CN111170763A - Ceramic glaze color fixative and preparation method thereof - Google Patents
Ceramic glaze color fixative and preparation method thereof Download PDFInfo
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- CN111170763A CN111170763A CN202010059078.6A CN202010059078A CN111170763A CN 111170763 A CN111170763 A CN 111170763A CN 202010059078 A CN202010059078 A CN 202010059078A CN 111170763 A CN111170763 A CN 111170763A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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Abstract
The invention discloses a ceramic glaze color fixative and a preparation method thereof. The invention adjusts the viscosity of the glaze color under the high temperature condition through the effective components of the ceramic color fixative, and prevents the color development effect of the pigment from being influenced by flowing or volatilization and the like caused by insufficient viscosity after the glaze color is melted under the high temperature. Meanwhile, the ceramic glaze has fluxing function when the glaze color is sintered at high temperature, thereby reducing the sintering temperature of the ceramic. The ceramic glaze color fixative provided by the invention can effectively prevent the phenomena of falling off, cracking, fading and the like of the glaze color at high temperature, and ensure that the color of the glaze color is uniform, the glaze color is bright and does not fade.
Description
Technical Field
The invention relates to the technical field of ceramics, in particular to a ceramic glaze color fixative and a preparation method thereof.
Background
The glaze color is an important material for decorating ceramic devices and also an important embodiment of the essence of Chinese traditional culture. According to different decoration modes, the decoration method can be divided into overglaze color, in-glaze color and underglaze color. Wherein the glaze coloring is formed by colored drawing on the fired porcelain and baking in a brocade kiln. Because the roasting temperature is not high and the treatment temperature is slightly low, the pigment which can withstand the temperature is many, and the color is most abundant. However, the pigment is easy to fall off to cause fading, which affects the beauty. Since the pigment is mainly heavy metal, the pigment may be released to cause heavy metal poisoning. The surface of the in-glaze color and the under-glaze color is coated with a layer of glaze, so that the migration or the leakage of the pigment can be prevented, and the safety is high. The in-glaze decoration and the under-glaze decoration are colored-painted under the glaze, namely, a layer of colorless transparent glaze is covered on the body after colored-painted, and the porcelain is fired at one time within the temperature range of 1300-1400 ℃. Because the color of the underglaze color is burnt at high temperature and can withstand high temperature, the color is not as rich as the color of the overglaze color. Under high temperature, a few of common colors such as blue-and-white, underglaze five-color and the like can exist stably, and most pigments cause serious fading phenomenon due to dissolution, decomposition or chemical reaction in the temperature range, so that the development and application of the ceramic decorative material are limited.
Disclosure of Invention
The invention aims to solve the technical problem of providing a color fixative for ceramic glaze colors aiming at the defect of the stability of the existing glaze colors at high temperature.
The invention also provides a preparation method of the ceramic glaze color fixative.
The purpose of the invention is realized by the following technical scheme:
the ceramic glaze color fixative mainly comprises strontium oxide, barium sulfate, and one or more of silicon oxide, ammonia water, alum and kaolin. The color fixative provided by the invention utilizes the effective components of strontium oxide and barium sulfate to adjust the viscosity of the glaze color under the high-temperature condition, and prevents the color development effect of the pigment from being influenced by flowing or volatilization and the like caused by insufficient viscosity after the glaze color is melted at high temperature. Meanwhile, the auxiliary components in the color fixative also have the fluxing function when the glaze color is sintered at high temperature, thereby reducing the sintering temperature of the ceramic.
Further, the silicon oxide includes one or more of sodium silicate, calcium silicate, aluminum silicate, and silicon dioxide.
Furthermore, the mass fractions of the raw materials of the ceramic glaze color fixative are 2-30 wt.% of strontium oxide, 5-15 wt.% of barium sulfate, 15-40 wt.% of silicon oxide, 10-30 wt.% of ammonia water, 1-7 wt.% of alum and 5-35 wt.% of kaolin.
Preferably, the mass fractions of the raw materials of the ceramic glaze color fixative are 5-20 wt.% of strontium oxide, 8-10 wt.% of barium sulfate, 20-30 wt.% of silicon oxide, 15-25 wt.% of ammonia water, 3-5 wt.% of alum and 15-30 wt.% of kaolin.
Further preferably, the mass fractions of the materials in the ceramic glaze color fixative are 15wt.% of strontium oxide, 8wt.% of barium sulfate, 23wt.% of silicon oxide, 20wt.% of ammonia water, 4wt.% of alum and 30wt.% of kaolin.
The preparation method of the ceramic glaze color fixative is provided, and the preparation steps comprise:
s1, weighing strontium oxide, barium sulfate and silicon oxide according to a raw material formula ratio, uniformly mixing, adding water to dissolve and preparing into a suspension;
s2, adding ammonia water into the solution of the S1, fully and uniformly stirring to form colloid, centrifuging to obtain slurry, mixing the slurry with alum and kaolin according to the raw material proportion, adding alcohol, and uniformly stirring to obtain a mixture;
and S3, sintering the mixture obtained in the step S2 at a high temperature, and grinding to obtain the powdery ceramic glaze color fixative.
Further, the amount of water added in S1 is 1 to 5 times of the mass of the raw material, and preferably 3 times of the mass of the raw material.
Further, the concentration of the ammonia water in S2 is 10-18%, and preferably, the concentration of the ammonia water is 15%.
Further, the temperature of the high-temperature sintering of S3 is 400-900 ℃, and the time is 30-60 min. Preferably, the high-temperature sintering temperature is 620 ℃ and the time is 45 min.
The color fixative for ceramic glaze color can be used for firing the in-glaze color and the under-glaze color of the ceramic, the color fixative for ceramic glaze color is mixed with the ceramic pigment according to the proportion, and the ceramic glaze color with pure color and fastness can be obtained according to the conventional ceramic coloring and firing.
Compared with the prior art, the beneficial effects are:
the invention creatively takes strontium oxide and barium sulfate as main materials to prepare the ceramic glaze color fixative which can enhance the adhesion of glaze color and blank materials, and after the ceramic glaze color fixative is mixed with the glaze color, the viscosity of the glaze color under the high temperature condition is adjusted, the pigment color development effect is prevented from being influenced by flowing or volatilization and the like caused by insufficient viscosity after the glaze color is melted at high temperature, so that the color stability of the in-glaze color and the under-glaze color is kept at 1300 ℃. Meanwhile, the invention further adds substances such as silicon oxide, alum, kaolin and the like, improves the stability of the color fixative to the glaze color at high temperature, enhances the adhesion of the glaze color and the blank, and effectively improves the fluxing action when the glaze color is sintered at high temperature, thereby reducing the sintering temperature of ceramics.
Drawings
FIG. 1 is a brown (mixed color) ceramic fired with the addition of a ceramic glaze color fixative;
FIG. 2 is a single color (blue) ceramic fired with the addition of a ceramic glaze color fixative;
FIG. 3 is a brown (mixed color) ceramic fired without the addition of a ceramic glaze color fixative;
FIG. 4 is a single color (blue) ceramic fired without the addition of a ceramic glaze color fixative;
FIG. 5 is a single color (blue) ceramic fired without the addition of strontium oxide to the color fixative of comparative example 1;
FIG. 6 shows a single-color (blue) ceramic fired without adding barium sulfate to the color fixative of comparative example 1.
Detailed Description
The following examples are further explained and illustrated, but the present invention is not limited in any way by the specific examples. Unless otherwise indicated, the methods and equipment used in the examples are conventional in the art and all materials used are conventional commercially available materials.
Example 1
The embodiment provides a ceramic glaze color fixative and a preparation method thereof, wherein the ceramic glaze color fixative comprises the following raw material formula:
| name (R) | Content (wt.%) | Name (R) | Content (wt.%) |
| Strontium oxide | 15 | Aqueous ammonia | 20 |
| Barium sulfate | 8 | Alum | 4 |
| Sodium silicate | 23 | Kaolin clay | 30 |
The preparation method comprises the following steps:
s1, weighing strontium oxide, barium sulfate and sodium silicate according to a raw material formula ratio, uniformly mixing, adding water with the mass of 3 raw materials, and dissolving to prepare a solution;
s2, adding ammonia water with the concentration of 15% into the solution of S1, uniformly stirring to obtain colloid, centrifuging to obtain slurry, mixing the slurry with alum and kaolin according to the raw material ratio, adding alcohol, and uniformly stirring to obtain a mixture;
s3, placing the mixture in the step S2 at a high temperature of 620 ℃ for sintering for 45min to obtain the powdery ceramic glaze color fixative.
Example 2
The embodiment provides a ceramic glaze color fixative and a preparation method thereof, wherein the ceramic glaze color fixative comprises the following raw material formula:
| name (R) | Content (wt.%) | Name (R) | Content (wt.%) |
| Strontium oxide | 12 | Aqueous ammonia | 20 |
| Barium sulfate | 8 | Alum | 3 |
| Calcium silicate | 30 | Kaolin clay | 27 |
The preparation method comprises the following steps:
s1, weighing strontium oxide, barium sulfate and calcium silicate according to a raw material formula ratio, uniformly mixing, adding 5 mass parts of water to dissolve, and preparing a solution;
s2, adding ammonia water with the concentration of 15% into the solution of S1, uniformly stirring to obtain colloid, centrifuging to obtain slurry, mixing the slurry with alum and kaolin according to the raw material ratio, adding alcohol, and uniformly stirring to obtain a mixture;
and S3, placing the mixture in the S2 at a high temperature of 900 ℃ for sintering for 30min to obtain the powdery ceramic glaze color fixative.
Example 3
The embodiment provides a ceramic glaze color fixative and a preparation method thereof, wherein the ceramic glaze color fixative comprises the following raw material formula:
| name (R) | Content (wt.%) | Name (R) | Content (wt.%) |
| Strontium oxide | 18 | Aqueous ammonia | 25 |
| Barium sulfate | 10 | Alum | 5 |
| Aluminium silicate | 22 | Kaolin clay | 30 |
The preparation method comprises the following steps:
s1, weighing strontium oxide, barium sulfate and aluminum silicate according to a raw material formula ratio, uniformly mixing, adding water with the mass of 3 raw materials, and dissolving to prepare a solution;
s2, adding ammonia water with the concentration of 18% into the solution of S1, uniformly stirring to obtain colloid, centrifuging to obtain slurry, mixing the slurry with alum and kaolin according to the raw material ratio, adding alcohol, and uniformly stirring to obtain a mixture;
and S3, placing the mixture in the S2 at a high temperature of 400 ℃ for sintering for 60min to obtain the powdery ceramic glaze color fixative.
Example 4
The embodiment provides a ceramic glaze color fixative and a preparation method thereof, wherein the ceramic glaze color fixative comprises the following raw material formula:
the preparation method comprises the following steps:
s1, weighing strontium oxide, barium sulfate and silicon dioxide according to a raw material formula ratio, uniformly mixing, adding water with the mass of 3 raw materials, and dissolving to prepare a solution;
s2, adding 10% ammonia water into the solution of S1, uniformly stirring to obtain a colloid, centrifuging to obtain slurry, mixing the slurry with alum and kaolin according to the raw material ratio, adding alcohol, and uniformly stirring to obtain a mixture;
s3, placing the mixture in the step S2 at a high temperature of 620 ℃ for sintering for 45min to obtain the powdery ceramic glaze color fixative.
Example 5
The embodiment provides a ceramic glaze color fixative and a preparation method thereof, wherein the ceramic glaze color fixative comprises the following raw material formula:
| name (R) | Content (wt.%) | Name (R) | Content (wt.%) |
| Strontium oxide | 12 | Aqueous ammonia | 21 |
| Barium sulfate | 9 | Alum | 5 |
| Sodium silicate | 28 | Kaolin clay | 25 |
The preparation method comprises the following steps:
s1, weighing strontium oxide, barium sulfate and sodium silicate according to a raw material formula ratio, uniformly mixing, adding water with the mass of 1 raw material, and dissolving to prepare a solution;
s2, adding ammonia water with the concentration of 15% into the solution of S1, uniformly stirring to obtain colloid, centrifuging to obtain slurry, mixing the slurry with alum and kaolin according to the raw material ratio, adding alcohol, and uniformly stirring to obtain a mixture;
s3, placing the mixture in the step S2 at a high temperature of 620 ℃ for sintering for 45min to obtain the powdery ceramic glaze color fixative.
Comparative example 1
This comparative example is identical to example 1 in raw materials and preparation process, except that strontium oxide was not added.
Comparative example 2
This comparative example is identical to the raw material and preparation process of example 1, except that barium sulfate was not added.
The color fixative for ceramic glaze color prepared in example 1 is mixed with brown glaze color and blue glaze color respectively, and the mixture is coated on the blank by using the color fixative for ceramic glaze color as the contrast, and the blank is fired into ceramic at the high temperature of about 1300 ℃ and then is taken out for comparison.
As shown in the figures 1-4, the glaze color added with the ceramic glaze color fixative still sticks to the blank after being fired at high temperature, and has no shedding and cracking phenomena. In addition, the color of the glaze is uniform, bright and fadeless by adding the ceramic glaze color protecting agent. The control group without the ceramic glaze color fixative adopts brown glaze color (i.e. color mixing) because part of the glaze color has better compatibility with the ceramic body at high temperature, cracks appear and the decoloration condition is relatively light. The blue glaze color (i.e. single color) has relatively single component and poor compatibility of the main component and the ceramic body, so that the fired ceramic glaze color is not firm in coloring, not only has a cracking phenomenon, but also has a large area of glaze color falling off.
The color fixative prepared in comparative example 1 and comparative example 2 is mixed with blue glaze respectively, and the blue glaze prepared by the lack of strontium oxide component in comparative example 1 has large-area crack and falling-off phenomenon. Cracking and micro-flaking of the blue enamel prepared with the barium sulfate lacking component of comparative example 2. Further firing with the brown enamel and the color fixative in comparative example 1 and comparative example 2, respectively, the black enamel exhibited better cracking and peeling than the blue enamel, but slight peeling and cracking remained, and the use of the color fixative in comparative example 1 had a slightly more number of defects. Both strontium oxide and barium sulfate have certain functions in the invention, wherein the strontium oxide function is the most important, the combination of strontium oxide and barium sulfate has certain synergistic effect, and the color fixative provided by the invention can not affect the primary color, and is especially suitable for various pigments.
It should be understood that the above-described embodiments of the present invention are merely examples for clearly illustrating the present invention, and are not intended to limit the embodiments of the present invention. Other variations and modifications will be apparent to persons skilled in the art in light of the above description. And are neither required nor exhaustive of all embodiments. Any modification, equivalent replacement, and improvement made within the spirit and principle of the present invention should be included in the protection scope of the claims of the present invention.
Claims (10)
1. The ceramic glaze color fixative is characterized in that the ceramic glaze color fixative comprises raw materials of strontium oxide and barium sulfate.
2. The color fixative of claim 1, wherein the raw materials further comprise one or more of silicon oxide, ammonia, alum and kaolin.
3. The ceramic glaze color fixative of claim 2, wherein the silicon oxide comprises one or more of sodium silicate, calcium silicate, aluminum silicate, and silicon dioxide.
4. The ceramic glaze color fixative according to claim 1 or 2, wherein the mass fractions of the materials in the ceramic glaze color fixative are 2-30 wt.% strontium oxide, 5-15 wt.% barium sulfate, 15-40 wt.% silicon oxide, 10-30 wt.% ammonia water, 1-7 wt.% alum and 5-35 wt.% kaolin.
5. The color fixative for ceramic glaze colors according to claim 4, wherein the mass fractions of the materials in the color fixative for ceramic glaze colors are 5-20 wt.% strontium oxide, 8-10 wt.% barium sulfate, 20-30 wt.% silicon oxide, 15-25 wt.% ammonia, 3-5 wt.% alum and 15-30 wt.% kaolin.
6. The color fixative for ceramic glaze color of claim 5, wherein the mass fractions of the materials in the color fixative for ceramic glaze color are strontium oxide 15wt.%, barium sulfate 8wt.%, silicon oxide 23wt.%, ammonia water 20wt.%, alum 4wt.% and kaolin 30 wt.%.
7. The method for preparing the ceramic glaze color fixative as claimed in any one of claims 1 to 6, wherein the preparation step comprises:
s1, weighing strontium oxide, barium sulfate and sodium silicate according to a raw material formula ratio, uniformly mixing, and adding water to prepare a suspension;
s2, adding ammonia water into the solution of the S1, fully and uniformly stirring, centrifuging to obtain slurry, mixing the slurry with alum and kaolin according to the raw material proportion, adding alcohol, and uniformly stirring to obtain a mixture;
and S3, sintering the mixture obtained in the step S2 at a high temperature, and then grinding to obtain the powdery ceramic glaze color fixative.
8. The method for preparing the color fixative for ceramic glaze colors as claimed in claim 7, wherein the amount of water added in S1 is 1-5 times of the amount of the raw materials.
9. The method for preparing the color fixative for ceramic glaze colors as claimed in claim 7, wherein the concentration of the ammonia water of S2 is 10-18%.
10. The method for preparing the color fixative for ceramic glaze colors as claimed in claim 7, wherein the temperature of the high temperature sintering of S3 is 400-900 ℃ for 30-60 min.
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Cited By (2)
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| CN112239371A (en) * | 2020-08-25 | 2021-01-19 | 湖南工业大学 | Treating agent for improving surface wettability of ceramic blank and application method thereof |
| CN114874000A (en) * | 2022-05-23 | 2022-08-09 | 泉州市永春华亿艺品有限公司 | Glaze ceramic decoration based on crystal stripes and manufacturing method |
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| CN114874000A (en) * | 2022-05-23 | 2022-08-09 | 泉州市永春华亿艺品有限公司 | Glaze ceramic decoration based on crystal stripes and manufacturing method |
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Application publication date: 20200519 |