CN111254746A - 一种溶液浸泡法制备超疏水滤纸的简易方法 - Google Patents

一种溶液浸泡法制备超疏水滤纸的简易方法 Download PDF

Info

Publication number
CN111254746A
CN111254746A CN202010063285.9A CN202010063285A CN111254746A CN 111254746 A CN111254746 A CN 111254746A CN 202010063285 A CN202010063285 A CN 202010063285A CN 111254746 A CN111254746 A CN 111254746A
Authority
CN
China
Prior art keywords
filter paper
taking out
solution
soaking
drying
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010063285.9A
Other languages
English (en)
Inventor
殷祚炷
薛名山
肖宇杰
罗一丹
洪珍
谢婵
谢宇
王法军
欧军飞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanchang Hangkong University
Original Assignee
Nanchang Hangkong University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nanchang Hangkong University filed Critical Nanchang Hangkong University
Priority to CN202010063285.9A priority Critical patent/CN111254746A/zh
Publication of CN111254746A publication Critical patent/CN111254746A/zh
Pending legal-status Critical Current

Links

Images

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/08—Filter paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/14—Carboxylic acids; Derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/64—Alkaline compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/66—Salts, e.g. alums
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/71—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes
    • D21H17/72—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes of organic material
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/04—Physical treatment, e.g. heating, irradiating
    • D21H25/06—Physical treatment, e.g. heating, irradiating of impregnated or coated paper

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Filtering Materials (AREA)

Abstract

本发明公开了一种溶液浸泡法制备超疏水滤纸的简易方法，其特征在于：将普通滤纸在0.5mol/L的FeCl3溶液中浸渍1～10min，取出后晾干，然后再次放入0.5mol/L的FeCl3溶液中浸渍1～10min，取出后晾干，如此重复3～5次；在0.5mol/L的NaOH溶液中浸渍5～10s，取出后晾干，然后再次放入在0.5mol/L的NaOH溶液中浸渍5～10s，取出后晾干，如此重复3～5次；在10g/L的硬脂酸乙醇溶液中浸渍5～10s，从而对产物进行低表面能物质修饰，取出后在60℃的烘箱中烘干1～2h，即得到超疏水滤纸。本发明提供的超疏水滤纸的制备方法简单高效，原料廉价可得，能耗小，应用范围广泛，所得滤纸与水的接触角均大于150°，滚动角小于5°，超疏水特性优良，易于进行大规模生产和应用。

Description

一种溶液浸泡法制备超疏水滤纸的简易方法
技术领域
本发明属于仿生材料领域，具体涉及一种溶液浸泡法制备超疏水滤纸的简易方法。
背景技术
滤纸是日常生活中常见和必不可少的材料。滤纸是由木材制成，其主要成分是纤维素，由于纤维素是一种结构多糖，有很多羟基，纸张呈亲水性，从而限制其应用领域的拓展。
受天然植物叶子的启发，超疏水材料(接触角大于150°，滚动角小于10°，这意味着一个水滴落在了超疏水表面上几乎是一个球体，容易滚动)以其粗糙表面微纳结构和良好的超疏水性能，可广泛应用于防冰、防腐、油水分离等领域。
超疏水表面可以形成许多衬底：如金属，玻璃，塑料等。与这些材料相比，滤纸上有不同于典型基材(如玻璃和金属)的性能。因此，研究滤纸的超疏水性能具有十分重要的意义。近年来，超疏水性滤纸表面的制备方法有模板法、逐层组装法、喷涂法等。但这些方法复杂、成本高、耗时长，限制了其在宏观产业中的应用。
发明内容
本发明的目的在于提供一种溶液浸泡法制备超疏水滤纸的简易方法，以克服现有制备方法复杂、成本高、耗时长。
本发明溶液浸泡法制备超疏水滤纸的简易方法，其特征在于：将普通滤纸在0.5mol/L的FeCl3溶液中浸渍1～10min，取出后晾干，然后再次放入0.5mol/L的FeCl3溶液中浸渍1～10min，取出后晾干，如此重复3～5次；在0.5mol/L的NaOH溶液中浸渍5～10s，取出后晾干，然后再次放入在0.5mol/L的NaOH溶液中浸渍5～10s，取出后晾干，如此重复3～5次；在10g/L的硬脂酸乙醇溶液中浸渍5～10s，从而对产物进行低表面能物质修饰，取出后在60℃的烘箱中烘干1～2h，即得到超疏水滤纸。
一种溶液浸泡法制备超疏水滤纸的简易方法，其特征在于按以下步骤进行：
一、将普通滤纸在0.1～1.0mol/L的FeCl3溶液中浸渍1～10min，取出后晾干；
二、然后再次放入0.1～1.0mol/L的FeCl3溶液中浸渍1～10min，取出后晾干，如此重复3～5次；
三、在0.1～1.0mol/L的NaOH溶液中浸渍5～10s，取出后晾干；
四、然后再次放入在0.1～1.0mol/L的NaOH溶液中浸渍5～10s，取出后晾干，如此重复3～5次；
五、在1～10g/L的硬脂酸乙醇溶液中浸渍5～10s，从而对产物进行低表面能物质修饰；
六、取出后在40～80℃的烘箱中烘干30min～120min，即得到超疏水滤纸。
本发明的优点是：使用简易的方法和设备，从而可以快速地制备具有超疏水性能的超疏水滤纸，制备方法简单，高效，快捷，成本较低，可进行大规模工业化生产及应用。
附图说明
图一为本发明产物在不同浓度FeCl3溶液下改性滤纸的SEM图；
图二为本发明产物在不同浓度FeCl3溶液下改性滤纸水滴静态接触角测试图。
具体实施方式
给出本发明的实施例并结合给出的实施例对本发明加以说明，但所给出的实施例对本发明不构成任何限制：
具体实施方式一：将普通滤纸在0.5mol/L的FeCl3溶液中浸渍5min，取出后晾干，然后再次放入0.5mol/L的FeCl3溶液中浸渍5min，取出后晾干，如此重复3～5次；在0.5mol/L的NaOH溶液中浸渍5～10s，取出后晾干，然后再次放入在0.5mol/L的NaOH溶液中浸渍5～10s，取出后晾干，如此重复3～5次；在10g/L的硬脂酸乙醇溶液中浸渍5～10s，从而对产物进行低表面能物质修饰，取出后在60℃的烘箱中烘干1～2h，即得到超疏水滤纸。
具体实施方式二：将普通滤纸在0.5mol/L的FeCl3溶液中浸渍5min，取出后晾干，然后再次放入0.5mol/L的FeCl3溶液中浸渍5min，取出后晾干，如此重复3～5次；在0.5mol/L的NaOH溶液中浸渍10s，取出后晾干，然后再次放入在0.5mol/L的NaOH溶液中浸渍10s，取出后晾干，如此重复3～5次；在10g/L的硬脂酸乙醇溶液中浸渍5～10s，从而对产物进行低表面能物质修饰，取出后在60℃的烘箱中烘干1～2h，即得到超疏水滤纸。
具体实施方式三：将普通滤纸在0.5mol/L的FeCl3溶液中浸渍5min，取出后晾干，然后再次放入0.5mol/L的FeCl3溶液中浸渍5min，取出后晾干，如此重复3～5次；在0.5mol/L的NaOH溶液中浸渍10s，取出后晾干，然后再次放入在0.5mol/L的NaOH溶液中浸渍10s，取出后晾干，如此重复3～5次；在10g/L的硬脂酸乙醇溶液中浸渍10s，从而对产物进行低表面能物质修饰，取出后在60℃的烘箱中烘干1～2h，即得到超疏水滤纸。
具体实施方式四：将普通滤纸在0.5mol/L的FeCl3溶液中浸渍5min，取出后晾干，然后再次放入0.5mol/L的FeCl3溶液中浸渍5min，取出后晾干，如此重复3～5次；在0.5mol/L的NaOH溶液中浸渍10s，取出后晾干，然后再次放入在0.5mol/L的NaOH溶液中浸渍10s，取出后晾干，如此重复3～5次；在10g/L的硬脂酸乙醇溶液中浸渍10s，从而对产物进行低表面能物质修饰，取出后在60℃的烘箱中烘干2h，即得到超疏水滤纸。

Claims (1)

1.一种溶液浸泡法制备超疏水滤纸的简易方法，其特征在于按以下步骤进行：
一、将普通滤纸在0.1～1.0mol/L的FeCl3溶液中浸渍1～10min，取出后晾干；
二、然后再次放入0.1～1.0mol/L的FeCl3溶液中浸渍1～10min，取出后晾干，如此重复3～5次；
三、在0.1～1.0mol/L的NaOH溶液中浸渍5～10s，取出后晾干；
四、然后再次放入在0.1～1.0mol/L的NaOH溶液中浸渍5～10s，取出后晾干，如此重复3～5次；
五、在1～10g/L的硬脂酸乙醇溶液中浸渍5～10s，从而对产物进行低表面能物质修饰；
六、取出后在40～80℃的烘箱中烘干30min～120min，即得到超疏水滤纸。
CN202010063285.9A 2020-01-20 2020-01-20 一种溶液浸泡法制备超疏水滤纸的简易方法 Pending CN111254746A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010063285.9A CN111254746A (zh) 2020-01-20 2020-01-20 一种溶液浸泡法制备超疏水滤纸的简易方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010063285.9A CN111254746A (zh) 2020-01-20 2020-01-20 一种溶液浸泡法制备超疏水滤纸的简易方法

Publications (1)

Publication Number Publication Date
CN111254746A true CN111254746A (zh) 2020-06-09

Family

ID=70923675

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202010063285.9A Pending CN111254746A (zh) 2020-01-20 2020-01-20 一种溶液浸泡法制备超疏水滤纸的简易方法

Country Status (1)

Country Link
CN (1) CN111254746A (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113882192A (zh) * 2021-10-25 2022-01-04 南昌航空大学 具有光催化性能的抗生物黏附滤纸及其制备方法
CN115710838A (zh) * 2022-09-28 2023-02-24 南昌航空大学 一种导电超疏水纤维素纸及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104561999A (zh) * 2014-12-19 2015-04-29 北京科技大学 一种在镁合金表面制备超疏水膜层的方法
CN106567284A (zh) * 2016-11-11 2017-04-19 镇江市高等专科学校 一种仿生微纳结构油水分离滤纸的制备方法及其应用
CN106925137A (zh) * 2017-02-27 2017-07-07 四川大学 耐刮擦超疏水亲油纤维素油水吸附/分离膜及其制备方法
CN107178006A (zh) * 2017-06-30 2017-09-19 常州亚环环保科技有限公司 一种耐溶解型油水分离滤纸的制备方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104561999A (zh) * 2014-12-19 2015-04-29 北京科技大学 一种在镁合金表面制备超疏水膜层的方法
CN106567284A (zh) * 2016-11-11 2017-04-19 镇江市高等专科学校 一种仿生微纳结构油水分离滤纸的制备方法及其应用
CN106925137A (zh) * 2017-02-27 2017-07-07 四川大学 耐刮擦超疏水亲油纤维素油水吸附/分离膜及其制备方法
CN107178006A (zh) * 2017-06-30 2017-09-19 常州亚环环保科技有限公司 一种耐溶解型油水分离滤纸的制备方法

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113882192A (zh) * 2021-10-25 2022-01-04 南昌航空大学 具有光催化性能的抗生物黏附滤纸及其制备方法
CN113882192B (zh) * 2021-10-25 2022-10-21 南昌航空大学 具有光催化性能的抗生物黏附滤纸及其制备方法
CN115710838A (zh) * 2022-09-28 2023-02-24 南昌航空大学 一种导电超疏水纤维素纸及其制备方法

Similar Documents

Publication Publication Date Title
CN102808357B (zh) 一种超疏水纸及其制备方法
CN111254746A (zh) 一种溶液浸泡法制备超疏水滤纸的简易方法
CN105599077A (zh) 一种基于溶凝胶法制备超疏水木材的方法
CN102796429B (zh) 水溶性涂料、制备方法及喷涂工艺
CN103241960B (zh) 空心玻璃微珠表面憎水防潮的改性方法
CN108976766B (zh) 一种防水透湿聚氨酯微孔薄膜及其制备方法
CN110922862A (zh) 一种纳米SiO2/改性环氧树脂超疏水涂层材料的制备方法
CN102230169A (zh) 一种在铜基体表面构建超疏水薄膜的方法
CN106366870A (zh) 一种复配水性金属烤漆及其涂装方法
Huang et al. Construction of HLNPs/Fe3O4 based superhydrophobic coating with excellent abrasion resistance, UV resistance, flame retardation and oil absorbency
CN107287903A (zh) 一种耐沸水的可用于油水分离的超疏水织物的制备方法
CN106046991A (zh) 一种防粘灰的水性涂料及其制备方法
CN111663330A (zh) 一种植物单宁介导的超疏水纤维素材料及其制备方法和应用
CN109750510B (zh) 一种超疏水羊毛织物及其制备方法
CN110922875B (zh) 一种改性海泡石/聚氨酯超疏水/超疏油涂层的制备方法
CN112029146B (zh) 一种基于蛋白质颗粒的超疏水涂层及制备方法
CN101818347A (zh) 低温定釉工艺前的处理剂及用处理剂制作产品的工艺方法
CN110041659B (zh) 膨胀石墨-环氧树脂-有机硅树脂耐压复合材料制备方法
CN107761039B (zh) 一种利用火焰喷涂技术制备仿猪笼草超润滑表面的方法
CN115992355A (zh) 一种海洋环境用复配缓蚀剂及其制备方法
CN111704822B (zh) 一种疏水改性硅藻壳材料及其制备方法和应用、包含其的疏水组件
CN114735994A (zh) 一种稻壳灰制备超疏水聚合物防水涂料的方法
CN110055812B (zh) 一种具有反应活性的超疏水纸及其制备方法和应用
CN114350223A (zh) 烯丙基磺酸盐接枝cs-go复合材料、制备方法和应用
CN103935096B (zh) 改性的水性聚氨酯乳胶膜及其制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20200609

WD01 Invention patent application deemed withdrawn after publication