CN111093802B - 高反应性气体的吸附剂辅助稳定化 - Google Patents

高反应性气体的吸附剂辅助稳定化 Download PDF

Info

Publication number
CN111093802B
CN111093802B CN201880060852.6A CN201880060852A CN111093802B CN 111093802 B CN111093802 B CN 111093802B CN 201880060852 A CN201880060852 A CN 201880060852A CN 111093802 B CN111093802 B CN 111093802B
Authority
CN
China
Prior art keywords
highly reactive
reactive gas
gas
mof
adsorbing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201880060852.6A
Other languages
English (en)
Chinese (zh)
Other versions
CN111093802A (zh
Inventor
格伦·M·汤姆
保罗·卫-曼·西乌
琼斯·阿诺
奥马尔·K·法尔哈
罗斯·韦尔普洛格
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Numat Technologies Inc
Original Assignee
Numat Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Numat Technologies Inc filed Critical Numat Technologies Inc
Publication of CN111093802A publication Critical patent/CN111093802A/zh
Application granted granted Critical
Publication of CN111093802B publication Critical patent/CN111093802B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/0407—Constructional details of adsorbing systems
    • B01D53/0415—Beds in cartridges
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
    • B01J20/226—Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078—Pore diameter
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C11/00—Use of gas-solvents or gas-sorbents in vessels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/102—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B01D2253/204—Metal organic frameworks (MOF's)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/25—Coated, impregnated or composite adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/308—Pore size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/20—Halogens or halogen compounds
    • B01D2257/204—Inorganic halogen compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/40—Nitrogen compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/55—Compounds of silicon, phosphorus, germanium or arsenic
    • B01D2257/553—Compounds comprising hydrogen, e.g. silanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/93—Toxic compounds not provided for in groups B01D2257/00 - B01D2257/708
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage

Landscapes

  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Separation Of Gases By Adsorption (AREA)
CN201880060852.6A 2017-09-25 2018-09-24 高反应性气体的吸附剂辅助稳定化 Active CN111093802B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201762562718P 2017-09-25 2017-09-25
US62/562,718 2017-09-25
PCT/US2018/052404 WO2019060818A2 (en) 2017-09-25 2018-09-24 HIGHLY REACTIVE GAS STABILIZATION ASSISTED BY ADSORBENT

Publications (2)

Publication Number Publication Date
CN111093802A CN111093802A (zh) 2020-05-01
CN111093802B true CN111093802B (zh) 2021-08-17

Family

ID=65808489

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201880060852.6A Active CN111093802B (zh) 2017-09-25 2018-09-24 高反应性气体的吸附剂辅助稳定化

Country Status (6)

Country Link
US (2) US10940426B2 (https=)
JP (1) JP7299879B2 (https=)
KR (1) KR102613700B1 (https=)
CN (1) CN111093802B (https=)
TW (1) TWI854961B (https=)
WO (1) WO2019060818A2 (https=)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7589338B2 (ja) * 2020-08-24 2024-11-25 カウンシル オブ サイエンティフィック アンド インダストリアル リサーチ 自動ジアゾメタン作製装置、反応装置及び固相クエンチャ
WO2022087045A1 (en) * 2020-10-23 2022-04-28 Entegris, Inc. Adsorbent-type storage and delivery vessels with high purity delivery of gas, and related methods
TWI832684B (zh) * 2022-01-27 2024-02-11 美商恩特葛瑞斯股份有限公司 用於儲存分子二硼烷的系統及方法
KR102870093B1 (ko) * 2023-01-26 2025-10-13 숙명여자대학교산학협력단 금속유기골격체의 반응성 저감 방법 및 반응성이 저감된 금속유기골격체

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5993766A (en) * 1996-05-20 1999-11-30 Advanced Technology Materials, Inc. Gas source and dispensing system
WO2002088148A1 (en) * 2001-04-30 2002-11-07 The Regents Of The University Of Michigan Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein,with application for gas storage
CN1719092A (zh) * 2004-07-08 2006-01-11 气体产品与化学公司 保持在液体介质中的气体的储存和输送系统
CN1769760A (zh) * 2004-10-15 2006-05-10 气体产品与化学公司 用于储存和运输路易斯酸性气体的含路易斯碱性反应性化合物的液体介质
CN104549164A (zh) * 2014-12-19 2015-04-29 浙江大学 用于甲烷和乙炔吸附和存储的微孔金属有机框架材料及其制备方法
CN105813711A (zh) * 2013-08-05 2016-07-27 纽麦特科技公司 用于电子气体储存的金属有机骨架材料
WO2017004682A1 (en) * 2015-07-08 2017-01-12 Commonwealth Scientific And Industrial Research Organisation Composition and system for gas storage

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6083298A (en) * 1994-10-13 2000-07-04 Advanced Technology Materials, Inc. Process for fabricating a sorbent-based gas storage and dispensing system, utilizing sorbent material pretreatment
JP3021412B2 (ja) * 1997-02-17 2000-03-15 高千穂化学工業株式会社 気体の貯蔵・送出方法及び気体の貯蔵・送出装置
JP2000210559A (ja) * 1999-01-22 2000-08-02 Osaka Gas Co Ltd ガス貯蔵性有機金属錯体、その製造方法およびガス貯蔵装置
US7404845B2 (en) 2004-09-23 2008-07-29 Air Products And Chemicals, Inc. Ionic liquid based mixtures for gas storage and delivery
US8633331B2 (en) * 2009-09-10 2014-01-21 Research Foundation Of The City University Of New York Nanocomposite materials comprising metal-organic-framework units and methods of using same
US9427722B2 (en) 2013-10-16 2016-08-30 Numat Technologies, Inc. Metal-organic frameworks for oxygen storage and air separation
US10272279B2 (en) * 2013-12-31 2019-04-30 Northwestern University Metal organic frameworks for the catalytic detoxification of chemical warfare nerve agents
US9925516B2 (en) 2014-12-02 2018-03-27 Numat Technologies, Inc. Formation of high surface area metal-organic frameworks
KR102301071B1 (ko) 2014-12-04 2021-09-14 누맷 테크놀로지스, 인코포레이티드 전자 가스의 저감 및 정제 및 탄화수소 스트림으로부터의 수은제거를 위한 다공성 중합체

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5993766A (en) * 1996-05-20 1999-11-30 Advanced Technology Materials, Inc. Gas source and dispensing system
WO2002088148A1 (en) * 2001-04-30 2002-11-07 The Regents Of The University Of Michigan Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein,with application for gas storage
CN1719092A (zh) * 2004-07-08 2006-01-11 气体产品与化学公司 保持在液体介质中的气体的储存和输送系统
CN1769760A (zh) * 2004-10-15 2006-05-10 气体产品与化学公司 用于储存和运输路易斯酸性气体的含路易斯碱性反应性化合物的液体介质
CN105813711A (zh) * 2013-08-05 2016-07-27 纽麦特科技公司 用于电子气体储存的金属有机骨架材料
CN104549164A (zh) * 2014-12-19 2015-04-29 浙江大学 用于甲烷和乙炔吸附和存储的微孔金属有机框架材料及其制备方法
WO2017004682A1 (en) * 2015-07-08 2017-01-12 Commonwealth Scientific And Industrial Research Organisation Composition and system for gas storage

Also Published As

Publication number Publication date
CN111093802A (zh) 2020-05-01
US10940426B2 (en) 2021-03-09
JP2020534998A (ja) 2020-12-03
KR102613700B1 (ko) 2023-12-14
JP7299879B2 (ja) 2023-06-28
TW201929942A (zh) 2019-08-01
US20190091620A1 (en) 2019-03-28
WO2019060818A3 (en) 2019-04-25
TWI854961B (zh) 2024-09-11
KR20200049794A (ko) 2020-05-08
US20210106940A1 (en) 2021-04-15
WO2019060818A2 (en) 2019-03-28

Similar Documents

Publication Publication Date Title
CN111093802B (zh) 高反应性气体的吸附剂辅助稳定化
EP3030336B1 (en) Metal organic frameworks for electronic gas storage
US20250216034A1 (en) Adsorbent-type storage and delivery vessels with high purity delivery of gas, and related methods
JPH11264500A (ja) 気体化合物の貯蔵と送出のシステム
JP2020534998A5 (https=)
JP3440232B2 (ja) 塩基性ガスの供給方法
TWI859586B (zh) 具有高純度輸送氣體之吸附劑型儲運容器及相關方法
WO2014088797A1 (en) Diborane storage and blending

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant