CN111908790A - Beverage bottle and preparation method thereof - Google Patents

Beverage bottle and preparation method thereof Download PDF

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Publication number
CN111908790A
CN111908790A CN202010775770.9A CN202010775770A CN111908790A CN 111908790 A CN111908790 A CN 111908790A CN 202010775770 A CN202010775770 A CN 202010775770A CN 111908790 A CN111908790 A CN 111908790A
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CN
China
Prior art keywords
parts
glass
beverage bottle
raw materials
crushing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010775770.9A
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Chinese (zh)
Inventor
许建勋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhengzhou Huayuan Glass Products Co ltd
Original Assignee
Zhengzhou Huayuan Glass Products Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhengzhou Huayuan Glass Products Co ltd filed Critical Zhengzhou Huayuan Glass Products Co ltd
Priority to CN202010775770.9A priority Critical patent/CN111908790A/en
Publication of CN111908790A publication Critical patent/CN111908790A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/002Use of waste materials, e.g. slags
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B25/00Annealing glass products
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B9/00Blowing glass; Production of hollow glass articles
    • C03B9/30Details of blowing glass; Use of materials for the moulds
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Manufacturing & Machinery (AREA)
  • Glass Compositions (AREA)

Abstract

The invention discloses a beverage bottle and a preparation method thereof, belonging to the technical field of glass production, wherein the beverage bottle comprises the following raw materials in parts by weight: the beverage bottle comprises, by optimization of a formula, glass slag 30-40 parts, quartz sand 30-35 parts, soda ash 10-15 parts, calcite 5-10 parts, lepidolite 5-10 parts, a nano material 4-8 parts and a decolorizing agent 3-6 parts, and comprises four steps of material preparation, high-temperature melting, processing and forming and annealing.

Description

Beverage bottle and preparation method thereof
Technical Field
A beverage bottle and a preparation method thereof belong to the technical field of glass production, and particularly relate to the technical field of beverage bottle production.
Background
The glass bottle is a container for packaging, and is mainly used for packaging beverages, wine and medical medicaments. The beverage bottle made of the glass bottle material can improve the aesthetic degree of the beverage due to the transparency, and simultaneously has the advantages of no toxicity, no smell, good barrier property, low price, reusability, heat resistance, pressure resistance and easy cleaning, can be sterilized at high temperature and stored at low temperature, and is a container widely applied at present.
In the existing production technology, due to the limitation of the source and the process of raw materials, part of iron in the mixture is not completely separated, so that iron impurities and colored substances in glass cannot be completely and perfectly removed, the transparency of the produced glass bottle is low, and the appearance is influenced.
Disclosure of Invention
The invention aims to: the beverage bottle and the preparation method thereof are provided, the bonding strength of the interface of the glass mother liquor can be improved, the toughening and reinforcing effects are achieved, the anti-cracking capacity of the glass is improved, the iron removal operation is carried out, the colored groups in the glass are effectively removed, and the transparency of the glass is high.
The technical scheme adopted by the invention is as follows:
in order to achieve the purpose, the invention provides a beverage bottle which comprises the following raw materials in parts by weight: 30-40 parts of glass slag, 30-35 parts of quartz sand, 10-15 parts of soda ash, 5-10 parts of calcite, 5-10 parts of lepidolite, 4-8 parts of nano material and 3-6 parts of decolorizing agent.
Preferably, the decolorizing agent is cerium dioxide.
Preferably, the nano material is nano calcium carbonate or nano talcum powder.
The invention also provides a preparation method of the beverage bottle, which comprises the following steps:
(1) preparing materials: weighing raw materials of glass slag, quartz sand, soda ash, calcite, lepidolite, nano material and decolorizing agent in proportion, crushing the raw materials and uniformly mixing to obtain a mixture;
(2) high-temperature melting: feeding the mixture into a kiln, melting at 1450-1550 ℃, and keeping for 15-25 h to obtain uniform bubble-free glass mother liquor;
(3) and (3) processing and forming: feeding the glass mother liquor into a forming device for blow forming to prepare a glass bottle;
(4) annealing: and transferring the glass bottle obtained by the forming processing into an annealing furnace with the temperature of 530-600 ℃, annealing, and finally naturally cooling to room temperature to obtain the annealed glass bottle.
Preferably, the glass slag is pure white glass. The use of glass with variegated colors is avoided, and the whiteness and the transparency of the glass are not influenced.
Preferably, in the step (1), the iron removal operation is performed simultaneously with the crushing and mixing.
Preferably, the iron removal operation is: the crushing blade of the crushing equipment and the stirrer of the mixing equipment are provided with strong magnets, and iron in the raw materials is adsorbed and removed by the strong magnets during crushing and mixing.
Preferably, in the step (2), the environment in the kiln is kept in an oxidizing atmosphere. The oxidizing atmosphere is maintained by controlling the environment in the kiln, so that the Fe in the residual iron is kept2+Conversion to Fe3+Albeit Fe2+And Fe3+Are all colored ions, but due to Fe2+Has strong coloring power with Fe3+Thus, it is converted into Fe3+The coloring power of the iron can be reduced, thereby improving the transparency of the glass.
In summary, due to the adoption of the technical scheme, the invention has the beneficial effects that:
1. according to the invention, the nano material is added into the glass formula, the compatibility of the whole formula system can be effectively improved after the nano material is added, acting force can be formed among molecules of each material, and then all substances are lapped by utilizing the acting force among the molecules, so that the bonding strength of the interface of the molten glass mother solution is improved, the toughening and reinforcing effects are achieved, and the crack resistance of the glass is improved.
2. According to the invention, the strong magnets are arranged on the crushing blade of the crushing equipment and the stirrer of the mixing equipment, so that the iron in the raw materials is adsorbed and removed by the strong magnets during crushing and mixing, the impure color groups in the glass can be effectively removed, and the transparency of the glass is improved.
3. The invention controls the environment in the kiln to maintain the oxidizing atmosphere, so that Fe in the residual iron is kept2+Conversion to Fe3+Albeit Fe2+And Fe3+Are all colored ions, but due to Fe2+Has strong coloring power with Fe3+Thus, it is converted into Fe3+The coloring power of the iron can be reduced, thereby improving the transparency of the glass.
Detailed Description
The technical solutions of the present invention are described clearly and completely below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
The embodiment provides a beverage bottle, which comprises the following raw materials in parts by weight: 30kg of glass slag, 30kg of quartz sand, 12kg of soda ash, 7kg of calcite, 7kg of lepidolite, 4kg of nano material and 3kg of decolorizing agent.
The preparation method of the beverage bottle comprises the following steps:
(1) preparing materials: weighing raw materials of glass slag, quartz sand, soda ash, calcite, lepidolite, a nano material and a decolorizing agent according to a proportion, crushing and uniformly mixing the raw materials to obtain a mixture, simultaneously performing iron removal operation during crushing and mixing, and adsorbing and removing iron in the raw materials by using strong magnets;
(2) high-temperature melting: feeding the mixture into a kiln, maintaining the environment in the kiln in an oxidizing atmosphere, melting at 1450-1550 ℃, and maintaining for 15-25 h to obtain uniform bubble-free glass mother liquor;
(3) and (3) processing and forming: feeding the glass mother liquor into a forming device for blow forming to prepare a glass bottle;
(4) annealing: and transferring the glass bottle obtained by the forming processing into an annealing furnace with the temperature of 530-600 ℃, annealing, and finally naturally cooling to room temperature to obtain the annealed glass bottle.
Example 2
The embodiment provides a beverage bottle, which comprises the following raw materials in parts by weight: 40kg of glass slag, 35kg of quartz sand, 12kg of soda ash, 5kg of calcite, 5kg of lepidolite, 7kg of nano material and 4kg of decolorizing agent, and the preparation method of the beverage bottle is the same as that of the example 1.
Example 3
The embodiment provides a beverage bottle, which comprises the following raw materials in parts by weight: 30kg of glass slag, 30kg of quartz sand, 10kg of soda ash, 10kg of calcite, 10kg of lepidolite, 6kg of nano-material and 3kg of decolorizing agent, and the preparation method of the beverage bottle is the same as that of the example 1.
Example 4
The embodiment provides a beverage bottle, which comprises the following raw materials in parts by weight: 40kg of glass slag, 30kg of quartz sand, 15kg of soda ash, 10kg of calcite, 10kg of lepidolite, 8kg of nano material and 6kg of decolorizing agent, and the preparation method of the beverage bottle is the same as that of the example 1.
Example 5
The embodiment provides a beverage bottle, which comprises the following raw materials in parts by weight: 35kg of glass slag, 40kg of quartz sand, 10kg of soda ash, 7kg of calcite, 7kg of lepidolite, 5kg of nano material and 3kg of decolorizing agent, and the preparation method of the beverage bottle is the same as that of the example 1.
Example 6
The embodiment provides a beverage bottle, which comprises the following raw materials in parts by weight: 40kg of glass slag, 35kg of quartz sand, 10kg of soda ash, 7kg of calcite, 10kg of lepidolite, 8kg of nano material and 5kg of decolorizing agent, and the preparation method of the beverage bottle is the same as that of the example 1.
Example 7
The embodiment provides a beverage bottle, which comprises the following raw materials in parts by weight: 35kg of glass slag, 35kg of quartz sand, 10kg of soda ash, 10kg of calcite, 8kg of lepidolite, 8kg of nano-material and 4kg of decolorizing agent, and the preparation method of the beverage bottle is the same as that of the example 1.
Finally, it should be noted that: the above examples are only intended to illustrate the technical solution of the present invention, but not to limit it; although the present invention has been described in detail with reference to the foregoing embodiments, it will be understood by those of ordinary skill in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some or all of the technical features may be equivalently replaced; these modifications and substitutions do not cause the essence of the corresponding technical solution to depart from the scope of the technical solution of the embodiments of the present invention, and are intended to be covered by the claims and the specification of the present invention.

Claims (8)

1. A beverage bottle is characterized by comprising the following raw materials in parts by weight: 30-40 parts of glass slag, 30-35 parts of quartz sand, 10-15 parts of soda ash, 5-10 parts of calcite, 5-10 parts of lepidolite, 4-8 parts of nano material and 3-6 parts of decolorizing agent.
2. A beverage bottle according to claim 1, wherein the decolorizing agent is selected from cerium dioxide.
3. A beverage bottle according to claim 1, wherein the nano material is nano calcium carbonate or nano talc.
4. A method for preparing a beverage bottle according to claim 1, comprising the steps of:
(1) preparing materials: weighing raw materials of glass slag, quartz sand, soda ash, calcite, lepidolite, nano material and decolorizing agent in proportion, crushing the raw materials and uniformly mixing to obtain a mixture;
(2) high-temperature melting: feeding the mixture into a kiln, melting at 1450-1550 ℃, and keeping for 15-25 h to obtain uniform bubble-free glass mother liquor;
(3) and (3) processing and forming: feeding the glass mother liquor into a forming device for blow forming to prepare a glass bottle;
(4) annealing: and transferring the glass bottle obtained by the forming processing into an annealing furnace with the temperature of 530-600 ℃, annealing, and finally naturally cooling to room temperature to obtain the annealed glass bottle.
5. A beverage bottle making method according to claim 4, wherein said glass residue is pure white glass.
6. A beverage bottle manufacturing method according to claim 4, wherein in the step (1), iron removal is performed simultaneously with the crushing and mixing.
7. A beverage bottle making method according to claim 6, wherein said iron removal operation is: the crushing blade of the crushing equipment and the stirrer of the mixing equipment are provided with strong magnets, and iron in the raw materials is adsorbed and removed by the strong magnets during crushing and mixing.
8. A beverage bottle making method according to claim 4, wherein in step (2), the kiln environment is maintained in an oxidizing atmosphere.
CN202010775770.9A 2020-08-05 2020-08-05 Beverage bottle and preparation method thereof Pending CN111908790A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010775770.9A CN111908790A (en) 2020-08-05 2020-08-05 Beverage bottle and preparation method thereof

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Application Number Priority Date Filing Date Title
CN202010775770.9A CN111908790A (en) 2020-08-05 2020-08-05 Beverage bottle and preparation method thereof

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CN111908790A true CN111908790A (en) 2020-11-10

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112299713A (en) * 2020-11-13 2021-02-02 郑州市华源玻璃制品有限公司 Production process of beer bottle

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63222039A (en) * 1987-03-12 1988-09-14 Showa Electric Wire & Cable Co Ltd Production of multi-component glass for optical fiber
CN108178512A (en) * 2018-01-23 2018-06-19 合肥利裕泰玻璃制品有限公司 A kind of high strength glass and its preparation process
CN109694199A (en) * 2019-02-13 2019-04-30 安徽金冠玻璃有限责任公司 A kind of production technology of high grade of transparency vial

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63222039A (en) * 1987-03-12 1988-09-14 Showa Electric Wire & Cable Co Ltd Production of multi-component glass for optical fiber
CN108178512A (en) * 2018-01-23 2018-06-19 合肥利裕泰玻璃制品有限公司 A kind of high strength glass and its preparation process
CN109694199A (en) * 2019-02-13 2019-04-30 安徽金冠玻璃有限责任公司 A kind of production technology of high grade of transparency vial

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
刘新华等: "《玻璃器皿生产技术》", 30 September 2006 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112299713A (en) * 2020-11-13 2021-02-02 郑州市华源玻璃制品有限公司 Production process of beer bottle

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Application publication date: 20201110