CN102283788B - Concentrate for preparing infant skin care product and application thereof - Google Patents
Concentrate for preparing infant skin care product and application thereof Download PDFInfo
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Abstract
The invention discloses concentrate for preparing an infant skin care product and application thereof. The concentrate can be quickly dissolved and stable without being demixed in cold water and has the functions of better cleaning, caring, moistening the infant skin and preserving moisture as well as low stimulation; the concentrate is flexible in use (can be adjusted according to requirements and formulas); and meanwhile, diluent has no stickiness in the use process, favorable moisture feeling, smooth feeling and fresh and cool feeling.
Description
Technical field
The present invention relates to a kind of infant skin care product concentrated solution and purposes, be mainly used in the preparation of infant skin care product.
Background technology
The kind of infant skin care product (such as wet tissue, hand towel, wiping face-cloth, cloth for cleaning, cotton balls, cotton swab etc.) is very many in the market, and its major function is skin-moisturizing, skin, cleaning-nursing, the combating diaper rash of releiving.Than common wet tissue, baby's wet tissue liquid generally all adopts emulsion-type liquid, in order to can reach the effect of good skin protection cleaning, gives simultaneously wet tissue more function.
For baby's wet tissue manufacturing enterprise, a large amount of production emulsions are cumbersome things.Show as: the firstth, power consumption, the preparation emulsion need to be heated to respectively 70~90 ℃ with water and oil phase, again oil phase and water is carried out mixing and emulsifying, and this needs considerable heat energy; Even if adopt the low-energy emulsification method, because volume of production is large, also consume energy very much, again cooling after the emulsifying, the heat energy major part has all lost, and does not meet the mode of production of current environmental protection.The secondth, consuming time, in whole emulsion process, the heat time heating time of water and oil phase, mixing and emulsifying time and temperature fall time need the time longer, are unfavorable for large-scale production.The 3rd is to need special equipment, and traditional stirred autoclave can not reach the function demand of emulsifying, and the preparation emulsion needs emulsion tank, and this occupies very large cost in production.Therefore, prepare a kind of (cold water preparation, fast dissolving) easy to use, diluent good stability, use flexibly that baby's wet tissue concentrated solution of (allotment of can filling a prescription as required) is necessary.
The characteristics of infant skin care product such as wet tissue product are to fully take into account the infant skin characteristics.Infant skin is delicate, vulnerable, with adult skin character a great difference is arranged.Wet tissue for baby except skin, eyes are not had the toxicity, also should be particular about nursing and safety especially, and wet tissue for baby has high protectiveness, high security, low irritating property characteristics simultaneously.Therefore, the raw material of baby's wet tissue liquid and formulation composition all are different from common wet tissue liquid.
The first, on material choice, select gentle non-stimulated emulsifying agent and skin moistening wetting agent, to reduce the zest to infant skin.The particularly selection of emulsifying agent, anion, cation and amphoteric emulsifying agent are electrically charged, meeting and protein bound, skin had larger zest, Ying Shenxuan, and nonionic emulsifier neutral, not can with protein bound, zest to skin is minimum, relatively is fit to baby products and uses.Simultaneously, on the toxicity of surfactant, the toxicity of non-ionic surface active agent will be much smaller than ionic surfactant.
The second, be different from common moisturizer on the formulation composition.Will reduce cleansing (cleaning function is mainly realized by a small amount of cleansing and non-woven fabrics) and oil phase, cleansing is high as far as possible, and zest is large, and oil-phase component is high, and it is too large to use sticky sense; Add simultaneously an amount of antiallergic factor, reduce zest and the combating diaper rash of raw material.
The wet tissue concentrated solution of in the market baby's special use is fewer.China Patent Publication No. CN1853602A, open day on November 1st, 2006, invention and created name is " cosmetic emulsion with long-time stability ", this application case discloses a kind of the have low viscosity of long-time stability, the emulsion oil-in-water of fine dispersion, and it comprises by the non-carbohydrate polyol partial esters (emulsifier component A) of the straight or branched with 6-22 carbon atom, saturated or unsaturated fatty acid and the emulsifier combination, one or more oils and the antiseptic that form based on the emulsifying agent (emulsifier component B) of carbohydrate.This cosmetic emulsion contains the triglyceride of ester, anion surfactant and the technical grade oleic acid of technical grade aliphatic alcohol mixture of carboxylic acids, relatively is suitable for the application of cosmetics and wet tissue liquid, but improper baby's wet tissue uses.China Patent Publication No. CN101011318A, open day on August 8th, 2007, the name of innovation and creation is called " low viscosity that can cold preparation and the cosmetic emulsion of prolonged-stability ", this application case disclose a kind of do not contain PEG, can meticulous oil-in-water emulsion cold preparation, prolonged-stability, low viscous, and preparation method thereof.The low viscosity that this application case is described and the emulsion form concentrated solution of prolonged-stability, the emulsifying preparation technology of employing low temperature, although can stablize at short notice, long-time stability are relatively poor.China Patent Publication No. CN1348357A, open day on May 8th, 2002, the name of innovation and creation is called " wet wiping towel that is of value to skin health ", this application case discloses a kind of soft wet wiping towel or wipe type products of promoting skin health, its manufacture method is this to be wiped towel or wipe type products and O/w emulsion compositions combine, said composition comprises natural fat or oil, sterol or sterol derivative, wetting agent, emulsifying surfactant, and water.The wet wiping towel of the skin-friendly health that this application case is described has adopted the glyceryl stearate emulsifying agent of mild, can be used for the baby and use, but this patent is not the concentrated type product.China Patent Publication No. CN1816318A, open day on August 9th, 2006, the name of innovation and creation is called " method for preparing wet wipe with concentrated emulsion ", this application case discloses a kind of preparation method of concentrated emulsion compositions, said composition contains nonionic, anion, cation and amphoteric surfactant, also is not suitable for the preparation of baby's wet tissue liquid.
Therefore, in existing patented technology, also do not have a kind of low irritant, can use flexibly and the concentrated solution that can be used for preparing baby's wet tissue steady in a long-term.Along with the continuity of the development of domestic economy, particularly baby boom, baby's wet tissue special will continue high speed development, also can continue to increase the demand of baby's wet tissue concentrated solution.
Summary of the invention
The invention provides a kind of infant skin care product that can be used for preparing, concentrated solution such as wet tissue, hand towel, wiping face-cloth, cloth for cleaning, cotton balls, cotton swab etc., its objective is the baby's wet tissue concentrated solution in order to provide a kind of and in cold water, can to dissolve fast, stablize not stratified, infant skin being had good cleaning-nursing, skin moistening moisturizing, diluent does not in use have sticky sense simultaneously, has good skinfeel.In order to reach low sticky sense and good smooth sense, clearly sense, concentrated solution of the present invention has reduced oil phase content in the prescription, has optimized formulation composition, has guaranteed the stability of emulsion and good skinfeel.
According to the present invention, described concentrated solution comprises:
A) the nonionic emulsifier component of 0.1~20 % by weight;
B) the oil preparation component of 0.1~15 % by weight;
C) the water preparation component of 50~99 % by weight;
D) the co-emulsifier component of 0.1~10 % by weight;
E) the functional additive component of 0.1~6 % by weight.
A in the described concentrated solution) the nonionic emulsifier % by weight is preferably 0.4~15, most preferably is 1~12;
B in the described concentrated solution) the oil preparation % by weight is preferably 0.4~12, most preferably is 1~10;
C in the described concentrated solution) the water preparation % by weight is preferably 62~90, most preferably is 70~85;
D in the described concentrated solution) the co-emulsifier % by weight is preferably 0.4~8, most preferably is 1~5;
E in the described concentrated solution) the functional additive % by weight is preferably 0.2~5, most preferably is 0.3~4.
The present invention comprises that also described concentrated solution is for the preparation of the purposes of infant skin care product (such as wet tissue, hand towel, wiping face-cloth, cloth for cleaning etc.), described infant care product zest is low, safety and stability is high, has good smooth sense, clearly sense and skin moistening sense.
The present invention also comprises a kind of infant skin care product (such as wet tissue, hand towel, wiping face-cloth, cloth for cleaning, cotton balls, cotton swab etc.) that contains concentrated solution, this care product zest is low, safety and stability is high, has good smooth sense, clearly sense and skin moistening sense.Described concentrated solution comprises:
A) the nonionic emulsifier component of 0.1~20 % by weight; % by weight is preferably 0.4~15, most preferably is 1~12;
B) the oil preparation component of 0.1~15 % by weight; % by weight is preferably 0.4~12, most preferably is 1~10;
C) the water preparation component of 50~99 % by weight; % by weight is preferably 62~90, most preferably is 70~85;
D) the co-emulsifier component of 0.1~10 % by weight; % by weight is preferably 0.4~8, most preferably is 1~5;
E) the functional additive component of 0.1~6 % by weight; % by weight is preferably 0.2~5, most preferably is 0.3~4.
The present invention also comprises a kind of preparation method that contains the infant skin care product of concentrated solution, comprising: a) get infant skin care product material (wet tissue, hand towel, wiping face-cloth, cloth for cleaning, cotton balls, cotton swab etc.) ready; B) with on described 20~300 times of rear coatings of concentrated solution dilution or immersion and the material; C) be prepared into the infant skin care product; The infant care product zest of the method preparation is low, safety and stability is high, has good smooth sense, clearly sense and skin moistening sense.Described concentrated solution comprises:
A) the nonionic emulsifier component of 0.1~20 % by weight; % by weight is preferably 0.4~15, most preferably is 1~12;
B) the oil preparation component of 0.1~15 % by weight; % by weight is preferably 0.4~12, most preferably is 1~10;
C) the water preparation component of 50~99 % by weight; % by weight is preferably 62~90, most preferably is 70~85;
D) the co-emulsifier component of 0.1~10 % by weight; % by weight is preferably 0.4~8, most preferably is 1~5;
E) the functional additive component of 0.1~6 % by weight; % by weight is preferably 0.2~5, most preferably is 0.3~4.
A in the described concentrated solution) nonionic emulsifier mainly is the nonionic emulsifier of ethoxylation;
A in the described concentrated solution) nonionic emulsifier is specially the mixture of a kind of in ceteareth-2, ceteareth-6, ceteareth-10, ceteareth-11, ceteareth-20, ceteareth-21, ceteareth-25, ceteareth-30, ethoxylation methyl glucoside stearate, the ethoxylated glycerol monostearate or at least two kinds.
B in the described concentrated solution) the oil preparation component is water-fast component, is selected from the mixture of a kind of in olive oil, Oleum Ricini, almond oil, mink oil, white oil, Miglyol 812N, Ethylhexyl stearate, glycerol monostearate, dimethicone, the methyl-silicone oil or at least two kinds.
C in the described concentrated solution) the water preparation component is water-soluble component, is selected from the mixture of a kind of in xanthan gum, EDETATE SODIUM, triethanolamine, hydroxy methocel, hydroxypropyl emthylcellulose, hydroxyethyl-cellulose, polyvinyl methyl ether/maleic anhydride, hyaluronate sodium, carbomer, the bisabolol or at least two kinds and distilled water;
Described carbomer, the viscosity of its 0.5% aqueous solution are 6000 ~ 60000 centipoises;
D in the described concentrated solution) the co-emulsifier component is two kinds or at least three kinds mixture in C16~18 alcohol, glycerol, propylene glycol, butanediol, pentanediol, ethohexadiol, the erythrol;
A in the described concentrated solution) nonionic emulsifier also comprises glycerol monostearate;
E in the described concentrated solution) functional additive is antiseptic and the antiallergic factor;
The weight ratio of described antiseptic and the antiallergic factor is 15:1~1:60, is preferably 10:1~1:50, most preferably is 6:1~1:40.
Described antiseptic is the hydroxyphenyl methyl ester, hydroxyphenyl ethyl ester, two kinds or at least three kinds of mixture in hydroxyphenyl propyl ester, hydroxyphenyl butyl ester, hydroxyphenyl isobutyl ester, phenoxyethanol, Methylisothiazolinone, the Sensiva SC50;
The described antiallergic factor is the mixture of a kind of in allantoin, cactus extraction, the Flos Matricariae chamomillae extracting solution or at least two kinds.
Concentrated solution of the present invention can adopt this area conventional method preparation; Perhaps preparation method is: 1. with A), B) and D) component mix post-heating to 80 ℃, insulation half an hour, use as oil phase; 2. with C) component is heated to 80 ℃, insulation half an hour, uses as water; 3. after emulsion tank was heated to 80 ℃, the water with 2/3 added emulsion tank, then with the whole suction of oil phase, and again with remaining water suction, high-speed stirred, homogenizing 5~10 minutes, emulsifying is complete, is incubated half an hour; Add E after being cooled to 40 ℃) component.
Infant skin care product of the present invention includes but not limited to wet tissue, hand towel, wiping face-cloth, cloth for cleaning, cotton balls, cotton swab etc.
The advantage that the present invention has is, concentrated solution can (5 ℃~15 ℃) dissolve in cold water fast, be convenient to production and application, and concentrated solution itself and diluent (diluting 20~300 times) all have extraordinary stability, (allotment of can filling a prescription as required) flexible and convenient to use, energy consumption is low, simultaneously, diluent does not have sticky sense when using, and has good smooth sense and salubrious sense and skin moistening sense.Concentrated solution is mainly used in the preparation of infant skin care product material (wet tissue, hand towel, wiping face-cloth, cloth for cleaning, cotton balls, cotton swab etc.).
Description of drawings
Fig. 1 is embodiment 5 skinfeel evaluation maps.
1 is 1# concentrated solution among the embodiment 1; 2 is 2# concentrated solution among the embodiment 1;
3 is 3# concentrated solution among the embodiment 1; 4 is 4# concentrated solution among the embodiment 1;
5 is 5# concentrated solution among the embodiment 1; 6 is 6# concentrated solution among the embodiment 1;
7 is 7# concentrated solution among the embodiment 1; 8 is 8# concentrated solution among the embodiment 1;
9 are the contrast sample: the board baby of Johnson ﹠ Johnson wet tissue (milk doubly moistens).
The specific embodiment
The following stated embodiment describes the present invention in detail.In these embodiments, all consumptions all be weight %.
1# to 8# concentrated solution (prescription sees Table 1) preparation method is: 1. with A), B) and D) component mix post-heating to 80 ℃, insulation half an hour, use as oil phase; 2. with C) component is heated to 80 ℃, insulation half an hour, uses as water; 3. after emulsion tank was heated to 80 ℃, the water with 2/3 added emulsion tank, then with the whole suction of oil phase, and again with remaining water suction, high-speed stirred, homogenizing 5~10 minutes, emulsifying is complete, is incubated half an hour; Add E after being cooled to 40 ℃) component.
Table 1. inventory of respectively filling a prescription
Embodiment 2
Reference standard QB/T2286-1997, the stability of observing 1# to 8# concentrated solution among the embodiment 1 the results are shown in Table 2, and all conformance with standard requirements of thermostability, tolerance to cold and centrifugal test of visible concentrated solution of the present invention have good stability.
The stability of each prescription of table 2.
Formula number | Thermostability | Tolerance to | Centrifugal test | |
1# | Without separating | Without separating | Not stratified | |
2# | Without separating | Without separating | Not stratified | |
3# | Without separating | Without separating | Not stratified | |
4# | Without separating | Without separating | Not stratified | |
5# | Without separating | Without separating | Not stratified | |
6# | Without separating | Without separating | Not stratified | |
7# | Without separating | Without separating | Not stratified | |
8# | Without separating | Without separating | Not stratified |
Embodiment 3
Diluent stability, after 20~300 times of 1# to 8# concentrated solution dilutions among the embodiment 1, reference standard QB/T2286-1997 does centrifugal test, the results are shown in Table 3, and the diluent of visible concentrated solution of the present invention does not have lamination, has good stability.
The stability of table 3. diluent
Embodiment 4
The cold water of concentrated solution (5 ℃~15 ℃) dissolution dispersity, under magnetic agitation, add respectively 1# to 8# concentrated solution among the embodiment 1 in the cold water according to extension rate, the dissolving jitter time of record dissolve complete, the results are shown in Table 4, can both dilute dissolve complete at three minutes with interior concentrated solution, visible concentrated solution of the present invention can dissolve dispersion fast in cold water, and forms stable diluting emulsion.
Table 4. dissolving jitter time (S)
Embodiment 5
Skinfeel evaluation after the concentrated solution dilution.After 20 times of 1# to 8# concentrated solution dilutions among the embodiment 1, add 0.2% allantoin, non-woven fabrics adopts spun-laced nonwoven fabric, and the immersion amount is 4 times of dried towel weight.The contrast sample is selected Johnson ﹠ Johnson's board baby wet tissue (milk doubly moistens) on the market.Select 10 of healthy volunteers, subject age is distributed as 25~35 years old, and tested position skin (left hand inboard arm) is without unusual.To in the use procedure and the smooth sense after using, moist feeling, clearly sense and sticky sense are estimated, and estimate minute seven grades, interval 25 minutes, total points 150 is averaged at last, the results are shown in Table 5 and Fig. 1.As seen from Figure 1, diluent of the present invention has good smooth sense, moist feeling and salubrious sense, has simultaneously low sticky sense, can bring baby's skin extraordinary use skinfeel.
Table 5. skinfeel evaluating data (meansigma methods)
Contain the preparation method of the infant skin care product of concentrated solution, comprising: a) get the used material of infant skin care product (non-woven fabrics, cotton etc.) ready; B) with on 20~300 times of rear coatings of 1# to 8# concentrated solution dilution or immersion and the material among the embodiment 1; C) be prepared into the infant skin care product.Prepared infant skin care product is as shown in table 6.
Table 6. infant skin care product
Claims (26)
1. the concentrated solution for the preparation of the infant skin care product is characterized in that, described concentrated solution comprises:
A) the nonionic emulsifier component of 0.1~20 % by weight;
B) the oil preparation component of 0.1~15 % by weight;
C) the water preparation component of 50~99 % by weight;
D) the co-emulsifier component of 0.1~10 % by weight;
E) the functional additive component of 0.1~6 % by weight;
C in the described concentrated solution) the water preparation component is water-soluble component, is selected from the mixture of a kind of in xanthan gum, EDETATE SODIUM, triethanolamine, hydroxy methocel, hydroxypropyl emthylcellulose, hydroxyethyl-cellulose, polyvinyl methyl ether/maleic anhydride, hyaluronate sodium, carbomer, the bisabolol or at least two kinds and distilled water;
D in the described concentrated solution) the co-emulsifier component is two kinds or at least three kinds mixture in C16~18 alcohol, glycerol, propylene glycol, butanediol, pentanediol, ethohexadiol, the erythrol;
E in the described concentrated solution) functional additive is antiseptic and the antiallergic factor;
Described antiseptic is the hydroxyphenyl methyl ester, hydroxyphenyl ethyl ester, two kinds or at least three kinds of mixture in hydroxyphenyl propyl ester, hydroxyphenyl butyl ester, hydroxyphenyl isobutyl ester, phenoxyethanol, Methylisothiazolinone, the Sensiva SC50;
The described antiallergic factor is the mixture of a kind of in allantoin, cactus extraction, the Flos Matricariae chamomillae extracting solution or at least two kinds.
2. concentrated solution according to claim 1 is characterized in that, A in the described concentrated solution) nonionic emulsifier is the nonionic emulsifier of ethoxylation.
3. concentrated solution according to claim 2, it is characterized in that A in the described concentrated solution) nonionic emulsifier is the mixture of a kind of in ceteareth-2, ceteareth-6, ceteareth-10, ceteareth-11, ceteareth-20, ceteareth-21, ceteareth-25, ceteareth-30, ethoxylation methyl glucoside stearate, the ethoxylated glycerol monostearate or at least two kinds.
4. concentrated solution according to claim 1 is characterized in that, A in the described concentrated solution) nonionic emulsifier also comprises glycerol monostearate.
5. concentrated solution according to claim 1, it is characterized in that, B in the described concentrated solution) the oil preparation component is water-fast component, is selected from the mixture of a kind of in olive oil, Oleum Ricini, almond oil, mink oil, white oil, Miglyol 812N, Ethylhexyl stearate, glycerol monostearate, dimethicone, the methyl-silicone oil or at least two kinds.
6. arbitrary described concentrated solution is characterized in that according to claim 1~5, and the weight ratio of described antiseptic and the antiallergic factor is 15:1~1:60.
7. concentrated solution according to claim 6 is characterized in that, the weight ratio of described antiseptic and the antiallergic factor is 10:1~1:50.
8. concentrated solution according to claim 6 is characterized in that, the weight ratio of described antiseptic and the antiallergic factor is 6:1~1:40.
9. arbitrary described concentrated solution is characterized in that according to claim 1~5, A in the described concentrated solution) the nonionic emulsifier % by weight is 0.4~15.
10. concentrated solution according to claim 9 is characterized in that, A in the described concentrated solution) the nonionic emulsifier % by weight is 1~12.
11. arbitrary described concentrated solution is characterized in that according to claim 1~5, B in the described concentrated solution) the oil preparation % by weight is 0.4~12.
12. concentrated solution according to claim 11 is characterized in that, B in the described concentrated solution) the oil preparation % by weight is 1~10.
13. arbitrary described concentrated solution is characterized in that according to claim 1~5, C in the described concentrated solution) the water preparation % by weight is 62~90.
14. arbitrary described concentrated solution is characterized in that according to claim 1~5, D in the described concentrated solution) the co-emulsifier % by weight is 0.4~8.
15. concentrated solution according to claim 14 is characterized in that, D in the described concentrated solution) the co-emulsifier % by weight is 1~5.
16. arbitrary described concentrated solution is characterized in that according to claim 1~5, E in the described concentrated solution) the functional additive % by weight is 0.2~5.
17. arbitrary described concentrated solution is characterized in that according to claim 1~5, preparation method is 1. with A), B), D) and E) the antiseptic mixing post-heating to 80 in the component ℃, insulation half an hour, use as oil phase; 2. with C) component is heated to 80 ℃, insulation half an hour, uses as water; 3. after emulsion tank was heated to 80 ℃, the water with 2/3 added emulsion tank, then with the whole suction of oil phase, and again with remaining water suction, high-speed stirred, homogenizing 5~10 minutes, emulsifying is complete, is incubated half an hour; Be cooled to after 40 ℃ and add E) anti-sensitizer in the component.
18. arbitrary described concentrated solution is for the preparation of the purposes of infant skin care product according to claim 1~5.
19. an infant skin care product that contains concentrated solution is characterized in that, described concentrated solution is the arbitrary described concentrated solution of claim 1~5.
20. an infant skin care product that contains concentrated solution is characterized in that, described concentrated solution is claim 6,10,11,14 arbitrary described concentrated solutions.
21. infant skin care product according to claim 18 is characterized in that, A in the described concentrated solution) the nonionic emulsifier % by weight is 0.4~15.
22. infant skin care product according to claim 18 is characterized in that, B in the described concentrated solution) the oil preparation % by weight is 0.4~12.
23. infant skin care product according to claim 18 is characterized in that, C in the described concentrated solution) the water preparation % by weight is 62~90.
24. infant skin care product according to claim 18 is characterized in that, D in the described concentrated solution) the co-emulsifier % by weight is 0.4~8.
25. infant skin care product according to claim 18 is characterized in that, E in the described concentrated solution) the functional additive % by weight is 0.2~5.
26. a preparation method that contains the infant skin care product of concentrated solution comprises: a) get infant skin care product material ready; B) apply or be soaked on the material with after 20~300 times of the described concentrated solution dilutions; C) be prepared into the infant skin care product; Described concentrated solution is the arbitrary described concentrated solution of claim 1~5.
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BR112015003869A2 (en) * | 2012-08-28 | 2017-07-04 | Basf Se | preservative mixtures and polymer solutions stabilized with those preservative mixtures |
CN103549909B (en) * | 2013-10-17 | 2017-01-04 | 海门黄海创业园服务有限公司 | A kind of biodegradable antibacterial wet tissue |
CN104287668A (en) * | 2014-04-09 | 2015-01-21 | 付强 | Formula and using method of infant wet tissue substitute |
CN104562652B (en) * | 2015-01-23 | 2018-09-28 | 张子剑 | A kind of spun-bonded non-woven fabrics with preventing diaper dermatitis function |
CN104594031B (en) * | 2015-01-23 | 2018-09-28 | 张子剑 | A kind of spun-bonded non-woven fabrics finishing agent with preventing diaper dermatitis function |
CN106880540A (en) * | 2015-12-16 | 2017-06-23 | 上海大萱化妆品有限公司 | It is a kind of with hypo-allergenic and maintenance effect cosmetic formulations |
CN106137863B (en) * | 2016-08-19 | 2019-01-18 | 澳思美日用化工(广州)有限公司 | A kind of infant's multiple-effect skin lotion |
CN107184506A (en) * | 2017-05-09 | 2017-09-22 | 丹东康齿灵保洁用品有限公司 | It is for baby to prevent chapped antifreeze frost and preparation method thereof |
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DE102006004353A1 (en) * | 2006-01-30 | 2007-08-02 | Goldschmidt Gmbh | Cold-preparable, low-viscosity and long-term stable cosmetic emulsions |
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