CN111407679B

CN111407679B - Moisturizing and repairing mask liquid

Info

Publication number: CN111407679B
Application number: CN201910249996.2A
Authority: CN
Inventors: 张帆; 苏湘豫; 阳如意; 熊一朴
Original assignee: Individual
Current assignee: Individual
Priority date: 2019-03-29
Filing date: 2019-03-29
Publication date: 2023-06-09
Anticipated expiration: 2039-03-29
Also published as: CN111407679A

Abstract

The invention discloses a moisturizing and repairing mask liquid which is composed of a plurality of active ingredients, mainly contains active ingredients such as nostoc sphaeroids kutz extract and cordyceps militaris extract, and is moderate in viscosity, excellent in moisturizing degree, non-sticky and greasy in skin feel, suitable for use, capable of improving skin microcirculation, constructing a skin water locking barrier, effectively supplementing and locking moisture, relieving skin dryness, repairing and maintaining skin and recovering elasticity.

Description

Moisturizing and repairing mask liquid

Technical Field

The invention belongs to the field of masks, and particularly relates to a moisturizing and repairing mask liquid.

Background

Facial mask liquid is one type of skin care product. The most basic and important purpose is to make up for the insufficient cleansing work of makeup removal and face washing, and other maintenance functions such as moisturizing, whitening, anti-aging, balancing grease and the like are realized by combining other essence components on the basis.

Nostoc sphaeroids kutz (Latin name: pogostemon auricularius (L.); academic name: nostoc sphaeroids kutz) is commonly known as Narcissus sphaeroids kutz, narcissus, auricularia, tian Muer. Nostoc, cyanobacteria, candida. Nostoc sphaeroids kutz has high nutritive value, the extract and the extraction method of nostoc sphaeroids kutz are researched in the prior art, nostoc sphaeroids kutz is applied to the field of facial masks, and the main application is moisture preservation, for example, patent application 201610865098.6 discloses a nostoc sphaeroids kutz cotton facial mask and a preparation method and application thereof. Patent application 2015170868. X discloses a whitening and moisturizing facial mask liquid containing nostoc sphaeroids kutz extract and a preparation method thereof.

Cordyceps militaris is a model species of Ascomycota, sarcophaga, clavipitaceae. The chemical name is Cordyceps militaris (l.ex Fr.) link. Cordyceps militaris, also called Cordyceps militaris, cordyceps militaris for short, is commonly called Cordyceps militaris, both of which are fungi of the same species, but have a large difference in nutritional ingredients. The traditional Chinese medicine considers that the traditional Chinese medicine can tonify lung yin and kidney yang, is mainly used for treating kidney deficiency, impotence, spermatorrhea, soreness of waist and knees, weakness after illness, weakness after chronic cough, cough with excessive phlegm blood, spontaneous perspiration, night sweat and the like, and is a traditional Chinese medicine capable of balancing and regulating yin and yang simultaneously. In the prior art, cordyceps militaris is applied to the mask, and the main effects are moisture preservation and wrinkle resistance. For example: 201610397952.0A Cordyceps militaris mud mask and its preparation method are provided, which are prepared from the following raw materials: 10-20wt% of cordyceps militaris mud, 6-1wt% of humectant, 0.5-1wt% of adhesion promoter, 3-10wt% of metal ion chelating agent and 0.05-0.08wt% of preservative. Patent application 201410681103.9 discloses a facial mask containing cordyceps militaris ingredients.

In the prior art, no product which simultaneously applies nostoc extract and cordyceps militaris extract to a mask exists.

Disclosure of Invention

Aiming at the defects of the prior art, the invention aims to develop a mask liquid product which has better moisturizing effect and repairing effect. Further research on the preparation process of the mask liquid and the extraction process of the raw materials ensures that the mask liquid has better usability, lower cost and better effect from the process angle.

In order to achieve the above purpose, the technical scheme of the invention is as follows:

a moisturizing and repairing mask liquid consists of a component A, a component B, a component C, a component D and a component E, wherein the components comprise the following components in parts by weight:

component A is 1.5 to 2.5 parts of hydrogenated polyisobutene, 1.0 to 2.0 parts of glycerol stearate, 1.0 to 2.0 parts of petrolatum, 0.3 to 0.8 parts of cetostearyl or cetyl alcohol, 0.3 to 0.8 parts of polydimethylsiloxane and 0.05 to 0.15 parts of tocopheryl acetate;

the component B comprises 70-80 parts of deionized water, 2-5 parts of glycerol, 2-4 parts of betaine, 2-4 parts of stearic acid, 1-4 parts of cordyceps militaris extract, 1.3-1.7 parts of nostoc sphaeroids kutz extract, 0.3-0.8 part of xanthan gum, 0.1-0.2 part of methyl paraben and 0.05-0.15 part of allantoin;

0.1-0.2 part of isopropyl palmitate as component C;

component D is 1-4 parts of oleum Trigonellae and 1-4 parts of Hamamelis mollis extract;

component E is deionized water 0.5-2 parts, bis (hydroxymethyl) imidazolidinyl urea 0.1-0.6 parts;

the preparation method of the mask liquid comprises the following steps:

step 1: adding the component A into an oil phase pot, heating to 85-95 ℃, and uniformly stirring;

step 2: adding the component B into a water phase pot, heating to 85-95 ℃, and uniformly stirring;

step 3: firstly pumping a part of the solution in the step 1 into an emulsifying pot at the temperature of 85-95 ℃, pumping the solution in the step 2 into the emulsifying pot, pumping the rest of the solution in the step 1 into the emulsifying pot, and emulsifying and homogenizing for 5-10min at the temperature of 85-95 ℃ and at the speed of 5000-6000 rpm;

step 4: homogenizing, cooling, adding component C when the temperature is reduced to 50-60deg.C, and homogenizing for 5-10min;

step 5: continuously cooling to 30-40 ℃, adding the component D and the component E, uniformly stirring, and cooling to room temperature.

In a preferred scheme, the nostoc sphaeroids kutz extract accounts for 1.3 to 1.7 percent of the mask liquid. More preferably, the nostoc sphaeroids kutz extract accounts for 1.5 percent of the mask liquid.

The nostoc sphaeroids kutz extract in the component B of the invention can be nostoc sphaeroids kutz extract prepared by the existing method, and the nostoc sphaeroids kutz extract is preferably prepared by the following extraction method:

1) Mixing fresh nostoc sphaeroids kutz with water according to a mass ratio of 1: (3-8) homogenizing, and then soaking in 15-25 times of 15% -25% ethanol for 20-30 hours to obtain a soaking solution;

2) Extracting the soaking solution in an extraction tank at 65-85 ℃ for 2-4h, and filtering to collect filtrate; homogenizing filter residues and 15% -25% ethanol according to the ratio of 1 (15-25), extracting in an extraction tank at 65-85deg.C for 2-4 hr, filtering, collecting filtrate, and repeating for 2-3 times;

3) Combining and concentrating the filtrate obtained in the step (2) to 1/(15-25) times of volume, precipitating with 70% -80% ethanol at 65-80 ℃ for 24-48h, centrifuging and collecting precipitate; fully dissolving the precipitate, filtering and collecting filtrate, precipitating with 70% -80% ethanol at 65-80deg.C for 24-48 hr, centrifuging and collecting precipitate, and repeating for 2-3 times;

4) Drying the precipitate until the water content is less than 5%, and obtaining nostoc sphaeroids kutz extract.

The cordyceps militaris extract in the component B can be prepared by extracting the cordyceps militaris extract by the existing method, and the cordyceps militaris extract is preferably prepared by the following method:

1) Pulverizing Cordyceps militaris, adding 8-15 times of ethanol with mass concentration of 15% -25% by volume, extracting in 90-100deg.C extraction tank for 2-4 hr, collecting extractive solution, repeating for 3-5 times, and mixing extractive solutions;

2) Concentrating the extractive solution in a concentrating tank to 1/(4-6) times volume, taking out, cooling to 15-25deg.C, adding ethanol until ethanol concentration is 25% -30%, precipitating with ethanol for 24-48 hr, centrifuging, and collecting supernatant; then adding ethanol until the ethanol concentration is 65-75%, precipitating with ethanol for 24-48h, centrifuging after precipitating with ethanol, and collecting precipitate;

3) And drying the precipitate until the moisture content is less than 5%, thus obtaining the cordyceps militaris extract.

Drawings

Fig. 1 is a flowchart of a preparation process of the mask liquid according to the embodiment.

Detailed Description

The invention is further illustrated and described below with reference to specific examples, wherein the percentages are by weight unless otherwise indicated.

Example 1

The formulation is shown in Table 1:

table 1 formulation of example 1

The witch hazel extract is a commercially available product from the company western An Si note biotechnology limited.

The nostoc sphaeroids kutz extract in the component B is prepared by the following extraction method:

1) Mixing fresh nostoc sphaeroids kutz with water according to a mass ratio of 1:5, homogenizing, and soaking in 20 times of 20% ethanol for 24 hours to obtain a soaking solution;

2) Extracting the soaking solution in an extraction tank at 75 ℃ for 2-4h, and filtering to collect filtrate; homogenizing the filter residue and 20% ethanol at a ratio of 1:20, extracting in an extraction tank at 75deg.C for 2-4 hr, filtering, collecting filtrate, and repeating for 2 times;

3) Combining and concentrating the filtrate obtained in the step (2) to 1/20 (one twentieth) of the volume, precipitating with 75% ethanol at 75 ℃ for 24 hours, and centrifugally collecting precipitate; dissolving the precipitate, filtering, collecting filtrate, precipitating with 75% ethanol at 75deg.C for 24 hr, centrifuging, collecting precipitate, and repeating for 2 times;

4) And combining and drying the precipitate until the water content is less than 5%, thus obtaining the nostoc sphaeroids kutz extract.

The cordyceps militaris extract in the component B is prepared by the following method:

1) Pulverizing Cordyceps militaris to 100 mesh, adding 10 times of ethanol with mass concentration of 20% and extracting in 100 deg.C extraction tank for 2 hr, collecting extractive solution, repeating for 3 times, and mixing extractive solutions;

2) Concentrating the extractive solution to 1/5 times volume in a concentrating tank, taking out, cooling to 15-25deg.C, adding ethanol until ethanol concentration is 30%, precipitating with ethanol for 24 hr, centrifuging, and collecting supernatant; then adding ethanol until the ethanol concentration is 70%, precipitating with ethanol for 30h, centrifuging after precipitating with ethanol, and collecting precipitate;

[ Art ]

The process control flow chart is shown in fig. 1, and specifically includes:

step 1: adding the component A into an oil phase pot, heating to 90 ℃, and uniformly stirring;

step 2: adding the component B into a water phase pot, heating to 90 ℃, and uniformly stirring;

step 3: pumping a part of the solution in the step 1 into an emulsifying pot at the temperature of about 90 ℃, pumping the solution in the step 2 into the emulsifying pot, pumping the rest of the solution in the step 1 into the emulsifying pot, and emulsifying and homogenizing for 10min at the temperature of 90 ℃ and at 6000 rpm;

step 4: homogenizing, cooling, adding phase C when the temperature is reduced to 50-60deg.C, and homogenizing for 5min;

The process control points are as in table 2:

TABLE 2 preparation Process control Point

Results: the mask liquid produced by the formula has moderate viscosity, excellent moistening degree and non-sticky skin feel (compared with transparent type mask liquid).

Example 2

The formulation is shown in Table 3:

table 3 formulation of example 2

1) Mixing fresh nostoc sphaeroids kutz with water according to a mass ratio of 1:6, homogenizing, and soaking in 22 times of 25% ethanol for 28 hours to obtain a soaking solution;

2) Extracting the soaking solution in an extraction tank at 70 ℃ for 4 hours, and filtering and collecting filtrate; homogenizing the filter residue and 25% ethanol at a ratio of 1:22, extracting in an extraction tank at 75deg.C for 4 hr, filtering, collecting filtrate, and repeating for 3 times;

3) Combining and concentrating the filtrate obtained in the step (2) to 1/18 (eighteenth) of the volume, precipitating with 80% ethanol at 70 ℃ for 36h, and centrifuging to collect precipitate; dissolving the precipitate, filtering, collecting filtrate, precipitating with 80% ethanol at 70deg.C for 48 hr, centrifuging, collecting precipitate, and repeating for 2 times;

1) Pulverizing Cordyceps militaris to 100 mesh, adding 12 times of ethanol with mass concentration of 25% and extracting at 90deg.C for 3 hr, collecting extractive solution, repeating for 4 times, and mixing extractive solutions;

2) Concentrating the extractive solution in a concentrating tank to 1/6 times volume, taking out, cooling to 20deg.C, adding ethanol, precipitating with ethanol until ethanol concentration is 35%, centrifuging, and collecting supernatant; then adding ethanol until the ethanol concentration is 75%, precipitating with ethanol for 30h, centrifuging after precipitating with ethanol, and collecting precipitate;

[ Art ]

The process control flow chart is shown in fig. 1, and specifically includes:

step 1: adding the component A into an oil phase pot, heating to 92 ℃, and uniformly stirring;

step 2: adding the component B into a water phase pot, heating to 92 ℃, and uniformly stirring;

step 3: firstly pumping a part of the solution in the step 1 into an emulsifying pot at the temperature of about 92 ℃, pumping the solution in the step 2 into the emulsifying pot, pumping the rest of the solution in the step 1 into the emulsifying pot, and emulsifying and homogenizing for 8min at the temperature of 92 ℃ and at 5000 rpm;

step 4: homogenizing, cooling, adding phase C when the temperature is reduced to 50-60deg.C, and homogenizing for 10min;

step 5: continuously cooling to 30 ℃, adding the component D and the component E, uniformly stirring, and cooling to room temperature.

As a result, the viscosity of the mask was moderate as in example 1.

Comparative example 1:

the formulation is shown in Table 4,

table 4 formulation of comparative example 1

[ Art ]

The preparation process is the same as in example 1.

Results: in the comparative example, the addition amount of nostoc sphaeroids kutz extract is too small, the liquid is too thin, the stability is poor, and the skin feel is not too moist.

Comparative example 2

The formulation is shown in table 5,

table 5 formulation of comparative example 2

[ Art ]

The preparation process is the same as in example 1.

Results: in the implementation, the nostoc sphaeroids kutz extract is excessively added, the formula is thick, and the nostoc sphaeroids kutz extract is not suitable for being used as mask liquid immersion liquid.

Comparative example 3

The formulation is shown in table 6,

table 6 formulation of comparative example 3

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Specific Process the same as in example 1

Results: the formula does not contain cordyceps militaris extract, 3% of the formula is nostoc sphaeroids kutz extract, and compared with the mask liquid prepared in the example 1, the mask liquid has thicker viscosity and slightly worse moistening degree.

Effect contrast:

1. moisturizing efficacy:

experiment skin surface of the same raw data under the same environment at the same time for comparison experiment, skin moisture values of different time periods were collected by a skin moisture meter, and the results are shown in the following table 7: the mask liquid for moisturizing and repairing mesona chinensis benth in the table is the mask liquid prepared in the embodiment 1 of the invention, the nostoc sphaeroids kutz moisturizing mask liquid is the mask liquid only containing nostoc sphaeroids kutz extract and not containing cordyceps militaris extract (other components and preparation processes are the same as those in the embodiment 1), the cordyceps sinensis moisturizing mask liquid is the moisturizing mask liquid only containing cordyceps militaris extract and not containing nostoc sphaeroids kutz extract (other components and preparation processes are the same as those in the embodiment 1), and a certain international brand moisturizing mask liquid is a commercially available existing product.

TABLE 7 product skin moisture detection data sheet

2 repairing efficacy:

1) The free radical scavenging ability of the mask liquid product of example 1 of the present invention was mainly measured.

The clearance rate of the mask liquid product of the embodiment 1 of the invention to DPPH is 46.7+/-8.4%; the inhibition rate of the mask liquid of the product to superoxide anions is 44.6+/-7.5%; the scavenging rate of the mask liquid of the product to the hydroxyl radical is 33.5 plus or minus 5.4 percent.

2) The skin elasticity change after 7 days, 15 days and 30 days of product use was supplemented (detected with skin elasticity tester). The skin elasticity is improved by 5+/-0.5% after the product is used for 7 days; the skin elasticity is improved by 7+/-0.5% after 15 days of using the product; the skin elasticity is improved by 10+/-0.5% after 30 days of using the product.

3. Conclusion: the mask liquid disclosed by the invention has good moisturizing and repairing effects, and the combination of the nostoc sphaeroids kutz extract and the cordyceps militaris extract improves the respective effects, so that the product has better moisturizing effect and skin repairing effect than a single component.

Claims

1. A moisturizing and repairing mask liquid consists of a component A, a component B, a component C, a component D and a component E, wherein the components comprise the following components in parts by weight:

0.1-0.2 part of isopropyl palmitate as component C;

the preparation method of the mask liquid comprises the following steps:

step 5: continuously cooling to 30-40 ℃, adding the component D and the component E, uniformly stirring, and cooling to room temperature;

4) Drying the precipitate until the water content is less than 5% to obtain nostoc sphaeroids kutz extract;

2. The moisturizing and repairing mask liquid according to claim 1, wherein the xanthan gum in the component B is mixed with deionized water after being uniformly mixed with glycerol and betaine.

3. The moisturizing repair mask liquid according to one of claims 1 or 2, wherein the nostoc sphaeroids kutz extract accounts for 1.3% to 1.7% of the mask liquid.

4. The moisturizing repair mask liquid according to claim 1 or 2, wherein the component a is 2 parts of hydrogenated polyisobutene, 1.5 parts of glycerol stearate, 1.50 parts of petrolatum, 0.5 parts of cetostearyl or cetyl alcohol, 0.5 parts of polydimethylsiloxane and 0.1 parts of tocopheryl acetate;

the component B comprises 74.15 parts of deionized water, 4 parts of glycerol, 3 parts of betaine, 3 parts of stearic acid, 2 parts of cordyceps militaris extract, 1.5 parts of nostoc sphaeroids kutz extract, 0.5 part of xanthan gum, 0.15 part of methyl benzoate and 0.1 part of allantoin;

component C is 0.15 part of isopropyl palmitate;

component D is 2.0 parts of oleum Trigonellae and 2.0 parts of Hamamelis mollis extract;

component E was 1.0 part deionized water, 0.35 part bis (hydroxymethyl) imidazolidinyl urea.