CN111205943A - Preparation method of efficient mite-killing handmade soap and efficient mite-killing handmade soap - Google Patents
Preparation method of efficient mite-killing handmade soap and efficient mite-killing handmade soap Download PDFInfo
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- CN111205943A CN111205943A CN202010122280.9A CN202010122280A CN111205943A CN 111205943 A CN111205943 A CN 111205943A CN 202010122280 A CN202010122280 A CN 202010122280A CN 111205943 A CN111205943 A CN 111205943A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P17/00—Drugs for dermatological disorders
- A61P17/10—Anti-acne agents
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P33/00—Antiparasitic agents
- A61P33/14—Ectoparasiticides, e.g. scabicides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D13/00—Making of soap or soap solutions in general; Apparatus therefor
- C11D13/10—Mixing; Kneading
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D13/00—Making of soap or soap solutions in general; Apparatus therefor
- C11D13/12—Cooling
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
Abstract
The invention discloses a preparation method of an efficient mite-killing handmade soap, which comprises the following steps: providing a mite removing agent R-301 and the following raw materials: fatty acid, fatty alcohol polyoxyethylene ether sodium sulfate, sorbitol, propylene glycol, alkali water mixed solution, sodium citrate water solution, sodium lauryl sulfate, glycerol and sucrose; uniformly stirring fatty acid, partial fatty alcohol polyoxyethylene ether sodium sulfate, sorbitol and propylene glycol; further stirring, and sequentially adding the cooled alkali water mixed solution and the sodium citrate aqueous solution; after saponification, sequentially adding sodium lauryl sulfate, the rest of sodium fatty alcohol polyoxyethylene ether sulfate, glycerol and sucrose, and uniformly stirring; adding the mite removing agent R-301, uniformly stirring, pouring materials, and cooling to obtain the high-efficiency mite removing handmade soap. The high-efficiency mite-removing handmade soap prepared by the preparation method has a good moistening effect on skin, the mite removing rate of the high-efficiency mite-removing handmade soap reaches over 90 percent, and the high-efficiency mite-removing handmade soap can effectively inhibit the growth of mites, improve acne muscles and clean skin.
Description
Technical Field
The invention relates to the technical field of soaps, in particular to a preparation method of an efficient mite-killing handmade soap and the efficient mite-killing handmade soap prepared by the method.
Background
Mites are tiny parasitic animals that are invisible to the naked eye. Mites found in the world are probably more than 5 thousands, second only to insects. Among these mites, the skin is most closely related, mainly three of them:
(1) and dust mites: mainly takes human and animal dander and desquamated corneocytes as food. As long as the temperature and the humidity are suitable, the breeding can be greatly carried out in the living environment of birds, mammals, nests and humans. The dust mites can be detected on the mattress, quilt, pillow towel, unwashed clothes, towel, carpet, sofa and other articles, so that the dust mites are everywhere and the places where the dust mites are located;
(2) demodex mites: the Demodex mites are classified into Demodex folliculorum and Demodex sebaceus, are small in size and invisible to the naked eye, and mainly live in hair follicles and sebaceous glands. Demodex mites mainly feed on sebum secreted from the skin and exfoliated keratinocytes, and are mainly distributed in areas with vigorous sebaceous gland secretion, such as the face, scalp, and back. Demodex mites are one of the causes of diseases such as acne rosacea, pimples (pox), seborrheic dermatitis and the like;
(3) and scabies and mites: parasitizing in the deep stratum corneum, taking the horny tissues and lymph as food, digging in the skin by means of chela and front grab, and digging a tunnel parallel to the skin, thus causing severe pruritus, reddening and edema of the skin.
Therefore, the mites are everywhere in our daily life, and the human body is easy to parasitize the mites, which seriously affects the physical health of people. Therefore, there is a need to develop a soap having a very good mite removing effect.
Disclosure of Invention
The invention aims to provide a preparation method of an efficient mite-killing handmade soap and the efficient mite-killing handmade soap prepared by the method, which can effectively inhibit growth of mites.
In order to achieve the purpose, the invention adopts the following technical scheme:
on the one hand, the preparation method of the high-efficiency mite-killing handmade soap comprises the following steps:
s10, providing a mite removing agent R-301 and the following raw materials: fatty acid, fatty alcohol polyoxyethylene ether sodium sulfate, sorbitol, propylene glycol, alkali water mixed solution, sodium citrate water solution, sodium lauryl sulfate, glycerol and sucrose; uniformly stirring the fatty acid, part of the fatty alcohol polyoxyethylene ether sodium sulfate, the sorbitol and the propylene glycol to prepare a first mixture;
s20, further stirring the first mixture, and sequentially adding the cooled alkali water mixed solution and the sodium citrate aqueous solution to prepare a second mixture;
s30, after the second mixture is saponified, sequentially adding the sodium lauryl sulfate, the remaining part of the sodium fatty alcohol polyoxyethylene ether sulfate, the glycerol and the sucrose, and uniformly stirring to obtain a third mixture;
s40, adding the mite removing agent R-301, stirring uniformly, pouring materials, and cooling to obtain the high-efficiency mite removing handmade soap.
In the invention, sodium lauryl sulfate is used as an anionic surfactant, is easy to dissolve in water, has good emulsifying, foaming, penetrating, decontaminating and dispersing properties, and is rich in foam and quick in biodegradation.
The sodium polyoxyethylene fatty alcohol sulfate serving as an anionic surfactant is mild in property, does not damage skin, and has excellent decontamination, emulsification, foamability and hard water resistance. Because the sodium fatty alcohol polyoxyethylene ether sulfate has excellent bubble performance, only part of the sodium fatty alcohol polyoxyethylene ether sulfate is added in the step S10, bubbles generated in the first mixture in the heating and stirring process are prevented, the addition of the alkali water mixed liquid in the step S20 and the observation of the dissolution condition are facilitated, and the remaining part of the sodium fatty alcohol polyoxyethylene ether sulfate is added in the sub-step S30, so that the prepared product has sufficient decontamination, emulsification, foamability and hard water resistance. Finally, the mite removing agent R-301 is added in the step S40, so that the high-efficiency mite removing handmade soap is prepared.
Wherein the fatty acids include 18 acids, 16 acids, 14 acids and 12 acids.
The alkali water mixed liquid is a mixed liquid of sodium hydroxide and potassium hydroxide, so that the hardness of the high-efficiency mite-killing handmade soap can be effectively reduced, and the user experience effect is improved.
The mite removing agent R-301 accounts for 0.85-1.13% of the total weight of the raw materials, is preferably 1%, and can enable the high-efficiency mite removing handmade soap to have a mite removing effect as high as 90%.
The raw materials comprise the following components in parts by weight:
310-380 parts of sorbitol, such as 311 parts, 312 parts, 313 parts, 315 parts, 318 parts, 320 parts, 325 parts, 330 parts, 335 parts, 340 parts, 345 parts, 350 parts, 355 parts, 360 parts, 365 parts, 370 parts, 375 parts or 378 parts;
120-170 parts of propylene glycol, such as 121 parts, 122 parts, 123 parts, 125 parts, 128 parts, 130 parts, 132 parts, 135 parts, 138 parts, 140 parts, 145 parts, 150 parts, 155 parts, 160 parts, 165 parts or 168 parts;
60-100 parts of fatty alcohol polyoxyethylene ether sodium sulfate, such as 61 parts, 62 parts, 63 parts, 64 parts, 65 parts, 67 parts, 68 parts, 70 parts, 71 parts, 72 parts, 75 parts, 78 parts, 80 parts, 82 parts, 85 parts, 88 parts, 90 parts, 95 parts or 98 parts;
120-170 parts of 18 acid, such as 121 parts, 122 parts, 123 parts, 125 parts, 128 parts, 130 parts, 132 parts, 135 parts, 138 parts, 140 parts, 145 parts, 150 parts, 155 parts, 160 parts, 165 parts or 168 parts;
20 to 40 parts of 16 acids, for example, 20.1 parts, 20.5 parts, 21 parts, 21.5 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts, 30 parts, 31 parts, 32 parts, 33 parts, 34 parts, 35 parts, 36 parts, 37 parts, 38 parts, 39 parts or the like;
14 acid 20-40 parts, such as 20.1 parts, 20.5 parts, 21 parts, 21.5 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts, 30 parts, 31 parts, 32 parts, 33 parts, 34 parts, 35 parts, 36 parts, 37 parts, 38 parts or 39 parts;
20 to 40 parts of 12 acid, for example, 20.1 parts, 20.5 parts, 21 parts, 21.5 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts, 30 parts, 31 parts, 32 parts, 33 parts, 34 parts, 35 parts, 36 parts, 37 parts, 38 parts or 39 parts;
20 to 30 parts of sodium hydroxide, such as 20.1 parts, 20.5 parts, 21 parts, 21.5 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 parts or 29 parts;
12 to 20 parts of potassium hydroxide, for example, 12.3 parts, 12.5 parts, 13 parts, 13.5 parts, 14 parts, 14.5 parts, 15 parts, 15.5 parts, 16 parts, 17 parts, 18 parts or 19 parts;
7-13 parts of sodium citrate, such as 7.1 parts, 7.2 parts, 7.3 parts, 7.4 parts, 7.5 parts, 7.8 parts, 8 parts, 8.2 parts, 8.5 parts, 8.8 parts, 9 parts, 9.5 parts, 10 parts, 10.5 parts, 11 parts, 11.5 parts, 12 parts or 12.5 parts;
20-40 parts of sodium lauryl sulfate, such as 20.1 parts, 20.5 parts, 21 parts, 21.5 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts, 30 parts, 31 parts, 32 parts, 33 parts, 34 parts, 35 parts, 36 parts, 37 parts, 38 parts or 39 parts;
90 to 125 parts of glycerin, such as 90.5 parts, 91 parts, 91.5 parts, 92 parts, 92.5 parts, 93 parts, 93.5 parts, 94 parts, 95 parts, 96 parts, 97 parts, 98 parts, 100 parts, 102 parts, 105 parts, 108 parts, 110 parts, 112 parts, 115 parts, 118 parts, 120 parts, 122 parts and the like;
120-160 parts of sucrose, such as 121 parts, 122 parts, 123 parts, 125 parts, 128 parts, 130 parts, 132 parts, 135 parts, 138 parts, 140 parts, 145 parts, 150 parts, 152 parts, 154 parts, 155 parts or 158 parts;
100 parts of deionized water;
adding 50 parts by weight of water into the mixed solution after mixing the sodium hydroxide and the potassium hydroxide, and dissolving to obtain the alkaline water mixed solution; and adding the sodium citrate into the rest 50 parts by weight of water, and dissolving to obtain the sodium citrate aqueous solution.
The raw materials comprise the following components in parts by weight:
wherein the mass ratio of the sodium fatty alcohol polyoxyethylene ether sulfate in the step S10 to the sodium fatty alcohol polyoxyethylene ether sulfate in the step S30 is 1: 1.
Wherein, in step S20, the further stirring of the first mixture means: stirring the first mixture at a rotating speed of 20r/min, simultaneously heating to a set temperature, and adjusting the stirring speed to 30-40 r/min when the first mixture is in a transparent state;
preferably, the set temperature is 60 to 70 ℃, and more preferably 65 ℃.
Wherein the stirring speed in step S10 is 20 r/min.
On the other hand, the high-efficiency mite-killing handmade soap is prepared by the preparation method.
The invention has the beneficial effects that: the high-efficiency mite-removing handmade soap has a good moistening effect on skin, the mite removing rate of the high-efficiency mite-removing handmade soap reaches over 90%, and the high-efficiency mite-removing handmade soap can effectively inhibit growth of mites, improve acne muscles and clean and thoroughly clean skin.
Detailed Description
The technical solution of the present invention is further explained by the following embodiments.
Unless otherwise specified, various starting materials of the present invention are commercially available or prepared according to conventional methods in the art.
Example 1
S10, adding 18 acid, 16 acid, 14 acid, 12 acid, sodium fatty alcohol polyoxyethylene ether sulfate, sorbitol and propylene glycol into a stirring pot according to the material components shown in the table 1, and stirring at the stirring speed of 20 r/min;
s20, heating to 65 ℃ while stirring to ensure that soap stock is transparent, accelerating stirring to 35r/min, and sequentially adding the cooled alkali water mixed solution and the sodium citrate aqueous solution;
s30, after saponification is fully carried out, sodium lauryl sulfate, the rest of sodium fatty alcohol polyoxyethylene ether sulfate, glycerol and sucrose are sequentially added and stirred uniformly;
and S40, pouring out part of the soap liquid to observe whether the sucrose and the sodium lauryl sulfate are completely dissolved or not after the soap liquid is transparent, adding the mite removing agent R-301 after the sucrose and the sodium lauryl sulfate are completely dissolved, uniformly stirring, pouring out materials, and cooling to obtain the high-efficiency mite removing handmade soap.
Example 2
S10, adding 18 acid, 16 acid, 14 acid, 12 acid, sodium fatty alcohol polyoxyethylene ether sulfate, sorbitol and propylene glycol into a stirring pot according to the material components shown in the table 1, and stirring at the stirring speed of 20 r/min;
s20, heating to 62 ℃ while stirring to ensure that soap stock is transparent, accelerating stirring to 40r/min, and sequentially adding the cooled alkali water mixed solution and the sodium citrate aqueous solution;
s30, after saponification is fully carried out, sodium lauryl sulfate, the rest of sodium fatty alcohol polyoxyethylene ether sulfate, glycerol and sucrose are sequentially added and stirred uniformly;
and S40, pouring out part of the soap liquid to observe whether the sucrose and the sodium lauryl sulfate are completely dissolved or not after the soap liquid is transparent, adding the mite removing agent R-301 after the sucrose and the sodium lauryl sulfate are completely dissolved, uniformly stirring, pouring out materials, and cooling to obtain the high-efficiency mite removing handmade soap.
Example 3
S10, adding 18 acid, 16 acid, 14 acid, 12 acid, sodium fatty alcohol polyoxyethylene ether sulfate, sorbitol and propylene glycol into a stirring pot according to the material components shown in the table 1, and stirring at the stirring speed of 20 r/min;
s20, heating to 68 ℃ while stirring to ensure that soap stock is transparent, accelerating stirring to 30r/min, and sequentially adding the cooled alkali water mixed solution and the sodium citrate aqueous solution;
s30, after saponification is fully carried out, sodium lauryl sulfate, the rest of sodium fatty alcohol polyoxyethylene ether sulfate, glycerol and sucrose are sequentially added and stirred uniformly;
and S40, pouring out part of the soap liquid to observe whether the sucrose and the sodium lauryl sulfate are completely dissolved or not after the soap liquid is transparent, adding the mite removing agent R-301 after the sucrose and the sodium lauryl sulfate are completely dissolved, uniformly stirring, pouring out materials, and cooling to obtain the high-efficiency mite removing handmade soap.
Comparative example 1
This comparative example is essentially the same as example 1 except that sodium fatty alcohol polyoxyethylether sulphate is added in one portion to step S10.
Comparative example 2
This comparative example is essentially the same as example 1 except that no acarus-killing agent R-301 was added.
TABLE 1 Components of materials used in examples 1-3 and comparative examples 1-2 (in parts by weight)
The samples prepared in examples 1-3 and comparative examples 1-2 were tested for their mite-repelling rate according to NY-T1151.2-2006, and the results are shown in Table 2.
TABLE 2 results of sample testing
| Sample source | Test concentration (%) | 24 Demodex Rate (%) |
| Example 1 | 100 | 91 |
| Example 2 | 100 | 90.5 |
| Example 3 | 100 | 90.8 |
| Comparative example 1 | 100 | 68 |
| Comparative example 2 | 100 | 14.5 |
Therefore, the high-efficiency mite-killing handmade soap prepared by the method has a good mite-killing effect.
The above examples are only intended to illustrate the detailed process of the present invention, and the present invention is not limited to the above detailed process, i.e., it is not intended that the present invention necessarily depends on the above detailed process for its implementation. It is understood by those skilled in the art that any modification of the present invention, equivalent substitutions of the raw materials of the product of the present invention and the addition of auxiliary components, selection of specific modes, etc., are within the scope and disclosure of the present invention.
Claims (10)
1. The preparation method of the high-efficiency mite-killing handmade soap is characterized by comprising the following steps of:
s10, providing a mite removing agent R-301 and the following raw materials: fatty acid, fatty alcohol polyoxyethylene ether sodium sulfate, sorbitol, propylene glycol, alkali water mixed solution, sodium citrate water solution, sodium lauryl sulfate, glycerol and sucrose; uniformly stirring the fatty acid, part of the fatty alcohol polyoxyethylene ether sodium sulfate, the sorbitol and the propylene glycol to prepare a first mixture;
s20, further stirring the first mixture, and sequentially adding the cooled alkali water mixed solution and the sodium citrate aqueous solution to prepare a second mixture;
s30, after the second mixture is saponified, sequentially adding the sodium lauryl sulfate, the remaining part of the sodium fatty alcohol polyoxyethylene ether sulfate, the glycerol and the sucrose, and uniformly stirring to obtain a third mixture;
s40, adding the mite removing agent R-301, stirring uniformly, pouring materials, and cooling to obtain the high-efficiency mite removing handmade soap.
2. The method for preparing the high-efficiency mite-killing handmade soap according to claim 1, wherein the fatty acid comprises 18 acid, 16 acid, 14 acid and 12 acid.
3. The method for preparing the high-efficiency mite-killing handmade soap according to claim 2, wherein the alkaline water mixed solution is an aqueous solution of sodium hydroxide and potassium hydroxide.
4. The preparation method of the high-efficiency mite-killing handmade soap according to claim 3, wherein the mite killing agent R-301 accounts for 0.85-1.13% of the total weight of the raw materials.
5. The preparation method of the high-efficiency mite-killing handmade soap according to claim 3, wherein the raw materials comprise the following components in parts by weight:
adding 50 parts by weight of water into the mixed solution after mixing the sodium hydroxide and the potassium hydroxide, and dissolving to obtain the alkaline water mixed solution; and adding the sodium citrate into the rest 50 parts by weight of water, and dissolving to obtain the sodium citrate aqueous solution.
6. The preparation method of the high-efficiency mite-killing handmade soap according to claim 5, wherein the raw materials comprise the following components in parts by weight:
7. the method for preparing the high-efficiency mite-killing handmade soap according to claim 1, wherein the mass ratio of the sodium fatty alcohol polyoxyethylene ether sulfate in the step S10 to the sodium fatty alcohol polyoxyethylene ether sulfate in the step S30 is 1: 1.
8. The method for preparing the high-efficiency mite-killing handmade soap according to claim 1, wherein in the step S20, the further stirring of the first mixture is as follows: stirring the first mixture at a rotating speed of 20r/min, simultaneously heating to a set temperature, and adjusting the stirring speed to 30-40 r/min when the first mixture is in a transparent state;
preferably, the set temperature is 60 to 70 ℃, and more preferably 65 ℃.
9. The method for preparing high-efficiency mite-killing handmade soap according to claim 1, wherein the stirring speed in the step S10 is 20 r/min.
10. A high-efficiency mite-killing handmade soap which is characterized by being prepared by the preparation method of any one of claims 1 to 9.
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| CN202010122280.9A CN111205943A (en) | 2020-02-27 | 2020-02-27 | Preparation method of efficient mite-killing handmade soap and efficient mite-killing handmade soap |
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| CN202010122280.9A CN111205943A (en) | 2020-02-27 | 2020-02-27 | Preparation method of efficient mite-killing handmade soap and efficient mite-killing handmade soap |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111893005A (en) * | 2020-07-01 | 2020-11-06 | 海南星光龙健康产业科技有限公司 | Antibacterial soap added with coconut shell activated carbon powder and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102787037A (en) * | 2012-08-28 | 2012-11-21 | 广西奥奇丽股份有限公司 | Transparent soap |
| CN104789375A (en) * | 2015-04-29 | 2015-07-22 | 青岛国航祥玉技术服务有限公司 | Skin-care laundry detergent for children |
-
2020
- 2020-02-27 CN CN202010122280.9A patent/CN111205943A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102787037A (en) * | 2012-08-28 | 2012-11-21 | 广西奥奇丽股份有限公司 | Transparent soap |
| CN104789375A (en) * | 2015-04-29 | 2015-07-22 | 青岛国航祥玉技术服务有限公司 | Skin-care laundry detergent for children |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111893005A (en) * | 2020-07-01 | 2020-11-06 | 海南星光龙健康产业科技有限公司 | Antibacterial soap added with coconut shell activated carbon powder and preparation method thereof |
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