CN106727133A - A kind of shower cream and preparation method thereof - Google Patents

A kind of shower cream and preparation method thereof Download PDF

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Publication number
CN106727133A
CN106727133A CN201611209731.2A CN201611209731A CN106727133A CN 106727133 A CN106727133 A CN 106727133A CN 201611209731 A CN201611209731 A CN 201611209731A CN 106727133 A CN106727133 A CN 106727133A
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China
Prior art keywords
shower cream
preparation
apg
aloe
solution
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CN201611209731.2A
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Chinese (zh)
Inventor
胡波
钟勇财
谢玉国
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JIANGXI YIXINTANG MEDICAL TECHNOLOGY Co Ltd
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JIANGXI YIXINTANG MEDICAL TECHNOLOGY Co Ltd
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Priority to CN201611209731.2A priority Critical patent/CN106727133A/en
Publication of CN106727133A publication Critical patent/CN106727133A/en
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/63Steroids; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42Amides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60Sugars; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60Sugars; Derivatives thereof
    • A61K8/602Glycosides, e.g. rutin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/737Galactomannans, e.g. guar; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/005Antimicrobial preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • A61K2800/592Mixtures of compounds complementing their respective functions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/70Biological properties of the composition as a whole
    • A61K2800/72Hypo-allergenic

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Dermatology (AREA)
  • Engineering & Computer Science (AREA)
  • Biotechnology (AREA)
  • Botany (AREA)
  • Microbiology (AREA)
  • Mycology (AREA)
  • Cosmetics (AREA)

Abstract

The invention belongs to daily chemical product field, and in particular to a kind of shower cream and preparation method thereof.The shower cream that the present invention is provided includes following components and its percentage by weight:Tea Saponin 15 25%, APG 15 25%, cocoyl isethionate 4 12%, dodecanamide propyl amine oxide 2 8%, cation guar gum 0.1 0.5%, sucrose fatty ester 1 10%, extract solution from aloe 4 10%, essence 0.1 0.3%, pH adjusting agent 0.05 0.15% and deionized water 9.05 58.75%.The formula of bath cream that the present invention is provided is reasonable, and raw material green safety is renewable, and human body is had no toxic side effect.Meanwhile, the shower cream moderate performance that the present invention is provided can alleviate the dry and astringent of skin, effectively suppress itch, have functions that bactericidal, anti-inflammatory anti-itch, have auxiliary therapeutic action to fash, prickly heat.

Description

A kind of shower cream and preparation method thereof
Technical field
The invention belongs to daily chemical product field, and in particular to a kind of shower cream and preparation method thereof.
Background technology
Tea Saponin is a kind of excellent natural green product, belongs to nonionic surfactant, steady with decontamination, foaming The surface propertys such as bubble, emulsification, wetting.Degradable, performance itself is soft simultaneously, and the aqueous solution is in subacidity.Early there is scholar from tea Tree different parts are extracted isolates Tea Saponin, and carries out experiment in vitro using Tea Saponin, find all to have it is certain anti-oxidant and Anti-inflammatory performance.
Traditional surfactant shower cream is main by fatty alcohol polyoxyethylene ether sulfate (AES) and glycine betaine or fat Sour soap composition, but because AES adsorptivities are strong, still have soapy feeling, the sordid sensation of flushing after crossing water, and also AES products are in mistake Cheng Zhonghui produces diox accessory substance, diox to belong to noxious material, can be irritant to skin, eye and respiratory system, and And liver, kidney and nervous system may be caused damage, long-term use is also possible to can be carcinogenic;Though present fatty acid soaps fundamental mode shower cream Right washability is good, but because its alkalescence is stronger, it is larger to skin irritation, dry and astringent, tight, itch is easily caused after washing.
Chinese patent application 201310304739.7 discloses a kind of tea saponin bath lotion and preparation method thereof, and the tea soap is washed one's hair Bath lotion includes tea soap Essence and auxiliary agent, and the shower cream for preparing has functions that moisturizing, skin care, moisturizing, impervious, anti-inflammatory. But there is after shower cream crosses water still has soapy feeling, rinses sordid problem.And used petrochemical industry in the invention The surfactant base (Sulfonates anion surfactant) of synthesis, has the secondary work of certain poison to the body and skin of people With and irritation effect.
Chinese patent CN103637963B discloses a kind of shower cream, and the shower cream is by Tea Saponin, APG, bay LAO, fatty acid potassium soap, cation guar gum, sucrose fatty ester, extract solution from aloe and other safety are helped Agent is formulated, and the shower cream for preparing is to alleviating that skin is dry and astringent, bactericidal, anti-inflammatory have certain curative effect.Make in the invention Fatty acid potassium soap alkalescence is stronger, although eliminate this defect with after APG, the cooperation of dodecanamide propyl amine oxide grams, But still have certain excitant to the skin of people.
The content of the invention
It is an object of the invention to overcome shower cream to cross still to have after water soapy feeling, punching not to wash clean, dry and astringent, tight, itch Problem, there is provided a kind of foaming abundancy, easily rinse and moderate performance, anti-inflammatory anti-itch be sterilized, the green of safe clean skin and skin care The shower cream of safety.
The invention provides a kind of shower cream, including following components and its percentage by weight:
Tea Saponin 15-25%, APG 15-25%, cocoyl isethionate 4-12%, dodecanamide propyl oxygen Change amine 2-8%, cation guar gum 0.1-0.5%, sucrose fatty ester 1-10%, extract solution from aloe 4-10%, essence 0.1- 0.3%th, pH adjusting agent 0.05-0.15% and deionized water 9.05-58.75%.Tea Saponin is purchased from Hunan Lang Lin biological products to be had Limit company, APG is purchased from Guangzhou Jian Chuan bio tech ltd, cocoyl isethionate CAS NO:61789- 32-0, cation guar gum is purchased from Anhui Zhong Xu bio tech ltd, and it is remote into creating section that sucrose fatty ester is purchased from Wuhan Skill Co., Ltd, extract solution from aloe is purchased from Xi'an Rui Ying bio tech ltd.
Further, described shower cream is made up of following components and its percentage by weight:
Tea Saponin 20%, APG 20%, cocoyl isethionate 8%, dodecanamide propyl amine oxide 5%, Cation guar gum 0.2%, sucrose fatty ester 5%, extract solution from aloe 8%, essence 0.15%, pH adjusting agent 0.1% and go Ionized water 33.55%.
The shower cream that the present invention is provided, each component is mutually cooperateed with, and enriches foam, and moderate performance, can alleviate the dry of skin It is puckery, effectively suppress itch, there is bactericidal, anti-inflammatory anti-itch.
In addition, present invention also offers a kind of preparation method of shower cream, it is characterised in that comprise the following steps:
Be placed in deionized water in batch can by S1, is heated to 50 DEG C, and cation guar gum and sucrose fat are added while stirring Acid esters, continues to be heated to 70-90 DEG C, and stirring and dissolving obtains solution A;
At 70-90 DEG C of S2 constant temperature, to addition Tea Saponin, dodecanamide propyl amine oxide and APG in the solution A Dissolving is evenly stirred until, cocoyl isethionate is added, stirred, obtain solution B;
The solution B is cooled to 20-40 DEG C by S3, and extract solution from aloe and essence are added while stirring, is uniformly mixed, It is 6.0-6.5 to adjust pH with pH adjusting agent again, is obtained final product.
Further, the temperature of heating is continued in the step S1 for 80 DEG C, the temperature cooled down in step S3 is 30 DEG C.
Further, pH is 6.3 in the step S3.
APG (APG), is synthesized by renewable resource natural fat alcohol and glucose, is that a kind of performance is more comprehensive New non-ionic surfactants, have the characteristic of conventional nonionic and anion surfactant concurrently, with high surface, Good ecological security and intermiscibility, is internationally recognized first-selection " green " functional surfactant.APG is nontoxic, to skin Skin stimulates small, safety, and thickening, thickening, detergency significantly, can produce foam that is abundant tight and being rich in steam, and foam is more thin It is greasy.
Dodecanamide propyl amine oxide is a kind of special nonionic surfactant, is prepared by natural oil, is green The surfactant of safety, while the also property with amphoteric surfactant.Not only there is good thickening, antistatic, soft Soft, foam enhancing, foam stabilizing and detergency ability, also with sterilized, anticalcium soap ability and biological degradability is good.
Cocoyl isethionate is prepared by natural coconut oleic acid, and its characteristic is extremely gentle, efficient, excitant is low, Foam is fine and smooth abundant, wash rear skin emolliency, it is smooth, have silk-like feeling.And cocoyl isethionate belongs to green, peace Full natural surfactant.
Sucrose fatty ester is edible nonionic surfactant prepared by a kind of natural material, in this invention may be used Play a part of to thicken foam stabilizing.
Cation guar gum is to be derived by natural guars and obtained, and main component is galactolipin and mannose, with preferable Skin care effect and thickening effect.
Extract solution from aloe is extracted by aloe and obtain, natural moisturizing water lock effect, anti-inflammatory and sterilization, and promotion wound is healed Cooperation is used, because having protective effect to skin rich in polysaccharide.
The mixture energy of APG, dodecanamide propyl amine oxide, cocoyl isethionate in instant component Enough and Tea Saponin plays good cooperative effect, maximizes and plays clean skin bactericidal effect, no longer adds any preservative.Together When, the compatibility of each component of the present invention rationally, science, mutually collaboration can effectively increase cleaning, moist, smooth and anti-inflammatory and stop The effect itched.
Compared with prior art, the shower cream that the present invention is provided, has the advantage that:
(1) shower cream that the present invention is provided, raw material sources green is renewable, and formula is reasonable, and dirt-removing power is moderate, spumescence Can be preferably;
(2) shower cream that the present invention is provided, moderate performance can alleviate dry and astringent, the tight feeling of skin after shower, effectively suppress Itch, and to the nutritious moisten effect of skin, long-term use can make skin tender;
(3) shower cream that the present invention is provided, energy bactericidal, anti-inflammatory anti-itch, has auxiliary therapeutic action to fash, prickly heat.
Specific embodiment
The present invention is described in further details below by specific embodiment, these embodiments are only used for the mesh of illustration , it is in no way intended to limit protection scope of the present invention.
A kind of preparation of the shower cream of embodiment 1
The shower cream is made up of following components and its percentage by weight:
Tea Saponin 15%, APG 15%, cocoyl isethionate 4%, dodecanamide propyl amine oxide 2%, Cation guar gum 0.1%, sucrose fatty ester 1%, extract solution from aloe 4%, essence 0.1%, pH adjusting agent 0.05% and go Ionized water 58.75%.
Preparation method:
Be placed in deionized water in batch can by S1, is heated to 50 DEG C, and cation guar gum and sucrose fat are added while stirring Acid esters, continues to be heated to 80 DEG C, and stirring and dissolving obtains solution A;
At 80 DEG C of S2 constant temperature, stirred to Tea Saponin, dodecanamide propyl amine oxide and APG is added in the solution A It is uniform to add cocoyl isethionate to dissolving, stir, obtain solution B;
The solution B is cooled to 30 DEG C by S3, and extract solution from aloe and essence are added while stirring, is uniformly mixed, then It is 6.3 to adjust pH with pH adjusting agent, is obtained final product.
A kind of preparation of the shower cream of embodiment 2
The shower cream is made up of following components and its percentage by weight:
Tea Saponin 20%, APG 20%, cocoyl isethionate 8%, dodecanamide propyl amine oxide 5%, Cation guar gum 0.2%, sucrose fatty ester 5%, extract solution from aloe 8%, essence 0.15%, pH adjusting agent 0.1% and go Ionized water 33.55%.
Preparation method is similar to Example 1.
A kind of preparation of the shower cream of embodiment 3
The shower cream is made up of following components and its percentage by weight:
Tea Saponin 25%, APG 25%, cocoyl isethionate 12%, dodecanamide propyl amine oxide 8%, Cation guar gum 0.5%, sucrose fatty ester 10%, extract solution from aloe 10%, essence 0.3%, the and of pH adjusting agent 0.15% Deionized water 9.05%.
Preparation method is similar to Example 1.
A kind of preparation of the shower cream of comparative example 1
The shower cream is made up of following components and its percentage by weight:
Tea Saponin 20%, APG 20%, dodecanamide propyl amine oxide 13%, cation guar gum 0.2%, sucrose Fatty acid ester 5%, extract solution from aloe 8%, essence 0.15%, pH adjusting agent 0.1% and deionized water 33.55%.
Preparation method is similar to Example 1.
Difference with embodiment 2 is, without addition cocoyl isethionate, increased dodecanamide propyl oxidation The consumption of amine.
A kind of preparation of the shower cream of comparative example 2
The shower cream is made up of following components and its percentage by weight:
Tea Saponin 20%, APG 20%, fatty acid potassium soap 8%, dodecanamide propyl amine oxide 5%,
Cation guar gum 0.2%, sucrose fatty ester 5%, extract solution from aloe 8%, essence 0.15%, pH adjusting agent 0.1% and deionized water 33.55%.
Preparation method is similar to Example 1.
Difference with embodiment 2 is that cocoyl isethionate is replaced with into fatty acid potassium soap.
Test example one, performance test
According to GB/T13174-2008 detergency test methods, the shower cream prepared to embodiment 1-3 and comparative example 1-2 Dirt-removing power is tested, and test result is shown in Table 1.
According to GB/T13173.6-2000 detergent foam power assay methods, with Roche brbble test embodiment 1-3 and right The foam height of shower cream prepared by ratio 1-2, test result is shown in Table 1.
The dirt-removing power of table 1 and foam height are tested
Known by table 1, shower cream dirt-removing power and foam height prepared by the present invention is preferable.And comparative example 1-2 prepare wash one's hair The dirt-removing power and foam height of bath lotion are poorer than the effect of shower cream prepared by embodiment of the present invention 1-3, illustrate compatibility of the present invention Rationally, science, each component collaboration improves dirt-removing power and foam height.
Test example two, skin irritation test
1. test material:Shower cream prepared by embodiment 1-3 and comparative example 1-2.
2. subjects:Choose healthy guinea pig 100, body weight 250-300g, male and female half and half.Rearing conditions:Temperature is 20- 24 DEG C, relative humidity is 60-70%, natural lighting, ad lib, drinking-water.
3. content of the test:Randomized be divided into 1 group of 5 groups, i.e. 1 group of embodiment, 2 groups of embodiment, 3 groups of embodiment and comparative example, 2 groups of comparative example, every group 20.Corresponding shower cream is smeared respectively, once a day, continuous 1 month.
3. result of the test:Testing result is shown in Table 2, and the shower cream that the present invention is provided is low to skin irritation.
Excitant of the table 2 to skin
Group Number of animals (only) Erythema, oedema (%)
1 group of embodiment 20 0
2 groups of embodiment 20 0
3 groups of embodiment 20 5
1 group of comparative example 20 15
2 groups of comparative example 20 20
Known by table 2, shower cream prepared by the present invention is low to skin irritation.And the excitant of comparative example 1-2 is than the present invention The effect of shower cream prepared by embodiment 1-3 is strong, illustrate that compatibility of the present invention is reasonable, science, and each component is cooperateed with, so as to eliminate or drop The low excitant to skin.

Claims (5)

1. a kind of shower cream, it is characterised in that including following components and its percentage by weight:
Tea Saponin 15-25%, APG 15-25%, cocoyl isethionate 4-12%, dodecanamide propyl amine oxide 2-8%, cation guar gum 0.1-0.5%, sucrose fatty ester 1-10%, extract solution from aloe 4-10%, essence 0.1- 0.3%th, pH adjusting agent 0.05-0.15% and deionized water 9.05-58.75%.
2. shower cream according to claim 1, it is characterised in that be made up of following components and its percentage by weight:
Tea Saponin 20%, APG 20%, cocoyl isethionate 8%, dodecanamide propyl amine oxide 5%, sun from Sub- guar gum 0.2%, sucrose fatty ester 5%, extract solution from aloe 8%, essence 0.15%, pH adjusting agent 0.1% and deionization Water 33.55%.
3. the preparation method of shower cream according to claim 1 and 2, it is characterised in that comprise the following steps:
Be placed in deionized water in batch can by S1, is heated to 50 DEG C, and cation guar gum and sucrose fatty ester are added while stirring, Continue to be heated to 70-90 DEG C, stirring and dissolving obtains solution A;
At 70-90 DEG C of S2 constant temperature, stirred to Tea Saponin, dodecanamide propyl amine oxide and APG is added in the solution A It is uniform to add cocoyl isethionate to dissolving, stir, obtain solution B;
The solution B is cooled to 20-40 DEG C by S3, and extract solution from aloe and essence are added while stirring, is uniformly mixed, then use PH adjusting agent regulation pH is 6.0-6.5, is obtained final product.
4. the preparation method of shower cream according to claim 3, it is characterised in that continue the temperature of heating in the step S1 It is 80 DEG C to spend, and the temperature cooled down in step S3 is 30 DEG C.
5. the preparation method of shower cream according to claim 3, it is characterised in that the pH value in the step S3 is 6.3.
CN201611209731.2A 2016-12-23 2016-12-23 A kind of shower cream and preparation method thereof Withdrawn CN106727133A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107789215A (en) * 2017-12-04 2018-03-13 胡江宇 A kind of preparation method of Astragaloside IV bath foam
CN107822995A (en) * 2017-12-06 2018-03-23 佛山早稻田科技服务有限公司 A kind of environmentally friendly shower cream
CN108004069A (en) * 2017-12-26 2018-05-08 洛阳神佳窑业有限公司 A kind of bath dew for baby
CN112220735A (en) * 2020-11-19 2021-01-15 聂绪明 EM (effective microorganism) fungus shower gel and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103637963A (en) * 2013-12-20 2014-03-19 黄山市徽山生物科技有限公司 Shower gel
CN103637964A (en) * 2013-12-20 2014-03-19 黄山市徽山生物科技有限公司 Preparation method of shower gel
CN105616250A (en) * 2014-11-07 2016-06-01 赵燕 Bath lotion

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103637963A (en) * 2013-12-20 2014-03-19 黄山市徽山生物科技有限公司 Shower gel
CN103637964A (en) * 2013-12-20 2014-03-19 黄山市徽山生物科技有限公司 Preparation method of shower gel
CN105616250A (en) * 2014-11-07 2016-06-01 赵燕 Bath lotion

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107789215A (en) * 2017-12-04 2018-03-13 胡江宇 A kind of preparation method of Astragaloside IV bath foam
CN107822995A (en) * 2017-12-06 2018-03-23 佛山早稻田科技服务有限公司 A kind of environmentally friendly shower cream
CN108004069A (en) * 2017-12-26 2018-05-08 洛阳神佳窑业有限公司 A kind of bath dew for baby
CN112220735A (en) * 2020-11-19 2021-01-15 聂绪明 EM (effective microorganism) fungus shower gel and preparation method thereof

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Application publication date: 20170531