CN111446027A - Film laminated structure - Google Patents
Film laminated structure Download PDFInfo
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- CN111446027A CN111446027A CN202010348904.9A CN202010348904A CN111446027A CN 111446027 A CN111446027 A CN 111446027A CN 202010348904 A CN202010348904 A CN 202010348904A CN 111446027 A CN111446027 A CN 111446027A
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- layer
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- refractive index
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B5/00—Non-insulated conductors or conductive bodies characterised by their form
- H01B5/14—Non-insulated conductors or conductive bodies characterised by their form comprising conductive layers or films on insulating-supports
Abstract
The invention discloses a film laminated structure, which comprises a substrate layer, an optical adjusting layer and a low-resistance conducting layer, wherein the optical adjusting layer comprises a first optical adjusting layer and a second optical adjusting layer; the low-resistance conducting layer is arranged on one side, far away from the base material layer, of the optical adjusting layer, and the reflection difference rate of the optical adjusting layer and the low-resistance conducting layer is smaller than 1. After the refractive indexes of the two optical adjusting layers are matched with each other, the two optical adjusting layers have good adjusting and matching effects on chromatic aberration generated by the low-resistance conducting layer and other layers in the display device.
Description
Technical Field
The present invention relates to a thin film stack structure, and more particularly, to a thin film stack structure including a color difference adjusting layer.
Background
In recent years, electronic devices in the display field are widely formed by bonding an electrode layer and a glass cover plate with liquid optical adhesive (OCA). The electrode layer is formed by laminating a conductive thin film made of a transparent conductive material on a film mainly made of a transparent base material; the conductive film is further etched by yellow light or is subjected to laser and the like to form an electrode layer, the transparent conductive material has different refractive indexes compared with glass or other layers such as Optical Cement (OCA), so that the interference of each layer is different due to the difference of the refractive indexes between the part of the electrode layer with the transparent conductive material and the part without the transparent electrode layer, and when the difference of the refractive indexes is large, the problem that etching lines or laser rays are visible is easily formed, and the visibility of a display interface is influenced.
In the prior art, an optical adjustment layer (IM) is usually arranged between an electrode layer and glass to solve the problem that etching lines or laser lines are visible, but a transparent conductive material is developed towards the direction of lowering resistance, and ITO or a transparent low-resistance conductive material different from ITO, which is thicker than conventional materials, is usually selected, so that in the conventional optical adjustment layer, it is difficult to sufficiently suppress chromatic aberration formed before the low-resistance electrode layer and other layers.
Disclosure of Invention
In order to solve the problem that the etching line is visible, the invention provides a film laminated structure which comprises a substrate layer, an optical adjusting layer and a low-resistance conducting layer, wherein the optical adjusting layer comprises a first optical adjusting layer and a second optical adjusting layer, the first optical adjusting layer is arranged on one side of the substrate layer, and the second optical adjusting layer is arranged on one side, far away from the substrate layer, of the first optical adjusting layer; the low-resistance conducting layer is arranged on one side, far away from the base material layer, of the optical adjusting layer; the reflection difference rate of the optical adjusting layer and the low-resistance conducting layer is less than 1.
The optical adjusting layer is arranged between the substrate layer and the conducting layer, and the problem of visible equal color difference of an etching line generated after the subsequent thin film laminated structure is adjusted and attached to the glass cover plate by using OCA is solved, the optical adjusting layer with two layers is particularly suitable for the situation that a low-resistance conducting material is adopted as the conducting layer, usually, one optical adjusting layer only generates a good refractive index matching effect on the conducting layer larger than 100 omega/□, for a particular low resistance conductive material, the lower the resistance, the lower the reflectivity of the required optical adjustment layer should be, but the current single optical adjustment layer can generate redundant refraction effect on low-resistance conductive materials, therefore, after the refractive indexes of the two optical adjusting layers are matched with each other, the difference between the reflection indexes of the low-resistance conducting layer and the optical adjusting layer is reduced, thereby having good adjustment and matching effects on chromatic aberration generated by the low-resistance conductive layer and other layers in the display device.
Preferably, the low-resistance conductive layer in the invention is a conductive layer with resistance less than 30 Ω/□. In practice, when the sheet resistance of the conductive layer is less than 30 Ω, the reflectance of the conductive layer is R, and the reflectance of the optical adjustment layer is RIM layerReflection difference △ R ═ R-RIM layer|，△R<1 is the best, and has better optical adjustment effect. Preferably, 0.2<△R<0.7。
Preferably, the substrate layer is a flexible transparent substrate, and the material is selected from one or more of polyethylene terephthalate (PET), Polyimide (PI), polypropylene (PP), Polystyrene (PS), cellulose Triacetate (TAC), FMH acrylonitrile-butadiene-styrene (ABS), polyvinyl chloride (PVC), Polycarbonate (PC), Polyethylene (PE), polymethyl methacrylate (PMMA), polytetrafluoroethylene (ptfe), cyclic olefin copolymer (COP, Arton), and polyethylene naphthalate (PEN). The purpose of the substrate layer is to serve as a load bearing conductive layer.
Preferably, the first optical adjustment layer includes a high refractive index resin and metal particles. The high-refractive-index resin is a resin with a refractive index within a range of 1.6-1.7, preferably, metal particles are uniformly distributed in the high-refractive-index resin, and the high-refractive-index resin is selected to be doped with the metal particles, so that the first optical adjustment layer has both high refractive index and good light transmittance, and the metal particles can make light rays diffuse and reflect on the first optical adjustment layer, so that the reflected light is more uniform; preferably, the high refractive index resin includes a plurality of benzene rings and epoxy structures. The metal particles are selected from one or more of silicon (Si), zirconium (Zr), titanium (Ti), iron (Fe) and cobalt (Co).
Preferably, the metal particles have a particle size of 20 to 100 nm. The metal particles in the particle size range are particularly suitable for being mixed with high-refractive-index resin, and have good light transmission and light uniformity. Preferably, the metal particles have a particle size of 30nm, 50nm, 70nm, 80nm, 100nm, 130nm, 150nm or 180 nm.
Preferably, the thickness of the first optical adjustment layer is 0.5-5 um, and the refractive index is 1.6-1.7.
Preferably, the refractive index is 1.6, 1.62, 1.65, 1.68 or 1.7.
Preferably, the second optical adjustment layer has an insulation sheet resistance >10^8 Ω/□.
Preferably, the second optical adjustment layer is a single-layer non-conductive metal layer with a thickness of 0.5-80 nm. In this embodiment, the thickness of the second optical adjustment layer is preferably 10nm, 30nm, 50nm or 70 nm. The material of the second optical adjusting layer is selected from one or more of titanium (Ti), indium (In), tin (Sn), indium tin alloy and silicon aluminum alloy. Preferably, the indium doping weight percentage in the indium-tin alloy is 0-50%, and the aluminum doping weight percentage in the silicon-aluminum alloy is 0-50%.
Preferably, the second optical adjustment layer comprises a high refractive index layer and a low refractive index layer.
Preferably, the thickness of the high-refractive-index layer is 2-200 nm, and the refractive index of the high-refractive-index layer is 1.8-2.4; preferably, the thickness of the high refractive index layer is 10nm, 30nm, 50nm, 80nm, 120nm or 160 nm; preferably, the high refractive index layer has a refractive index of 1.8, 1.9, 2.0, 2.1, 2.2, 2.3 or 2.4; preferably, the material of the refractive index layer is selected from metal oxide, nitride, sulfide or their dopant with the refractive index of 1.8-2.4. Preferably, the dopant material is selected from one or more of aluminum (Al), gallium (Ga), zirconium (Zr), boron (B), yttrium (Y), molybdenum (Mo), and sulfur (S);
preferably, the high refractive index layer material is TiO2, SnO2, ZnO, Nb2O5, Ta2O5, Si3N4, ZnS, and the dopant includes AZO, GZO, YZO, and the like.
Preferably, the low refractive index layer has a thickness of 10 to 500nm and a refractive index of 1.2 to 1.7. Preferably, the low refractive index layer has a thickness of 10nm, 20nm, 50nm, 80nm, 120nm, 180nm, 250nm or 400 nm. Preferably, the low refractive index layer has a refractive index of 1.2, 1.3, 1.4, 1.5, 1.6 or 1.7; the material of the low-refractive-index layer is selected from metal oxides, non-metal oxides, sulfides, fluorides and carbides with the refractive index of 1.2-1.7, and preferably, the material with the refractive index is SiO2, Al2O3, MgF, MgS or SiC.
Preferably, the first optical adjustment layer is formed by a coating method, and the second optical adjustment layer is formed by a sputtering method. Preferably, the coating method may be spin coating, spray coating, dip coating, slit coating, roll coating, Meyer rod coating, but is not limited thereto. It is understood that when the first optical adjustment layer contains an organic material such as a high refractive index resin, the coating method is used to provide good coverage of the coating material and good light transmittance. Preferably, the sputtering method is magnetron sputtering. The compactness of the second optical adjustment layer can be increased by using a sputtering method.
Preferably, the film laminated structure is formed by sequentially and adjacently stacking a substrate layer, a first optical adjusting layer, a second optical adjusting layer and a low-resistance conducting layer from bottom to top. The first optical adjustment layer is arranged on the substrate layer, the high-refractive-index resin-doped metal particles are selected to be well attached to the substrate layer by a coating method, the second optical adjustment layer can be a single layer or a double layer, the materials are all inorganic materials, and the sputtering method is selected to improve the compactness of the second optical adjustment layer and increase the adhesive force of the inorganic materials on the first optical adjustment layer. It is understood that the adhesion of both optical adjustment layers by coating is poor, and the light transmittance of both optical adjustment layers by sputtering is poor, resulting in yellowing affecting the color system. The two optical adjusting layers formed by one layer of coating and one layer of sputtering not only ensure the adhesive force between the laminated layers, but also can not form yellowing to cause chromatic aberration. And the second optical adjusting layer (sputtering coating) is adjacent to the low-resistance conducting layer and is an inorganic material layer, so that the low-resistance conducting layer is not corroded and damaged.
Drawings
FIG. 1 is a cross-sectional view of one embodiment of a thin film stack configuration of the present invention.
Fig. 2 is a cross-sectional view of another embodiment of a thin film stack structure of the present invention.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is further described in detail with reference to the following embodiments. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
Solvents, reagents, coating methods, technical parameters, coating equipment and the like used in the present invention are all conventional solvents, reagents, methods, parameters, equipment and the like in the technical field unless otherwise specified.
Example 1
As shown in fig. 1, the embodiment provides a film laminated structure, which sequentially comprises a substrate layer 1, a first optical adjustment layer 3, a second optical adjustment layer 5, and a low-resistance conductive layer 7 from bottom to top, wherein the substrate layer 1 is PET, the first optical adjustment layer 3 comprises resin and titanium (Ti) particles with a refractive index in a range of 1.6-1.7, and is disposed on the PET by a coating method, and the thickness of the first optical adjustment layer 3 is 2 μm. The second optical adjustment layer 5 is a single-layer non-conductive metal layer, and is made of indium tin alloy (InSn), wherein indium (In) accounts for 40% of the alloy, the indium tin alloy (InSn) is sputtered above the first optical adjustment layer 3 by a magnetron sputtering method, and the thickness of the second optical adjustment layer 5 is 30 nm.
Example 2
As shown in fig. 2, the embodiment provides a film laminated structure, which sequentially comprises a substrate layer 1, a first optical adjustment layer 3, a second optical adjustment layer 5, and a low-resistance conductive layer 7 from bottom to top, wherein the substrate layer 1 is PET, the first optical adjustment layer 3 comprises resin and silicon (Si) particles with a refractive index in a range of 1.6-1.7, and is disposed on the PET by a coating method, and the thickness of the first optical adjustment layer 3 is 4 μm. The second optical adjustment layer 5 includes a low refractive index layer 51 and a high refractive index layer 52, and the material of the low refractive index layer 51 is titanium dioxide (TiO)2) Is arranged above the first optical adjustment layer 3 by a magnetron sputtering method, the thickness of the low refractive index layer is 50nm, and the material of the high refractive index layer 52 is silicon dioxide (SiO)2) And is disposed above the low refractive index layer 51 by means of magnetron sputtering, and the high refractive index layer 52 has a thickness of 100 nm.
Example 3
As shown in fig. 2, the embodiment provides a film laminated structure, which sequentially comprises a substrate layer 1, a first optical adjustment layer 3, a second optical adjustment layer 5, and a low-resistance conductive layer 7 from bottom to top, wherein the substrate layer 1 is PET, the first optical adjustment layer 3 comprises resin and titanium (Ti) particles with a refractive index in a range of 1.6-1.7, and is disposed on the PET by a coating method, and the thickness of the first optical adjustment layer 3 is 3 μm. The second optical adjustment layer 5 includes a low refractive index layer 51 and a high refractive index layer 52, and the material of the low refractive index layer 51 is aluminum oxide (Al)2O3) The optical film is arranged above the first optical adjusting layer 3 by a magnetron sputtering method, the thickness of the low refractive index layer is 400nm, and the material of the high refractive index layer 52 is tin oxide (SnO)2) And is disposed above the low refractive index layer 51 by means of magnetron sputtering, and the high refractive index layer 52 has a thickness of 50 nm.
Example 4
As shown in fig. 2, the embodiment provides a thin film laminated structure, which sequentially comprises a substrate layer 1, a first optical adjustment layer 3, a second optical adjustment layer 5, and a low-resistance conductive layer 7 from bottom to top, wherein the substrate layer 1 is PMMA, the first optical adjustment layer 3 includes resin and silicon aluminum alloy (SiAl) particles (aluminum content in the silicon aluminum alloy is 40%) having a refractive index in a range of 1.6 to 1.7, and is disposed on the PMMA by a coating method, and the thickness of the first optical adjustment layer 3 is 1 μm. The second optical adjustment layer 5 comprises a low refractive index layer 51 and a high refractive index layer 52, the low refractive index layer 51 is made of magnesium sulfide (MgS) and is arranged above the first optical adjustment layer 3 through a magnetron sputtering method, the thickness of the low refractive index layer is 250nm, and the high refractive index layer 52 is made of silicon nitride (Si)3N4) And is disposed above the low refractive index layer 51 by means of magnetron sputtering, and the high refractive index layer 52 has a thickness of 10 nm.
Comparative example 1
This comparative example provides a thin film stack structure, and differs from example 3 only in that the second optical adjustment layer is formed by a coating method.
Comparative example 2
This comparative example provides a thin film stack structure, and differs from example 3 only in that the first optical adjustment layer is formed by magnetron sputtering.
Comparative example 3
This comparative example provides a thin film stack structure, and is different from example 2 only in that the thickness of the high refractive index layer is 300 nm.
Comparative example 4
This comparative example provides a thin film stack structure, differing from example 4 only in that tin oxide (SnO) for the silicon aluminum alloy (SiAl)2) Substitute for Chinese traditional medicineAnd (4) replacing.
The sheet resistance test, the adhesion test by the Baige test method, and the light transmittance test were performed on the film laminated structures of the above examples and comparative examples, and the results are shown in the following table;
measuring the difference value of the average reflectivity values of the low-resistance conducting layer and the optical adjusting layer in the range of 400-700 nm by using a UV-VIS spectrophotometer for the above examples and comparative examples, and obtaining the results as shown in the following table;
| resistance (omega/□) | Transmittance (%) | Adhesion force | Difference in reflectance △ R | |
| Example 1 | 10.8 | 90.4 | 5B | 0.38 |
| Example 2 | 7.2 | 88.5 | 5B | 0.64 |
| Example 3 | 15.5 | 90.2 | 5B | 0.28 |
| Example 4 | 18.1 | 90.7 | 5B | 0.21 |
| Comparative example 1 | 15.2 | 86.4 | 3B | 1.58 |
| Comparative example 2 | 16.8 | 87.2 | 5B | 2.98 |
| Comparative example 3 | 15.8 | 86.2 | 5B | 1.46 |
| Comparative example 4 | 16.2 | 85.4 | 5B | 1.87 |
TABLE 1
As shown in table 1, it can be confirmed that the first optical adjustment layer is coated, and the second optical adjustment layer is sputtered to effectively improve the adhesion of the second optical adjustment layer, thereby improving the light transmittance of the thin film stack structure and reducing the difference in reflectance between the low-resistance conductive layer and the optical adjustment layer in example 3, comparative example 1, and comparative example 2.
From example 2 and comparative example 3, it was confirmed that the thickness of the high refractive index in the optical adjustment layer was 2 to 200nm, which effectively reduces the resistance of the thin film laminated structure.
From example 4 and comparative example 4, it was confirmed that the refractive index of the first optical adjustment layer was 1.6 to 1.7, which can improve the light transmittance of the thin film laminated structure and reduce the difference in reflectance between the low-resistance conductive layer and the optical adjustment layer.
Although the present invention has been described in detail, the foregoing description is in all aspects illustrative of the present invention and is not intended to limit the scope thereof. Thus, various modifications or changes may be made without departing from the scope of the invention.
Claims (10)
1. A thin film stack structure comprising
A substrate layer;
the optical adjustment layer comprises a first optical adjustment layer and a second optical adjustment layer, the first optical adjustment layer is arranged on one side of the base material layer, and the second optical adjustment layer is arranged on one side, far away from the base material layer, of the first optical adjustment layer;
the low-resistance conducting layer is arranged on one side, far away from the base material layer, of the optical adjusting layer;
the reflection difference rate of the optical adjusting layer and the low-resistance conducting layer is less than 1.
2. The thin film stack structure of claim 1, wherein the first optical adjustment layer comprises a high refractive index resin and metal particles.
3. The thin film stack structure of claim 1, wherein the first optical adjustment layer is formed by a coating method and the second optical adjustment layer is formed by a sputtering method.
4. The thin film stack structure of claim 1, wherein the first optical adjustment layer has a thickness of 0.5 to 5um and a refractive index of 1.6 to 1.7.
5. The thin film laminate structure of claim 2 wherein the metal particles have a particle size of
200nm-100nm。
6. The thin film stack structure of claim 1, wherein the second optical adjustment layer comprises a high refractive index layer and a low refractive index layer.
7. The thin film stack structure according to claim 6, wherein the high refractive index layer has a thickness of 2 to 200nm and a refractive index of 1.8 to 2.4; the low refractive index layer has a thickness of 10 to 500nm and a refractive index of 1.2 to 1.7.
8. The film stack structure of claim 1, wherein the film stack structure is formed by sequentially and adjacently stacking a substrate layer, a first optical adjustment layer, a second optical adjustment layer and a low-resistance conductive layer from bottom to top.
9. The thin film stack structure of claim 1, wherein the low resistance conductive layer has a resistance of 30 Ω/□ or less.
10. The thin film stack structure of claim 1, wherein the second optical adjustment layer is a single non-conductive metal layer with a thickness of 0.5-80 nm, and the material is one or more selected from Ti, In, Sn, InSn alloy or SiAl alloy.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010348904.9A CN111446027A (en) | 2020-04-28 | 2020-04-28 | Film laminated structure |
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| Application Number | Priority Date | Filing Date | Title |
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| CN202010348904.9A CN111446027A (en) | 2020-04-28 | 2020-04-28 | Film laminated structure |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116075418A (en) * | 2020-11-30 | 2023-05-05 | 迪睿合株式会社 | Optical laminate and article |
| CN116694245A (en) * | 2023-06-05 | 2023-09-05 | 佛山纳诺特科技有限公司 | Vehicle cover and preparation method and application thereof |
-
2020
- 2020-04-28 CN CN202010348904.9A patent/CN111446027A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116075418A (en) * | 2020-11-30 | 2023-05-05 | 迪睿合株式会社 | Optical laminate and article |
| CN116075418B (en) * | 2020-11-30 | 2024-03-12 | 迪睿合株式会社 | Optical laminate and article |
| CN116694245A (en) * | 2023-06-05 | 2023-09-05 | 佛山纳诺特科技有限公司 | Vehicle cover and preparation method and application thereof |
| CN116694245B (en) * | 2023-06-05 | 2023-12-15 | 佛山纳诺特科技有限公司 | Vehicle cover and preparation method and application thereof |
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