JP2652169B2 - Scratching agent for glass containers - Google Patents
Scratching agent for glass containersInfo
- Publication number
- JP2652169B2 JP2652169B2 JP62216299A JP21629987A JP2652169B2 JP 2652169 B2 JP2652169 B2 JP 2652169B2 JP 62216299 A JP62216299 A JP 62216299A JP 21629987 A JP21629987 A JP 21629987A JP 2652169 B2 JP2652169 B2 JP 2652169B2
- Authority
- JP
- Japan
- Prior art keywords
- acid
- group
- polysiloxane
- component
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D23/00—Details of bottles or jars not otherwise provided for
- B65D23/08—Coverings or external coatings
- B65D23/0807—Coatings
- B65D23/0814—Coatings characterised by the composition of the material
- B65D23/0821—Coatings characterised by the composition of the material consisting mainly of polymeric materials
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Details Of Rigid Or Semi-Rigid Containers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Surface Treatment Of Glass (AREA)
- Paints Or Removers (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は果汁飲料びん，清涼飲料びん，ビールびん等
のガラス容器のかすれ傷塗布剤に係り、特に塗膜の乾燥
性が良好で、かつすべり、べとつききがないガラス容器
のかすれ傷塗布剤に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a coating agent for frost on glass containers such as fruit juice beverage bottles, soft drink bottles, beer bottles, etc. The present invention relates to a coating agent for scratches on glass containers without slippage or stickiness.
果汁飲料びん，清涼飲料びん，ビールびん等のガラス
容器は使用後回収され、繰り返し使用されているのが現
状であるが、そのうちにびん詰め工程や流通過程等にお
いて、ガラス容器の表面にかすれ傷が生じ、外観が損な
われて商品価値が低下してくる。At present, glass containers such as fruit juice beverage bottles, soft drink bottles, and beer bottles are collected after use and are repeatedly used, but during the bottling process and distribution process, the glass container surface is scratched. Is caused, the appearance is impaired, and the commercial value is reduced.
このため、近年では各種塗布剤をガラス容器表面に塗
布することによって前記かすれ傷の遮蔽を行い、ガラス
容器の美観を保護している。For this reason, in recent years, the aforementioned scratches are shielded by applying various coating agents to the surface of the glass container, thereby protecting the aesthetic appearance of the glass container.
この種の塗布剤として、従来、流動パラフィンあるい
はシリコーン油を主成分とする乳化液ないしは水分散液
が知られている。Conventionally, as this type of coating agent, an emulsion or an aqueous dispersion containing liquid paraffin or silicone oil as a main component has been known.
しかし、これらは結露により塗膜が流されて遮蔽性が
劣るばかりでなく、塗布後べとつきやすべりがあり、こ
のため触感性が悪くかつ容器が手からすべり落ちる危険
性もあり、また、ほこりが付着し易く、さらに、冷水中
あるいはショーケース中で塗膜が剥離してしまって耐水
性が悪いばかりでなく、その剥離物の油が水面に浮き上
がったり、あるいは洗びん工程でその油が容器内部に再
付着して中味に悪影響を与える危険性もある。However, these are not only inferior in the shielding property due to the coating being washed away due to condensation, but also sticky and slippery after application, so that the tactile sensation is poor and there is a risk that the container may slip off from the hand, and that dust is also removed. Not only is it easy to adhere, and the coating film peels off in cold water or in a showcase, causing not only poor water resistance, but also the oil of the peeled material floating on the water surface, or the oil inside the container during the bottle washing process. There is also a danger that the contents may be adversely affected by redepositing on the surface.
これらの問題点を解決する塗布剤として、フェニル基
を含むオルガノポリシロキサンの硬化生成物が知られて
いる（特開昭55−56040号公報）。この種の塗布剤は空
の容器に塗布する場合や、室温以上の中味を詰める際の
塗布の場合には前述の各種欠点を改良して良好に用いら
れるが、室温以下の温度の中味を詰めた後に塗布する場
合には、容器表面には温度差により結露が発生するた
め、この結露により塗膜が剥離され、流されて遮蔽効果
が失われてしまう。As a coating agent which solves these problems, a cured product of an organopolysiloxane containing a phenyl group is known (JP-A-55-56040). This kind of coating agent can be used well by improving the above-mentioned drawbacks when it is applied to an empty container or when filling the contents above room temperature. In the case of application after the application, dew condensation occurs on the surface of the container due to a temperature difference, and the dew condensation causes the coating film to be peeled off and washed away, thereby losing the shielding effect.
さらにまた、この種の塗布剤は通常の洗びん工程では
塗膜の除去が必ずしも充分ではないという欠点をも有し
ている。Furthermore, this type of coating agent has the disadvantage that the coating film is not always sufficiently removed in the ordinary bottle washing step.
そこで本出願人は前述の公知技術に存する各種欠点を
改良し、べとつきやすべりがなく、ほこりも付着せず、
耐水性が良好であって水に浸漬した時に油が浮かぶよう
なことがなく、このため中味の品質に悪影響を与えず、
さらに容器中に室温以下の温度の中味を詰めた後に塗布
する際にも結露によって膜が流されるようなことがな
く、したがって遮蔽性良好であり、かつ洗びん工程で塗
膜が容易に除去されるガラス容器のかすれ傷塗布剤を先
願として出願している。（特願昭61−107141号）。Therefore, the present applicant has improved the various disadvantages of the above-mentioned known technology, has no stickiness or slip, does not adhere dust,
It has good water resistance and oil does not float when immersed in water, so it does not adversely affect the quality of the contents,
Furthermore, the film is not washed away due to dew condensation even when applying after filling the contents of the room temperature or lower in the container, so the shielding property is good, and the coating film is easily removed in the bottle washing process. Has filed a filing application for a flawless glass container. (Japanese Patent Application No. 61-107141).
本発明の目的は前述の先願にかかる発明の改良であっ
て、前記先願発明の利点に加えてさらに塗膜の乾燥性が
良好で、かつすべり、べとつきが改良された新規なガラ
ス容器のかすれ傷塗布剤を提供することにある。An object of the present invention is to improve the invention according to the above-mentioned prior application. In addition to the advantages of the above-mentioned prior application, a novel glass container having good drying properties of a coating film and improved slippage and tackiness is provided. An object of the present invention is to provide a scuff coating.
前述の目的を達成するため、本発明の塗布剤によれ
ば、次の成分（Ａ）、（Ｂ）および（Ｃ）の群から選択
された二種または二種以上の配合物を含むガラス容器の
かすれ傷塗布剤において、前記配合物にさらに次の成分
（Ｄ）を、前記配合物100重量部に対して２〜10重量部
配合することを特徴とする。In order to achieve the above object, according to the coating agent of the present invention, a glass container containing two or more compounds selected from the group consisting of the following components (A), (B) and (C) A non-abrasive coating composition is characterized in that the following component (D) is further added to the above-mentioned composition in an amount of 2 to 10 parts by weight based on 100 parts by weight of the above-mentioned composition.
（Ａ）一般式 RSi（OR′）ｎの重合物。(A) A polymer of the general formula RSi (OR ') n.
（Ｂ）一般式 Si（OR′）４の重合物。(B) A polymer of the general formula Si (OR ') 4 .
（Ｃ）前記（Ａ）、（Ｂ）の一般式で示される化合物の
反応によって生じる反応生成物。(C) Reaction products generated by the reaction of the compounds represented by the general formulas (A) and (B).
（Ｄ）イソラウリン酸，イソミリスチン酸，イソパルミ
チン酸，イソステアリン酸およびイソアラキン酸からな
る物質の群から選択された１種または１種以上。(D) one or more selected from the group of substances consisting of isolauric acid, isomyristic acid, isopalmitic acid, isostearic acid and isoarachinic acid.
ただし、前記（Ａ）および（Ｂ）の式において、Ｒは
メチル、エチル、ジメチル、メチルエチル基であり、
Ｒ′はC1乃至C4のアルキル基であり、ｎは２乃至３の整
数である。However, in the above formulas (A) and (B), R is a methyl, ethyl, dimethyl, methylethyl group,
R 'is an alkyl group of C 1 to C 4, n is an integer of 2 to 3.
以下、本発明を具体的に詳述する。 Hereinafter, the present invention will be described in detail.
前述の一般式RSi（OR′）ｎは具体的にはメチルトリ
メトキシシラン，メチルトリエトキシシラン，メチルト
リプロポキシシラン，メチルトリブトキシシラン，エチ
ルトリメトキシシラン，エチルトリエトキシシラン，エ
チルトリプロポキシシラン，エチルトリブトキシシラ
ン，ジメチルジメトキシシラン，ジメチルジエトキシシ
ラン，ジメチルジプロポキシシラン，ジメチルジブトキ
シシラン，メチルエチルジメトキシシラン，メチルエチ
ルジエトキシシラン，メチルエチルジプロポキシシラ
ン，メチルエチルジブトキシシラン，メチルトリイソプ
ロポキシシラン，メチルトリイソブトキシシラン，エチ
ルトリイソプロポキシシラン，エチルトリイソブトキシ
シラン，ジメチルジイソプロポキシシラン，ジメチルジ
イソブトキシシラン，メチルエチルイソプロポキシシラ
ン，メチルエチルイソブトキシシラン等であり、これら
化合物は0.1乃至0.01Nの塩酸，硫酸，スルフォン酸，ク
ロロ酢酸等、希酸の存在下で容易に重合して本発明にか
かる成分（Ａ）を生成する。これら成分（Ａ）は具体的
にはアルコキシ基含有のアルキルポリシロキサンであっ
て、例えば、メトキシ基含有のメチルポリシロキサン，
エチルポリシロキサン，ジメチルポリシロキサン，メチ
ルエチルポリシロキサン，エトキシ基含有のメチルポリ
シロキサン，エチルポリシロキサン，ジメチルポリシロ
キサン，メチルエチルポリシロキサン，プロポキシ含有
のメチルポリシロキサン，エチルポリシロキサン，ジメ
チルポリシロキサン，メチルエチルポリシロキサン，ブ
トキシ基含有のメチルポリシロキサン，エチルポリシロ
キサン，ジメチルポリジロキサン，メチルエチルシロキ
サン，イソプロポキシ基含有のメチルポリシロキサン，
エチルポリシロキサン，ジメチルポリシロキサン，メチ
ルエチルポリシロキサン，イソブトキシ基含有のメチル
ポリシロキサン，エチルポリシロキサン，ジメチルポリ
シロキサン，メチルエチルポリシロキサン等である。The aforementioned general formula RSi (OR ') n is specifically methyltrimethoxysilane, methyltriethoxysilane, methyltripropoxysilane, methyltributoxysilane, ethyltrimethoxysilane, ethyltriethoxysilane, ethyltripropoxysilane, Ethyl tributoxy silane, dimethyl dimethoxy silane, dimethyl diethoxy silane, dimethyl dipropoxy silane, dimethyl dibutoxy silane, methyl ethyl dimethoxy silane, methyl ethyl diethoxy silane, methyl ethyl dipropoxy silane, methyl ethyl dibutoxy silane, methyl triiso Propoxysilane, methyltriisobutoxysilane, ethyltriisopropoxysilane, ethyltriisobutoxysilane, dimethyldiisopropoxysilane, dimethyldiisobutoxysilane, methyl Ethyl isopropoxy silane, methyl ethyl isobutoxy silane, etc. These compounds are easily polymerized in the presence of a dilute acid such as 0.1 to 0.01 N hydrochloric acid, sulfuric acid, sulfonic acid, chloroacetic acid, etc. to form the component according to the present invention ( A) is generated. The component (A) is specifically an alkoxy-containing alkylpolysiloxane, for example, a methoxy-containing methylpolysiloxane,
Ethyl polysiloxane, dimethyl polysiloxane, methyl ethyl polysiloxane, methyl polysiloxane containing ethoxy group, ethyl polysiloxane, dimethyl polysiloxane, methyl ethyl polysiloxane, methyl polysiloxane containing propoxy, ethyl polysiloxane, dimethyl polysiloxane, methyl Ethylpolysiloxane, butoxy group-containing methylpolysiloxane, ethylpolysiloxane, dimethylpolydioxane, methylethylsiloxane, isopropoxy group-containing methylpolysiloxane,
Ethyl polysiloxane, dimethyl polysiloxane, methyl ethyl polysiloxane, methyl polysiloxane containing isobutoxy group, ethyl polysiloxane, dimethyl polysiloxane, methyl ethyl polysiloxane and the like.
また、前述の一般式Si（OR′）４は例えば、テトラメ
トキシシラン，テトラエトキシシラン，テトラプロポキ
シシラン，テトラブトキシシラン，テトライソプロポキ
シシラン，テトライソブトキシシラン等であり、これら
化合物は成分（Ａ）と同様に重合して本発明にかかる成
分（Ｂ）を生成する。The above-mentioned general formula Si (OR ') 4 is, for example, tetramethoxysilane, tetraethoxysilane, tetrapropoxysilane, tetrabutoxysilane, tetraisopropoxysilane, tetraisobutoxysilane, and the like. ) To produce the component (B) according to the present invention.
これら成分（Ｂ）は具体的にはアルコキシ基含有のポ
リシロキサンであって、例えば、メトキシ基，エトキシ
基，プロポキシ基，ブトキシ基，イソプロポキシ基，イ
ソブトキシ基等含有のポリシロキサンである。The component (B) is specifically a polysiloxane containing an alkoxy group, for example, a polysiloxane containing a methoxy group, an ethoxy group, a propoxy group, a butoxy group, an isopropoxy group, an isobutoxy group, or the like.
本発明にかかる成分（Ｃ）は前述成分（Ａ）および
（Ｂ）の一般式で示される化合物が前述の成分（Ａ）と
同様の条件下で反応して生じる反応生成物であって、具
体的にはオルソシリケート結合のアルキルポリシロキサ
ンであり、例えば、オルソシリケート結合のメチルポリ
シロキサン，エチルポリシロキサン，ジメチルポリシロ
キサン，メチルエチルポリシロキサン等である。The component (C) according to the present invention is a reaction product produced by reacting the compounds represented by the general formulas of the components (A) and (B) under the same conditions as the components (A). Specifically, it is an orthosilicate-bonded alkyl polysiloxane, for example, an orthosilicate-bonded methyl polysiloxane, ethyl polysiloxane, dimethyl polysiloxane, methyl ethyl polysiloxane, or the like.
本発明は前述（Ａ），（Ｂ）および（Ｃ）の群から選
択された二種以上の配合物、すなち、（Ａ）（Ｂ），
（Ａ）（Ｃ），（Ｂ）（Ｃ）または（Ａ）（Ｂ）（Ｃ）
の配合物に対して成分（Ｄ）、すなわち、イソラウリン
酸、イソミリスチン酸、イソパルミチン酸、イソステア
リン酸、およびイソアラキン酸からなる物質の群から選
択された１種または１種以上を配合してなる。The present invention relates to two or more compounds selected from the group of the above (A), (B) and (C), that is, (A), (B),
(A) (C), (B) (C) or (A) (B) (C)
(D), that is, one or more selected from the group consisting of substances consisting of isolauric acid, isomyristic acid, isopalmitic acid, isostearic acid, and isoarachinic acid. .
前述の成分（Ａ）、（Ｂ）または（Ｃ）配合物の配合
量は任意であるが、（Ａ）（Ｂ），（Ａ）（Ｃ）配合の
場合、成分（Ａ）100重量部に対して成分（Ｂ）および
（Ｃ）がそれぞれ0.5乃至100重量部が好ましく、また1.
0乃至60重量部がより好ましい。成分（Ｂ）（Ｃ）の場
合は成分（Ｃ）100重量部に対して成分（Ｂ）が0.5乃至
100重量部が好ましく、また1.0乃至60が一層好ましい。
さらに成分（Ａ），（Ｂ），（Ｃ）の場合は成分（Ａ）
100重量部に対して成分（Ｂ）（Ｃ）の合計が0.5乃至10
0重量部が好ましく、また、1.0乃至60重量部が好まし
い。The amount of the component (A), (B) or (C) is optional, but in the case of the components (A), (B), (A) and (C), the amount of the component (A) is 100 parts by weight. On the other hand, the components (B) and (C) are each preferably 0.5 to 100 parts by weight, and 1.
0 to 60 parts by weight is more preferable. In the case of the components (B) and (C), the component (B) is 0.5 to 100 parts by weight of the component (C).
100 parts by weight is preferable, and 1.0 to 60 is more preferable.
Further, in the case of the components (A), (B) and (C), the component (A)
The total of components (B) and (C) is 0.5 to 10 per 100 parts by weight.
0 parts by weight is preferable, and 1.0 to 60 parts by weight is preferable.
さらに成分（Ｄ）の配合量は前述（Ａ）、（Ｂ）また
は（Ｃ）の配合物100重量部に対して２〜10重量部であ
る。The amount of the component (D) is 2 to 10 parts by weight based on 100 parts by weight of the compound of the above (A), (B) or (C).
上述の本発明塗布剤は原液のまま、または、水やアル
コール類、炭化水素類等の有機溶媒と混和希釈して、
布、スポンジ，フェルト，刷毛，ベルトなどにより塗布
され、あるいは、浸漬，噴霧など任意の方法により塗布
される。The above-mentioned coating composition of the present invention is undiluted, or diluted with water or an organic solvent such as alcohols and hydrocarbons.
It is applied by a cloth, sponge, felt, brush, belt, or the like, or by any method such as dipping or spraying.
（実施例） 成分（Ａ）としてエトキシ基含有メチルエチルポリシ
ロキサン，成分（Ｂ）としてエトキシ基含有ポリシロキ
サン，成分（Ｃ）としてオルソシリケート結合のジメチ
ルポリシロキサンを用いた。Example An ethoxy group-containing methylethylpolysiloxane was used as the component (A), an ethoxy group-containing polysiloxane was used as the component (B), and an orthosilicate-bonded dimethylpolysiloxane was used as the component (C).
成分（Ａ）の合成は次のようにして行った。すなわ
ち、メチルエチルエトキシシラン１モルに蒸溜水１モル
を塩酸の存在下で滴下し均一透明になってから、81℃ま
で昇温し、１時間還流する。低沸点物を留去しながら、
130℃まで昇温し、減圧下（400mm/Hg）130℃の温度で１
時間熟成して、エトキシ基含有メチルエチルポリシロキ
サン成分（Ａ）を得た。The synthesis of the component (A) was performed as follows. That is, 1 mol of distilled water is added dropwise to 1 mol of methylethylethoxysilane in the presence of hydrochloric acid, and the mixture becomes uniformly transparent. Then, the temperature is raised to 81 ° C. and refluxed for 1 hour. While distilling low-boiling substances,
The temperature is raised to 130 ° C and reduced pressure (400mm / Hg) at 130 ° C
After aging for a time, an ethoxy group-containing methyl ethyl polysiloxane component (A) was obtained.
成分（Ｂ）の合成は、テトラエトキシシラン１モルに
蒸留水1.4モルを塩酸の存在下で滴下し、成分（Ａ）の
方法と同様にして行い、エトキシ基含有ポリシロキサン
成分（Ｂ）を得た。Component (B) is synthesized by adding 1.4 mol of distilled water dropwise to 1 mol of tetraethoxysilane in the presence of hydrochloric acid in the same manner as in the method of component (A) to obtain an ethoxy group-containing polysiloxane component (B). Was.
又、成分（Ｃ）の合成は、ジメチルエトキシシラン0.
5モルと、テトラエトキシシラン0.5モルを混合し、蒸留
水１モルを塩酸の存在下で滴下し、成分（Ａ）、（Ｂ）
の方法と同様にして行いオルソシリケート結合のジメチ
ルポリシロキサンを得た。The synthesis of component (C) was carried out using dimethylethoxysilane 0.
5 mol and 0.5 mol of tetraethoxysilane are mixed, and 1 mol of distilled water is added dropwise in the presence of hydrochloric acid to obtain components (A) and (B).
In the same manner as in the above, an orthosilicate-bonded dimethylpolysiloxane was obtained.
これら（Ａ）、（Ｂ）、（Ｃ）の配合物100重量部に
対して以下の成分（D1）、（D2）、（D3）、（D4）およ
び（D5）を表−１に示す量配合して本発明塗布剤を得
た。The following components (D1), (D2), (D3), (D4) and (D5) were added to 100 parts by weight of the blend of (A), (B) and (C) in the amounts shown in Table-1. This was mixed to obtain the coating composition of the present invention.
成分（Ｄ） （１）イソラウリン酸（C12） （２）イソミリスチン酸（C14） （３）イソパルミチン酸（C16） （４）イソステアリン酸（C18） （５）イソアラキン酸（C20） 次いで、表−１の各試料をエタノールで10倍に希釈
し、これらの各試料について表−２に示す性能試験を行
ない、結果を表−２に示した。表−２において、ブラン
クは成分（Ｄ）が添加されていない試料である。Component (D) (1) Isolauric acid (C 12 ) (2) Isomyristic acid (C 14 ) (3) Isopalmitic acid (C 16 ) (4) Isostearic acid (C 18 ) (5) Isoarachiic acid (C 20 ) ) Next, each sample in Table 1 was diluted 10-fold with ethanol, and the performance test shown in Table 2 was performed on each sample. The results are shown in Table 2. In Table 2, the blank is a sample to which the component (D) was not added.
性能試験は次のようにして行った。 The performance test was performed as follows.
清涼飲料びん（200ml）およびビールびん（633ml）に
各試料をスポンジを用いて塗布し、室温で１日、２日、
３日および５日放置した後乾燥性を調べ乾燥性は手で剥
離状態を調べて剥離するかどうかを調べることにより行
った。Apply each sample to a soft drink bottle (200 ml) and a beer bottle (633 ml) using a sponge,
After standing for 3 days and 5 days, the drying property was examined, and the drying property was examined by examining the peeling state by hand to determine whether or not the film was peeled.
前述の条件で放置した後、指触によりべとつきすべり
性を調べた。After being left under the above-described conditions, the stickiness was examined by touching with a finger.
表−２から、本発明にかかる塗布剤は膜の乾燥性、べ
とつき、すべり性について著しく向上し、特にイソミリ
シチン酸が上述の性能を良好に改良することがわかっ
た。 From Table 2, it was found that the coating composition of the present invention significantly improved the drying property, stickiness, and slipperiness of the film, and in particular, that the isomylicitic acid favorably improved the above-mentioned performance.
以上のとおり、本発明にかかる塗布剤は膜の乾燥性が
良好で、かつ、べとつきや、すべりがなく、前述の先願
にかかる発明をさらに改良した発明である。As described above, the coating composition according to the present invention has good drying properties of the film, has no stickiness or slippage, and is an invention obtained by further improving the invention according to the above-mentioned prior application.
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭55−164255（ＪＰ，Ａ) 特開 昭58−74541（ＪＰ，Ａ) 特開 昭58−65774（ＪＰ，Ａ) 特開 昭60−151254（ＪＰ，Ａ) 特公 平７−77972（ＪＰ，Ｂ２) ──────────────────────────────────────────────────続 き Continuation of front page (56) References JP-A-55-164255 (JP, A) JP-A-58-74541 (JP, A) JP-A-58-65774 (JP, A) JP-A-60-1985 151254 (JP, A) JP 7-77972 (JP, B2)
Claims (1)
から選択された二種または二種以上の配合物を含むガラ
ス容器のかすれ傷塗布剤において、前記配合物にさらに
次の成分（Ｄ）を、前記配合物100重量部に対して２〜1
0重量部配合することを特徴とするガラス容器のかすれ
傷塗布剤。 （Ａ）一般式 RSi（OR′）ｎの重合物。 （Ｂ）一般式 Si（OR′）４の重合物。 （Ｃ）前記（Ａ）、（Ｂ）の一般式で示される化合物の
反応によって生じる反応生成物。 （Ｄ）イソラウリン酸，イソミリスチン酸，イソパルミ
チン酸，イソステアリン酸およびイソアラキン酸からな
る物質の群から選択された１種または１種以上。 ただし、前記（Ａ）および（Ｂ）の式において、Ｒはメ
チル，エチル、ジメチル、メチルエチル基であり、Ｒ′
はC1乃至C4のアルキル基であり、ｎは２乃至３の整数で
ある。An abrasion coating composition for a glass container comprising two or more compounds selected from the group consisting of the following components (A), (B) and (C): The following component (D) is used in an amount of 2 to 1 based on 100 parts by weight of the above-mentioned composition.
A coating agent for scratches on glass containers, which is added in an amount of 0 parts by weight. (A) A polymer of the general formula RSi (OR ') n . (B) A polymer of the general formula Si (OR ') 4 . (C) Reaction products generated by the reaction of the compounds represented by the general formulas (A) and (B). (D) one or more selected from the group of substances consisting of isolauric acid, isomyristic acid, isopalmitic acid, isostearic acid and isoarachinic acid. However, in the formulas (A) and (B), R is a methyl, ethyl, dimethyl, methylethyl group, and R ′
Is a C 1 to C 4 alkyl group, and n is an integer of 2 to 3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62216299A JP2652169B2 (en) | 1987-09-01 | 1987-09-01 | Scratching agent for glass containers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62216299A JP2652169B2 (en) | 1987-09-01 | 1987-09-01 | Scratching agent for glass containers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6462364A JPS6462364A (en) | 1989-03-08 |
| JP2652169B2 true JP2652169B2 (en) | 1997-09-10 |
Family
ID=16686353
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62216299A Expired - Lifetime JP2652169B2 (en) | 1987-09-01 | 1987-09-01 | Scratching agent for glass containers |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2652169B2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4824862B2 (en) * | 2001-04-20 | 2011-11-30 | 東レ・ダウコーニング株式会社 | Glass container scratching agent |
| HRP20090259A2 (en) * | 2009-05-11 | 2010-12-31 | Institut Ru�er Bo�kovi� | Agent for chemical treatment of glass, ceramic and stone surfaces |
| CN111333343B (en) * | 2020-03-30 | 2022-07-15 | 河南绿澳化工科技有限公司 | Glass recovery bottle mark removing agent and preparation method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6017380B2 (en) * | 1979-06-06 | 1985-05-02 | ダイセル化学工業株式会社 | Composition for surface coating |
| JPS5865774A (en) * | 1981-10-14 | 1983-04-19 | Toshiba Corp | Coating composition for surface protection |
| JPS5874541A (en) * | 1981-10-27 | 1983-05-06 | Dainippon Toryo Co Ltd | Coating composition for frosting glass |
| US4548842A (en) * | 1983-12-20 | 1985-10-22 | Union Carbide Corporation | Fatty ethenoid acylaminoorganosilicon compounds and their use in compositions for coating glass |
-
1987
- 1987-09-01 JP JP62216299A patent/JP2652169B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6462364A (en) | 1989-03-08 |
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