CN111481425A - Microenvironment hydrogen supply breathable layer and external application bag - Google Patents
Microenvironment hydrogen supply breathable layer and external application bag Download PDFInfo
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61H—PHYSICAL THERAPY APPARATUS, e.g. DEVICES FOR LOCATING OR STIMULATING REFLEX POINTS IN THE BODY; ARTIFICIAL RESPIRATION; MASSAGE; BATHING DEVICES FOR SPECIAL THERAPEUTIC OR HYGIENIC PURPOSES OR SPECIFIC PARTS OF THE BODY
- A61H33/00—Bathing devices for special therapeutic or hygienic purposes
- A61H33/14—Devices for gas baths with ozone, hydrogen, or the like
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M31/00—Devices for introducing or retaining media, e.g. remedies, in cavities of the body
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M35/00—Devices for applying media, e.g. remedies, on the human body
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/02—Preparation of oxygen
- C01B13/0203—Preparation of oxygen from inorganic compounds
- C01B13/0211—Peroxy compounds
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/065—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents from a hydride
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/08—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents with metals
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/10—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with metals
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61H—PHYSICAL THERAPY APPARATUS, e.g. DEVICES FOR LOCATING OR STIMULATING REFLEX POINTS IN THE BODY; ARTIFICIAL RESPIRATION; MASSAGE; BATHING DEVICES FOR SPECIAL THERAPEUTIC OR HYGIENIC PURPOSES OR SPECIFIC PARTS OF THE BODY
- A61H33/00—Bathing devices for special therapeutic or hygienic purposes
- A61H33/14—Devices for gas baths with ozone, hydrogen, or the like
- A61H2033/148—Devices for gas baths with ozone, hydrogen, or the like with hydrogen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M2202/00—Special media to be introduced, removed or treated
- A61M2202/02—Gases
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Abstract
The invention provides a microenvironment hydrogen supply breathable layer and an external application bag, comprising: a thin layer, which is wrapped with a hydrogen production formula, wherein the outer side of the thin layer is air-tight, the inner side surface of the thin layer is provided with a plurality of small holes, and the thin layer can be a single layer or a composite layer; and a hydrogen production formula, which is wrapped in the thin layer, can not escape, and can absorb moisture or liquid water in the air to generate hydrogen; the hydrogen is released to the skin and the inside of the human body through the small holes; wherein the hydrogen production formula comprises metal peroxide, metal hydroxide, or metal hydride and aluminum powder or silicon powder; the air permeable layer can be used in external application bag or other sanitary product, and has effects of improving nonbacterial inflammation and promoting health.
Description
The present application claims priority from a chinese patent application filed by the chinese patent office on 25/01/2019 under the name "microenvironment hydrogen supply permeable layer" with application number 201910073960.3, the entire contents of which are incorporated herein by reference.
Technical Field
The invention provides a microenvironment hydrogen supply breathable layer containing a hydrogen production formula and an external application bag, and the microenvironment hydrogen supply breathable layer and the external application bag achieve the purposes of health care and disease improvement by the advantages of no irritation, excellent diffusion capacity, no harmful byproducts in reaction and the like of hydrogen through supplying the hydrogen to the skin or the inside of a human body, and belong to the field of life health care.
Background
Hydrogen (H)2) The hydrogen gas is a colorless and tasteless gas, research reports in 1975 indicate that the hydrogen gas can be used as an antioxidant gas for treating cancers, Japanese scholars in 2007 neutralize toxic free radicals with the hydrogen gas to treat cerebral ischemia-reperfusion injury, and a large number of researches later confirm that the hydrogen gas has a treatment effect on various diseases and injuries. Hydrogen can selectively neutralize free radicals, and generate effects of antioxidation, anti-inflammation, anti-apoptosis and the like without influencing active oxygen with physiological effects in vivo, such as: superoxide anion, hydrogen peroxide and the like, which indicate that the hydrogen is safe to be used for human bodies. The hydrogen has the additional advantage of strong diffusion capacity, the cell membrane and various biological barriers do not influence the diffusion and permeation of the hydrogen, the hydrogen can reach any part of the body, and the hydrogen is considered to have the treatment effect on common acute and chronic diseases such as stroke, diabetes, arteriosclerosis, Parkinson's disease and the like.
The hydrogen gas can be used by a method of inhaling hydrogen gas, drinking hydrogen water, or injecting hydrogen brine, or the like. The inhaled hydrogen has the effect of improving nervous and cardiovascular diseases such as apoplexy and myocardial infarction, and drinking hydrogen water is reported to have the treatment effect on diabetes and metabolic diseases; in addition, in animal models, drinking hydrogen water has also been shown to improve allergic diseases such as: atopic dermatitis; it can be directly injected into eyeball with retinopathy for treating ocular fundus diseases. The cooperation of Japan island university and Indonesia SamRatulagi university, high-concentration hydrogen water is adopted and the anticancer drug 5 fluorouracil is used, and two modes of cytology and animal model are utilized, so that the hydrogen can promote the apoptosis of tumor cells, obviously increase the antitumor effect of the 5 fluorouracil, and prolong the life of animals with tumors.
At present, common hydrogen supply modes comprise a hydrogen water or a high-pressure hydrogen tank, hydrogen is fused in water by the hydrogen water, a hydrogen manufacturing machine is needed firstly, the size is large, power consumption is needed, and the manufactured hydrogen water is not easy to store; if high-purity hydrogen is to be supplemented, a high-pressure hydrogen cylinder is usually used, but in addition to the inconvenience in carrying caused by the volume and weight, the high-pressure hydrogen cylinder has potential safety risks and also has a concern in use. Because the hydrogen making machine and the high-pressure hydrogen cylinder are inconvenient to carry and not easy to popularize, the practical application of the hydrogen is limited, so that the problems to be solved by the invention are that how to supply the hydrogen which can be conveniently used anytime and anywhere can easily solve the nonbacterial inflammation and other health-care effects.
Various kinds of sanitary products (including masks, face masks, facial masks and the like) which contact skin closely are available on the market, and the sanitary products are in direct contact with the skin, so the wearing comfort and convenience are often marked, however, in recent years, people in the field also aim at achieving the effect aiming at other combinations, and strive to improve and break through, for example, the reaction of internal materials to supply beneficial gases such as oxygen and the like to human bodies; however, since the gas supply comes from internal chemical interaction between materials, more materials or combinations of materials are often included to enhance health benefits, thereby risking the escape of materials or unsafe byproducts.
Therefore, how to provide a breathable layer capable of supplying hydrogen in sanitary products is an important problem to be solved by the present invention.
Disclosure of Invention
To solve the above problems, the present inventors provide a microenvironment hydrogen supply permeable layer, comprising: a thin layer, which is wrapped with a hydrogen production formula and has a plurality of small holes on the inner surface, wherein the outer side of the thin layer is air-tight, the inner side of the thin layer is air-tight, and the inner side of the thin layer is provided with a plurality of small holes, and the thin layer can be a single layer or a composite layer; the hydrogen production formula is wrapped in the thin layer, cannot escape, and can absorb moisture or liquid water in the air to generate hydrogen; the hydrogen is released to the skin and the inside of the human body through the small holes.
In a further technical scheme, the inner side of the thin layer can be made of silica gel, non-woven fabric or a plastic breathable film.
In a further technical scheme, the outer side of the thin layer is made of polypropylene, a polyethylene plastic film, an aluminum film or a composite film.
In a further technical scheme, the hydrogen production formula can be in a powder shape or a granular shape.
In a further technical scheme, the hydrogen production formula comprises metal peroxide, metal hydroxide, or metal hydride and aluminum powder or silicon powder.
In a further technical scheme, the weight ratio of the metal peroxide or the metal hydroxide to the aluminum powder is as follows: 1:100-100:1.
In a further technical scheme, the weight ratio of the metal peroxide or the metal hydroxide to the aluminum powder is as follows: 1:10-10:1.
In an optional embodiment, the metal peroxide is selected from the group consisting of calcium peroxide, magnesium peroxide, sodium peroxide, and potassium peroxide; the metal hydroxide is selected from the group consisting of calcium hydroxide, magnesium hydroxide, sodium hydroxide, potassium hydroxide; the metal hydride is selected from the group consisting of magnesium hydride, calcium hydride, and silicon hydride.
For the purpose of the present invention, the hydrogen production formulation may further comprise a solid acid selected from the group consisting of solid citric acid, solid lactic acid, solid oxalic acid, solid hydrochloric acid, solid phytic acid, and solid silicic acid.
In an optional technical scheme, the hydrogen production formula can further comprise a high water absorption polymer, an activating agent or a catalyst.
In an optional technical scheme, the thin layer can further comprise an oxygen and active oxygen generating unit.
In an optional technical scheme, the breathable layer can be used in a sanitary product, and the sanitary product comprises an eye patch, a mask, a face mask, a bra, a breast patch, a galactorrhea patch, a sanitary napkin, a paper diaper, a sanitary pad, a wound dressing, a band-aid, a bandaging gauze, a bedsore pad or an external application bag.
Based on the same inventive concept, the present application provides an external application bag for inhibiting inflammation, comprising:
a thin layer, which is wrapped with a hydrogen production formula and an oxygen production formula, wherein the outer side of the thin layer is air-tight, the inner side surface of the thin layer is provided with a plurality of small holes, and the thin layer can be a single layer or a composite layer;
the hydrogen production formula is wrapped in the thin layer, cannot escape, and can absorb moisture or liquid water in the air to generate hydrogen; the hydrogen is released to the skin through the plurality of small pores;
the oxygen-making formula is wrapped in the thin layer, cannot escape, and can absorb moisture or liquid water in the air to generate oxygen; the oxygen is released to the skin through the plurality of small pores.
In a further technical scheme, the inner side of the thin layer can be made of silica gel, non-woven fabric or a plastic breathable film.
In a further technical scheme, the outer side of the thin layer is made of polypropylene, a polyethylene plastic film, an aluminum film or a composite film. Wherein the hydrogen production formula and the oxygen production formula can be in powder and particle shapes.
For the purpose of the present invention, the hydrogen production formulation comprises a metal peroxide, a metal hydroxide, or a metal hydride and aluminum powder or silicon powder.
In a further technical scheme, the weight ratio of the metal peroxide or the metal hydroxide to the aluminum powder is as follows: 1:100-100:1.
In a further technical scheme, the weight ratio of the metal peroxide or the metal hydroxide to the aluminum powder is as follows: 1:10-10:1.
In an optional embodiment, the metal peroxide is selected from the group consisting of calcium peroxide, magnesium peroxide, sodium peroxide, and potassium peroxide.
In an alternative embodiment, the metal hydroxide is selected from the group consisting of calcium hydroxide, magnesium hydroxide, sodium hydroxide, and potassium hydroxide.
In an alternative embodiment, the metal hydride is selected from the group consisting of magnesium hydride, calcium hydride, and silicon hydride. The hydrogen production formulation may be supplemented with a solid acid selected from the group consisting of solid citric acid, solid lactic acid, solid oxalic acid, solid hydrochloric acid, solid phytic acid and solid silicic acid, such that the hydrogen production formulation has a pH of between 4-9.
In an alternative embodiment, the oxygen generating formulation is a metal peroxide selected from the group consisting of calcium peroxide, magnesium peroxide, sodium peroxide, and potassium peroxide.
In an optional technical scheme, the weight ratio of the oxygen preparation formula to the hydrogen preparation formula is 1:1-1: 50.
In particular embodiments, the inflammation is non-bacterial inflammation.
The invention is a breathable layer containing a hydrogen production formula, can generate a large amount of hydrogen in a short time, and supplies the hydrogen to the skin, nostrils, oral cavity, eyes or other contacted parts of a human body, and has the following beneficial effects:
(1) the use is safe and convenient, the steel cylinder pipeline or the power plug is not needed, the carrying is convenient, the formula is harmless, and the patch type disposable medical bottle can be used by being attached to the body.
(2) No harmful by-products are derived.
(3) Can be easily absorbed close to skin.
(4) The wide body health uses of hydrogen:
excellent diffusion capacity, without restriction of the site of arrival;
-non-toxic, mild and safe reducing agents;
can neutralize free radicals, has excellent antioxidant and anti-inflammatory effects, especially against non-bacterial inflammation;
-improving the in vivo flora.
(5) The oxygen addition further improves the problem of oxygen deprivation of past conventional dressings due to prolonged use.
The present invention further discloses preferred hydrogen production formulations, oxygen production formulation ratios and dosages required to achieve optimal health benefits of the breathable layer, and exemplifies the use of breathable layers in sanitary products, as well as extended applications of the present invention.
Drawings
FIG. 1 is a schematic view of a microenvironment hydrogen supply permeable layer;
FIG. 2 is an exploded view of the gas permeable layer;
FIG. 3 is a cross-sectional view of the breathable layer;
FIG. 4 is a schematic view of the breathable layer applied to an eye mask;
fig. 5A and 5B are schematic views of the breathable layer applied to a mask;
FIG. 6 is a schematic view of the breathable layer applied to a mask;
FIG. 7 is a schematic view of the application of the breathable layer to a wound dressing;
FIG. 8A is the effect of the external application bag of the present application not yet used at gout sites;
FIG. 8B is the effect of using the dressing of the present application for 2 hours at gout sites;
FIG. 8C is the effect of using the externally applied bag of the present application for 3 hours at gout sites;
FIG. 8D is a graph of the effect of the application of the dressing on day 4 in gout locations;
FIG. 9 is a schematic view of the application of the dressing to ankle pain;
fig. 10 is a schematic view of the application of the external application bag to physiological pain.
Reference numerals:
1-a breathable layer;
11-a thin layer;
111-small holes;
12-hydrogen production formula.
Detailed Description
The present invention is illustrated by the following examples, but the present invention is not limited thereto, and the features, applications and advantages of the microenvironment hydrogen supply permeable layer and the application bag are described in detail, however, equivalent implementations or modifications without departing from the technical spirit of the present invention should be included in the claims of the present application.
As shown in fig. 1 to 3, the present invention provides a breathable layer 1, comprising: a thin layer 11 wrapping a hydrogen production formula, wherein the outside of the thin layer 11 is air-tight and the inside is air-permeable, the inner surface is provided with a plurality of small holes 111, and the thin layer can be a single layer or a composite layer; and a hydrogen production formula 12, which is wrapped in the thin layer 11, does not escape, and absorbs moisture or liquid water in the air to generate hydrogen; as can be seen from fig. 2, the hydrogen gas will be absorbed into the human body through the plurality of small holes 111 via the skin, nostrils, mouth, eyes, other parts of the human body in contact therewith.
The hydrogen production formula 12 is covered by the thin layer 11 which is airtight at the outer side and breathable at the inner side, wherein the aperture of the small hole 111 at the inner side of the thin layer is smaller than the diameter of the hydrogen production formula 12 so as to ensure that the hydrogen production formula 12 does not leak, the outer side of the thin layer 11 is made of airtight materials, and the inner side of the thin layer is made of skin-friendly materials.
During storage, the hydrogen production formula 12 is packaged by an airtight material to ensure that water in the air does not react with the hydrogen production formula in advance; when in use, the airtight package is torn off and applied to a required position; by using the breathable layer 1, moisture such as sweat, moisture and the like can be trapped through the outer side air-impermeable material without leaking, so that the hydrogen production formula 12 can be fully reacted, and hydrogen can be supplied to the skin in a directional manner.
The inner material of the thin layer 11 for coating the hydrogen production formula 12 can be silica gel, non-woven fabric or a plastic breathable film; the outer material can be polypropylene, polyethylene plastic film, aluminum film or composite film.
The hydrogen production formulation 12, which may be in the form of powder or granules, comprises a metal peroxide, a metal hydroxide, or a metal hydride and aluminum powder or silicon powder.
Wherein the metal peroxide is selected from the group consisting of calcium peroxide, magnesium peroxide, sodium peroxide and potassium peroxide, and the metal hydroxide is selected from the group consisting of calcium hydroxide, magnesium hydroxide, sodium hydroxide and potassium hydroxide.
The hydrogen production formulation may also include compounds that are permeable to moisture to form metal hydroxides, such as: magnesium hydride, calcium hydride, silicon hydride.
The hydrogen production formula can be selectively added with a solid acid which has a neutralization function with the hydrogen production formula, so that the pH value of the hydrogen production formula is between 4 and 9 to avoid skin irritation and improve the hydrogen absorption effect, and the solid acid is selected from a group consisting of solid citric acid, solid lactic acid, solid oxalic acid, solid hydrochloric acid, solid phytic acid and solid silicic acid.
The following reaction formula is the mechanism for supplying hydrogen for the hydrogen production formulation:
in the case of metal peroxides, the reaction proceeds first with water to form metal hydroxides and release oxygen, according to the formula:
2XO2+2H2O→2X(OH)2+O2(X is calcium or magnesium) or
2Y2O2+2H2O→4Y(OH)+O2(X is sodium or potassium)
The metal hydroxide can react with aluminum powder to generate hydrogen, as shown in the following reaction formula:
2Al+2H2O+X(OH)2＝X(AlO2)2+3H2
2Al+2H2O+2Y(OH)＝2YAlO2+3H2
the metal hydride can react with water to generate hydrogen and metal hydroxide, and the metal hydroxide can react with water to continuously generate hydrogen.
In the above reaction, if a large amount of hydrogen gas is to be rapidly generated, a peroxide or hydroxide of an alkali metal (group IA) (i.e., sodium or potassium) having a large activity may be selected as a reactant.
Through the combined application of the above-mentioned exemplary hydrogen production formulations, those skilled in the art can also conceivably apply the reaction of silicon with hydroxide and water to generate hydrogen, which is an equivalent implementation of the present combination and is included in the scope of the present hydrogen production formulation, and the reaction formula is as follows:
Si+4H2O＝H4SiO4+2H2
H4SiO4+2NaOH＝Na2SiO3+3H2
to avoid discomfort due to oxygen deficiency due to the outer impermeable skin over long periods of time, the sheet 11 may further incorporate an oxygen generating formulation 13, wherein the oxygen generating formulation 13 may be in the form of a powder, granules, and comprises a metal peroxide or metal superoxide.
Metal peroxides, which react with water by permeation and release oxygen, have the formula:
2XO2+2H2O→2X(OH)2+O2(X is calcium or magnesium) or
2Y2O2+2H2O→4Y(OH)+O2(X is sodium or potassium)
To obtain the preferred dose ratios, therefore, the hydrogen generation efficiency was tested for each reactant in the range of 0.01-100 grams, the hydrogen production formulation described above was tested at the following weight ratios of metal peroxide or metal hydroxide: when the aluminum powder is 1:100-100:1, the aluminum powder can react to generate hydrogen, and when the weight ratio is 1:10-10:1, the hydrogen generation efficiency is better, if oxygen is required to further generate to overflow out of the thin layer 1, the weight ratio of the oxygen generation formula to the hydrogen generation formula is 1:1-1: 50.
The breathable film can be applied to sanitary product for close fitting, including but not limited to eye mask (fig. 4), gauze mask (fig. 5A and 5B), face mask, facial mask (fig. 6), bra, breast patch, galactorrhea patch, sanitary napkin, paper diaper, sanitary pad, wound dressing (fig. 7), band-aid, bandaging gauze, bedsore pad, and external application bag.
The method comprises the following steps of recruiting subjects with various related diseases and symptoms, wherein the subjects comprise neurological diseases, which are treated by radiotherapy, constipation, ultraviolet injury, eye acerbity, eye discomfort and trauma recently, distributing and using life and health products such as masks, eyepatches, facial masks or wound dressings and the like containing the breathable films, continuously using the life and health products for three months, three times a week and two hours at a time, filling questionnaires after the completion of the operation, investigating the improvement effect and the comfort degree of the use of the diseases and symptoms when the hydrogen production formula of the breathable layer is applied to the life and health products, and the higher the hydrogen production formula of the breathable layer is used as a scoring standard, the more remarkable the effect is expressed; meanwhile, the average result of each score statistic is described below in comparison with the general product without gas generating material (hereinafter referred to as market) and the group without aluminum powder (without generating hydrogen gas); the hydrogen production formula in the breathable film is adjusted according to the preferable proportion (100: 80-120: metal peroxide or metal hydroxide: aluminum powder) and the content is adjusted according to the corresponding sanitary product.
First embodiment, mask
The test groups and results are shown in table 1 below, wherein 10 g of metal peroxide, 10 g of metal hydroxide, 1 g of aluminum powder and a proper amount of citric acid are added to the skin through water or externally added water to generate hydrogen.
The results show that the hydrogen production formula can improve diseases/symptoms such as neurological diseases, radiotherapy side effects, constipation and the like, and the effects can not be achieved no matter the mask is sold on the market or the mask only generates oxygen (does not contain aluminum powder); in addition, each combination of the scheme has better comfort level than the mask sold on the market, and the comfort level is better when peroxide, hydroxide and solid acid are contained simultaneously.
TABLE 1 improvement of the efficacy and comfort of the breathable layer in the mask for various diseases and conditions
Second embodiment, eye mask
The test groups and results are shown in table 2 below, wherein the metal peroxide is sodium peroxide, the metal hydroxide is sodium hydroxide, 1-10 g of aluminum powder and a proper amount of oxalic acid are used, and water is added externally to generate hydrogen.
The result shows that the hydrogen production formula can improve the eye acerbity, eye diseases and the like, and has better effect compared with the commercially available eye mask or the group without aluminum powder (without hydrogen generation); in addition, each combination of the scheme has better comfort level than the eye mask sold on the market, and when peroxide, hydroxide and solid acid are simultaneously contained, the comfort level is improved, and if an oxygen preparation formula is simultaneously added, a large amount of hydrogen and a large amount of oxygen are simultaneously generated, so that the comfort level is better. Meanwhile, the oxygen generation formula is added, so that the discomfort caused by the oxygen deficiency due to overlong contact time of the external application bag can be avoided.
TABLE 2 improvement of efficacy and comfort of the breathable layer in the eye mask for various diseases and symptoms
EXAMPLE III facial mask
The test groups and results are shown in table 3 below, where the metal peroxide is magnesium peroxide, the metal hydroxide is magnesium hydroxide, both of which are 12.5 g, the silicon powder is 6.25 g, the solid acid is lactic acid in a proper amount, and water is added through the solid acid to generate hydrogen.
The results show that compared with the commercially available facial mask or the facial mask without aluminum powder (which cannot generate hydrogen), the hydrogen production formula has the effects of improving ultraviolet injury, radiotherapy side effects, neurological diseases and the like; in addition, each combination has better comfort level than the commercially available facial masks, and the comfort level is better if the facial masks simultaneously contain peroxide, hydroxide and solid acid.
TABLE 3 improvement of the Permeability layer in the mask for various diseases and symptoms and comfort
EXAMPLE four wound dressings
The test groups and results are shown in Table 4 below, wherein the metal peroxide is potassium peroxide, the metal hydroxide is potassium hydroxide and is 2.5 g, the aluminum powder is 2.5 g, and the solid acid is proper amount of phytic acid; the wound dressing can absorb moisture to generate hydrogen, can further keep moisture not reversely released to a wound, and can obtain the improved effect of supplying hydrogen and avoiding secondary infection of the wound through the design that the breathable layer is only used for ventilation.
The results show that compared with the commercially available wound dressing or the group without aluminum powder (hydrogen can not be generated), the hydrogen production formula has the effects of improving ultraviolet injury, radiotherapy side effects, wound healing and the like; in addition, each of these combinations has better comfort than commercially available dressings, and the comfort is better when peroxide, hydroxide, and solid acid are simultaneously present.
TABLE 4-efficacy and comfort of the air-permeable layer in wound dressings for improvement of various diseases, symptoms
EXAMPLE V external application bag
In order to avoid long time for the external application bag to contact the skin, because of discomfort caused by oxygen deficiency, the external application bag is additionally provided with an oxygen generating material, namely peroxide, so as to generate more oxygen; the wound dressing can absorb moisture to generate hydrogen and oxygen, can further keep moisture not reversely released to a wound, and can obtain hydrogen supply and simultaneously avoid discomfort of skin and the wound caused by oxygen deficiency through the design that the breathable layer is only used for ventilation.
Example five-1 gout
55 year old male testers suffered from gout attack, had red and swollen thumbs on the right feet and severe pain (fig. 8A), the external application bag was sprayed with water and stuck to the red and swollen part, the pain was significantly relieved after one hour, the external application bag was changed every hour, fig. 8B shows the effect after the second external application bag was used, fig. 8C shows the effect of diminishing swelling by about 40% at the gout part after the 3 rd external application bag was used, 3 external application bags were used every day, the gout part was significantly reduced in swelling after 10 tablets were used (day 4) (fig. 8D), and no discomfort such as allergy and the like caused by the external application bag contacting the skin was generated. The external application bag contains 2.5 g of calcium peroxide and 1.5 g of aluminum powder, and can generate a large amount of hydrogen and a large amount of oxygen.
Example five-2 ankle pain
The ankle of a 65-year-old male tester is sprained and is painful, the pain is more serious when the male tester walks, the external application bag is used 4 days after the ankle is sprained, the external application bag is sprayed to be pasted on the ankle pain part (as shown in figure 9), the pain is obviously reduced by about half after 10 minutes, the pain is obviously reduced by about 70% after 20 minutes, the male tester does not feel the pain after 1 hour and can normally walk, and discomfort such as allergy and the like caused by the fact that the external application bag contacts the skin is not generated after external application.
Example five-3 cervical pain
A60-year-old male tester has cervical vertebra pain for more than 20 years, the external application bag is sprayed with water and is attached to the cervical vertebra, the pain is obviously relieved after 30 minutes, and discomfort such as allergy and the like caused by the fact that the external application bag contacts the skin is avoided.
Example five-4 premenstrual breast distending pain
The 21 year old female test person has premenstrual syndrome, such as premenstrual breast distending pain and the like. When the breast is distended and painful before menstruation, the external application bag is sprayed with water and is stuck to the breast, the pain is obviously relieved after one hour, and discomfort such as allergy and the like caused by the fact that the external application bag contacts the skin is not generated. The external application bag contains 2.5 g of calcium peroxide and 1.5 g of aluminum powder, and can generate a large amount of hydrogen and a large amount of oxygen.
Example five-5, physiological pain
A30-year-old female testers have endometriosis, and all patients have physiological pain in the physiological period. When the pain is caused in the physiological period, the external application bag is sprayed with water and is attached to the position around the navel (as shown in figure 10), after 10 minutes, the pain is obviously relieved, the dressing is continuously used for 3 days and 8 hours every day, and discomfort such as allergy and the like caused by the fact that the dressing contacts the skin is not generated. The external application bag contains 1 g of magnesium peroxide, 1.5 g of potassium hydroxide as hydroxide, 1.5 g of aluminum powder and a proper amount of phytic acid, and can generate a large amount of hydrogen and oxygen.
Example five-6, pain in the hip bone
A55-year-old male tester has long-term trouble of hip pain, the external application bag is sprayed with water and is attached to the pain position of the hip, after 20 minutes, the pain is obviously relieved, and discomfort such as allergy and the like caused by the fact that the external application bag contacts the skin is not generated.
The results show that the combination of the hydrogen production formula and the oxygen production formula can effectively improve deep inflammation and pain of muscles, bones and internal organs compared with the commercial external application bag, and the external application bag does not generate discomfort such as allergy caused by the contact of the external application bag with skin because of oxygen supply.
In addition, when the sanitary napkin and the sanitary towel are used, especially when the liquid does not leak, the high molecular water-absorbing material (i.e. the high water-absorbing polymer) can be added to absorb the liquid, so as to achieve the dual effects of simultaneously supplying hydrogen and avoiding skin infection and inflammation caused by liquid backflow.
In summary, no matter what hydrogen production formula is combined, the breathable layer and the external application bag can improve neurological diseases, radiotherapy side effects, constipation, ultraviolet injury, eye acerbity, eye discomfort and wound healing when applied to the sanitary products, and break through the function scope limited by the conventional sanitary products at one stroke by virtue of the antioxidant effect of hydrogen and the effect of improving in-vivo flora; compared with the group only generating hydrogen (without aluminum powder), the application of the hydrogen production formula can achieve more excellent, wide and diversified health care effects and favorable effects; because the oxygen can be generated at the same time, the comfortable feeling is better than that of the market (without the gas generating formula), the feeling of gas tightness is avoided, and the comfort in use is improved; when peroxide, hydroxide and solid acid are added simultaneously, the best effect of improving diseases, symptoms and comfort is achieved.
In summary, the scheme can generate a large amount of hydrogen and oxygen in a short time to supply to the skin, nostrils, oral cavity, eyes or other contacted parts of the human body, compared with the common method and apparatus for generating hydrogen, the hydrogen generator has the advantages of no need of a steel cylinder pipeline, a manufacturing machine or power plug, is convenient to carry, has no harm to the formula, can be used close to the skin, is simple and convenient to generate hydrogen, does not derive harmful byproducts, and the like.
In addition, the hydrogen gas is simple in structure, so that the hydrogen gas has excellent diffusion capacity, is not limited in reaching positions, is a non-toxic and mild safe reducing agent, has the advantages of excellent effect of removing free radicals, improvement of in vivo flora and the like, and obtains wider benefit with improved effect compared with the aspect of health care application of the existing sanitary products.
The diseases listed in the invention are the corresponding disease applications by eliminating free radicals through hydrogen, and by means of the embodiment of the invention, the breathable layer can be reasonably applied to improve other diseases caused by the two factors, such as: cancer, chemotherapy side effects, metabolic disease, immune disease, allergy, diabetes, weight management, colitis or other non-bacterially induced inflammation.
In order to improve the hydrogen generation effect, the hydrogen production formula can further comprise a high water absorption polymer, an activating agent or a catalyst according to the condition; in addition, a generating unit capable of generating oxygen and active oxygen can be further added, and the proportion is adjusted to meet different requirements to achieve the required effect.
The above detailed description is specific to possible embodiments of the present invention, but the embodiments are not intended to limit the scope of the present invention, and equivalent implementations or modifications without departing from the technical spirit of the present invention are intended to be included in the scope of the present invention.
It will be apparent to those skilled in the art that various changes and modifications may be made in the embodiments of the present invention without departing from the spirit and scope of the invention. Thus, if such modifications and variations of the present invention fall within the scope of the claims of the present invention and their equivalents, the present invention is intended to include such modifications and variations.
Claims (28)
1. A microenvironment hydrogen supply permeable layer, comprising:
the thin layer is wrapped with a hydrogen production formula, the outer side of the thin layer is air-tight, the inner side surface of the thin layer is provided with a plurality of small holes, and the thin layer comprises a single layer or a composite layer;
the hydrogen production formula is wrapped in the thin layer and absorbs moisture or liquid water in the air to generate hydrogen;
the hydrogen is released to the skin and the inside of the human body through the small holes.
2. The microenvironment hydrogen-supplying permeable layer of claim 1, wherein the inner side of the thin layer is made of silicone, non-woven fabric, or plastic permeable membrane.
3. The microenvironment hydrogen-supplying permeable layer of claim 1, wherein the outer side of the thin layer is made of polypropylene, polyethylene plastic film, aluminum film or composite film.
4. The microenvironment hydrogen supply permeable layer of claim 1, wherein the hydrogen-producing formulation comprises a powder or a pellet.
5. The microenvironment hydrogen-supplying gas permeable layer of claim 1, wherein the hydrogen-producing formulation comprises a metal peroxide, a metal hydroxide, a metal hydride, aluminum powder, or silicon powder.
6. The microenvironment hydrogen-supply permeable layer of claim 5, wherein the weight ratio of the metal peroxide or metal hydroxide to the aluminum powder is: 1:100 to 100: 1.
7. The microenvironment hydrogen-supply permeable layer of claim 6, wherein the weight ratio of the metal peroxide or metal hydroxide to the aluminum powder is: 1:10-10: 1.
8. The microenvironment hydrogen-supplying gas permeable layer of claim 5, wherein the metal peroxide is selected from the group consisting of calcium peroxide, magnesium peroxide, sodium peroxide, and potassium peroxide.
9. The microenvironment hydrogen-supplying permeable layer of claim 5, wherein the metal hydroxide is selected from the group consisting of calcium hydroxide, magnesium hydroxide, sodium hydroxide, and potassium hydroxide.
10. The microenvironment hydrogen-supplying permeable layer of claim 5, wherein the metal hydride is selected from the group consisting of magnesium hydride, calcium hydride, and silicon hydride.
11. The microenvironment hydrogen-supplying permeable layer of claim 5, wherein the hydrogen-producing formulation is supplemented with a solid acid selected from the group consisting of solid citric acid, solid lactic acid, solid oxalic acid, solid hydrochloric acid, solid phytic acid, and solid silicic acid, such that the hydrogen-producing formulation has a ph of between 4 and 9.
12. The microenvironment hydrogen-supplying gas-permeable layer of claim 1, wherein the hydrogen-producing formulation further comprises a super absorbent polymer, an activator, or a catalyst.
13. The microenvironment hydrogen-supplying gas permeable layer of claim 1, wherein the thin layer further comprises oxygen and reactive oxygen species generating units.
14. The microenvironment hydrogen-donating breathable layer of claim 1, wherein the breathable layer is used in a sanitary product comprising an eye mask, a face mask, a brassiere, a breast patch, a galactorrhea patch, a sanitary napkin, a paper diaper, a sanitary pad, a wound dressing, a wound patch, a bandaging gauze, a pressure sore pad, or an external application bag.
15. An external application bag, comprising:
the thin layer is wrapped with a hydrogen production formula and an oxygen production formula, the outer side of the thin layer is air-tight, the inner side surface of the thin layer is provided with a plurality of small holes, and the thin layer comprises a single layer or a composite layer;
the hydrogen production formula is wrapped in the thin layer and absorbs moisture or liquid water in the air to generate hydrogen; the hydrogen gas is released to the skin through the plurality of small pores;
the oxygen generation formula is wrapped in the thin layer and absorbs moisture or liquid water in the air to generate oxygen; the oxygen is released to the skin through the plurality of small pores.
16. A topical bag according to claim 15 wherein the inner side of the sheet comprises a silicone, non-woven or plastic gas permeable membrane.
17. An external application bag according to claim 15 wherein the outer material of said sheet comprises polypropylene, polyethylene plastic film, aluminium film or composite film.
18. An external application bag according to claim 15 wherein said hydrogen-generating formulation, said oxygen-generating formulation comprises a powder or a granulate.
19. An external application bag according to claim 15 wherein the hydrogen-producing formulation comprises a metal peroxide, metal hydroxide, or metal hydride, aluminum powder or silicon powder.
20. An external application bag according to claim 19 wherein the weight ratio of metal peroxide or metal hydroxide to aluminum powder is: 1:100 to 100: 1.
21. An external application bag according to claim 20 wherein the weight ratio of metal peroxide or metal hydroxide to aluminum powder is: 1:10-10: 1.
22. A topical bag according to claim 19 wherein the metal peroxide is selected from the group consisting of calcium peroxide, magnesium peroxide, sodium peroxide, potassium peroxide.
23. A topical bag according to claim 19 wherein the metal hydroxide is selected from the group consisting of calcium hydroxide, magnesium hydroxide, sodium hydroxide, potassium hydroxide.
24. A topical application bag according to claim 19 wherein the metal hydride is selected from the group consisting of magnesium hydride, calcium hydride, and silicon hydride.
25. An external application bag according to claim 19 wherein said hydrogen-producing formulation is supplemented with a solid acid selected from the group consisting of solid citric acid, solid lactic acid, solid oxalic acid, solid hydrochloric acid, solid phytic acid and solid silicic acid, such that the hydrogen-producing formulation has a ph of between 4 and 9.
26. The external application bag of claim 15 wherein the oxygen generating formulation is a metal peroxide selected from the group consisting of calcium peroxide, magnesium peroxide, sodium peroxide, potassium peroxide.
27. The external application bag of claim 15, wherein the weight ratio of the oxygen-generating formulation to the hydrogen-generating formulation is 1:1 to 1: 50.
28. The topical bag of claim 15, wherein the inflammation is non-bacterial inflammation.
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| CN2019100739603 | 2019-01-25 | ||
| CN201910073960 | 2019-01-25 |
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| CN112456438A (en) * | 2020-11-30 | 2021-03-09 | 杭州粟源科技有限公司 | Mixture capable of generating hydrogen for human body and carrier thereof |
| CN112843087A (en) * | 2021-02-24 | 2021-05-28 | 江西浣星谷科技有限公司 | Preparation method of fabric for adjuvant therapy of pectoral and pulmonary diseases |
| WO2021213028A1 (en) * | 2020-04-21 | 2021-10-28 | 杭州氢源素生物科技有限公司 | Sandwich mask capable of hydrogen production, heating, and heat preservation |
| CN115417375A (en) * | 2022-09-30 | 2022-12-02 | 中国计量大学 | Silicon/metal hydride composite material for rapid hydrolysis hydrogen production and preparation method thereof |
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