CN111133070A - Adhesive sheet - Google Patents
Adhesive sheet Download PDFInfo
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- CN111133070A CN111133070A CN201880061266.3A CN201880061266A CN111133070A CN 111133070 A CN111133070 A CN 111133070A CN 201880061266 A CN201880061266 A CN 201880061266A CN 111133070 A CN111133070 A CN 111133070A
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- Prior art keywords
- radiation
- irradiation
- pressure
- sensitive adhesive
- acrylic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
- C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/385—Acrylic polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/312—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Adhesive Tapes (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Provided is a pressure-sensitive adhesive sheet which can design the adhesive force of a pressure-sensitive adhesive layer before radiation irradiation so that it can be re-attached and thereafter unnecessary portions can be peeled off, and which can perform radiation irradiation to increase the adhesive force of necessary portions of the pressure-sensitive adhesive layer and remain as an attached article on an adherend and can peel off and remove unnecessary portions. Provided is a pressure-sensitive adhesive sheet having, on a substrate, an acrylic pressure-sensitive adhesive layer which increases the adhesive force by irradiation with radiation, the pressure-sensitive adhesive layer being formed from an acrylic pressure-sensitive adhesive derived from a raw material containing: (A) an active hydrogen-containing acrylic polymer, (B) a crosslinking agent, (C) a monofunctional acrylic monomer having no active hydrogen, and (D) a photoinitiator, and the adhesive force of the aforementioned adhesive layer is constituted as follows: the adhesive force before irradiation with radiation is 1N/25mm or less, the adhesive force after irradiation with radiation is 5N/25mm or more, and the adhesive force after irradiation with radiation is 5 times or more the adhesive force before irradiation with radiation.
Description
Technical Field
The present invention relates to a pressure-sensitive adhesive sheet (pressure-sensitive adhesive sheet) having a pressure-sensitive adhesive layer with a property of increasing adhesive strength by irradiation with radiation. More specifically, the present invention relates to a pressure-sensitive adhesive sheet comprising: the adhesive force of the pressure-sensitive adhesive layer before irradiation with radiation is designed to be such an extent that the pressure-sensitive adhesive layer can be reattached to an adherend, and the adhesive force of the radiation-irradiated portion after irradiation with radiation is increased, and the pressure-sensitive adhesive layer is firmly adhered to the adherend.
Background
Pressure-sensitive adhesive sheets that change the adhesive strength of a pressure-sensitive adhesive layer by irradiation with radiation such as ultraviolet rays are known, and are widely used in the field of IC chip production as dicing tapes and UV tapes, for example. The dicing tape and the UV tape have the following specific adhesive layers: has a characteristic that the adhesive force is reduced by irradiation with radiation such as ultraviolet rays. When the production of an IC chip is described as an example, the adhesive layer desirably has the following properties. That is, the pressure-sensitive adhesive layer before radiation irradiation has a sufficient adhesive force to fix the semiconductor wafer and the divided chips, and has a sufficient holding force to prevent the chips from being misaligned or scattered by receiving the cutting resistance of the high-speed rotating blade during dicing, and the adhesive force of the pressure-sensitive adhesive layer is reduced by radiation irradiation, so that the chips can be easily peeled without damaging the chips.
For example, patent documents 1 and 2 and the like have proposed various proposals relating to dicing tapes having an adhesive layer having the above-described characteristics. As described above, all of these have a characteristic of reducing the adhesive force of the pressure-sensitive adhesive layer after irradiation with radiation such as ultraviolet rays.
Documents of the prior art
Patent document
Patent document 1: japanese patent No. 2887274
Patent document 2: international publication No. 2014/061629
Disclosure of Invention
Problems to be solved by the invention
In view of the above-described technology, the present inventors considered that it would be effective if an adhesive layer having the following characteristics could be obtained, and conducted intensive studies. That is, it is considered effective to provide a pressure-sensitive adhesive sheet which changes its adhesive force by irradiation with radiation, which is performed in the conventional tape cutting technique, leaves a necessary portion of the pressure-sensitive adhesive layer after the pressure-sensitive adhesive sheet is attached to an adherend such as a film or glass, and can remove an unnecessary portion by irradiation with radiation such as ultraviolet rays.
However, in the course of the research, the pressure-sensitive adhesive compositions used in conventional dicing tapes have not provided the objective pressure-sensitive adhesive sheet. In the conventional dicing tape technique, since the semiconductor wafer, the divided chips, and the like are temporarily fixed (fixed) in a good state so as not to be displaced at the time of dicing, and then the adhesive force of a necessary portion is lowered to easily peel off the temporarily fixed (fixed) portion, the adhesive force of the pressure-sensitive adhesive layer does not change greatly by irradiation with radiation. That is, the adhesive force of the pressure-sensitive adhesive layer before irradiation with radiation in the related art cannot be firmly adhered to the adherend.
Therefore, in the case of a configuration in which a necessary portion of the psa sheet is left on an adherend and an unnecessary portion is irradiated with radiation to reduce the adhesive force of the adhesive layer by the conventional dicing tape technique, the psa sheet should be much stronger than the adhesive force required for temporary fixing (fixing) in the prior art, so that the adhesive force of the psa layer at the necessary portion left on the adherend is sufficient. However, if such an adhesive sheet is once applied, peeling becomes difficult. For example, when peeling is required for the purpose of alignment or the like, the adhesive remains on the adherend, or when the adherend is thin and easily broken like a polyimide film, the adherend is broken. On the other hand, when the pressure-sensitive adhesive sheet is attached to an adherend, troubles such as displacement and air bubble inclusion are inherent, and in view of workability and productivity, it is a necessary characteristic that the pressure-sensitive adhesive sheet can be reattached when faced with these troubles.
In view of the above points, the present inventors have recognized that it is very useful if the adhesive layer of the adhesive sheet can be designed as follows, and the use thereof can be expanded. That is, it is very useful if a pressure-sensitive adhesive sheet can be developed in which the pressure-sensitive adhesive layer before irradiation with radiation has such a degree of adhesive force that it can be re-attached and then finally peeled off and discarded, and the adhesive force of the pressure-sensitive adhesive layer at a necessary portion of the pressure-sensitive adhesive sheet to be left on an adherend is increased by irradiation with radiation, and the pressure-sensitive adhesive sheet can be sufficiently firmly attached. However, the conventional techniques have not considered at all that the adhesive strength of a pressure-sensitive adhesive layer which is weak and can be re-stuck is difficult to be changed to a high adhesive strength such that a necessary portion is firmly adhered to an adherend by irradiation with radiation when the adherend is free from adhesive residue and the film is not broken. According to the studies of the present inventors, it is not easy to change a weak adhesive force to a large adhesive force by irradiation with radiation.
Accordingly, an object of the present invention is to provide a pressure-sensitive adhesive sheet having a pressure-sensitive adhesive layer, which can be designed so that the pressure-sensitive adhesive layer before irradiation with radiation has a small adhesive force, so that it can be reattached when there is trouble such as misalignment, bubble inclusion, or the like, and thereafter unnecessary portions can be peeled off, and on the other hand, the adhesive force of the pressure-sensitive adhesive layer after irradiation can be increased by irradiation with radiation. Specifically, provided is an adhesive sheet having an adhesive agent layer which can increase the adhesive force of a necessary portion to remain on an adherend by irradiation with radiation and peel off and remove an unnecessary portion.
Means for solving the problems
The present inventors have intensively studied the problems of the above-mentioned prior art and found a structure of a pressure-sensitive adhesive capable of forming a pressure-sensitive adhesive layer comprising: the pressure-sensitive adhesive sheet having an acrylic pressure-sensitive adhesive layer has been achieved by irradiating a necessary portion with radiation to significantly increase the adhesive strength of the pressure-sensitive adhesive layer to at least 5 times the adhesive strength before radiation irradiation.
The above object is achieved by the following invention. Namely, the present invention provides:
[1] a pressure-sensitive adhesive sheet comprising an acrylic pressure-sensitive adhesive layer having an adhesive strength increased by irradiation with radiation on a substrate, wherein the acrylic pressure-sensitive adhesive layer is formed from an acrylic pressure-sensitive adhesive derived from a raw material containing: (A) an active hydrogen-containing acrylic polymer, (B) a crosslinking agent, (C) a monofunctional acrylic monomer having no active hydrogen, and (D) a photoinitiator (wherein use of a polyfunctional acrylic monomer in an amount exceeding 2 parts by mass relative to 100 parts by mass of the aforementioned (a) polymer is excluded), the adhesive force of the aforementioned acrylic adhesive layer is constituted in the following manner: the adhesive force before irradiation with radiation is 1N/25mm or less, the adhesive force after irradiation with radiation is 5N/25mm or more, and the adhesive force after irradiation with radiation is 5 times or more the adhesive force before irradiation with radiation.
Preferred embodiments of the present invention include the following pressure-sensitive adhesive sheets.
[2] The pressure-sensitive adhesive sheet according to the above [1], wherein when the pressure-sensitive adhesive force of the acrylic pressure-sensitive adhesive layer is a pressure-sensitive adhesive force to a polyimide film, the pressure-sensitive adhesive force before the irradiation of the radiation is 0.1 to 1N/25mm, and the pressure-sensitive adhesive force after the irradiation of the radiation is 5 to 20N/25 mm.
[3] The adhesive sheet according to the above [1] or [2], wherein the glass transition temperature (Tg) of the active hydrogen-containing acrylic polymer (A) is-70 ℃ to 0 ℃, the active hydrogen thereof is an active hydrogen-containing group of a carboxyl group and/or a hydroxyl group, and the monofunctional acrylic monomer (C) having no active hydrogen group is an alkylene oxide-modified acrylate.
[4] The adhesive sheet according to any one of the above [1] to [3], wherein the active hydrogen-containing acrylic polymer (A) is a copolymer formed from a raw material monomer in which a monomer (a2) that is copolymerizable and has active hydrogen in the molecule is blended in a range of 0.1 parts by mass or more and 7.0 parts by mass or less with respect to 100 parts by mass of a (meth) acrylate monomer (a 1).
[5] The adhesive sheet according to any one of the above [1] to [4], wherein the amount of the monofunctional acrylic monomer having no active hydrogen of the above (C) is 10 parts by mass or more and 100 parts by mass or less based on 100 parts by mass of the acrylic polymer containing an active hydrogen group of the (A).
ADVANTAGEOUS EFFECTS OF INVENTION
According to the present invention, there is provided: a pressure-sensitive adhesive sheet (pressure-sensitive adhesive sheet) in which the adhesive strength of the pressure-sensitive adhesive layer at the irradiated portion is significantly increased by irradiation with radiation such as ultraviolet rays as compared to before irradiation with radiation. According to the present invention, the psa sheet of the present invention has low adhesive strength before irradiation with radiation, and therefore can be reattached, resulting in accurate positioning and placement of the psa sheet. Further, there is provided: a pressure-sensitive adhesive sheet having a useful pressure-sensitive adhesive layer, which can remarkably increase the adhesive strength of a portion after irradiation by irradiating the pressure-sensitive adhesive layer of the necessary portion with radiation, and therefore, can easily remove an unnecessary portion from the pressure-sensitive adhesive sheet after arrangement while leaving only the necessary portion on an adherend.
Detailed Description
Next, the present invention will be described in further detail by referring to preferred embodiments for carrying out the present invention. In the claims and the specification of the present invention, the term of "(meth) acrylic acid" means both "acrylic acid" and "methacrylic acid", and the term of "(meth) acrylate" means both "acrylate" and "methacrylate".
The pressure-sensitive adhesive sheet of the present invention is characterized by having an acrylic pressure-sensitive adhesive layer on a substrate, the adhesive strength of which is increased by irradiation with radiation. The acrylic adhesive layer is formed from an acrylic adhesive derived from a starting material comprising: (A) an active hydrogen group-containing acrylic polymer, (B) a crosslinking agent, (C) a monofunctional acrylic monomer having no active hydrogen group, and (D) a photoinitiator (wherein use of a polyfunctional acrylic monomer in an amount exceeding 2 parts by mass relative to 100 parts by mass of the aforementioned (a) polymer is excluded). Further, the adhesive force of the acrylic adhesive layer is constituted as follows: the adhesive force before irradiation with radiation is 1N/25mm or less, the adhesive force after irradiation with radiation is 5N/25mm or more, and the adhesive force after irradiation with radiation is 5 times or more the adhesive force before irradiation with radiation. The raw material components of the acrylic adhesive used in the present invention and characterized in the present invention will be described below.
[ (A) acrylic Polymer containing active Hydrogen ]
The acrylic pressure-sensitive adhesive layer constituting the pressure-sensitive adhesive sheet of the present invention contains (a) an active hydrogen-containing acrylic polymer as a main component. (A) The active hydrogen-containing acrylic polymer (hereinafter, sometimes referred to as "polymer of (a)") has the (a1) (meth) acrylate component (hereinafter, sometimes referred to as "component (a 1)" or "main component monomer") as a main component of the monomers constituting the polymer of (a) (the mass% in the copolymer is more than 50%). Further, there may be mentioned: the component (a1) is obtained by copolymerizing a monomer (a2) which is copolymerizable with the monomer and has an active hydrogen in the molecule (hereinafter, may be referred to as "component (a 2)"). (a1) The ratio of the component (a1) is not particularly limited as long as the component (a1) is in an amount of more than 50% by mass of the copolymer and becomes the main component, but is, for example, more than 50% by mass, preferably 93.5% by mass or less of the component (a1) in 100% by mass of the copolymer.
On the other hand, the use ratio of the component (a2) is preferably 0.1 part by mass or more and 7.0 parts by mass or less of the component (a2) per 100 parts by mass of the component (a 1). (a2) If the ratio of the component (A) is less than the above range, the ratio of active hydrogen contained in the polymer (A) may be excessively decreased, and crosslinking with the crosslinking agent (B) described later may become insufficient. If the ratio of the component (a2) used exceeds the above range, the adhesive strength of the pressure-sensitive adhesive layer formed from the polymer of (a) before irradiation with radiation may be excessively increased.
Examples of the component (a1) as the main component monomer include methyl (meth) acrylate, ethyl (meth) acrylate, propyl (meth) acrylate, isopropyl (meth) acrylate, butyl (meth) acrylate, isobutyl (meth) acrylate, sec-butyl (meth) acrylate, tert-butyl (meth) acrylate, pentyl (meth) acrylate, hexyl (meth) acrylate, heptyl (meth) acrylate, octyl (meth) acrylate, isooctyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, nonyl (meth) acrylate, isononyl (meth) acrylate, decyl (meth) acrylate, isodecyl (meth) acrylate, undecyl (meth) acrylate, dodecyl (meth) acrylate, tridecyl (meth) acrylate, tetradecyl (meth) acrylate, dodecyl (meth) acrylate, and the like, Alkyl (meth) acrylates such as pentadecyl (meth) acrylate, hexadecyl (meth) acrylate, heptadecyl (meth) acrylate, and octadecyl (meth) acrylate; cycloalkyl (meth) acrylates such as cyclohexyl (meth) acrylate; aryl (meth) acrylates such as phenyl (meth) acrylate, and the like. These (meth) acrylate components may be used alone or in combination of 2 or more.
The polymer (a) constituting the present invention can be formed by copolymerizing a copolymerizable monomer having an active hydrogen in the molecule of the component (a2) among the components (a1) of the main component monomer. Examples of the copolymerizable monomer having an active hydrogen in the molecule include a monomer having an active hydrogen-containing group, that is, a monomer having a hydroxyl group (hydroxyl group-containing monomer) component and a monomer having a carboxyl group (carboxyl group-containing monomer) component.
Examples of the hydroxyl group-containing monomer include 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, 4-hydroxybutyl (meth) acrylate, 6-hydroxyhexyl (meth) acrylate, polyethylene glycol mono (meth) acrylate, polypropylene glycol mono (meth) acrylate, and glycerol mono (meth) acrylate.
Examples of the carboxyl group-containing monomer include (meth) acrylic acid, carboxyethyl (meth) acrylate, carboxypentyl (meth) acrylate, maleic anhydride, and itaconic acid. Preferred examples thereof include (meth) acrylic acid and carboxyethyl (meth) acrylate. These can be used alone or in combination of 2 or more.
In addition to the component (a2), a vinyl carboxylate, a glycidyl group-containing monomer, or the like may be copolymerized in the component (a1) of the main component monomer. Examples of the vinyl carboxylate include vinyl acetate, vinyl propionate, vinyl butyrate, and vinyl decanoate. In addition, as the glycidyl group-containing monomer, glycidyl (meth) acrylate may be mentioned. These may be used alone or in combination of 2 or more. The ratio of the monomers used may be suitably adjusted depending on the ratio of the components (a1) and (a2) used, and is preferably in the range of 0.1 to 6.5% by mass, for example, based on 100% by mass of the copolymer.
(A) The polymer of (3) can be produced by ordinary solution polymerization, bulk polymerization, emulsion polymerization, suspension polymerization, or the like. Particularly preferably produced by solution polymerization of the polymer of (a) in a solution. That is, the polymer of (a) is obtained as a solution, and the crosslinking agent of (B), (C) a monofunctional acrylic monomer having no active hydrogen, and (D) a photoinitiator, which will be described later, can be directly blended to obtain the adhesive used for forming the adhesive layer constituting the adhesive sheet of the present invention.
Examples of the organic solvent used in the copolymerization by solution polymerization include ketone-based, ester-based, alcohol-based, and aromatic organic solvents. Among them, a solvent having a boiling point of 60 to 120 ℃ and being a good solvent for general acrylic polymers such as toluene, ethyl acetate, isopropyl alcohol, benzyl cellosolve, ethyl cellosolve, acetone, methyl ethyl ketone and the like is preferably used.
Further, as the polymerization initiator used in the polymerization, for example, an azo-bis-type initiator such as α' -azobisisobutyronitrile, etc., an organic peroxide-type initiator such as benzoyl peroxide, etc. may be used alone or in combination, and in this case, a catalyst and a polymerization inhibitor may be used in combination as necessary, and the polymerization temperature and the polymerization time may be adjusted, and then the addition reaction in the functional group may be carried out, whereby the polymer (a) having a desired molecular weight may be obtained.
The weight average molecular weight (in terms of standard polystyrene as measured by GPC) of the polymer of (A) obtained by the above copolymerization is preferably in the range of 20 to 200 ten thousand, and more preferably in the range of 40 to 100 ten thousand. If the weight average molecular weight is less than 20 ten thousand, the durability of the pressure-sensitive adhesive layer may be insufficient when the pressure-sensitive adhesive layer is formed. On the other hand, if the weight average molecular weight exceeds 200 ten thousand, the compatibility with the crosslinking agent (B) described later is deteriorated, and there is a possibility that the haze value of the pressure-sensitive adhesive layer formed is increased or the durability of the pressure-sensitive adhesive layer becomes insufficient.
The glass transition temperature (Tg) of the polymer (A) is preferably from-70 ℃ to 0 ℃, more preferably from-65 ℃ to-20 ℃ from the viewpoint of achieving adhesiveness. If the Tg is too low, the cohesive force of the pressure-sensitive adhesive cannot be sufficiently exhibited, while if it is too high, the pressure-sensitive adhesive becomes too hard, the wettability to an adherend is poor, and air bubbles are likely to be mixed at the time of attachment. When the polymer of (a) is a homopolymer, the glass transition temperature (Tg) is a value measured by DSC. When the polymer (a) is a copolymer, the Tg of the polymer (a) is a theoretical value determined from the following FOX formula using the Tg of the homopolymer.
1/Tg＝W1/Tg1+W2/Tg2+···Wn/Tgn
In the above formula, Tg represents the glass transition temperature of a polymer (copolymer) of n kinds of monomer components (monomers 1 to n). W1、W2、···WnDenotes the mass fraction of the monomers (1, 2,. cndot. cndot.) relative to the total amount of the n monomer components, Tg1、Tg2、···TgnRepresents the glass transition temperature of the homopolymer of each monomer (1, 2,. cndot.
When the solid content of the polymer (A) is 15 to 45% in a solution state using the organic solvent as described above, the viscosity at 25 ℃ is preferably 1000 to 10000 mPas.
[ (B) crosslinking agent ]
The acrylic adhesive used in the present invention, which imparts the characteristics to the present invention, needs to be derived from a raw material containing both (a) the active hydrogen-containing acrylic polymer and (B) the crosslinking agent described above. By using the crosslinking agent (B) in combination, the polymer (a) can be crosslinked before irradiation with radiation, and an appropriate adhesive force and cohesive force can be imparted to the pressure-sensitive adhesive layer before irradiation with radiation. The crosslinking agent (B) includes, for example, an isocyanate compound having an isocyanate group, and preferably includes, for example, a polyisocyanate compound having 2 or more isocyanate groups in 1 molecule. By using a polyisocyanate compound as the crosslinking agent (B), the polymer of (A) can be crosslinked before radiation curing.
Examples of the polyisocyanate compound suitably used in the present invention include various polymers such as tolylene diisocyanate, diphenylmethane diisocyanate, hexamethylene diisocyanate, and isophorone diisocyanate, and biuret type, isocyanurate type, adduct type, and block type polymers thereof. Specifically, toluene diisocyanate-adduct type crosslinking agent (product name: Coronate L-45E, manufactured by Tosoh corporation), isocyanurate structure of hexamethylene diisocyanate, and the like can be given.
In addition, a crosslinking agent other than the isocyanate compound may be used, and in this case, the polymer (a) needs to have a functional group reactive with the crosslinking agent to be used. Examples of the crosslinking agent other than the isocyanate compound include an epoxy crosslinking agent, an aziridine crosslinking agent, a melamine resin crosslinking agent, a urea resin crosslinking agent, an acid anhydride compound crosslinking agent, a polyamine crosslinking agent, a carboxyl group-containing polymer crosslinking agent, a metal chelate crosslinking agent, a carbodiimide crosslinking agent, and the like, and these crosslinking agents can be appropriately selected from among them and used. Particularly preferred is a metal chelate-based crosslinking agent.
Examples of the metal chelate-based crosslinking agent include metal chelate compounds such as aluminum chelate, zirconium chelate and titanium chelate, and among them, aluminum chelate and titanium chelate are preferable. They may be used alone or in combination. Specific examples of the metal chelate-based crosslinking agent include aluminum tris (acetylacetonate) (product name: aluminum chelate A, manufactured by Kawaken Fine Chemical Company).
(B) The amount of the crosslinking agent to be used is preferably 0.5 to 8 parts by mass, more preferably 0.5 to 5 parts by mass, per 100 parts by mass of the polymer (A). When the content is within the above range, at least a part of the polymer of (a) can be crosslinked at the stage of blending, the adhesive strength of the pressure-sensitive adhesive layer before irradiation with radiation can be made appropriate, and a pressure-sensitive adhesive layer having excellent aggregation power can be formed, and therefore, the content is preferable.
[ (C) monofunctional acrylic monomer having no active Hydrogen ]
The acrylic adhesive used in the present invention, which imparts the characteristics to the present invention, needs to be derived from a raw material containing both (a) the active hydrogen-containing acrylic polymer and (B) the crosslinking agent described above, and (C) a monofunctional acrylic monomer having no active hydrogen (hereinafter, sometimes simply referred to as a monomer of "(C)). By containing the monomer of (C) and the photoinitiator of (D) described later in the constituent components of the pressure-sensitive adhesive, the reaction of the monomer of (C) is initiated by irradiation with radiation, as a result of which the adhesive strength of the pressure-sensitive adhesive layer after irradiation with radiation is increased, and the adhesive strength of the pressure-sensitive adhesive layer after irradiation with radiation becomes 5 times or more the adhesive strength of the pressure-sensitive adhesive layer before irradiation with radiation.
Examples of the monomer (C) include phenol ethylene oxide-modified acrylate, nonylphenol ethylene oxide-modified acrylate, orthophenylphenol ethylene oxide-modified acrylate, p-cumylphenol ethylene oxide-modified acrylate, and nonylphenol propylene oxide-modified acrylate.
(C) The monomer (2) preferably has a flash point of 100 ℃ or higher. If the flash point is low, the coating evaporates during drying, and the target performance may not be exhibited. The monomer (C) preferably has a viscosity of 200 mPas or less at 25 ℃.
The homopolymer (homopolymer) of the monomer (C) is preferably a homopolymer having a glass transition point (Tg) of-30 to 50 ℃. If the Tg is less than-30 ℃, the cohesive force of the adhesive layer after irradiation with radiation may be insufficient. On the other hand, if Tg is higher than 50 ℃, the adhesive strength of the pressure-sensitive adhesive layer after irradiation with radiation does not become large, and there is a possibility that Tg does not become 5 times or more the adhesive strength before irradiation with radiation as defined in the present invention.
Specific examples of the monomer (C) include Aronix M-101A (trade name, Tg-8 ℃ C.), Aronix M-102 (trade name, Tg-18 ℃ C.), Aronix M-106 (trade name, Tg-30 ℃ C.), Aronix M-110 (trade name, Tg-35 ℃ C.), Aronix M-111 (trade name, Tg-17 ℃ C.), and Aronix M-113 (trade name, Tg-20 ℃ C.), manufactured by Toyo Seiki Kabushiki Kaisha.
The amount of the monomer (C) is preferably 10 to 120 parts by mass, more preferably 30 to 90 parts by mass, and still more preferably 50 to 70 parts by mass, based on 100 parts by mass of the polymer (A). According to the studies of the present inventors, the monomer (C) acts as a so-called plasticizer for the polymer (a) before irradiation with radiation, and has an effect of reducing the adhesive strength of the pressure-sensitive adhesive layer. On the other hand, polymerization proceeds after irradiation with radiation, and the polymer of (a) reacts (crosslinks) to act as an acrylic polymer component to improve the cohesive force, and therefore, there is an effect of increasing the adhesive force of the pressure-sensitive adhesive layer. Therefore, if the amount of the monomer (C) used is less than 10 parts by mass, the reaction ratio between the polymer (a) and the crosslinking agent (B) is relatively increased, so that the adhesive strength before irradiation with radiation becomes large, and even if the adhesive strength is improved by subsequent irradiation with radiation, there is no fear that the adhesive strength before irradiation with radiation is 5 times or more as high as the adhesive strength before irradiation with radiation as defined in the present invention. On the other hand, if the amount of the monomer (C) used is more than 120 parts by mass, the cohesive force before irradiation with radiation may be insufficient, and the holding power of the adhesive may be insufficient.
In the present invention, a polyfunctional acrylic monomer may be used in an amount of 2 parts by mass or less based on 100 parts by mass of the polymer (a) together with the monofunctional acrylic monomer (C) having no active hydrogen. Examples of the polyfunctional acrylic monomer include trimethylolpropane triacrylate and the like. Specifically, Aronix M-309 (trade name) manufactured by Toyo Synthesis Co. According to the studies of the present inventors, since the use of a polyfunctional acrylic monomer has an effect of reducing the adhesive force after irradiation with radiation, the adhesive force after irradiation with radiation can be adjusted to a desired level by using the polyfunctional acrylic monomer in the above range.
[ (D) photoinitiator ]
The acrylic pressure-sensitive adhesive used in the present invention and characterized by the present invention is composed of the above-mentioned (a) acrylic polymer containing active hydrogen, (B) crosslinking agent, (C) monofunctional acrylic monomer having no active hydrogen, and (D) photoinitiator. By containing (D) the photoinitiator, the polymerization and curing (crosslinking) of the polymer (a) and the monomer (C) can be efficiently performed when the pressure-sensitive adhesive layer is irradiated with radiation.
Examples of the photoinitiator (D) include general ultraviolet polymerization initiators listed below, for example, in addition to benzoin alkyl ether initiators, benzophenone initiators, aromatic ketone initiators, aromatic ketal initiators, thioxanthone initiators, benzil initiators, and benzoin initiators, α -ketol compounds (, aromatic sulfonyl chloride compounds, photoactive oxime compounds, camphorquinone, haloketone, acyl phosphine oxide, and acyl phosphonate), which may be used alone or in combination of 2 or more.
Specifically, α -hydroxyacetophenone oligomer, namely, ESACURE KIP 150 (trade name, manufactured by Lamberti Co., Ltd.) can be mentioned.
The amount of the photoinitiator (D) to be used is suitably selected from the range of preferably 0.5 to 30 parts by mass, more preferably 1 to 20 parts by mass, based on 100 parts by mass of the polymer (A).
The acrylic pressure-sensitive adhesive layer constituting the present invention may contain various additives in addition to the above-mentioned substances, in the range not to impair the effects of the present invention, depending on the characteristics required for the purpose of further adjusting the adhesive strength and the like. For example, it may contain a terpene-based, terpene-phenol-based, coumarone-indene-based, styrene-based, rosin-based, xylene-based, phenol-based, or petroleum-based tackifier resin, an antioxidant, an ultraviolet absorber, a filler, a pigment, and the like.
The acrylic pressure-sensitive adhesive layer formed of the acrylic pressure-sensitive adhesive used in the present invention and having the above-described configuration and having the characteristics of the present invention is adjusted to have a pressure-sensitive adhesive strength of 1N/25mm or less before irradiation with radiation and to have a pressure-sensitive adhesive strength of such a degree that the pressure-sensitive adhesive sheet can be reattached after being adhered to an adherend. The acrylic pressure-sensitive adhesive layer is characterized in that the adhesive strength of the acrylic pressure-sensitive adhesive layer is increased to 5N/25mm or more by irradiation with radiation, and the adhesive strength after irradiation with radiation is 5 times or more the adhesive strength before irradiation with radiation. For example, in the case of the adhesive force to the polyimide film, the adhesive force before irradiation with radiation is preferably 0.1 to 1N/25mm, and the adhesive force after irradiation with radiation is preferably 5 to 20N/25 mm.
[ adhesive sheet ]
The pressure-sensitive adhesive sheet of the present invention is characterized by having the acrylic pressure-sensitive adhesive layer whose adhesive strength is increased by irradiation with radiation as described above on a substrate. Examples of the substrate constituting the pressure-sensitive adhesive sheet of the present invention include PET films and various functional materials in sheet form.
The adhesive sheet of the present invention can be easily produced as follows, for example. First, a pressure-sensitive adhesive composition containing at least the polymer (a), the crosslinking agent (B), the monomer (C), and the photoinitiator (D) is applied to one side or both sides of the substrate by a commonly used application device, for example, a roll coater. Next, the coating layer is dried to form an adhesive layer on the surface of the base material. The drying may be carried out by heating, or may be carried out by crosslinking by heating to effectively cure the adhesive layer, whereby the adhesive layer having the adhesive force defined in the present invention can be formed. As another method, the adhesive composition may be applied to a release film such as a polyethylene terephthalate film (PET film) having a surface coated with a release agent such as a silicone resin, dried to form an adhesive layer, and then a sheet-like functional material such as a polarizing plate as a base material is attached to the adhesive layer to form an adhesive sheet.
The coating amount in forming the pressure-sensitive adhesive layer is preferably such that the thickness of the dried pressure-sensitive adhesive layer is about 10 to 50 μm, more preferably 10 to 30 μm. When the thickness of the pressure-sensitive adhesive layer is within the above range, the reaction (curing) occurs by irradiation with radiation, and the pressure-sensitive adhesive layer has an adhesive force after irradiation with radiation that is 5 times or more the adhesive force before irradiation with radiation. The adhesive sheet of the present invention having the adhesive layer having the above characteristics can be used for various applications by using various sheet-like functional materials as a substrate. For example, an adhesive sheet or the like having an adhesive layer having the following useful characteristics can be provided: the pressure-sensitive adhesive sheet can be accurately positioned and arranged, and thereafter, the radiation irradiation can be performed to the pressure-sensitive adhesive layer of the necessary portion, whereby the unnecessary portion can be removed from the accurately arranged pressure-sensitive adhesive sheet and only the necessary portion can be left on the adherend.
Examples
The present invention will be described in more detail below with reference to production examples, and comparative examples. In the present specification, "part(s)" and "%" are based on mass.
Production example 1: (A) production of acrylic Polymer containing active Hydrogen ]
After nitrogen gas was sealed in a reaction apparatus equipped with a stirrer, a thermometer, a reflux condenser and a nitrogen gas introduction tube, 90 parts of 2-ethylhexyl acrylate (2EHA) as the component (a1), 10 parts of Butyl Acrylate (BA), 3 parts of 2-hydroxyethyl acrylate (2HEA) as the component (a2) and 0.1 part of azobisisobutyronitrile as a polymerization initiator were charged together with 120 parts of ethyl acetate. Then, the reaction mixture was stirred and reacted at 75 ℃ for 10 hours in a nitrogen stream. After the completion of the reaction, the reaction mixture was diluted with ethyl acetate to obtain an acrylic polymer solution A-1 having a solid content of 42.0% and a weight-average molecular weight of 54 ten thousand. The composition and physical properties are shown in Table 1. The amounts of the monomers in table 1 were normalized so that the total amount of the monomers became 100 parts.
Production examples 2 to 14: (A) production of acrylic Polymer containing active Hydrogen ]
Acrylic polymer solutions A-2 to A-14 were obtained in the same manner as in production example 1, except that the monomer components and the blending amounts in production example 1 were changed to those shown in Table 1. The physical properties are shown in tables 1-1 and 1-2.
Tables 1 to 1: composition and physical properties of polymer [ unit: portions ]
Tables 1 to 2: composition and physical properties of polymer [ unit: portions ]
The abbreviations in table 1 represent the following compounds.
2 EHA: 2-ethylhexyl acrylate
BA: acrylic acid butyl ester
MA: acrylic acid methyl ester
VAc: vinyl acetate (VAA)
AAc: acrylic acid
2 HEA: 2-Hydroxyethyl acrylate
In table 1, the value of the weight average molecular weight (Mw) is a polystyrene-equivalent molecular weight measured by gpc (gel registration chromatography) method. Specifically, a coating film obtained by drying the copolymer at room temperature was dissolved in tetrahydrofuran, and the solution was measured by high performance liquid chromatography [ LC-10ADvp (trade name), column KF-G + KF-806X 2, manufactured by Shimadzu corporation ], to determine a weight average molecular weight in terms of polystyrene. In Table 1, the viscosity (mPas/25 ℃ C.) was measured in accordance with JIS K6833-1: 2008, a value measured with a BH type rotational viscometer (BHII viscometer, manufactured by Toyobo industries Co., Ltd.) at a rotation speed of 10rpm and a temperature of 25 ℃.
Example 1: preparation of adhesive composition constituting the invention
To 1100 parts (solid content 42 parts) of the polymer solution a to 1100 parts (C) obtained above, 25 parts of Aronix M-111 (trade name, product of tokyo Chemical corporation, Tg 17 ℃) as a monofunctional acrylic monomer having no active hydrogen, and 2.5 parts of ESACURE KIP 150 (trade name, product of Lamberti) as an α -hydroxyacetophenone oligomer as a photoinitiator (D) were added, and after stirring, 1.5 parts of a crosslinking agent a (Takenate D-170N, product of samboda Chemical corporation) as a crosslinking agent (B), and 1.0 part (solid content 0.05 part) of a crosslinking agent C (5 mass% dissolved product of aluminum chelate a, product of Kawaken Fine Chemical Company) as a crosslinking agent (B) were added to the polymer solution a to 1100 parts (solid content 42 parts) to obtain a pressure-sensitive adhesive composition of example 1 used in the present invention.
[ examples 2 to 18: preparation of adhesive composition constituting the invention
Compositions used in the present invention were obtained in the same manner as in example 1 except that the crosslinking agent a in example 1 was replaced with the crosslinking agents b and c, and the components and the blending amounts were replaced with those described in tables 2-1 and 2-2.
Table 2-1: compounding composition of examples [ unit: portions ]
The ratio (% of crosslinking agent to solid component of (A) is set in the range of
Tables 2 to 2: compounding composition of examples [ unit: portions ]
The ratio (% of crosslinking agent to solid component of (A) is set in the range of
Comparative examples 1 to 10: preparation of adhesive composition constituting comparative example of the present invention
Adhesive compositions for comparison were obtained in the same manner as in example 1, except that the components and the blending amounts in example 1 were changed to those shown in tables 2 to 3.
Tables 2 to 3: compounding composition of comparative example [ unit: portions ]
The ratio (% of crosslinking agent to solid component of (A) is set in the range of
The abbreviations in table 2 represent the following compounds, respectively.
M-111: aronix M-111 (trade name, Toyo Synthesis Co., Ltd.)Prepared), nonylphenol EO modification of the formula
Acrylic esters
M-113: aronix M-113 (trade name, manufactured by Toyo Synthesis Co., Ltd.) and nonylphenol EO-modified
Acrylic esters
M-101A: aronix M-101A (trade name, manufactured by Toyo Seisaku Co., Ltd.) and a phenol EO-modified (n ≈ 2) acrylate of the following formula
M-309: aronix M-309 (trade name, manufactured by Toyo Seisaku Co., Ltd.), trimethylolpropane triacrylate
M-600A: epoxy ester M-600A (trade name, product of Kyoeisha chemical Co., Ltd.), 2-hydroxy-3-phenoxypropyl acrylate
HOA-MS: HOA-MS (N) (trade name, product of Kyoeisha chemical Co., Ltd.), 2-acryloyloxyethyl succinate
Crosslinker a: isocyanurate structure of hexamethylene diisocyanate (trade name: Takenate D-170N, product of Mitsui Kogyo chemical Co., Ltd., solid content: 100% by mass)
Crosslinker b: TDI isocyanate adduct (trade name: Coronate L-45E, manufactured by Tosoh corporation, solid content: 45% by mass)
Crosslinker c: a5% by mass solution of aluminum tris (acetylacetonate) (trade name of aluminum tris (acetylacetonate): aluminum chelate A, manufactured by Kawaken Fine Chemical Company)
[ evaluation ]
Using each of the pressure-sensitive adhesive compositions prepared in the above examples and comparative examples, a pressure-sensitive adhesive layer was formed on a PET film by the following method to prepare a pressure-sensitive adhesive sheet. That is, the adhesive compositions of examples and comparative examples were applied to a silicone resin-coated PET film (releasable substrate), and then dried at 100 ℃ for 1 minute to remove the solvent, thereby forming an adhesive layer having a thickness of 25 μm. A PET film having a thickness of 75 μm was attached to the surface on which the pressure-sensitive adhesive layer was formed, and then the film was aged at 45 ℃ for 3 days to prepare a sample for evaluation. Then, using the prepared evaluation sample of the adhesive sheet, each test described later was performed, and evaluation was performed based on each evaluation criterion. The results are summarized in Table 3.
1. Adhesion (on polyimide film) test
(adhesive force before radiation irradiation)
The above-prepared evaluation sample was cut into a size of 80mm × 25mm, and the release film was peeled off at 23 ℃ under 50% RH atmosphere, and the film was reciprocatingly stuck to a polyimide film having a thickness of 26 μm by a 19.6N roller 1 to prepare a test piece. Then, 20 minutes after the pasting, the film was stretched at a rate of 300 mm/minute in the 180 ° direction, and the peel strength was measured. The measured values obtained are shown in table 3. The unit of the adhesive force in Table 3 is N/25 mm.
(adhesive force after radiation irradiation)
Test pieces were produced in the same manner as described above. Then, the peel strength was measured in the same manner as described above except that the surface of the PET film was irradiated with ultraviolet rays under the following conditions. The measured values obtained are shown in table 3. The ultraviolet curing conditions were as follows: using a metal halide lamp at an illuminance of 300mW/cm2And an accumulated light amount 990mJ/cm2The irradiation is carried out under the conditions of (1). The illuminance and light meter used was "UV POWER PUCK" manufactured by EIT.
2. Retention force
The holding force was measured by measuring the above-prepared test pieces for evaluation at 40 ℃ under a load of 1kg according to JIS Z0237 and measuring the time until the test pieces fell. Then, the measured time was used to evaluate the aggregating force on the following criteria. The evaluation results are shown in table 3. The adhesion strength (on the polyimide film) was evaluated in the same manner as described above with respect to the retention strength after irradiation with radiation.
< evaluation Standard >
◎ no drop and no offset in 5 hours
○ no drop and offset in 5 hours
△ falling within 1 to 5 hours
X: fall within 1 hour
3. Adhesion test of base Material
Specifically, in the adhesion (on the polyimide film) test, the case where the adhesive layer was not transferred from the PET film to the polyimide film when the adhesive layer was peeled from the polyimide film was referred to as "○", and the case where the adhesive layer was transferred from the PET film to the polyimide film was referred to as "x", and the adhesion to the substrate was evaluated, and in the same manner as in the adhesion (on the polyimide film) test, the irradiation with radiation was performed, and the adhesion to the substrate after the irradiation with radiation was also evaluated, the results are summarized in table 3.
Table 3-1: evaluation results-1
Tables 3-2: evaluation results-2
Tables 3 to 3: evaluation results-3
As shown in tables 3-1 to 3-3, the adhesive compositions of the examples all had an adhesive force of 1N/25mm or less before irradiation with radiation (ultraviolet rays), an adhesive force of 5N/25mm or more after irradiation with radiation (ultraviolet rays), and an adhesive force after irradiation with radiation of 5 times or more the adhesive force before irradiation with radiation. From the evaluation results of the pressure-sensitive adhesive compositions of examples 15 to 18, it was confirmed that if the amount of the monofunctional acrylic monomer having no active hydrogen (C) used is increased, the adhesive strength before irradiation with radiation is decreased, and the adhesive strength after irradiation with radiation is also decreased.
On the other hand, in comparative examples 4 to 7, the adhesiveness to the substrate and the focusing power were evaluated well, but the adhesive strength after irradiation with radiation (ultraviolet ray) was not 5N/25mm or more, and the target physical properties were not obtained. The reason for this is considered to be that the amount of the polyfunctional acrylic monomer used is larger than in the examples. In comparative examples 7 and 8, in which the amount of the polyfunctional acrylic monomer used was large, the adhesive strength before irradiation with radiation (ultraviolet rays) was high.
In addition, in comparative examples 9 and 10 in which a monofunctional acrylic monomer having active hydrogen was used instead of (C) a monofunctional acrylic monomer having no active hydrogen, the focusing power before irradiation with radiation (ultraviolet light) was low, and the adhesion to the substrate was also poor.
Industrial applicability
According to the present invention, there can be provided: since a psa sheet (pressure-sensitive psa sheet) having a psa layer with a property of increasing adhesive strength by irradiation with radiation has not been able to be used in a variety of applications, it is expected to be useful.
Claims (5)
1. A pressure-sensitive adhesive sheet comprising a substrate and an acrylic pressure-sensitive adhesive layer having an adhesive strength increased by irradiation with radiation,
the acrylic adhesive layer is formed from an acrylic adhesive derived from a starting material comprising: (A) an active hydrogen-containing acrylic polymer, (B) a crosslinking agent, (C) a monofunctional acrylic monomer having no active hydrogen, and (D) a photoinitiator, wherein the use of a polyfunctional acrylic monomer in an amount exceeding 2 parts by mass relative to 100 parts by mass of the (A) polymer is excluded,
the adhesive force of the acrylic adhesive layer is constituted as follows: the adhesive force before irradiation with radiation is 1N/25mm or less, the adhesive force after irradiation with radiation is 5N/25mm or more, and the adhesive force after irradiation with radiation is 5 times or more the adhesive force before irradiation with radiation.
2. The adhesive sheet according to claim 1, wherein when the adhesive force of the acrylic adhesive layer to a polyimide film is an adhesive force, the adhesive force before irradiation with radiation is 0.1 to 1N/25mm, and the adhesive force after irradiation with radiation is 5 to 20N/25 mm.
3. The adhesive sheet according to claim 1 or 2, wherein the (A) active hydrogen-containing acrylic polymer has a glass transition temperature (Tg) of-70 ℃ to 0 ℃ and active hydrogen is an active hydrogen-containing group of a carboxyl group and/or a hydroxyl group,
the (C) monofunctional acrylic monomer having no active hydrogen is an alkylene oxide-modified acrylate.
4. The adhesive sheet according to any one of claims 1 to 3, wherein the active hydrogen-containing acrylic polymer (A) is a copolymer formed from a raw material monomer in which a monomer (a2) that is copolymerizable and has active hydrogen in the molecule is blended in a range of 0.1 parts by mass or more and 7.0 parts by mass or less with respect to 100 parts by mass of a (meth) acrylate monomer (a 1).
5. The adhesive sheet according to any one of claims 1 to 4, wherein the amount of the monofunctional acrylic monomer having no active hydrogen (C) used is 10 parts by mass or more and 100 parts by mass or less based on 100 parts by mass of the acrylic polymer containing active hydrogen (A).
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| JP2017190066A JP6566324B2 (en) | 2017-09-29 | 2017-09-29 | Adhesive sheet |
| JP2017-190066 | 2017-09-29 | ||
| PCT/JP2018/035879 WO2019065817A1 (en) | 2017-09-29 | 2018-09-27 | Adhesive sheet |
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| CN111133070B CN111133070B (en) | 2022-03-29 |
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| KR (1) | KR102470279B1 (en) |
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| CN115109527A (en) * | 2021-03-23 | 2022-09-27 | 三星Sdi株式会社 | Adhesive film, optical member including the same, and optical display device including the same |
| CN115109536A (en) * | 2021-03-23 | 2022-09-27 | 三星Sdi株式会社 | Adhesive film, optical member including the same, and optical display device including the same |
| CN115109525A (en) * | 2021-03-23 | 2022-09-27 | 三星Sdi株式会社 | Adhesive film, optical member including the same, and optical display device including the same |
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| JP7077673B2 (en) * | 2018-03-06 | 2022-05-31 | 東亞合成株式会社 | Active energy ray-curable pressure-sensitive adhesive composition |
| JP7275463B2 (en) * | 2019-03-27 | 2023-05-18 | 日本カーバイド工業株式会社 | Adhesive composition and adhesive sheet |
| JP7275462B2 (en) * | 2019-03-27 | 2023-05-18 | 日本カーバイド工業株式会社 | Adhesive composition and adhesive sheet |
| KR102635555B1 (en) * | 2021-06-18 | 2024-02-08 | (주)이녹스첨단소재 | Adhesive sheet for display and display comprising the same |
| KR20240141455A (en) * | 2023-03-20 | 2024-09-27 | 삼성에스디아이 주식회사 | Adhesive film, optical member comprising the same and optical display apparatus comprising the same |
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| JP2019065113A (en) | 2019-04-25 |
| CN111133070B (en) | 2022-03-29 |
| KR20200062255A (en) | 2020-06-03 |
| JP6566324B2 (en) | 2019-08-28 |
| WO2019065817A1 (en) | 2019-04-04 |
| KR102470279B1 (en) | 2022-11-25 |
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