CN111333343A - Glass recovery bottle mark removing agent and preparation method thereof - Google Patents
Glass recovery bottle mark removing agent and preparation method thereof Download PDFInfo
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- CN111333343A CN111333343A CN202010238520.1A CN202010238520A CN111333343A CN 111333343 A CN111333343 A CN 111333343A CN 202010238520 A CN202010238520 A CN 202010238520A CN 111333343 A CN111333343 A CN 111333343A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/30—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/72—Decorative coatings
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Composite Materials (AREA)
- Grinding-Machine Dressing And Accessory Apparatuses (AREA)
Abstract
The invention discloses a trace removing agent for a glass recovery bottle and a preparation method thereof, belonging to the technical field of trace removing agents and being prepared from the following raw materials in percentage by weight: 4-6% of modified amino silicone oil, 2-4% of fatty alcohol-polyoxyethylene ether, 20-40% of cosolvent and the balance of water. The preparation method of the mark removing agent for the recycled beer glass bottles comprises the following steps: adding a cosolvent into water, uniformly stirring, adding fatty alcohol-polyoxyethylene ether, and uniformly mixing to obtain a mixed solution 1; and adding the modified amino silicone oil into the mixed solution 1, and uniformly stirring to obtain the trace removing agent for the glass recovery bottle. The trace removing agent for the glass recovery bottle has the characteristics of stable performance, low cost, no color and no smell, good light transmittance, easiness in recovery and cleaning and the like, and is suitable for recovering and removing traces of glass bottles with various colors. Has wide market value and application prospect.
Description
Technical Field
The invention relates to the technical field of mark removing agents, and particularly relates to a mark removing agent for a glass recovery bottle and a preparation method of the mark removing agent.
Background
The glass bottle has the advantages of cleanness, sanitation, beauty, transparence, high chemical stability, air impermeability, easy sealing, unchanged property of the contained articles, multiple turnover use, rich raw materials, low price and the like, and becomes a packaging material widely used in the industries of food, medicine, chemistry and the like. The glass bottle can is of various types and can be classified into a recycled bottle and a non-recycled bottle according to the use condition.
At present, in the processes of recycling, transporting, loading and unloading bottles for multiple times and stacking in a bottle yard, the outer surfaces of the bottles are easy to wear, white scratches and galling on the surfaces are easy to cause by mutual collision and friction of the bottles, the image and the perception of consumers of the products are seriously influenced, and further the sales of the products is influenced. The use of a glass recycle bottle tracer to repair and refurbish is an effective way to solve this problem.
The mark removing agent for the recovered glass bottle is a new product for repairing and renewing the surface scratches of the recovered glass bottle. The main principle is that the scratch part on the surface of the glass bottle is covered or filled with a mark removing agent, so that the refractive index of the scratch part is changed, and the appearance is beautified like a new bottle on the surface. The traditional mark removing agent for the recycled glass bottles comprises two types of aqueous products and oily products. The trace removing agent for the water-based recycled glass bottle is divided into two types of strong water-absorbing inorganic matters which are dissolved in water and oily substances which are emulsified into the water at high speed, and the trace removing agent prepared by dissolving the strong water-absorbing inorganic matters in the water has the defects of uneven distribution on the glass bottle due to too large surface energy, poor adhesive force of the water-based trace removing agent, easy abrasion and falling in the transportation, loading and unloading processes and poor trace removing effect; the mark removing agent prepared by emulsifying the oily substance into water at high speed has the defects of poor atomization effect, easy sagging and flowing, label pollution, product appearance damage and influence on sensory effect in the application process, and the mark removing agent is unstable, is easy to layer after a long time and influences use. Although the oily mark removing agent has good stability and is easy to atomize, the oily mark removing agent is not easy to dissolve in water, and brings many problems to production enterprises when a recovery bottle is cleaned, the oily mark removing agent cannot be reused seriously, the bottle washing cost is increased slightly, and unnecessary waste is caused.
Disclosure of Invention
The invention provides a mark removing agent for a glass recovery bottle and a preparation method thereof, and solves the technical problems of uneven distribution, poor mark removing effect, poor atomization, label pollution, instability, difficulty in recycling of glass bottles and the like of the conventional mark removing agent.
In order to solve the technical problems, the technical scheme of the invention is as follows:
the trace removing agent for the glass recovery bottle is characterized by being prepared from the following raw materials in percentage by weight: 4-6% of modified amino silicone oil, 2-4% of fatty alcohol-polyoxyethylene ether, 20-40% of cosolvent and the balance of water.
Wherein, preferably, the modified amino silicone oil is prepared by the following preparation method:
(1) amino silicone oil modification: adding 10-20 parts by weight of carboxymethyl cellulose aqueous solution into a reaction kettle, mixing and stirring for 1-2h, adding 4-6 parts by weight of amino silicone oil, stirring and reacting for 2-4h to fully react; filtering with a 100-mesh filter screen, and drying at 110-115 ℃ to obtain modified amino silicone oil;
(2) emulsification: taking 100 parts by weight of modified amino silicone oil, adding 20-30 parts by weight of tridecyl alcohol polyether, and uniformly mixing to obtain an oil phase: adding 8-12 parts by weight of propylene glycol and 3-5 parts by weight of glacial acetic acid into 400 parts by weight of water, and uniformly mixing to obtain a water phase; and adding the oil phase into the water phase for multiple times, starting a blade type stirrer for stirring in the adding process, continuously stirring for 40-60min after the adding is finished, standing to be transparent, and filtering by using a 100-mesh filter screen to obtain the modified amino silicone oil.
The mass percentage concentration of the carboxymethyl cellulose aqueous solution is 25-40%.
In the emulsification process of the step (2), the temperature is controlled to be 65-68 ℃.
The fatty alcohol-polyoxyethylene ether is AEO-03, AEO-07 or AEO-11.
The cosolvent is any one of polyvinylpyrrolidone, alkyl glycoside, diethylene glycol and diethylene glycol ethyl ether.
A preparation method of a mark removing agent for a glass recovery bottle comprises the following steps:
(1) adding a cosolvent into water, starting stirring, starting a heating device, keeping the temperature at 65 +/-3 ℃, uniformly stirring, adding fatty alcohol-polyoxyethylene ether, and continuously stirring for 30min to obtain a mixed solution 1;
(2) adding the modified amino silicone oil into the mixed solution 1, stirring for 40-60 minutes, and filtering by using a 100-mesh filter screen to obtain the trace removing agent for the glass recovery bottle.
The invention has the beneficial effects that:
according to the invention, carboxymethyl cellulose is adopted to carry out surface modification on amino silicone oil, and as the carboxymethyl cellulose has adhesiveness and dispersibility, the carboxymethyl cellulose can be adsorbed to the surface of mixture particles, and a plurality of hydrophilic hydroxyl groups face outwards, a network structure with steric hindrance effect is formed on the surface of the particles, and the carboxymethyl cellulose and the amino silicone oil are subjected to modification reaction, and can be grafted and compounded, so that the adhesive strength of the mark removing agent and the glass surface is improved, and the problem that the existing aqueous mark removing agent is easy to wear and fall off is solved.
In addition, the modified amino silicone oil is emulsified by tridecyl alcohol polyether, propylene glycol and glacial acetic acid to obtain amino silicone oil microemulsion, the microemulsion further improves the water solubility of the amino silicone oil and the water solubility stability of the amino silicone oil, and the stability of the amino silicone oil is further improved by adding a cosolvent.
Furthermore, the content of the emulsified and modified amino silicone oil is only 4-6%, the content is low, but the content can meet the requirement of filling scratches of glass bottles, the effects of changing the refractive index and removing the scratches can be achieved, and the cost is reduced.
Furthermore, the fatty alcohol-polyoxyethylene ether is added in the invention, so that the surface energy of the solution is further reduced, the solution is easier to atomize in the application process, and the trace removing agent is more uniformly distributed on the glass bottle.
In the production process, the solution in each step is strictly controlled to be filtered by a 100-mesh filter screen, so that the equipment is not blocked in the application process.
The raw materials used in the invention are all food grade, and the prepared product is colorless and tasteless, can be applied to recycled glass bottles with various colors, and does not generate negative influence.
The trace removing agent for the glass recovery bottle has the characteristics of stable performance, low cost, no color and no smell, good light transmittance, easiness in recovery and cleaning and the like, and is suitable for recovering and removing traces of glass bottles with various colors. Has wide market value and application prospect.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
The embodiment provides a trace removing agent for a glass recovery bottle, which is prepared from the following raw materials in percentage by weight: 5% of modified amino silicone oil, AEO-033%, 30% of diethylene glycol and the balance of water.
The modified amino silicone oil is prepared by the following preparation method:
(1) amino silicone oil modification: adding 15 parts by weight of 30% carboxymethyl cellulose aqueous solution, mixing and stirring for 1.5h, adding 5 parts by weight of amino silicone oil, stirring and reacting for 3h, filtering by using a 100-mesh filter screen, and drying at 110-115 ℃ to obtain modified amino silicone oil;
(2) emulsification: taking 100 parts by weight of modified amino silicone oil, adding 25 parts by weight of tridecyl alcohol polyether, and uniformly mixing to obtain an oil phase: adding 10 parts by weight of propylene glycol and 4 parts by weight of glacial acetic acid into 350 parts by weight of water, and uniformly mixing to obtain a water phase; adding the oil phase into the water phase for several times, starting a blade type stirrer for stirring during the addition process, controlling the temperature at 65-68 ℃, continuing stirring for 50min after the addition is finished, standing to be transparent, and filtering by a 100-mesh filter screen to obtain the modified amino silicone oil.
The preparation method of the mark removing agent for the glass recovery bottle comprises the following steps:
(1) adding 30 parts of diethylene glycol into 62 parts of water, uniformly stirring, then adding 3 parts of AEO-03, and uniformly mixing to obtain a mixed solution 1;
(2) and adding 5 parts of modified amino silicone oil into the mixed solution 1, stirring for 40-60 minutes, and filtering by using a 100-mesh filter screen to obtain the trace removing agent for the glass recovery bottle.
Example 2
The embodiment provides a trace removing agent for a glass recovery bottle, which is prepared from the following raw materials in percentage by weight: 6% of modified amino silicone oil, AEO-034%, 20% of diethylene glycol ethyl ether and the balance of water.
The modified amino silicone oil is prepared by the following preparation method:
(1) amino silicone oil modification: adding 10 parts by weight of 40% carboxymethyl cellulose aqueous solution, mixing and stirring for 1h, adding 6 parts by weight of amino silicone oil, stirring and reacting for 2h to fully react; filtering with a 100-mesh filter screen, and drying at 110-115 ℃ to obtain modified amino silicone oil;
(2) emulsification: taking 100 parts by weight of modified amino silicone oil, adding 30 parts by weight of tridecyl alcohol polyether, and uniformly mixing to obtain an oil phase: adding 8 parts by weight of propylene glycol and 5 parts by weight of glacial acetic acid into 300 parts by weight of water, and uniformly mixing to obtain a water phase; adding the oil phase into the water phase for several times, starting a blade type stirrer for stirring during the addition process, controlling the temperature at 65-68 ℃, continuing stirring for 60min after the addition is finished, standing to be transparent, and filtering by a 100-mesh filter screen to obtain the modified amino silicone oil.
The preparation method of the mark removing agent for the glass recovery bottle comprises the following steps:
(1) adding 20 parts of diethylene glycol ethyl ether into 70 parts of water, uniformly stirring, then adding 4 parts of AEO-03, and uniformly mixing to obtain a mixed solution 1;
(2) and adding 6 parts of modified amino silicone oil into the mixed solution 1, stirring for 40-60 minutes, and filtering by using a 100-mesh filter screen to obtain the trace removing agent for the glass recovery bottle.
Example 3
The embodiment provides a trace removing agent for a glass recovery bottle, which is prepared from the following raw materials in percentage by weight: 5% of modified amino silicone oil, AEO-072%, 25% of alkyl glycoside and the balance of water.
The modified amino silicone oil is prepared by the following preparation method:
(1) amino silicone oil modification: adding 20 parts by weight of 25% carboxymethyl cellulose aqueous solution, mixing and stirring for 2 hours, adding 4 parts by weight of amino silicone oil, stirring and reacting for 4 hours to fully react; filtering with a 100-mesh filter screen, and drying at 110-115 ℃ to obtain modified amino silicone oil;
(2) emulsification: taking 100 parts by weight of modified amino silicone oil, adding 20 parts by weight of tridecyl alcohol polyether, and uniformly mixing to obtain an oil phase: adding 12 parts by weight of propylene glycol and 3 parts by weight of glacial acetic acid into 00 parts by weight of water, and uniformly mixing to obtain a water phase; adding the oil phase into the water phase for several times, starting a blade type stirrer for stirring during the addition process, controlling the temperature at 65-68 ℃, continuing stirring for 60min after the addition is finished, standing to be transparent, and filtering by a 100-mesh filter screen to obtain the modified amino silicone oil.
The preparation method of the mark removing agent for the glass recovery bottle comprises the following steps:
(1) adding 25 parts of alkyl glycoside into 68 parts of water, stirring uniformly, then adding 2 parts of AEO-07, and mixing uniformly to obtain a mixed solution 1;
(2) and (3) adding 5 parts of modified amino silicone oil into the mixed solution 1, stirring for 40 minutes, and filtering by using a 100-mesh filter screen to obtain the trace removing agent for the glass recovery bottle.
Example 4
The embodiment provides a trace removing agent for a glass recovery bottle, which is prepared from the following raw materials in percentage by weight: 6% of modified amino silicone oil, AEO-073%, 20% of polyvinylpyrrolidone and the balance of water.
The modified amino silicone oil is prepared by the following preparation method:
(1) amino silicone oil modification: adding 12 parts by weight of 35% carboxymethyl cellulose aqueous solution, mixing and stirring for 2 hours, adding 5 parts by weight of amino silicone oil, stirring and reacting for 4 hours to fully react; filtering with a 100-mesh filter screen, and drying at 110-115 ℃ to obtain modified amino silicone oil;
(2) emulsification: taking 100 parts by weight of modified amino silicone oil, adding 22 parts by weight of tridecyl alcohol polyether, and uniformly mixing to obtain an oil phase: adding 11 parts by weight of propylene glycol and 3.5 parts by weight of glacial acetic acid into 320 parts by weight of water, and uniformly mixing to obtain a water phase; adding the oil phase into the water phase for several times, starting a blade type stirrer for stirring during the adding process, controlling the temperature at 65-68 ℃, continuing stirring for 40-60min after the adding is finished, standing to be transparent, and filtering by a 100-mesh filter screen to obtain the modified amino silicone oil.
The preparation method of the mark removing agent for the glass recovery bottle comprises the following steps:
(1) adding 20 parts of polyvinylpyrrolidone into 71 parts of water, uniformly stirring, then adding 3 parts of AEO-07, and uniformly mixing to obtain a mixed solution 1;
(2) and adding 6 parts of modified amino silicone oil into the mixed solution 1, stirring for 60 minutes, and filtering by using a 100-mesh filter screen to obtain the trace removing agent for the glass recovery bottle.
Example 5
The embodiment provides a trace removing agent for a glass recovery bottle, which is prepared from the following raw materials in percentage by weight: 5% of modified amino silicone oil, AEO-113%, 35% of diethylene glycol and the balance of water.
The modified amino silicone oil is prepared by the following preparation method:
(1) amino silicone oil modification: adding 18 parts by weight of 28% carboxymethyl cellulose aqueous solution, mixing and stirring for 2 hours, adding 5 parts by weight of amino silicone oil, stirring and reacting for 3 hours to fully react; filtering with a 100-mesh filter screen, and drying at 110-115 ℃ to obtain modified amino silicone oil;
(2) emulsification: taking 100 parts by weight of modified amino silicone oil, adding 28 parts by weight of tridecyl alcohol polyether, and uniformly mixing to obtain an oil phase: adding 9 parts by weight of propylene glycol and 4 parts by weight of glacial acetic acid into 350 parts by weight of water, and uniformly mixing to obtain a water phase; adding the oil phase into the water phase for several times, starting a blade type stirrer for stirring during the addition process, controlling the temperature at 65-68 ℃, continuing stirring for 60min after the addition is finished, standing to be transparent, and filtering by a 100-mesh filter screen to obtain the modified amino silicone oil.
The preparation method of the mark removing agent for the glass recovery bottle comprises the following steps:
(1) adding 57 parts of diethylene glycol into 35 parts of water, uniformly stirring, adding 3 parts of AEO-11, and uniformly mixing to obtain a mixed solution 1;
(2) and adding 5 parts of modified amino silicone oil into the mixed solution 1, stirring for 50 minutes, and filtering by using a 100-mesh filter screen to obtain the trace removing agent for the glass recovery bottle.
The physical and chemical indexes of the trace removing agent for the glass recycling bottles prepared in examples 1 to 5 are as follows:
tests prove that the mark removing agent for the glass recovery bottle prepared by the embodiment has no layering phenomenon within 30 days, the appearance of the recovery bottle treated by the product can basically achieve the effect of a new bottle, and the recovery bottle is smooth and transparent, is free from dust adhesion, is free from greasy feeling and has no phenomenon of falling off of the mark removing agent.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that fall within the spirit and principle of the present invention are intended to be included therein.
Claims (7)
1. The trace removing agent for the glass recovery bottle is characterized by being prepared from the following raw materials in percentage by weight: 4-6% of modified amino silicone oil, 2-4% of fatty alcohol-polyoxyethylene ether, 20-40% of cosolvent and the balance of water.
2. The traceback agent for the glass recycle bottle according to claim 1, wherein the traceback agent comprises: the modified amino silicone oil is prepared by the following preparation method:
(1) amino silicone oil modification: adding 10-20 parts by weight of carboxymethyl cellulose aqueous solution into a reaction kettle, mixing and stirring for 1-2h, adding 4-6 parts by weight of amino silicone oil, stirring and reacting for 2-4h to fully react; filtering with a 100-mesh filter screen, and drying at 110-115 ℃ to obtain modified amino silicone oil;
(2) emulsification: taking 100 parts by weight of modified amino silicone oil, adding 20-30 parts by weight of tridecyl alcohol polyether, and uniformly mixing to obtain an oil phase: adding 8-12 parts by weight of propylene glycol and 3-5 parts by weight of glacial acetic acid into 400 parts by weight of water, and uniformly mixing to obtain a water phase; and adding the oil phase into the water phase for multiple times, starting a blade type stirrer for stirring in the adding process, continuously stirring for 40-60min after the adding is finished, standing to be transparent, and filtering by using a 100-mesh filter screen to obtain the modified amino silicone oil.
3. The traceback agent for the glass recycle bottle according to claim 2, wherein the traceback agent comprises: the mass percentage concentration of the carboxymethyl cellulose aqueous solution is 25-40%.
4. The traceback agent for the glass recycle bottle according to claim 2, wherein the traceback agent comprises: and (3) controlling the temperature to be 65-68 ℃ in the emulsification process of the step (2).
5. The traceback agent for the glass recycle bottle according to claim 1, wherein the traceback agent comprises: the fatty alcohol-polyoxyethylene ether is AEO-03, AEO-07 or AEO-11.
6. The traceback agent for the glass recycle bottle according to claim 1, wherein the traceback agent comprises: the cosolvent is any one of polyvinylpyrrolidone, alkyl glycoside, diethylene glycol and diethylene glycol ethyl ether.
7. A method for preparing a traceback agent for a recycled glass bottle according to any one of claims 1 to 6, comprising the following steps:
(1) adding a cosolvent into water, starting stirring, starting a heating device, keeping the temperature at 65 +/-3 ℃, uniformly stirring, adding fatty alcohol-polyoxyethylene ether, and continuously stirring for 30min to obtain a mixed solution 1;
(2) adding the modified amino silicone oil into the mixed solution 1, stirring for 40-60 minutes, and filtering by using a 100-mesh filter screen to obtain the trace removing agent for the glass recovery bottle.
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