CN109022167A - A kind of vial compound alkaline cleaner and preparation method thereof - Google Patents

A kind of vial compound alkaline cleaner and preparation method thereof Download PDF

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Publication number
CN109022167A
CN109022167A CN201810710522.9A CN201810710522A CN109022167A CN 109022167 A CN109022167 A CN 109022167A CN 201810710522 A CN201810710522 A CN 201810710522A CN 109022167 A CN109022167 A CN 109022167A
Authority
CN
China
Prior art keywords
vial
sodium
alkaline cleaner
compound alkaline
oxidant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810710522.9A
Other languages
Chinese (zh)
Inventor
王鲜珍
张庆霞
刘志杰
刘昊芃
刘永涛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henan Green Australia Chemical Technology Co Ltd
Original Assignee
Henan Green Australia Chemical Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henan Green Australia Chemical Technology Co Ltd filed Critical Henan Green Australia Chemical Technology Co Ltd
Priority to CN201810710522.9A priority Critical patent/CN109022167A/en
Publication of CN109022167A publication Critical patent/CN109022167A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/044—Hydroxides or bases
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/06—Phosphates, including polyphosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/364—Organic compounds containing phosphorus containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3942—Inorganic per-compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Abstract

The present invention provides a kind of vial compound alkaline cleaners and preparation method thereof, it is characterized in that according to a certain ratio, centainly technique is reacted with requirement by water, potassium hydroxide, surfactant, oxidant, complexing agent, bleeding agent etc..Present invention is mainly used for the cleanings of the support industryization of beer, beverage, seasoning recovery vial；The present invention aims at that wash bottle is de- to be marked with and the watermark bottle as caused by mildew, greasy dirt, originally water evaporation is difficult to clean and researches and develops, it is cleaned with the strength of the watermark bottle caused by mildew, greasy dirt, originally water evaporation, it is low with use cost, the rate of cleaning is high, safety is good, the features such as alkaline stability and thermal stability are good, and permeability is strong.

Description

A kind of vial compound alkaline cleaner and preparation method thereof
Technical field
The present invention relates to a kind of industrialization for beer, beverage, seasoning recovery vial to assist cleaning, and in particular to A kind of vial compound alkaline cleaner and preparation method thereof.
Background technique
Currently, Chinese beer, beverage, flavouring rapid development, national requirements for environmental protection it is stringent, packing material vial Production is increasingly difficult to, and recovery and rinsing recycling becomes particularly important.Due to the difference of adhesive type, existing cleaning agent is to part The residual mark of band is difficult to remove on bottle body, in addition the watermark bottle as caused by mildew, greasy dirt, originally water evaporation in vial in alkali It is difficult to clean under the conditions of property.
Mildew, greasy dirt, originally the main component of watermark bottle caused by water evaporation is tannin, protein, calcium scale etc..
Therefore, be added in wash bottle liquid can be the water as caused by mildew, greasy dirt, originally water evaporation for market in urgent need one kind The cleaning agent that print bottle is removed very well.
Summary of the invention
Present invention aims at trade mark and glass in order to overcome the disadvantages and deficiencies of the prior art, can be made to be easy to remove, It is that watermark bottle is easy to clean under alkaline condition.
The purpose of the invention is achieved by the following technical solution:
A kind of compound alkaline cleaner of vial, it is characterised in that the mass ratio of each ingredient are as follows: water 100, potassium hydroxide 5-15, surfactant 3-8, oxidant 10-20, complexing agent 3-10, bleeding agent 1-5.
The oxidant refer to potassium permanganate, potassium bichromate, sodium hypochlorite, hydrogen peroxide it is one or more.
The surfactant is OP-10, AEO7- 7, polyethers L-61's is one or more.
The complexing agent refers to sodium pyrophosphate, calgon, sodium ammonium triacetate (N TA), edetate (EDETATE SODIUM or four sodium), diethylenetriamine pentacarboxylic acid salt (DTPA), hydrolysis of polymaleic anhydride, ethylenediamine tetraacetic methene sodium phosphate (EDTMPS), diethylene triamine pentamethylene phosphonic salt (DETPMPS), aminotrimethylene phosphate salt etc. is one or more.
The bleeding agent is diisooctyl maleate sulfonate (aerosol-OT salt), bleeding agent (JFC) i.e. one or two of fatty alcohol polyoxyethylene ether.
A method of preparing a kind of compound alkaline cleaner of vial described in claim 1, it is characterised in that packet Include following steps:
(1) it adds water in reaction kettle, then the 80% of addition potassium hydroxide, stirring and dissolving, static about 20 minutes, temperature Near 40 DEG C or less；
(2) surfactant, oxidant, complexing agent, bleeding agent are slowly added into reaction kettle in the case where at the uniform velocity stirring, are stirred Uniformly, continue stirring 30 minutes；
(3) again with remaining 20% potassium hydroxide adjustment product alkalinity and specific gravity in a certain range；
(4) continue stirring 20 minutes, i.e. the acquisition compound alkaline cleaner of vial.
Specific embodiment
Following example will be explained in detail operating method of the invention, but cannot function as limitation of the invention.
Embodiment one
A kind of compound alkaline cleaner of vial, it is characterised in that the mass ratio of each ingredient are as follows: water 60, potassium hydroxide 13, surfactant 6.1, oxidant 12, complexing agent 6, bleeding agent 3.
The oxidant refer to potassium permanganate, potassium bichromate, sodium hypochlorite, hydrogen peroxide it is one or more.
The surfactant is OP-10, AEO7- 7, polyethers L-61's is one or more.
The complexing agent refers to sodium pyrophosphate, calgon, sodium ammonium triacetate (N TA), edetate (EDETATE SODIUM or four sodium), diethylenetriamine pentacarboxylic acid salt (DTPA), hydrolysis of polymaleic anhydride, ethylenediamine tetraacetic methene sodium phosphate (EDTMPS), diethylene triamine pentamethylene phosphonic salt (DETPMPS), aminotrimethylene phosphate salt etc. is one or more.
The bleeding agent is diisooctyl maleate sulfonate (aerosol-OT salt), bleeding agent (JFC) i.e. one or two of fatty alcohol polyoxyethylene ether.
A method of preparing a kind of compound alkaline cleaner of vial described in claim 1, it is characterised in that packet Include following steps:
(1) in 60 kilograms of addition reaction kettles of water, will then be added the 80% of potassium hydroxide is 10.4 kilograms, stirring and dissolving, Static about 20 minutes, near 40 DEG C of temperature or less；
(2) in the case where at the uniform velocity stirring that 6.1 kilograms of surfactant, 12 kilograms of oxidant, 6 kilograms of complexing agent, bleeding agent 3 is public Jin is slowly added into reaction kettle, is stirred evenly, and stirring 30 minutes is continued；
(3) again with remaining 20% potassium hydroxide i.e. 2.6 kilogram adjustment product alkalinity and specific gravity in a certain range；
(4) continue stirring 20 minutes, i.e. the acquisition compound alkaline cleaner of vial.
Embodiment two
A kind of compound alkaline cleaner of vial, it is characterised in that the mass ratio of each ingredient are as follows: water 56, potassium hydroxide 15, surfactant 6.8, oxidant 14, complexing agent 6, bleeding agent 2.
The oxidant refer to potassium permanganate, potassium bichromate, sodium hypochlorite, hydrogen peroxide it is one or more.
The surfactant is OP-10, AEO7- 7, polyethers L-61's is one or more.
The complexing agent refers to sodium pyrophosphate, calgon, sodium ammonium triacetate (N TA), edetate (EDETATE SODIUM or four sodium), diethylenetriamine pentacarboxylic acid salt (DTPA), hydrolysis of polymaleic anhydride, ethylenediamine tetraacetic methene sodium phosphate (EDTMPS), diethylene triamine pentamethylene phosphonic salt (DETPMPS), aminotrimethylene phosphate salt etc. is one or more.
The bleeding agent is diisooctyl maleate sulfonate (aerosol-OT salt), bleeding agent (JFC) i.e. one or two of fatty alcohol polyoxyethylene ether.
A method of preparing a kind of compound alkaline cleaner of vial described in claim 1, it is characterised in that packet Include following steps:
(1) 80% i.e. 12 kilograms of potassium hydroxide in 56 kilograms of addition reaction kettles of water, will then be added, stirring and dissolving is quiet Only about 20 minutes, near 40 DEG C of temperature or less；
(2) in the case where at the uniform velocity stirring that 6.8 kilograms of surfactant, 14 kilograms of oxidant, 6 kilograms of complexing agent, bleeding agent 2 is public Jin is slowly added into reaction kettle, is stirred evenly, and stirring 30 minutes is continued；
(3) again with remaining 20% potassium hydroxide i.e. 3 kilogram adjustment product alkalinity and specific gravity in a certain range；
(4) continue stirring 20 minutes, i.e. the acquisition compound alkaline cleaner of vial.
For the different formulations embodiment of the present invention one with embodiment two through detecting, technical indicator is as follows:
Inspection project Standard Embodiment one Embodiment two
Appearance Weak yellow liquid Weak yellow liquid Weak yellow liquid
Surface-active contents (%) ≧5 6.0 6.5
Specific gravity (25 DEG C, g/cm3) 1.10-1.14 1.12 1.13
Detergency ≧95 98 99

Claims (4)

1. a kind of compound alkaline cleaner of vial, it is characterised in that the mass ratio of each ingredient are as follows: water 100, potassium hydroxide 5- 15, surfactant 3-8, oxidant 10-20, complexing agent 3-10, bleeding agent 1-5.
2. a kind of compound alkaline cleaner of vial according to claim 1, it is characterised in that: the oxidant refers to Potassium permanganate, potassium bichromate, sodium hypochlorite, hydrogen peroxide it is one or more.
3. a kind of compound alkaline cleaner of vial according to claim 1, it is characterised in that: the complexing agent refers to Sodium pyrophosphate, calgon, sodium ammonium triacetate (N TA), edetate (EDETATE SODIUM or four sodium), divinyl three Amine pentacarboxylic acid salt (DTPA), ethylenediamine tetraacetic methene sodium phosphate (EDTMPS), diethylene triamine pentamethylene phosphonic salt (DETPMPS), Three methene phosphate of amine etc. it is one or more.
4. a kind of method for preparing the compound alkaline cleaner of a kind of vial described in claim 1, it is characterised in that including Following steps:
1) it adds water in reaction kettle, is then added the 80% of potassium hydroxide, stirring and dissolving, static about 20 minutes, temperature was near 40 DEG C or less；
2) surfactant, oxidant, complexing agent, bleeding agent are slowly added into reaction kettle in the case where at the uniform velocity stirring, are stirred evenly, Continue stirring 30 minutes；
3) again with remaining 20% potassium hydroxide adjustment product alkalinity and specific gravity in a certain range；
4) continue stirring 20 minutes, i.e. the acquisition compound alkaline cleaner of vial.
CN201810710522.9A 2018-07-02 2018-07-02 A kind of vial compound alkaline cleaner and preparation method thereof Pending CN109022167A (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Publication Number Publication Date
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111333343A (en) * 2020-03-30 2020-06-26 河南绿澳化工科技有限公司 Glass recovery bottle mark removing agent and preparation method thereof
CN112210451A (en) * 2020-10-21 2021-01-12 苏州海黄龙生物技术有限公司 Cleaning fluid and preparation method thereof
CN114989901A (en) * 2022-06-27 2022-09-02 广东韶钢松山股份有限公司 Cleaning agent and cleaning method for inductively coupled plasma emission spectrometer rectangular tube

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102453625A (en) * 2010-10-25 2012-05-16 颜卫 Food glass container cleaning agent
CN103666839A (en) * 2013-11-11 2014-03-26 青岛佰众化工技术有限公司 Cleanser
CN104403851A (en) * 2014-12-04 2015-03-11 柳州立洁科技有限公司 Adhesive sticker cleaner based on normal temperature water
CN105268708A (en) * 2014-07-23 2016-01-27 艺康美国股份有限公司 Method for pretreating container, and method and equipment for cleaning container
CN107338121A (en) * 2017-08-04 2017-11-10 北京长江脉医药科技有限责任公司 Dairy processing instruments alkaline cleaning composition and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102453625A (en) * 2010-10-25 2012-05-16 颜卫 Food glass container cleaning agent
CN103666839A (en) * 2013-11-11 2014-03-26 青岛佰众化工技术有限公司 Cleanser
CN105268708A (en) * 2014-07-23 2016-01-27 艺康美国股份有限公司 Method for pretreating container, and method and equipment for cleaning container
CN104403851A (en) * 2014-12-04 2015-03-11 柳州立洁科技有限公司 Adhesive sticker cleaner based on normal temperature water
CN107338121A (en) * 2017-08-04 2017-11-10 北京长江脉医药科技有限责任公司 Dairy processing instruments alkaline cleaning composition and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111333343A (en) * 2020-03-30 2020-06-26 河南绿澳化工科技有限公司 Glass recovery bottle mark removing agent and preparation method thereof
CN112210451A (en) * 2020-10-21 2021-01-12 苏州海黄龙生物技术有限公司 Cleaning fluid and preparation method thereof
CN114989901A (en) * 2022-06-27 2022-09-02 广东韶钢松山股份有限公司 Cleaning agent and cleaning method for inductively coupled plasma emission spectrometer rectangular tube
CN114989901B (en) * 2022-06-27 2024-01-05 广东韶钢松山股份有限公司 Cleaning agent and cleaning method for moment tube of inductively coupled plasma emission spectrometer

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Application publication date: 20181218

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