formation is coefficient with crystal growth
As a result, the principal crystalline phase of gloss marzacotto is glass phase, it is desirable that remaining crystal phase and crystallization are seldom, traditionally using " quasi- non-anti-
Answer " sintering mechanism promote liquid phase the lower temperature stage generate the transparent glaze of gloss and raw material to be not involved in high temperature physical reaction be difficult
To reach requirement.Firing temperature can be made to substantially reduce when being burnt into low-temp ceramics, but be not appropriate for low temperature gloss marzacotto
Preparation and production.
Summary of the invention
The purpose of the invention is to overcome the above-mentioned prior art, a kind of low temperature gloss marzacotto powder is provided
Formula and preparation method thereof, the low temperature gloss marzacotto powder composition can be reduced to the firing temperature of glaze 1150 DEG C, burn
It is 3 hours or so at the period；Sintered Ceramic glaze is flat and smooth, glossiness is good, hardness is high, water absorption rate is low, thermal stability,
Chemical stability is good, and ensure that glaze firing after glaze paint appearance property it is good, glossiness, light transmittance and hardness meet state
Family's Glaze for chinaware standard.
The technical solution adopted by the present invention to solve the technical problems is: a kind of low temperature gloss marzacotto powder composition,
Including following component: the pink mud of 30-40wt% potassium feldspar, 5-10wt%, 5-10wt% talcum, 25-30wt% quartz, 2-
5wt%Al2O3, 15-20wt% calcite, 3-5wt%ZnO.
In addition, including the following steps: the invention further relates to the preparation method of low temperature gloss marzacotto powder composition
(1) weigh in the balance the pink mud of 30-40wt% potassium feldspar, 5-10wt%, 5-10wt% talcum, 25-30wt% quartz,
2-5wt%Al2O3, 15-20wt% calcite, 3-5wt%ZnO；
(2) it is 250 mesh meshes above-mentioned raw materials component high speed grinding to fineness with ball mill and tails over < 0.5%, obtains low
Warm gloss marzacotto powder.
Potassium feldspar is produced using Hunan Deng Feng, white.Chemical formula K (AlSi3O8), it is most common most basic in feldspar race
It is a kind of.Each component theory group becomes 16.9%K2O, 18.4%Al2O3, 64.7%SiO2, belong to monoclinic system, common Ka Siba is bis-
Crystalline substance, density 2.56~2.59, Mohs' hardness 6.1150 DEG C ± 20 DEG C start to decompose melting, generate white garnet (K2O·Al2O3·
4SiO2) and silica glass, melt temperature scope is wide, and viscosity of high-temperature melt is big, and the raising of viscosity with temperature reduces quickly, has
Apparent fluxing action, while can also play high-temperature thermoplastic and high temperature cementation, it prevents ceramic high temperature from deforming, it is dry to improve it
Dry intensity.
Talcum uses Guangxi forest products, blocky, white.Chemical formula 3MgO4SiO2·H2O, each component theory group become
31.9%MgO, 63.4%SiO2, 4.7%H2O belongs to monoclinic system, and for crystal at hexagon or diamond shape plate, crystal structure is by two
A tetrahedral layer clips an octahedral layer and the unit that constitutes, and each ion electricity price has neutralized in layer, therefore contacts secured.Crystal collection
Zoarium is often at flakey or compact massive.Density 2.70~2.80, Mohs' hardness 1.Glaze layer elasticity can be improved as flux, reduced
Thermal expansion coefficient improves thermal stability, improves the whiteness, transparency and intensity of ceramic, can increase the temperature flowing of glaze,
Promote body-glaze intermediate layer to generate, improves the two associativity.But its flat crystal structure is easy to be formed in base glaze and align, and makes
It generates anisotropy, different directions can be caused to shrink in firing and cooling procedure uneven, so that biggish internal stress is generated,
Product is caused to crack.
Calcite is produced using Guangxi Quanzhou, white.Chemical formula CaCO3, each component theory group become CaO56%,
CO244%, belong to rectangle, six sides or trigonal system, aggregate granulates or plate sometimes at rhombohedron or scalenohedron body, density
2.71~2.94, Mohs' hardness 3.898.6 DEG C of decomposition temperature, when being used as ceramic blank glaze, plays leanization before decomposing, risen after decomposition
Fluxing action can shorten firing time, increase light transmittance, make once to be formed preferably among base glaze, enhance glaze-body bonding；Also it can be improved
Glaze paint refractive index increases its glossiness.
Pink mud is produced using Hunan, at pale pink color.Pink mud is a kind of complex mineral raw material, with more water containing 7*10-10m
Based on kaolin, and the quartzy impurity in part.More water kaolin structural formulas are Al2O32SiO22H2O belongs to monoclinic system.Each group
Sub-argument opinion group becomes 39.5%Al2O3, 46.54%SiO2, 13.96%H2O, density 2.54~2.60, Mohs' hardness 1.Belong to 1:
1 type layer aluminosilicate structure is contacted by Si-O tetrahedron Al-O or Al-OH octahedral layer by shared oxygen atom.
Pink mud is rich in SiO2And Al2O3, it is possible to provide glassy state forming agent is one of common raw mineral materials in glaze or blank.
Quartz is produced using Hunan Linxiang, white.SiO2Content is greater than 98%.The chief component of ceramic glaze is constituted
Glassy state skeleton can play the chemical stability and thermal stability of adjustment Ceramic glaze, increase its hardness, but the excessively high firing of dosage
Temperature is then excessively high.
In conclusion the firing temperature of glaze can be reduced to 1150 by low temperature gloss marzacotto powder composition of the invention
DEG C, firing period is 3 hours or so；Sintered Ceramic glaze is flat and smooth, glossiness is good, hardness is high, water absorption rate is low, hot steady
It is qualitative, chemical stability is good, and ensure that glaze firing after glaze paint appearance property it is good, glossiness, light transmittance and hardness are equal
Meet national Glaze for chinaware standard.
Specific embodiment
Embodiment 1
A kind of low temperature gloss marzacotto powder composition described in the present embodiment 1, including following component: 40g potassium feldspar,
The pink mud of 5g, 5g talcum, 25g quartz, 5gAl2O3, 15g calcite, 5gZnO.
In addition, including the following steps: the invention further relates to the preparation method of low temperature gloss marzacotto powder composition
(1) the pink mud of 40g potassium feldspar, 5g, 5g talcum, 25g quartz, 5gAl are weighed in the balance2O3, 15g calcite, 5gZnO；
(2) it is 250 mesh meshes above-mentioned raw materials component high speed grinding to fineness with ball mill and tails over < 0.5%, obtains low
Warm gloss marzacotto powder.
Potassium feldspar is produced using Hunan Deng Feng, white.Chemical formula K (AlSi3O8), it is most common most basic in feldspar race
It is a kind of.Each component theory group becomes 16.9%K2O, 18.4%Al2O3, 64.7%SiO2, belong to monoclinic system, common Ka Siba is bis-
Crystalline substance, density 2.56~2.59, Mohs' hardness 6.1150 DEG C ± 20 DEG C start to decompose melting, generate white garnet (K2O·Al2O3·
4SiO2) and silica glass, melt temperature scope is wide, and viscosity of high-temperature melt is big, and the raising of viscosity with temperature reduces quickly, has
Apparent fluxing action, while can also play high-temperature thermoplastic and high temperature cementation, it prevents ceramic high temperature from deforming, it is dry to improve it
Dry intensity.
Talcum uses Guangxi forest products, blocky, white.Chemical formula 3MgO4SiO2·H2O, each component theory group become
31.9%MgO, 63.4%SiO2, 4.7%H2O belongs to monoclinic system, and for crystal at hexagon or diamond shape plate, crystal structure is by two
A tetrahedral layer clips an octahedral layer and the unit that constitutes, and each ion electricity price has neutralized in layer, therefore contacts secured.Crystal collection
Zoarium is often at flakey or compact massive.Density 2.70~2.80, Mohs' hardness 1.Glaze layer elasticity can be improved as flux, reduced
Thermal expansion coefficient improves thermal stability, improves the whiteness, transparency and intensity of ceramic, can increase the temperature flowing of glaze,
Promote body-glaze intermediate layer to generate, improves the two associativity.But its flat crystal structure is easy to be formed in base glaze and align, and makes
It generates anisotropy, different directions can be caused to shrink in firing and cooling procedure uneven, so that biggish internal stress is generated,
Product is caused to crack.
Calcite is produced using Guangxi Quanzhou, white.Chemical formula CaCO3, each component theory group become CaO56%,
CO244%, belong to rectangle, six sides or trigonal system, aggregate granulates or plate sometimes at rhombohedron or scalenohedron body, density
2.71~2.94, Mohs' hardness 3.898.6 DEG C of decomposition temperature, when being used as ceramic blank glaze, plays leanization before decomposing, risen after decomposition
Fluxing action can shorten firing time, increase light transmittance, make once to be formed preferably among base glaze, enhance glaze-body bonding；Also it can be improved
Glaze paint refractive index increases its glossiness.
Pink mud is produced using Hunan, at pale pink color.Pink mud is a kind of complex mineral raw material, with more water containing 7*10-10m
Based on kaolin, and the quartzy impurity in part.More water kaolin structural formulas are Al2O32SiO22H2O belongs to monoclinic system.Each group
Sub-argument opinion group becomes 39.5%Al2O3, 46.54%SiO2, 13.96%H2O, density 2.54~2.60, Mohs' hardness 1.Belong to 1:
1 type layer aluminosilicate structure is contacted by Si-O tetrahedron Al-O or Al-OH octahedral layer by shared oxygen atom.
Pink mud is rich in SiO2And Al2O3, it is possible to provide glassy state forming agent is one of common raw mineral materials in glaze or blank.
Quartz is produced using Hunan Linxiang, white.SiO2Content is greater than 98%.The chief component of ceramic glaze is constituted
Glassy state skeleton can play the chemical stability and thermal stability of adjustment Ceramic glaze, increase its hardness, but the excessively high firing of dosage
Temperature is then excessively high.
Embodiment 2
The present embodiment 2 is to be changed on the basis of embodiment 1, and specifically the content of each component is different, specific as follows:
A kind of low temperature gloss marzacotto powder composition, including following component: the pink mud of 30g potassium feldspar, 10g, 10g talcum, 30g stone
English, 2gAl2O3, 15g calcite, 3gZnO.
The above described is only a preferred embodiment of the present invention, not making any form to technical solution of the present invention
On limitation.According to the technical essence of the invention any simple modification to the above embodiments, equivalent variations and repair
Decorations, in the range of still falling within technical solution of the present invention.
Claims (2)
1. a kind of low temperature gloss marzacotto powder composition, which is characterized in that including following component: 30-40wt% potassium feldspar, 5-
The pink mud of 10wt%, 5-10wt% talcum, 25-30wt% quartz, 2-5wt%Al2O3, 15-20wt% calcite, 3-5wt%
ZnO。
2. the preparation method of low temperature gloss marzacotto powder composition according to claim 1, which is characterized in that including such as
Lower step:
(1) the pink mud of 30-40wt% potassium feldspar, 5-10wt%, 5-10wt% talcum, 25-30wt% quartz, 2- are weighed in the balance
5wt%Al2O3, 15-20wt% calcite, 3-5wt%ZnO；
(2) it is 250 mesh meshes above-mentioned raw materials component high speed grinding to fineness with ball mill and tails over < 0.5%, obtains low temperature light
Damp marzacotto powder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811407609.5A CN109369218A (en) | 2018-11-23 | 2018-11-23 | A kind of low temperature gloss marzacotto powder composition and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811407609.5A CN109369218A (en) | 2018-11-23 | 2018-11-23 | A kind of low temperature gloss marzacotto powder composition and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109369218A true CN109369218A (en) | 2019-02-22 |
Family
ID=65383681
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811407609.5A Withdrawn CN109369218A (en) | 2018-11-23 | 2018-11-23 | A kind of low temperature gloss marzacotto powder composition and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109369218A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110015884A (en) * | 2019-04-10 | 2019-07-16 | 福建省德化县冠鸿陶瓷有限公司 | A kind of antibacterial environment protection domestic ceramics and preparation method thereof |
| CN112125521A (en) * | 2020-09-24 | 2020-12-25 | 德化县嘉祥陶瓷有限公司 | Clay glaze and preparation method of domestic ceramic with same |
-
2018
- 2018-11-23 CN CN201811407609.5A patent/CN109369218A/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110015884A (en) * | 2019-04-10 | 2019-07-16 | 福建省德化县冠鸿陶瓷有限公司 | A kind of antibacterial environment protection domestic ceramics and preparation method thereof |
| CN112125521A (en) * | 2020-09-24 | 2020-12-25 | 德化县嘉祥陶瓷有限公司 | Clay glaze and preparation method of domestic ceramic with same |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102826872B (en) | Formula and preparation method of national flag bright red glazed brick | |
| CN102320723B (en) | Preparation method of quartz crucible | |
| CN102531397B (en) | Milky white glass ceramic suitable for all electric melting and preparation process for milky white glass ceramic | |
| CN104230309A (en) | Formula for firing light ceramic once and production method of light ceramic | |
| Niu et al. | Effect of Na2CO3 content on thermal properties of foam-glass ceramics prepared from smelting slag | |
| CN112794707B (en) | High-whiteness and high-strength light-transmitting ceramic tile and preparation method thereof | |
| CN103755330B (en) | Desert wind sand is utilized to prepare the method for quartzose pottery | |
| CN105693202A (en) | Medium-temperature hard fine porcelain with high whiteness, high transparency and high strength and preparation method of medium-temperature hard fine porcelain | |
| CN102924126B (en) | Milky-white frit for zirconium-free glaze and method for producing milky-white frit for zirconium-free glaze | |
| CN102596836A (en) | Silico-sodo-calcic glass-ceramic material | |
| CN103253865B (en) | A kind of containing the exquisite glaze of crystal frit and the manufacture craft of exquisite product | |
| JPH0155206B2 (en) | ||
| CN106747277A (en) | Magnesium soil ceramic batch and preparation method thereof | |
| CN109369218A (en) | A kind of low temperature gloss marzacotto powder composition and preparation method thereof | |
| CN105130196B (en) | Process for the preparation of a ceramic glass plate, plate obtained by this process and its use | |
| CN112374863A (en) | Manufacturing process of ice-crack glaze jun porcelain artwork | |
| CN1071658A (en) | Self-releasing enamel low-temp ceramics | |
| CN109336388A (en) | A kind of preparation method and process for calcining of ultralow temperature glaze | |
| CN109160741A (en) | A kind of direct sintering coal ash for manufacturing for devitrified glass method | |
| CN105776864B (en) | A kind of frit of the high grade of transparency and preparation method thereof | |
| CN102344251B (en) | Preparation method for lepidolite glass ceramic | |
| CN107043214A (en) | Brownish black floor iron red colored crystalline point ceramic glaze and the method using its preparation ceramics | |
| CN103570219A (en) | Production method of lead-free ceramic-simulating glass winebottles | |
| CN109400211A (en) | A kind of celeste glaze and preparation method thereof | |
| CN109369010A (en) | A kind of mixed nanometer low-temperature glaze powder composition and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20190222 |