CN111333343B - Glass recovery bottle mark removing agent and preparation method thereof - Google Patents
Glass recovery bottle mark removing agent and preparation method thereof Download PDFInfo
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- CN111333343B CN111333343B CN202010238520.1A CN202010238520A CN111333343B CN 111333343 B CN111333343 B CN 111333343B CN 202010238520 A CN202010238520 A CN 202010238520A CN 111333343 B CN111333343 B CN 111333343B
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/30—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/72—Decorative coatings
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
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- Materials Engineering (AREA)
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Abstract
The invention discloses a trace removing agent for a glass recovery bottle and a preparation method thereof, belonging to the technical field of trace removing agents and being prepared from the following raw materials in percentage by weight: 4-6% of modified amino silicone oil, 2-4% of fatty alcohol-polyoxyethylene ether, 20-40% of cosolvent and the balance of water. The preparation method of the mark removing agent for the recycled beer glass bottles comprises the following steps: adding a cosolvent into water, uniformly stirring, then adding fatty alcohol-polyoxyethylene ether, and uniformly mixing to obtain a mixed solution 1; and adding the modified amino silicone oil into the mixed solution 1, and uniformly stirring to obtain the mark removing agent for the glass recovery bottle. The trace removing agent for the glass recovery bottle has the characteristics of stable performance, low cost, no color and no smell, good light transmittance, easiness in recovery and cleaning and the like, and is suitable for recovering and removing traces of glass bottles with various colors. Has wide market value and application prospect.
Description
Technical Field
The invention relates to the technical field of mark removing agents, in particular to a mark removing agent for a glass recovery bottle and a preparation method thereof.
Background
The glass bottle has the advantages of cleanness, sanitation, beauty, transparence, high chemical stability, air impermeability, easy sealing, unchanged property of the contained articles, multiple turnover use, rich raw materials, low price and the like, and becomes a packaging material widely used in the industries of food, medicine, chemistry and the like. The glass bottle can has various types, and can be classified into a recycled bottle and a non-recycled bottle according to the use condition.
At present, in the processes of recycling, transporting, loading and unloading bottles for multiple times and stacking in a bottle yard, the outer surfaces of the bottles are easy to wear, white scratches and galling on the surfaces are easy to cause by mutual collision and friction of the bottles, the image and the perception of consumers of the products are seriously influenced, and further the sales of the products is influenced. The repair and renovation by adopting the trace removing agent of the glass recovery bottle is an effective way to solve the problem.
The mark removing agent for the recovered glass bottle is a new product for repairing and renewing the scratches on the surface of the recovered glass bottle. The main principle is that the scratch part on the surface of the glass bottle is covered or filled with a mark removing agent, so that the refractive index of the scratch part is changed, and the appearance is beautified like a new bottle on the surface. The traditional mark removing agent for the recycled glass bottles comprises two types of aqueous products and oily products. The trace removing agent for the water-based recycled glass bottle is divided into two types of strong water-absorbing inorganic matters which are dissolved in water and oily substances which are emulsified into the water at high speed, and the trace removing agent prepared by dissolving the strong water-absorbing inorganic matters in the water has the defects of uneven distribution on the glass bottle due to too large surface energy, poor adhesive force of the water-based trace removing agent, easy abrasion and falling in the transportation, loading and unloading processes and poor trace removing effect; the mark removing agent prepared by emulsifying the oily substance into water at high speed has the defects of poor atomization effect, easy sagging and flowing, label pollution, product appearance damage and influence on sensory effect in the application process, and the mark removing agent is unstable, is easy to layer after a long time and influences use. Although the oily mark removing agent has good stability and is easy to atomize, the oily mark removing agent is not easy to dissolve in water, and brings many problems to production enterprises when a recovery bottle is cleaned, the oily mark removing agent cannot be reused seriously, the bottle washing cost is increased slightly, and unnecessary waste is caused.
Disclosure of Invention
The invention provides a mark removing agent for a glass recovery bottle and a preparation method thereof, which solve the technical problems of uneven distribution, poor mark removing effect, poor atomization, label pollution, instability, difficulty in recycling of glass bottles and the like of the conventional mark removing agent.
In order to solve the technical problems, the technical scheme of the invention is as follows:
the trace removing agent for the glass recovery bottle is characterized by being prepared from the following raw materials in percentage by weight: 4-6% of modified amino silicone oil, 2-4% of fatty alcohol-polyoxyethylene ether, 20-40% of cosolvent and the balance of water.
Wherein, preferably, the modified amino silicone oil is prepared by the following preparation method:
(1) amino silicone oil modification: adding 10-20 parts by weight of carboxymethyl cellulose aqueous solution into a reaction kettle, mixing and stirring for 1-2 hours, adding 4-6 parts by weight of amino silicone oil, stirring and reacting for 2-4 hours to fully react; filtering with a 100-mesh filter screen, and drying at 110-115 ℃ to obtain modified amino silicone oil;
(2) emulsification: taking 100 parts by weight of modified amino silicone oil, adding 20-30 parts by weight of tridecyl alcohol polyether, and uniformly mixing to obtain an oil phase: adding 8-12 parts by weight of propylene glycol and 3-5 parts by weight of glacial acetic acid into 400 parts by weight of water, and uniformly mixing to obtain a water phase; and adding the oil phase into the water phase for multiple times, starting a blade type stirrer during the addition process, stirring for 40-60min continuously after the addition is finished, standing to be transparent, and filtering by using a 100-mesh filter screen to obtain the modified amino silicone oil.
The mass percentage concentration of the carboxymethyl cellulose aqueous solution is 25-40%.
In the emulsification process of the step (2), the temperature is controlled to be 65-68 ℃.
The fatty alcohol-polyoxyethylene ether is AEO-03, AEO-07 or AEO-11.
The cosolvent is any one of polyvinylpyrrolidone, alkyl glycoside, diethylene glycol and diethylene glycol ethyl ether.
A preparation method of a mark removing agent for a glass recovery bottle comprises the following steps:
(1) adding a cosolvent into water, starting stirring, starting a heating device, keeping the temperature at 65 +/-3 ℃, uniformly stirring, adding fatty alcohol-polyoxyethylene ether, and continuously stirring for 30min to obtain a mixed solution 1;
(2) adding the modified amino silicone oil into the mixed solution 1, stirring for 40-60 minutes, and filtering by using a 100-mesh filter screen to obtain the trace removing agent for the glass recovery bottle.
The invention has the beneficial effects that:
according to the invention, carboxymethyl cellulose is adopted to carry out surface modification on amino silicone oil, and as the carboxymethyl cellulose has adhesiveness and dispersibility, the carboxymethyl cellulose can be adsorbed to the surface of mixture particles, and a plurality of hydrophilic hydroxyl groups face outwards, a network structure with steric hindrance effect is formed on the surface of the particles, and the carboxymethyl cellulose and the amino silicone oil are subjected to modification reaction, and can be grafted and compounded, so that the adhesive strength of the mark removing agent and the glass surface is improved, and the problem that the existing aqueous mark removing agent is easy to wear and fall off is solved.
In addition, the modified amino silicone oil is emulsified by tridecyl alcohol polyether, propylene glycol and glacial acetic acid to obtain amino silicone oil microemulsion, the microemulsion further improves the water solubility of the amino silicone oil and the water solubility stability of the amino silicone oil, and the cosolvent is added to further improve the stability of the amino silicone oil.
Furthermore, the content of the emulsified and modified amino silicone oil is only 4-6%, the content is low, but the content can meet the requirement of filling scratches of glass bottles, the effects of changing the refractive index and removing the scratches can be achieved, and the cost is reduced.
Furthermore, the fatty alcohol-polyoxyethylene ether is added in the invention, so that the surface energy of the solution is further reduced, the solution is easier to atomize in the application process, and the trace removing agent is more uniformly distributed on the glass bottle.
In the production process, the solution in each step is strictly controlled to be filtered by a 100-mesh filter screen, so that the equipment is not blocked in the application process.
The raw materials used in the invention are all food grade, and the prepared product is colorless and tasteless, can be applied to recycled glass bottles with various colors, and does not generate negative influence.
The trace removing agent for the glass recovery bottle has the characteristics of stable performance, low cost, no color and no smell, good light transmittance, easiness in recovery and cleaning and the like, and is suitable for recovering and removing traces of glass bottles with various colors. Has wide market value and application prospect.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be obtained by a person skilled in the art without making any creative effort based on the embodiments in the present invention, belong to the protection scope of the present invention.
Example 1
The embodiment provides a trace removing agent for a glass recovery bottle, which is prepared from the following raw materials in percentage by weight: 5% of modified amino silicone oil, AEO-033%, 30% of diethylene glycol and the balance of water.
The modified amino silicone oil is prepared by the following preparation method:
(1) amino silicone oil modification: adding 15 parts by weight of 30 percent carboxymethyl cellulose aqueous solution, mixing and stirring for 1.5h, adding 5 parts by weight of amino silicone oil, stirring and reacting for 3h, filtering by a 100-mesh filter screen, and drying at 110-115 ℃ to obtain modified amino silicone oil;
(2) emulsification: taking 100 parts by weight of modified amino silicone oil, adding 25 parts by weight of tridecyl polyether, and uniformly mixing to obtain an oil phase: adding 10 parts by weight of propylene glycol and 4 parts by weight of glacial acetic acid into 350 parts by weight of water, and uniformly mixing to obtain a water phase; adding the oil phase into the water phase for several times, starting a blade type stirrer during the adding process, stirring, controlling the temperature at 65-68 ℃, continuing stirring for 50min after the adding is finished, standing to be transparent, and filtering by a 100-mesh filter screen to obtain the modified amino silicone oil.
The preparation method of the trace removing agent for the glass recovery bottle comprises the following steps:
(1) adding 30 parts of diethylene glycol into 62 parts of water, uniformly stirring, then adding 3 parts of AEO-03, and uniformly mixing to obtain a mixed solution 1;
(2) and adding 5 parts of modified amino silicone oil into the mixed solution 1, stirring for 40-60 minutes, and filtering by using a 100-mesh filter screen to obtain the trace removing agent for the glass recovery bottle.
Example 2
The embodiment provides a trace removing agent for a glass recovery bottle, which is prepared from the following raw materials in percentage by weight: 6% of modified amino silicone oil, AEO-034%, 20% of diethylene glycol ethyl ether and the balance of water.
The modified amino silicone oil is prepared by the following preparation method:
(1) amino silicone oil modification: adding 10 parts by weight of 40% carboxymethyl cellulose aqueous solution, mixing and stirring for 1h, adding 6 parts by weight of amino silicone oil, stirring and reacting for 2h to fully react; filtering with a 100-mesh filter screen, and drying at 110-115 ℃ to obtain modified amino silicone oil;
(2) emulsification: taking 100 parts by weight of modified amino silicone oil, adding 30 parts by weight of tridecyl alcohol polyether, and uniformly mixing to obtain an oil phase: adding 8 parts by weight of propylene glycol and 5 parts by weight of glacial acetic acid into 300 parts by weight of water, and uniformly mixing to obtain a water phase; adding the oil phase into the water phase for several times, starting a blade type stirrer during the adding process, stirring, controlling the temperature at 65-68 ℃, continuing stirring for 60min after the adding is finished, standing to be transparent, and filtering by a 100-mesh filter screen to obtain the modified amino silicone oil.
The preparation method of the trace removing agent for the glass recovery bottle comprises the following steps:
(1) adding 20 parts of diethylene glycol ethyl ether into 70 parts of water, uniformly stirring, then adding 4 parts of AEO-03, and uniformly mixing to obtain a mixed solution 1;
(2) and adding 6 parts of modified amino silicone oil into the mixed solution 1, stirring for 40-60 minutes, and filtering by using a 100-mesh filter screen to obtain the trace removing agent for the glass recovery bottle.
Example 3
The embodiment provides a trace removing agent for a glass recovery bottle, which is prepared from the following raw materials in percentage by weight: 5% of modified amino silicone oil, AEO-072%, 25% of alkyl glycoside and the balance of water.
The modified amino silicone oil is prepared by the following preparation method:
(1) amino silicone oil modification: adding 20 parts by weight of 25% carboxymethyl cellulose aqueous solution, mixing and stirring for 2 hours, adding 4 parts by weight of amino silicone oil, stirring and reacting for 4 hours to fully react; filtering with a 100-mesh filter screen, and drying at 110-115 ℃ to obtain modified amino silicone oil;
(2) emulsification: taking 100 parts by weight of modified amino silicone oil, adding 20 parts by weight of tridecyl polyether, and uniformly mixing to obtain an oil phase: adding 12 parts by weight of propylene glycol and 3 parts by weight of glacial acetic acid into 00 parts by weight of water, and uniformly mixing to obtain a water phase; adding the oil phase into the water phase for several times, starting a blade type stirrer for stirring during the addition process, controlling the temperature at 65-68 ℃, continuing stirring for 60min after the addition is finished, standing to be transparent, and filtering by a 100-mesh filter screen to obtain the modified amino silicone oil.
The preparation method of the mark removing agent for the glass recovery bottle comprises the following steps:
(1) adding 25 parts of alkyl glycoside into 68 parts of water, uniformly stirring, then adding 2 parts of AEO-07, and uniformly mixing to obtain a mixed solution 1;
(2) and (3) adding 5 parts of modified amino silicone oil into the mixed solution 1, stirring for 40 minutes, and filtering by using a 100-mesh filter screen to obtain the trace removing agent for the glass recovery bottle.
Example 4
The embodiment provides a trace removing agent for a glass recovery bottle, which is prepared from the following raw materials in percentage by weight: 6% of modified amino silicone oil, AEO-073%, 20% of polyvinylpyrrolidone and the balance of water.
The modified amino silicone oil is prepared by the following preparation method:
(1) amino silicone oil modification: adding 12 parts by weight of 35% carboxymethyl cellulose aqueous solution, mixing and stirring for 2 hours, adding 5 parts by weight of amino silicone oil, stirring and reacting for 4 hours to fully react; filtering with a 100-mesh filter screen, and drying at 110-115 ℃ to obtain modified amino silicone oil;
(2) emulsification: taking 100 parts by weight of modified amino silicone oil, adding 22 parts by weight of tridecyl polyether, and uniformly mixing to obtain an oil phase: adding 11 parts by weight of propylene glycol and 3.5 parts by weight of glacial acetic acid into 320 parts by weight of water, and uniformly mixing to obtain a water phase; adding the oil phase into the water phase for several times, starting a blade type stirrer during the adding process, stirring, controlling the temperature at 65-68 ℃, continuing stirring for 40-60min after the adding is finished, standing to be transparent, and filtering by a 100-mesh filter screen to obtain the modified amino silicone oil.
The preparation method of the mark removing agent for the glass recovery bottle comprises the following steps:
(1) adding 20 parts of polyvinylpyrrolidone into 71 parts of water, uniformly stirring, then adding 3 parts of AEO-07, and uniformly mixing to obtain a mixed solution 1;
(2) and adding 6 parts of modified amino silicone oil into the mixed solution 1, stirring for 60 minutes, and filtering by using a 100-mesh filter screen to obtain the trace removing agent for the glass recovery bottle.
Example 5
The embodiment provides a trace removing agent for a glass recovery bottle, which is prepared from the following raw materials in percentage by weight: 5% of modified amino silicone oil, AEO-113%, 35% of diethylene glycol and the balance of water.
The modified amino silicone oil is prepared by the following preparation method:
(1) amino silicone oil modification: adding 18 parts by weight of 28% carboxymethyl cellulose aqueous solution, mixing and stirring for 2 hours, adding 5 parts by weight of amino silicone oil, stirring and reacting for 3 hours to fully react; filtering with a 100-mesh filter screen, and drying at 110-115 ℃ to obtain modified amino silicone oil;
(2) emulsification: taking 100 parts by weight of modified amino silicone oil, adding 28 parts by weight of tridecyl alcohol polyether, and uniformly mixing to obtain an oil phase: adding 9 parts by weight of propylene glycol and 4 parts by weight of glacial acetic acid into 350 parts by weight of water, and uniformly mixing to obtain a water phase; adding the oil phase into the water phase for several times, starting a blade type stirrer during the adding process, stirring, controlling the temperature at 65-68 ℃, continuing stirring for 60min after the adding is finished, standing to be transparent, and filtering by a 100-mesh filter screen to obtain the modified amino silicone oil.
The preparation method of the mark removing agent for the glass recovery bottle comprises the following steps:
(1) adding 57 parts of diethylene glycol into 35 parts of water, uniformly stirring, adding 3 parts of AEO-11, and uniformly mixing to obtain a mixed solution 1;
(2) and adding 5 parts of modified amino silicone oil into the mixed solution 1, stirring for 50 minutes, and filtering by using a 100-mesh filter screen to obtain the trace removing agent for the glass recovery bottle.
The physical and chemical indexes of the stain remover for the recovered glass bottles prepared in examples 1 to 5 are as follows:
tests prove that the mark removing agent for the glass recovery bottle prepared by the embodiment has no layering phenomenon within 30 days, the appearance of the recovery bottle treated by the product can basically achieve the effect of a new bottle, and the recovery bottle is smooth and transparent, is free from dust adhesion, is free from greasy feeling and has no phenomenon of falling off of the mark removing agent.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that fall within the spirit and principle of the present invention are intended to be included therein.
Claims (6)
1. The trace removing agent for the glass recovery bottle is characterized by being prepared from the following raw materials in percentage by weight: 4-6% of modified amino silicone oil, 2-4% of fatty alcohol-polyoxyethylene ether, 20-40% of cosolvent and the balance of water; the modified amino silicone oil is prepared by the following preparation method:
(1) amino silicone oil modification: adding 10-20 parts by weight of carboxymethyl cellulose aqueous solution into a reaction kettle, mixing and stirring for 1-2h, adding 4-6 parts by weight of amino silicone oil, stirring and reacting for 2-4h to fully react; filtering with a 100-mesh filter screen, and drying at 110-115 ℃ to obtain the modified amino silicone oil
(2) Emulsification: taking 100 parts by weight of modified amino silicone oil, adding 20-30 parts by weight of tridecyl alcohol polyether, and uniformly mixing to obtain an oil phase: adding 8-12 parts by weight of propylene glycol and 3-5 parts by weight of glacial acetic acid into 400 parts by weight of water, and uniformly mixing to obtain a water phase; and adding the oil phase into the water phase for multiple times, starting a blade type stirrer during the addition process, stirring for 40-60min continuously after the addition is finished, standing to be transparent, and filtering by using a 100-mesh filter screen to obtain the modified amino silicone oil.
2. The traceback agent for the glass recycle bottle according to claim 1, wherein the traceback agent comprises: the mass percentage concentration of the carboxymethyl cellulose aqueous solution is 25-40%.
3. The traceback agent for the glass recycling bottle according to claim 1, wherein the traceback agent comprises the following components in percentage by weight: and (3) controlling the temperature to be 65-68 ℃ in the emulsification process of the step (2).
4. The traceback agent for the glass recycling bottle according to claim 1, wherein the traceback agent comprises the following components in percentage by weight: the fatty alcohol-polyoxyethylene ether is AEO-03, AEO-07 or AEO-11.
5. The traceback agent for the glass recycle bottle according to claim 1, wherein the traceback agent comprises: the cosolvent is any one of polyvinylpyrrolidone, alkyl glycoside, diethylene glycol and diethylene glycol ethyl ether.
6. A method for preparing a traceback agent for a glass recycle bottle according to any one of claims 1 to 5, which is characterized by comprising the following steps:
(1) adding a cosolvent into water, starting stirring, starting a heating device, keeping the temperature at 65 +/-3 ℃, uniformly stirring, adding fatty alcohol-polyoxyethylene ether, and continuously stirring for 30min to obtain a mixed solution 1;
(2) and adding the modified amino silicone oil into the mixed solution 1, stirring for 40-60 minutes, and filtering by using a 100-mesh filter screen to obtain the mark removing agent for the glass recovery bottle.
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Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2941105A1 (en) * | 1978-10-14 | 1980-04-24 | Kirin Brewery | Covering scratches in glass objects esp. bottles - with a compsn. comprising polysiloxane, hardening catalyst and surfactant |
| US4741773A (en) * | 1984-11-12 | 1988-05-03 | Mitsubishi Chemical Industries Limited | Water repellent composition |
| JP2005350313A (en) * | 2004-06-11 | 2005-12-22 | Daito Paint Kk | Method of masking scratch on bottle |
| JP2005350312A (en) * | 2004-06-11 | 2005-12-22 | Daito Paint Kk | Masking liquid for scratch on bottle |
| CN1774346A (en) * | 2003-02-17 | 2006-05-17 | 精工爱普生株式会社 | Liquid composition |
| CN102372444A (en) * | 2011-07-29 | 2012-03-14 | 广州泰成生化科技有限公司 | Recycled beer glass bottle enamel |
| CN102781865A (en) * | 2009-12-14 | 2012-11-14 | 阿肯马弗利辛恩公司 | Process for scratch masking of glass containers |
| CN108300599A (en) * | 2018-03-05 | 2018-07-20 | 河南绿澳化工科技有限公司 | A kind of environment protection multifunctional vial cleaning agent and its preparation method |
| JP6462364B2 (en) * | 2015-01-10 | 2019-01-30 | 京セラ株式会社 | THROW-AWAY TYPE DRILL AND METHOD FOR MANUFACTURING CUTTING PRODUCT USING THE SAME |
| CN109678356A (en) * | 2019-01-11 | 2019-04-26 | 湖北新四海化工股份有限公司 | A kind of high light transmission glass hydrophobing agent and preparation method thereof |
| CN110105804A (en) * | 2018-05-08 | 2019-08-09 | 致达应材股份有限公司 | A kind of coating with self-cleaning and anti-reflective, preparation method and substrate |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5556040A (en) * | 1978-10-14 | 1980-04-24 | Kirin Brewery Co Ltd | Glass container scratch cover |
| JPS6026057B2 (en) * | 1981-04-27 | 1985-06-21 | アサヒビール株式会社 | How to shield glass containers from scratches |
| JP2652169B2 (en) * | 1987-09-01 | 1997-09-10 | 大三工業株式会社 | Scratching agent for glass containers |
| JPH0610094B2 (en) * | 1989-06-14 | 1994-02-09 | 信越化学工業株式会社 | Scratch-shielding agent for glass containers |
| JPH0776115B2 (en) * | 1989-06-15 | 1995-08-16 | アサヒビール株式会社 | Scratch-shielding agent for glass bottles |
| JPH1192178A (en) * | 1997-09-22 | 1999-04-06 | Toyo Ink Mfg Co Ltd | Scratch hiding agent for glass vessel and method for hiding scratch on glass vessel |
| JP3847544B2 (en) * | 2000-09-13 | 2006-11-22 | ジーイー東芝シリコーン株式会社 | Emulsion composition for coating glass container and glass container coated with the emulsion composition |
| EP1794098B1 (en) * | 2004-08-25 | 2011-09-21 | Ecolab Inc. | Coating product for masking scuffings on glass or plastic surfaces |
| JP6244691B2 (en) * | 2013-05-29 | 2017-12-13 | セメダイン株式会社 | Glass scratched surface coating composition, glass with a glass scratched surface coated with the composition, and glass scratched surface coating method using the composition |
| CN109022167A (en) * | 2018-07-02 | 2018-12-18 | 河南绿澳化工科技有限公司 | A kind of vial compound alkaline cleaner and preparation method thereof |
| CN109504554A (en) * | 2019-01-03 | 2019-03-22 | 深圳市天正隆科技有限公司 | A kind of glass cleaner and preparation method thereof |
-
2020
- 2020-03-30 CN CN202010238520.1A patent/CN111333343B/en active Active
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2941105A1 (en) * | 1978-10-14 | 1980-04-24 | Kirin Brewery | Covering scratches in glass objects esp. bottles - with a compsn. comprising polysiloxane, hardening catalyst and surfactant |
| US4741773A (en) * | 1984-11-12 | 1988-05-03 | Mitsubishi Chemical Industries Limited | Water repellent composition |
| CN1774346A (en) * | 2003-02-17 | 2006-05-17 | 精工爱普生株式会社 | Liquid composition |
| JP2005350313A (en) * | 2004-06-11 | 2005-12-22 | Daito Paint Kk | Method of masking scratch on bottle |
| JP2005350312A (en) * | 2004-06-11 | 2005-12-22 | Daito Paint Kk | Masking liquid for scratch on bottle |
| CN102781865A (en) * | 2009-12-14 | 2012-11-14 | 阿肯马弗利辛恩公司 | Process for scratch masking of glass containers |
| CN102372444A (en) * | 2011-07-29 | 2012-03-14 | 广州泰成生化科技有限公司 | Recycled beer glass bottle enamel |
| JP6462364B2 (en) * | 2015-01-10 | 2019-01-30 | 京セラ株式会社 | THROW-AWAY TYPE DRILL AND METHOD FOR MANUFACTURING CUTTING PRODUCT USING THE SAME |
| CN108300599A (en) * | 2018-03-05 | 2018-07-20 | 河南绿澳化工科技有限公司 | A kind of environment protection multifunctional vial cleaning agent and its preparation method |
| CN110105804A (en) * | 2018-05-08 | 2019-08-09 | 致达应材股份有限公司 | A kind of coating with self-cleaning and anti-reflective, preparation method and substrate |
| CN109678356A (en) * | 2019-01-11 | 2019-04-26 | 湖北新四海化工股份有限公司 | A kind of high light transmission glass hydrophobing agent and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| "2013 年国外有机硅进展";周勤等;《技术进展》;20140725;第28卷(第4期);第299-318页 * |
| "在线和离线自洁玻璃工艺及硅油对亲水性能的影响";辛崇飞;《中国玻璃》;20080831(第4期);第14-17页 * |
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