JP6814239B2 - Ventilation layer - Google Patents

Description

The present invention provides an aerated layer containing a hydrogen-producing composition. The present invention provides health by supplying hydrogen to the skin and the inside of the human body because of the advantages that hydrogen is not irritating, has excellent diffusivity, and the reaction does not produce harmful by-products. , Achieves the use of disease improvement, belongs to the area of living health.

Hydrogen (H ₂ ) is a colorless and tasteless gas, and according to research reports in 1975, hydrogen can treat cancer as an antioxidant gas. In 2007, Japanese scholars neutralized toxic radicals with hydrogen to treat cerebral ischemia and perfuse the damage. Subsequent extensive studies have confirmed that hydrogen has a therapeutic effect on many illnesses and injuries. As a biological antioxidant, hydrogen can selectively neutralize radicals, has antioxidative, anti-inflammatory and anti-apoptotic effects, and does not affect active oxygen, which has a physiological effect in the body. For example, superoxide anion hydrogen peroxide and the like explain that hydrogen can be safely used in the human body. Another advantage of hydrogen is that it has a strong diffusive power, and because the cell membrane and each biological barrier do not affect the diffusion and penetration of hydrogen and reach any part of the body, stroke, diabetes, arteriosclerosis, Parkinson's disease. It is considered to have a therapeutic effect on common acute and chronic diseases such as.

The use of hydrogen includes methods such as inhaling hydrogen, drinking hydrogen water, or injecting hydrogen salt water. Inhalation of hydrogen has an improving effect on neurological and cardiovascular diseases such as stroke and myocardial infarction. Drinking hydrogen water has been reported to have therapeutic effects on diabetes and metabolic diseases. On the other hand, in animal models, drinking hydrogen water has been shown to improve allergic diseases. For example, atopic eczema and fundus disease can be treated by direct injection into the eyeball of retinopathy. As a result of cooperation between Kagoshima University in Japan and Sam Ratulangi University in Indonesia, high-concentration hydrogen water was adopted, used in combination with the anticancer drug 5-fluorouracil, and two patterns of cytology and animal model were used. It has been demonstrated that hydrogen not only promotes tumor apoptosis, but can also clearly increase the antitumor effect of 5-fluorouracil, prolonging the lifespan of tumor-affected animals.

Current common hydrogen supply methods include hydrogen water and high pressure hydrogen tanks. Hydrogen water fuses hydrogen in water. The first hydrogen maker had a large volume and required electric power, and the produced hydrogen water was difficult to store. When replenishing high-purity hydrogen, a high-pressure hydrogen tank was usually used. In addition to the inconvenience of carrying due to volume and weight, there were concerns about its use due to the potential safety risks of high pressure gas tanks. Since the hydrogen maker and the high-pressure hydrogen tank are difficult to carry, it is not easy to spread and the actual application of hydrogen is limited. Therefore, how to supply easy-to-use hydrogen anytime, anywhere is a problem to be solved by the present invention.

There are various skin-touching living hygiene materials on the market (mouth masks, face masks, facial masks, etc.). Because it comes into direct contact with the skin, it is often advertised for comfort and convenience. However, in recent years, those skilled in the art have also sought improvements and breakthroughs in other mergers and achievable effects. For example, the reaction of internal materials supplies the human body with beneficial gases such as oxygen. However, since the gas supply is due to internal chemistry between the materials, it should always contain more materials and at the same time include more types of material combinations in order to improve the health effect. Is required and there is a risk of material leakage or unsafe by-products.

Therefore, providing a ventilation layer capable of supplying hydrogen into the living hygiene material is an important problem to be solved by the present invention.

To solve the above problems, the inventor of the present application provides a hydrogen-supplying aeration layer containing a thin layer and a hydrogen-producing composition. The outside of the thin layer is not ventilated, the inside is ventilated, and the inner surface has a number of small holes. The thin layer is a single layer or a multi-layer. Then, the hydrogen-producing composition is contained in the thin layer and absorbs water in the air or liquid water without leaking to generate hydrogen. The hydrogen passes through the plurality of small holes and is discharged into the skin and the inside of the human body.

In order to achieve the object of the present invention, the material inside the thin layer may be silica gel, non-woven fabric, or plastic breathable membrane.

In order to achieve the object of the present invention, the outer material of the thin layer may be polypropylene, a polyethylene plastic thin film, an aluminum film, or a composite film.

In order to achieve the object of the present invention, the hydrogen producing composition may be in the form of powder or pellets.

To achieve the object of the present invention, the hydrogen producing composition comprises a metal peroxide, a metal hydroxide or a metal hydride, and an aluminum powder or a silicon powder.

In order to achieve the object of the present invention, the weight ratio of the hydrogen generation composition is metal peroxide or metal hydroxide: aluminum powder = 1: 100-100: 1, preferably 1:10-10: 1. It may be.

In order to achieve the object of the present invention, the metal peroxide is selected from the group consisting of calcium peroxide, magnesium peroxide, sodium peroxide, and potassium peroxide. The metal hydroxide is selected from the group consisting of calcium hydroxide, magnesium hydroxide, sodium hydroxide, and potassium hydroxide. The metal hydride is selected from the group consisting of magnesium hydride, calcium hydride, and silicon hydride.

In order to achieve the object of the present invention, a solid acid is added to the hydrogen producing composition. The solid acid is selected from the group consisting of solid citric acid, solid lactic acid, solid oxalic acid, solid hydrochloric acid, solid phytic acid and solid silicic acid.

In order to achieve the object of the present invention, the hydrogen producing composition may further contain a superabsorbent polymer, an activator or a catalyst.

To achieve the object of the present invention, the thin layer may further contain oxygen and reactive oxygen species producing units.

In order to achieve the object of the present invention, the ventilation layer can be used in a living hygiene material. The living hygiene materials include eye masks, mouth masks, face masks, packs, bras, pasties, chest pads, napkins, paper diapers, sanitary pads, wound dressings, adhesive plasters, gauze, and hemorrhoid pads.

The present invention relates to an aerated layer containing a hydrogen producing composition, which can generate a large amount of hydrogen in a short time and supply it to the skin, nostrils, oral cavity, eyes, or other touching human body parts of the human body. The advantageous effects of the present invention are as follows.
(1) Safe and convenient to use.
No tank pipeline or plugin required. It is easy to carry, the composition is harmless, and it can be used in contact with the body.
(2) Do not produce harmful by-products
(3) Since it is close to the skin, it is easily absorbed.
(4) Provide a wide range of physical health uses for hydrogen.
-Has excellent diffusive power and has no restrictions on the reachable area.
-A non-toxic, safe reducing agent that is gentle on the human body.
-Has excellent antioxidant and anti-inflammatory effects.
-Improves indigenous bacteria.

In order to obtain the most favorable health effects of the aerated layer, the present invention further indicates the necessary and optimal proportion and dosage of the hydrogen-producing composition, the aerated layer is used in the living hygiene material, and the present invention. Illustrate the application.

It is a schematic diagram of the ventilation layer which supplies hydrogen. It is an exploded view of the ventilation layer. It is sectional drawing of the ventilation layer. It is a schematic diagram of the ventilation layer applied to an eye mask. It is a schematic diagram of the ventilation layer applied to a mouth mask. It is a schematic diagram of the ventilation layer applied to a mouth mask. It is a schematic diagram of the ventilation layer applied to a pack. It is a schematic diagram of the ventilation layer applied to a wound dressing.

The present invention will be described as shown in the following examples, but the present invention is not limited to the following examples. Hereinafter, the features, applications and advantages contained in the hydrogen-supplying ventilation layer of the present application will be specifically described, but any equivalent implementation or modification that does not deviate from the technical spirit of the present invention is claimed in the present application. Included in the range.

As shown in FIGS. 1 to 3, the present invention provides a thin layer 11 containing a hydrogen-producing composition and a ventilation layer 1 containing the thin layer 11. The outside of the thin layer 11 is not ventilated, the inside is ventilated, and the inner surface has a plurality of small holes. The thin layer may be a single layer or a multi-layer. Then, the hydrogen generation composition 12 is contained in the thin layer 11 and absorbs water in the air or liquid water without leaking to generate hydrogen. As shown in FIG. 2, the hydrogen passes through the plurality of small holes 111 and is absorbed into the human body via the skin, nostrils, oral cavity, eyes and other touching human body parts.

In the present invention, the hydrogen generation composition 12 is covered with the thin layer 11 which does not ventilate the outside but ventilates the inside. In order to prevent the hydrogen production composition 12 from leaking, the pore diameter of the small holes 111 inside the thin layer is smaller than the diameter of the hydrogen production composition 12. The outside of the thin layer 11 is made of a non-ventilating material, and the inside is made of a skin-friendly material.

At the time of storage, it is wrapped in a closed material so that the moisture in the air does not react with the hydrogen generation composition 12 first. When using, remove the sealed packaging and apply to the required position. By using the ventilation layer 1, moisture such as sweat water and moisture can be cut by the material that does not ventilate on the outside, and moisture does not leak. Therefore, the hydrogen-producing composition 12 can be sufficiently reacted to supply hydrogen to the skin.

The material inside the thin layer 11 used to cover the hydrogen production composition 12 may be silica gel, a non-woven fabric, or a plastic breathable membrane. The outer material of the thin layer 11 may be polypropylene, a polyethylene plastic thin film, an aluminum film, or a composite film.

The hydrogen generation composition 12 may be in the form of powder or pellets. Then, the hydrogen generation composition 12 contains a metal peroxide, a metal hydroxide or a metal hydride, and an aluminum powder or a silicon powder.

Among them, the metal peroxide is selected from the group consisting of calcium peroxide, magnesium peroxide, sodium peroxide, and potassium peroxide. The metal hydroxide is selected from the group consisting of calcium hydroxide, magnesium hydroxide, sodium hydroxide, and potassium hydroxide.

The hydrogen-producing composition may further contain a compound capable of forming a metal hydroxide with water. Such compounds are, for example, magnesium hydride, calcium hydride, and silicon hydride.

The hydrogen-producing composition selectively adds a solid acid to neutralize the hydrogen-producing composition to bring the pH value between 4-9, thereby avoiding irritation to the skin. The hydrogen absorption effect can be improved. The solid acid is selected from the group consisting of solid citric acid, solid lactic acid, solid oxalic acid, solid hydrochloric acid, solid phytic acid and solid silicic acid.

The following reaction formula represents the mechanism by which the hydrogen production composition supplies hydrogen.
If it is a peroxide, it first reacts with water to generate a hydroxide and discharge oxygen. The reaction formula is as follows.

2XO ₂ + 2H ₂ O → 2X (OH) ₂ + O ₂ (X is calcium and magnesium) or
2Y ₂ O ₂ + 2H ₂ O → 4Y (OH) + O ₂ (Y is sodium and potassium)

Hydroxides can react with aluminum powder to produce hydrogen. See the reaction equation below.
2Al + 2H ₂ O + X (OH) ₂ = X (AlO ₂ ) ₂ + 3H ₂
2Al + 2H ₂ O + 2Y (OH) = 2YAlO ₂ + 3H ₂

Metal hydrides react with water to produce hydrogen and metal hydroxides. The metal hydroxide reacts with water again and continues to produce hydrogen.

If a large amount of hydrogen is to be produced faster in the above reaction, a peroxide or hydroxide of a highly active alkali metal (Group IA) (that is, sodium or potassium) can be selected as the reactant.

In the application of the combination of hydrogen production compositions exemplified above, a person having ordinary technology in the industry can also associate the application that hydrogen is generated by reacting silicon with hydroxide and water. This should be within the scope of the equivalent implementation of the combination of the present application, the claims of the hydrogen production composition of the present application, the reaction formula of which is:

Si + 4H ₂ O = H ₄ SiO ₄ + 2H ₂
H ₄ SiO ₄ + 2 NaOH = Na ₂ SiO ₃ + 3H ₂

To determine the preferred dosage ratio, hydrogen production efficiency is measured when each reactant is in the range of 0.01-100 g. The hydrogen production composition reacts to generate hydrogen when the ratio of metal peroxide or metal hydroxide: aluminum powder = 1: 100-100: 1. When the weight ratio is 1:10-10: 1, the most preferable hydrogen production efficiency is achieved.

The breathable membrane is applied to a living hygiene material and can be used in contact with the body. The living hygiene materials include eye masks (Fig. 4), mouth masks (Fig. 5A, Fig. 5B), face masks, packs (Fig. 6), brassieres, pasties, chest pads, napkins, paper diapers, sanitary pads, and wound dressings. Figure 7), including, but not limited to, adhesive plasters, gauze, and hemorrhoid pads.

The following is a collection of testers with all related diseases and symptoms (including neurological disorders, recent radiation therapy, constipation, UV damage, astringency of the eyes, eye tightness, trauma) and the ventilation. Living hygiene materials, including membrane mouth masks, eye masks, packs, or wound coverings, were distributed and used. Continuous use for 3 months, 3 times a week, 2 hours at a time, then answer the questionnaire, and apply the hydrogen generation composition of the ventilation layer to various living hygiene materials. The improvement effect of the above and the comfort of its use were investigated (using 1-10 as an evaluation standard, the larger the value, the higher the effect). At the same time, it was compared with a general product that does not contain a commercially available gas generating material (hereinafter abbreviated as commercially available) and a product that does not contain aluminum powder (does not generate hydrogen). The average result of each evaluation statistic is shown below. The hydrogen-producing composition in the air-permeable membrane had the above-mentioned preferable ratio (metal peroxide or metal hydroxide: aluminum powder = 100: 80-120), and the content was adjusted according to the corresponding living hygiene material. ..

Example 1, mouth mask

Table 1 shows the test sets and results. The peroxide is calcium peroxide, and the hydroxide is calcium hydroxide, both of which weigh 10 g. The amount of aluminum powder is 1 g, and the amount of citric acid is appropriate. Hydrogen was produced by skin moisture or added water.

The results showed that the hydrogen-producing composition of the present application can improve diseases / symptoms such as neurological diseases, side effects of radiotherapy, and constipation. These effects cannot be achieved with either commercially available mouth masks or pairs that produce only oxygen (without aluminum powder). In addition, the comfort of each combination of the present application is better than that of any commercially available mouth mask. And, when having a peroxide, a hydroxide, and a solid acid at the same time, a more preferable effect of improving the disease and comfort could be achieved.

Table 1-Improvement effect and comfort of each disease and symptom of the ventilation layer in the mouth mask

Example 2, eye mask

Table 2 shows the test sets and results. The peroxide is sodium peroxide and the hydroxide is sodium hydroxide, both of which weigh 1 g. The amount of aluminum powder is 10 g, and the amount of oxalic acid is appropriate. Hydrogen was produced by the added water.

The results showed that the hydrogen-producing composition of the present application can improve eye astringency and eye diseases. Both have better effects than commercially available eye masks or sets that do not contain aluminum powder (cannot generate hydrogen). In addition, the comfort of each combination of the present application is better than that of any commercially available eye mask. And, when having a peroxide, a hydroxide, and a solid acid at the same time, the most preferable effect and comfort could be achieved.

Table 2-Improvement effect and comfort of each disease and symptom of the ventilation layer in the eye mask

Example 3, pack

Table 3 shows the test sets and results. The peroxide is magnesium peroxide, and the hydroxide is magnesium hydroxide, both of which weigh 12.5 g. The amount of aluminum powder is 6.25 g, and the amount of lactic acid, which is a solid acid, is appropriate. Hydrogen was produced by the added water.

As a result, the hydrogen production composition of the present application has an effect of improving ultraviolet damage, radiotherapy side effects, neurological diseases, etc., as compared with a commercially available pack or a set that does not contain aluminum powder (cannot generate hydrogen). Shown. In addition, the comfort of each union of the present application is better than that of a commercially available pack. And, when having a peroxide, a hydroxide, and a solid acid at the same time, a more preferable effect of improving the disease and comfort could be achieved.

Table 3-Improvement effect and comfort of each disease and symptom of the ventilation layer in the pack

Example 4, wound dressing

Table 4 shows the test sets and results. The peroxide is potassium peroxide, and the hydroxide is potassium hydroxide, both of which weigh 2.5 g. The amount of aluminum powder is 2.5 g, and the amount of phytic acid, which is a solid acid, is appropriate. The wound dressing produced hydrogen by absorbing water. It was able to retain more water and prevent it from draining into the wound in the opposite direction. By designing to circulate only the gas of the ventilation layer, the improvement effect of supplying hydrogen and at the same time avoiding secondary infection of the wound was obtained.

As a result, the hydrogen producing composition of the present application has an effect of improving ultraviolet damage, side effects of radiotherapy, wound healing, etc., as compared with a commercially available wound dressing or a set containing no aluminum powder (which cannot generate hydrogen). It has been shown. In addition, the comfort of each combination of the present application is better than that of commercially available covering materials. And, when having a peroxide, a hydroxide, and a solid acid at the same time, the most preferable effect and comfort could be achieved.

Table 4-Improvement effect and comfort of each disease and symptom of the ventilation layer in the wound dressing

Further, when a napkin or the like which has a demand that the liquid does not leak is used, a polymer water absorbing material (that is, a super absorbent polymer) can be added at the same time. This achieves the double effect of absorbing the liquid and supplying hydrogen, while at the same time preventing the liquid from regurgitating, causing skin infections and inflammation.

Taken together, the breathable layers of the present invention, when applied in living hygiene materials in any combination of hydrogen-producing compositions, all include neurological disorders, radiotherapy side effects, constipation, UV damage, astringency of the eyes, tightness of the eyes, wounds. Can improve healing. By improving the antioxidant effect of hydrogen and the effect of indigenous bacteria, it is possible to break through the conventional function of restricting living hygiene materials at once. For a set that produces only oxygen (without aluminum powder), the application of the hydrogen producing composition of the present application can achieve a better, broader range of physical health effects, with beneficial effects. And, due to the fact that the by-product can generate oxygen, it is more comfortable to wear, does not feel hot and humid, and is more comfortable to use than the commercially available one (which does not contain a composition that generates gas). When peroxides, hydroxides and solid acids are added at the same time, the most preferable effects of disease and symptom improvement and comfort can be achieved.

Taken together, the present application can generate large amounts of hydrogen in a short period of time and supply it to human skin, nostrils, oral cavity, eyes, or other touching human body parts. It has the advantage of not requiring a tank pipeline, manufacturing machine or plug-in over common hydrogen generating methods and appliances, is easy to carry, the composition is harmless, can be used near the skin, and of hydrogen. It is easy to produce and has excellent effects such as no harmful by-products.

Since hydrogen has a simple structure, it has excellent diffusive power and there is no limitation on the reachable part. Hydrogen is a non-toxic, safe reducing agent that is kind to the human body, has an excellent antioxidant effect, and has advantages such as improving indigenous bacteria, so it is more suitable for the health use of conventional well-known living hygiene materials. A wide range of benefits for improving effectiveness can be obtained.

The breathable layer exemplified in the present invention can be applied to a corresponding disease by improving the antioxidant effect of hydrogen and the effect of indigenous bacteria, and the breathable layer of the present application can be reasonably improved by the examples of the present application. It can be applied to other diseases resulting from any of the two causes (eg, cancer, chemotherapy side effects, metabolic diseases, immune diseases, allergies, diabetes, weight control, colitis, etc.).

In order to improve the hydrogen production effect, the hydrogen production composition may further contain a super absorbent polymer, an activator or a catalyst, if necessary. In addition, a production unit capable of generating oxygen and active oxygen can be further added to the hydrogen production composition to adjust the ratio, and the required effect can be achieved for different demands.

Although specific examples of the present invention have been described in detail above, the present invention is not limited to the examples. Any equivalent practice or modification that does not deviate from the technical spirit of the present invention is included in the claims of the present application.

Since the above-mentioned multiple effects are patent requirements that are truly novel and inventive, they are filed by law. Your office will approve the patent application proposal for the present invention, and we will enforce the invention with this.

1 Ventilation layer 11 Thin layer 111 Small holes 12 Hydrogen production composition

Claims (9)

A thin layer that is thin, not ventilated on the outside, ventilated on the inside, has multiple small holes on the inner surface, and is single or multi-layered.
A hydrogen-producing composition contained in the thin layer, which absorbs water in the air or liquid water without leaking to generate hydrogen.
Including
The hydrogen passes through the plurality of small holes and is discharged and supplied into the skin and the human body.
The hydrogen production composition contains a metal peroxide or a metal hydroxide, and an aluminum powder.
Weight ratio of said hydrogen product composition, metal peroxides or metal hydroxide: aluminum powder = 1: 100-100: 1, preferably 1: 10-10: Ri 1 der,
The hydrogen production composition is added with a solid acid so that the pH is between 4-9.
The solid acid is selected from the group consisting of solid citric acid, solid lactic acid, solid oxalic acid, solid hydrochloric acid, solid phytic acid and solid silicic acid.
Ventilation layer. The material inside the thin layer is silica gel, non-woven fabric, or plastic breathable membrane.
The ventilation layer according to claim 1. The outer material of the thin layer is polypropylene, polyethylene plastic thin film, or aluminum film.
The ventilation layer according to claim 1. The hydrogen production composition is in the form of powder or pellets.
The ventilation layer according to claim 1. The metal peroxide is selected from the group consisting of calcium peroxide, magnesium peroxide, sodium peroxide, and potassium peroxide.
The ventilation layer according to claim 1. The metal hydroxide is selected from the group consisting of calcium hydroxide, magnesium hydroxide, sodium hydroxide, and potassium hydroxide.
The ventilation layer according to claim 1. The hydrogen production composition further comprises a super absorbent polymer, or a catalyst.
The ventilation layer according to claim 1. The thin layer further contains oxygen and reactive oxygen species.
The ventilation layer according to claim 1. The ventilation layer can be used in living hygiene materials
The living hygiene materials include eye masks, mouth masks, face masks, packs, bras, pasties, chest pads, napkins, paper diapers, sanitary pads, wound dressings, adhesive plasters, gauze, and hemorrhoid pads.
The ventilation layer according to claim 1.

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